CN113801549A - Environment-friendly water-based alkyd resin coating and preparation method thereof - Google Patents
Environment-friendly water-based alkyd resin coating and preparation method thereof Download PDFInfo
- Publication number
- CN113801549A CN113801549A CN202110897164.9A CN202110897164A CN113801549A CN 113801549 A CN113801549 A CN 113801549A CN 202110897164 A CN202110897164 A CN 202110897164A CN 113801549 A CN113801549 A CN 113801549A
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- China
- Prior art keywords
- waterborne
- alkyd resin
- modified
- dispersion machine
- environment
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920000180 alkyd Polymers 0.000 title claims abstract description 63
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 20
- 230000000996 additive effect Effects 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- -1 corrosion resistance Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims description 34
- 238000002156 mixing Methods 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229920006243 acrylic copolymer Polymers 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 3
- 229960002887 deanol Drugs 0.000 claims description 3
- 239000012972 dimethylethanolamine Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000002932 luster Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000001514 detection method Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses an environment-friendly water-based alkyd resin coating and a preparation method thereof, wherein the coating comprises the following components: 40-60% of waterborne alkyd resin, 5-12% of waterborne modified alkyd resin, 2-9% of environment-friendly pigment, 8-30% of deionized water and 0.04-1.2% of additive. The invention solves the problem that the VOC content in the traditional oily alkyd paint exceeds the standard, improves the indexes of the paint such as corrosion resistance, adhesive force, weather resistance, luster and the like, and brings great economic benefit and social benefit while reducing environmental pollution.
Description
Technical Field
The invention relates to the technical field of paint, in particular to an environment-friendly water-based alkyd resin coating and a preparation method thereof.
Background
The alkyd resin occupies a great proportion in the field of paint, and has the advantages of cheap and easily available raw materials, good paint film adhesion, brightness, fullness, good pigment wettability and the like.
Most of the traditional alkyd resin coatings are solvent-based, contain a large amount of organic solvents, and the organic solvents are volatilized into the atmosphere in the construction process, so that the alkyd resin coatings have serious influence on human bodies and ecological environment. Along with the improvement of environmental awareness of people and the coming of various regulations restricting VOC and HAPS in various countries, the aquosity of the alkyd resin has great significance.
Disclosure of Invention
The invention aims to solve the defects in the prior art, provides an environment-friendly water-based alkyd resin coating and a preparation method thereof, solves the problem that the VOC content in the traditional oily alkyd coating exceeds the standard, improves the indexes of the coating such as corrosion resistance, adhesive force, weather resistance and luster, and brings great economic and social benefits while reducing environmental pollution.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides an environment-friendly water-based alkyd resin coating, which comprises the following components: 40-60% of waterborne alkyd resin, 5-12% of waterborne modified alkyd resin, 2-9% of environment-friendly pigment, 8-30% of deionized water and 0.04-1.2% of additive.
Further, the content ratio of the waterborne alkyd resin to the waterborne modified alkyd resin is 5: 1-8: 1.
further, the waterborne alkyd resin comprises one or more of a waterborne alkyd resin, a waterborne modified alkyd resin, a styrene-acrylic copolymer, a waterborne additive type resin emulsion and a waterborne acrylic modified resin.
Further, the waterborne modified alkyd resin comprises one or more of a waterborne alkyd resin, a waterborne modified alkyd resin, a styrene-acrylic copolymer, a waterborne additive type resin emulsion and a waterborne acrylic modified resin.
Further, the environment-friendly pigment comprises one or more of film-coated rutile type titanium dioxide, talcum powder, calcium carbonate, organic yellow, titanium cyan and organic red.
Further, the deionized water is the pure water from which impurities in the form of ions have been removed.
Further, the additive comprises one or more of dimethylethanolamine, polyether modified polysiloxane, pigment affinity group-containing high-molecular copolymer, acrylic copolymer solution, alkanolamine of multifunctional copolymer, ionic acrylic acid solution, organic modified sheet silicate, blocked p-toluenesulfonic acid, polyether modified silicone, nano-alumina dispersion and cerium oxide nanoparticle dispersion.
The invention also provides a preparation method of the environment-friendly water-based alkyd resin coating, which comprises the following steps:
s1, adding the water-based alkyd resin and the water-based modified alkyd resin into a dispersing machine according to the mass fraction. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S2, continuously adding the additives and the deionized water which do not exceed the mass fraction into the dispersing machine. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S3, continuously adding the environment-friendly pigment in the mass fraction into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
s4, grinding the mixture obtained in the step S3 in a grinder, wherein the grinding times are 2-5;
s5, adding the rest deionized water into the mixture obtained in the S4, and putting the mixture into a dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S6, adding the rest additives into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min.
Compared with the prior art, the invention has the beneficial effects that: the problem that the VOC content in the traditional oily alkyd paint exceeds the standard is solved, the indexes of the paint such as corrosion resistance, adhesive force, weather resistance, luster and the like are improved, and great economic benefit and social benefit are brought while the environmental pollution is reduced.
Detailed Description
The invention will be described in more detail below, and various embodiments can be combined with each other to constitute other embodiments not shown in the following description.
In the description of the present invention, it should be noted that, for the terms of orientation, there are terms of orientation such as "central", "lateral", "longitudinal", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise" and the like, which are used for convenience of description and simplification of the description, and do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and should not be construed as limiting the specific scope of protection of the present invention.
Furthermore, if the terms "first" and "second" are used for descriptive purposes only, they are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features. Thus, a definition of "a first" or "a second" feature may explicitly or implicitly include one or more of the features, and in the description of the invention, "a number" means two or more unless explicitly defined otherwise.
In the present invention, unless otherwise expressly specified or limited, the terms "assembled", "connected", and "connected" are to be construed broadly, e.g., as meaning fixedly connected, detachably connected, or integrally connected; or may be a mechanical connection; the two elements can be directly connected or connected through an intermediate medium, and the two elements can be communicated with each other. The specific meanings of the above terms in the present invention can be understood by those of ordinary skill in the art according to specific situations.
An environment-friendly water-based alkyd resin coating comprises the following components: 40-60% of waterborne alkyd resin, 5-12% of waterborne modified alkyd resin, 2-9% of environment-friendly pigment, 8-30% of deionized water and 0.04-1.2% of additive.
The content ratio of the waterborne alkyd resin to the waterborne modified alkyd resin is 5: 1-8: 1.
the waterborne alkyd resin comprises one or more of waterborne alkyd resin, waterborne modified alkyd resin, styrene-acrylic copolymer, waterborne additive type resin emulsion and waterborne acrylic modified resin.
The waterborne modified alkyd resin comprises one or more of waterborne alkyd resin, waterborne modified alkyd resin, styrene-acrylic copolymer, waterborne additive type resin emulsion and waterborne acrylic modified resin.
The waterborne modified alkyd resin enables the paint to be quick-drying, and has better luster and weather resistance.
The environment-friendly pigment comprises one or more of coating rutile type titanium dioxide, talcum powder, calcium carbonate, organic yellow, titanium cyan and organic red.
Deionized water is pure water from which impurities in the form of ions have been removed.
The additive comprises one or more of dimethylethanolamine, polyether modified polysiloxane, a high molecular copolymer containing pigment affinity groups, an acrylic copolymer solution, alkanolamine of a multifunctional copolymer, an ionic acrylic acid solution, organic modified sheet silicate, enclosed p-toluenesulfonic acid, polyether modified organosilicon, nano-alumina dispersion and cerium oxide nanoparticle dispersion.
A preparation method of an environment-friendly water-based alkyd resin coating comprises the following steps:
s1, adding the water-based alkyd resin and the water-based modified alkyd resin into a dispersing machine according to the mass fraction. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S2, continuously adding the additives and the deionized water which do not exceed the mass fraction into the dispersing machine. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S3, continuously adding the environment-friendly pigment in the mass fraction into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
s4, grinding the mixture obtained in the step S3 in a grinder for 2-5 times;
s5, adding the rest deionized water into the mixture obtained in the S4, and putting the mixture into a dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S6, adding the rest additives into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min.
The following experiments were performed on the coatings prepared in the present invention:
three groups of the invention are respectively taken for testing two batches, two similar products on the market are selected as comparative examples, and the experimental results are as follows:
wherein, the VOC detection is in accordance with GB 30981-2020.2, the paint film adhesion detection is in accordance with GB/T9286, and the impact strength detection is in accordance with GB/T1732.
According to the data, the invention greatly improves the adhesive force and the impact strength of the product while obviously reducing VOC.
The sample is subjected to a drying time performance test, and the detection result is as follows:
it can be seen that the drying time is shorter in the present invention.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (8)
1. An environment-friendly water-based alkyd resin coating is characterized by comprising the following components: 40-60% of waterborne alkyd resin, 5-12% of waterborne modified alkyd resin, 2-9% of environment-friendly pigment, 8-30% of deionized water and 0.04-1.2% of additive.
2. The environmentally friendly waterborne alkyd coating of claim 1, wherein: the content ratio of the waterborne alkyd resin to the waterborne modified alkyd resin is 5: 1-8: 1.
3. the environmentally friendly waterborne alkyd coating of claim 1, wherein: the waterborne alkyd resin comprises one or more of waterborne alkyd resin, waterborne modified alkyd resin, styrene-acrylic copolymer, waterborne additive type resin emulsion and waterborne acrylic modified resin.
4. The environmentally friendly waterborne alkyd coating of claim 1, wherein: the waterborne modified alkyd resin comprises one or more of waterborne alkyd resin, waterborne modified alkyd resin, styrene-acrylic copolymer, waterborne additive type resin emulsion and waterborne acrylic modified resin.
5. The environmentally friendly waterborne alkyd coating of claim 1, wherein: the environment-friendly pigment comprises one or more of film-coated rutile titanium dioxide, talcum powder, calcium carbonate, organic yellow, titanium cyan and organic red.
6. The environmentally friendly waterborne alkyd coating of claim 1, wherein: the deionized water is pure water from which impurities in the form of ions have been removed.
7. The environmentally friendly waterborne alkyd coating of claim 1, wherein: the additive comprises one or more of dimethylethanolamine, polyether modified polysiloxane, a high molecular copolymer containing pigment affinity groups, an acrylic copolymer solution, alkanolamine of a multifunctional copolymer, an ionic acrylic acid solution, organic modified sheet silicate, enclosed p-toluenesulfonic acid, polyether modified organosilicon, nano-alumina dispersion and cerium oxide nanoparticle dispersion.
8. The preparation method of the environment-friendly water-based alkyd resin coating is characterized by comprising the following steps:
s1, adding the mass fraction of the water-based alkyd resin and the water-based modified alkyd resin into a dispersing machine. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
s2, continuously adding the additive and the deionized water which do not exceed the mass fraction of the additive in the claim 1 into the dispersion machine. Wherein the mixing time of the dispersion machine is 20-30 minutes, and the rotating speed of the dispersion machine is 500 r/min;
s3, continuously adding the environment-friendly pigment with the mass fraction as described in the claim I into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
s4, grinding the mixture obtained in the step S3 in a grinder, wherein the grinding times are 2-5;
s5, adding the rest deionized water into the mixture obtained in the S4, and putting the mixture into a dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min;
and S6, adding the rest additives into the dispersing machine. Wherein the mixing time of the dispersion machine is 30-40 minutes, and the rotating speed of the dispersion machine is 500 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110897164.9A CN113801549A (en) | 2021-08-05 | 2021-08-05 | Environment-friendly water-based alkyd resin coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110897164.9A CN113801549A (en) | 2021-08-05 | 2021-08-05 | Environment-friendly water-based alkyd resin coating and preparation method thereof |
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| CN113801549A true CN113801549A (en) | 2021-12-17 |
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| CN202110897164.9A Pending CN113801549A (en) | 2021-08-05 | 2021-08-05 | Environment-friendly water-based alkyd resin coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116478413A (en) * | 2023-05-10 | 2023-07-25 | 扬州市祥华新材料科技有限公司 | Method for modifying alkyd resin by acrylic acid prepolymer block type and application thereof |
| CN116622276A (en) * | 2023-04-18 | 2023-08-22 | 广东贝壳新材料科技有限公司 | Water-based plastic coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880749A (en) * | 2017-11-24 | 2018-04-06 | 桂林市和鑫防水装饰材料有限公司 | Water alcohol acid anticorrosive paint |
-
2021
- 2021-08-05 CN CN202110897164.9A patent/CN113801549A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880749A (en) * | 2017-11-24 | 2018-04-06 | 桂林市和鑫防水装饰材料有限公司 | Water alcohol acid anticorrosive paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116622276A (en) * | 2023-04-18 | 2023-08-22 | 广东贝壳新材料科技有限公司 | Water-based plastic coating and preparation method thereof |
| CN116478413A (en) * | 2023-05-10 | 2023-07-25 | 扬州市祥华新材料科技有限公司 | Method for modifying alkyd resin by acrylic acid prepolymer block type and application thereof |
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Application publication date: 20211217 |
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