CN101864236A - Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish - Google Patents
Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish Download PDFInfo
- Publication number
- CN101864236A CN101864236A CN 201010215899 CN201010215899A CN101864236A CN 101864236 A CN101864236 A CN 101864236A CN 201010215899 CN201010215899 CN 201010215899 CN 201010215899 A CN201010215899 A CN 201010215899A CN 101864236 A CN101864236 A CN 101864236A
- Authority
- CN
- China
- Prior art keywords
- epoxy ester
- modified epoxy
- acrylic modified
- aqueous acrylic
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish. The baking finish consists of the following components in part by weight: 45 to 65 parts of aqueous acrylic modified epoxy ester resin, 2 to 20 parts of amino resin, 5 to 35 parts of pigment, 0 to 15 parts of filler, 1 to 3 parts of water dispersible dryer, 0.1 to 0.55 part of pH regulator, 5 to 15 parts of softened water, 0.2 to 0.4 part of dispersant, 0.3 to 0.5 part of wetting agent, 0.15 to 0.25 part of flatting agent, 0.3 to 0.5 part of antifoaming agent, and 0.2 to 0.3 part of preservative and mildew preventive. Without organic solvent, the baking finish is safe, energy-saving and free from pollution; the pencil hardness reaches 2H, the coating performance is stable, the film-coating mechanical strength is high, the positive and negative impact resistance can reach 5Kg.cm, and the flexibility can reach 1mm; the baking finish can integrate antirust and anticorrosive functions, can be used as primer or topcoat, reduces the construction process, is simple and quick to operate, can be sprayed or dip-coated, and can be quickly cured; a coated film does not become yellow; and the baking finish meets the development direction of aqueous anticorrosive paint.
Description
Technical field
The invention belongs to technical field of coatings, be particularly useful for the protection and the ornamental aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish of vehicular traffic, engineering machinery, household electrical appliance and steel furniture production etc.
Background technology
Existing domestic water-based anticorrosive paint still is divided into two kinds of priming paint and finish paints mostly, to use respectively during brushing, so just must consider whether priming paint and finish paint can supportingly use, and whether can combine in the film process, therefore bring certain trouble to construction.In order to reduce construction technology, reduce construction cost, the research of water-based anticorrosive paint has in recent years focused on the aqueous corrosion resisting paint without need of cleaning rust of bottom surface unification.In addition, water-based anticorrosive paint is strong to the dependency of construction environment, how to guarantee to obtain fast drying, well behaved coating under high humidity, low temperature and enclosed environment, is still the following problem of research emphatically that needs of water-based anticorrosive paint.Patent CN101591500A adopts the aqueous self-drying acrylic acid modified alkyd antirust paint of self-crosslinking technology preparation, and rate of drying is improved, but its performance of filming such as hardness etc. also need the long duration just can reach specified value.A kind of water-based acrylic acid modified alcoholic acid amino baking vanish that Inst. of Marine Chemical Engineering (CN1405254A) is introduced, drying condition is 120 * 30min, and the mechanical property of filming is strong, and hardness reaches 2H, but only limits to use as priming paint, and its drying time is slightly long.
Summary of the invention
The object of the present invention is to provide a kind of.A kind of aqueous acrylic modified epoxy ester bottom surface unification baking vanish and preparation method thereof is provided.To realize
Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish of the present invention is that the component by following weight part constitutes:
Aqueous acrylic modified epoxy ester resin 45-65; Aminoresin 2-20; Pigment 5-35; Filler 0-15; Aqueous dispersion type siccative 1-3; PH conditioning agent 0.1-0.55; Softening water 5-15; Dispersion agent 0.2-0.4 part; Wetting agent 0.3-0.5 part, flow agent 0.15-0.25 part, defoamer 0.3-0.5 part, sanitas and mould inhibitor 0.2-0.3 part.
Described aqueous acrylic modified epoxy ester resin is to carry out grafting under the action of evocating by the acrylic monomer of the vinyl monomer of the epoxy ester performed polymer of 20-30 weight part and 5-15 part, 5-15 part, 0.5-1 part, again through the resulting water-soluble products of Water-borne modification; Its acid number is 20-40mgKOH/g, and solid part is 30-50%., apply for patent of invention on the same day in addition, denomination of invention is: " a kind of aqueous acrylic modified epoxy ester resin and synthetic method thereof ", application number are 201010215288.6.
Its solid part of aqueous acrylic modified epoxy ester resin is 30-50%; It is the base-material as protective system, and film after the curing existing Resins, epoxy mechanical properties strength height, the good characteristics of antiseptic property have acrylic resin good weatherability, ornamental high characteristics again.
Described aminoresin comprise following one or more: the pure etherificate melamine resin of first (fourth, isobutyl), the pure etherificate trimeric cyanamide methylal resin of first (fourth, isobutyl), the pure etherificate trimeric cyanamide of first (fourth, isobutyl)-urea methylal resin.Its optimum amount is 3-8 part.
Described aqueous dispersion type siccative comprise following one or more: cobalt iso-octoate, zirconium naphthenate, zinc naphthenate; Its optimum amount is 1-3 part.
Described PH conditioning agent comprises following one or more: ammoniacal liquor, triethylamine, N, N-dimethylethanolamine, optimum amount are 0.2-0.5 part.
Described softening water is deionized water or distilled water.
Described pigment comprise following one or more: titanium dioxide, red iron oxide, iron oxide yellow, phthalocyanine blue, high-carbon black pigment, zinc oxide, strontium chromate, medium chrome yellow medium yellow, zinc phosphate, modified zinc phosphate, aluminium triphosphate, modification aluminium triphosphate etc., its optimum amount is 10-30 part.Pigment and metal base be by physical shielding or chemical passivation, effectively hinders water vapour and oxygen permeates to metal base, thus obstacle corrosion of metal effectively.
Described filler comprise following one or more: process white, talcum powder, sericite, calcined kaolin, silica powder, diatomite, its optimum amount are 0-0 part.The coating cost has not only been lowered in the use of filler, and can play the effect that improves functional coating film.Can prevent the coating sagging and in filming, absorb the function of stretching stress, minimizing crack and hole as talcum powder; Sericite in powder can improve the weathering resistance of filming, anti-water-permeable greatly, strengthen and film and matrix sticking power and coating strength, improves film apparent; Process white can improve coating suspension, improves smoothness etc.
Described dispersion agent is one or more of sodium, ammonium or amine salt of ethene modification unsaturated carboxylic acid (ester) multipolymer, and optimum amount is 0.2-0.4 part;
Described wetting agent is one or more among Tego-245, BYK-341, the SURFYNOLGA, and its optimum amount is 0.3-0.5 part;
Described flow agent is not solvent-laden modified siloxane, and as the EFKA-3580 of Efka company, optimum amount is 0.15-0.25 part;
Described defoamer is the organic silicon modified by polyether defoamer, mainly is among the EFKA-2550 of the SN313 of BYK-020, German Henkel company, Dutch Efka company one or more, and optimum amount is 0.3-0.5 part; Sanitas and mould inhibitor are the heterocyclic type compound, are mainly the KATHONLXE sanitas of Rohm-Hass, one or more in the ActicideTHP sanitas of SKANEM8 mould inhibitor and Britain Thor company, and optimum amount is respectively 0.2-0.3 part.
The preparation method of aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish may further comprise the steps:
(1) presses aqueous acrylic modified epoxy ester resin 45-65, aminoresin 2-20, pigment 5-35, filler 0-15, dispersion agent 0.2-0.4 part; Wetting agent 0.3-0.5 part, flow agent 0.15-0.25 part, defoamer 0.3-0.5 part, sanitas and mould inhibitor 0.2-0.3 part), siccative 1-3, PH conditioning agent 0.1-0.55, deionized water 5-15 get the raw materials ready;
(2) in Scattered Kettle, add the softening water, the dispersion agent in the formula ratio auxiliary agent, wetting agent of formula ratio, 2/3 defoamer, stir with the adjustable high-speed dispersion machine;
(2) add the aqueous acrylic modified epoxy ester resin of formula ratio 1/2 and the aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir;
(3) pigment, the filler of adding formula ratio stir, and keep 1-2 hour, get slurry;
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤45um;
(5) be transferred to proportion container at above-mentioned mill base, add second half aqueous acrylic modified epoxy ester resin again, flow agent, sanitas, mould inhibitor and the remaining defoamer of formula ratio stirs;
(6) detect pH value, add an amount of PH conditioning agent, regulating PH is between 8 to 10;
(7) filter, packing gets finished product.
Advantage of the present invention:
(1) be base-material with homemade aqueous acrylic modified epoxy ester resin, be substantially free of organic solvent, especially benzene kind solvent is safe, energy-conservation and pollution-free; (2) poly-hydroxy and amino resin crosslinked excessively in the acrylic modified epoxy ester water-base resin, two keys on the unsaturated fatty acids also can be cross-linked with each other, formed higher cross-linking density, so pencil hardness is up to 2H, coating property is stable, the physical strength of filming height, impact resistance is positive and negative all can to reach 50Kg.cm, and snappiness can reach 1mm.(3) (4) can be integrated antirust and anti-corrosion function, and antirust, anti-corrosive is once brushed, and has saved and has been coated with ETL estimated time of loading and cost; Both can be used as the priming paint use and also can be used as the finish paint use, need not consider the matching capacity problem of bottom surface lacquer during construction, therefore reduced construction technology, (5) are simple and quick, both can spray, but also dip-coating, storing temperature can be low to moderate 120 ℃ (guaranteeing storing time 20 minutes), and storing time can be soon to 10 minutes (keeping 140 ℃ of storing temperatures), under this baking condition, but completely solidified, the not xanthochromia of filming; (6) reduced energy consumption, energy-conserving and environment-protective; The developing direction that meets the water-repellent preservation lacquer.
Embodiment
Below illustrate the present invention, but the present invention not only be confined in these examples-
Embodiment 1: the synthetic method of aqueous acrylic modified epoxy ester resin
(1) linolic acid 650g, eleostearic acid 300g, E-12 Resins, epoxy 240.5g are added in the reaction flask.Stirring is warming up to 150 ~ 190 ℃, adds tetramethylolmethane 140g, TriMethylolPropane(TMP) 185g, m-phthalic acid 280g, ester catalyst plumbous oxide 1.5g successively.Be warming up to 220 ℃, and make acid number reach 20mgKOH/g.Be cooled to 150 ℃, add phthalic anhydride 110g, be warming up to 210 ℃, keep reacting to acid number 20mgKOH/g, cooling is preserved with dimethylbenzene 450g latting drown, makes the epoxy ester performed polymer.
(2) getting above-mentioned epoxy ester performed polymer 615g adds in the reaction flask 2, vinylbenzene 300g, butyl acrylate 130g, vinylformic acid 70g, benzoyl peroxide (BPO) 20g are mixed, after treating BPO dissolving fully, adopt the dropping mode reinforced, under reflux state, dripped off in 3 hours, insulation was kept 1 hour again, continue to drip initiator solution 2 hours, and insulation was kept 2 hours, extract solvent, add propylene glycol monomethyl ether 250g, obtaining acid number is 50mgKOH/g, and solid part is 74% acrylic modified epoxy ester resin.
Add triethylamine 30g and stir in above-mentioned acrylic modified epoxy ester resin, slowly adding deionized water 1200g to PH then is 9.8.Obtain water-soluble acrylic modified epoxy ester resin a.Its acid number is 39mgKOH/g, and solid part is 45%.
Embodiment 2
(1) the defoamer EFKA-2550 of adding 135g deionized water, 3g dispersant B YK-P105,4g wetting agent BYK-341,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 250g and the 40g methylated melamine aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) adding 30g titanium dioxide, 6g phthalocyanine blue, 6g high-carbon black pigment, 88.5g ultra-fine barium sulfate, 22.5g strontium chromate, 132g medium chrome yellow medium yellow stir, and keep 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 250g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative zinc naphthenate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer EFKA-2550 again and stir.
(6) detect pH value, add the PH conditioning agent diethanolamine of 3g, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish a.
Embodiment 3
(1) the defoamer EFKA-2550 of adding 130g deionized water, 3g dispersant B YK-P105,4g wetting agent Tego-245,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 250g and the 40g isopropylcarbinol etherify melamine formal aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) adding 15g titanium dioxide, 147g iron oxide red, 78g zinc phosphate, 3g ultra-fine barium sulfate, 2g strontium chromate stir, and keep 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 250g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative cobalt iso-octoate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer EFKA-2550 again and stir.
(6) detect pH value, add 3gPH conditioning agent triethylamine, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish b.
Embodiment 4:
(1) the defoamer BYK-020 of adding 140g deionized water, 3g dispersant B YK-P105,4g wetting agent BYK-341,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 250g and the 40g butanol etherification trimeric cyanamide-urea formal aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) add 27g high-carbon black pigment, 20g ultra-fine barium sulfate and 100g aluminium triphosphate and stir, kept 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 250g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative zinc naphthenate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer BYK-020 again and stir.
(6) detect pH value, add the PH conditioning agent diethanolamine of 3g, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish c.
Embodiment 5
(1) the defoamer BYK-020 of adding 90g deionized water, 3g dispersant B YK-P105,4g wetting agent Tego-245,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 300g and the 50g methylated melamine aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) add 165g titanium dioxide, 30g phthalocyanine blue, 20g ultra-fine barium sulfate and 5g strontium chromate and stir, kept 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 300g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative cobalt iso-octoate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer BYK-020 again and stir.
(6) detect pH value, add the PH conditioning agent triethylamine of 4g, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish d.
Embodiment 6
(1) the defoamer EFKA-2550 of adding 150g deionized water, 3g dispersion agent EFKA-4560,4g wetting agent BYK-341,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 300g and the 50g isopropylcarbinol etherify melamine formal aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) add 40g high-carbon black pigment, 100g ultra-fine barium sulfate and 20g strontium chromate and stir, kept 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 300g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative zinc naphthenate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer EFKA-2550 again and stir.
(6) detect pH value, add the PH conditioning agent diethanolamine of 4g, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish e.
Embodiment 7
(1) the defoamer BYK-020 of adding 140g deionized water, 3g dispersion agent EFKA-4560,4g wetting agent Tego-245,2.7g in Scattered Kettle stirs with the adjustable high-speed dispersion machine.
(2) add the aqueous acrylic modified epoxy ester resin of 300g and the 50g butanol etherification trimeric cyanamide-urea formal aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir.
(3) add 5g high-carbon black pigment, 150g iron oxide red and 10g strontium chromate and stir, kept 1-2 hour, get slurry.
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤35um.
(5) be transferred to proportion container at above-mentioned mill base, add 300g aqueous acrylic modified epoxy ester resin, 2g flow agent EFKA-3580,20g siccative cobalt iso-octoate, 2g sanitas ActicideTHP, 2g mould inhibitor SKANEM8 and 1.3g defoamer BYK-020 again and stir.
(6) detect pH value, add the PH conditioning agent triethylamine of 4g, regulate PH between 8 to 10.
(7) filter, packing, the stock gets aqueous acrylic modified epoxy ester bottom surface unification baking vanish f.
The performance of the water-repellent preservation baking vanish of the foregoing description preparation is listed in table 1
Table 1 water-repellent preservation baking vanish performance
Claims (5)
1. an aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish is characterized in that, is that the component by following weight part constitutes: aqueous acrylic modified epoxy ester resin 45-65; Aminoresin 2-20; Pigment 5-35; Filler 0-15; Aqueous dispersion type siccative 1-3; PH conditioning agent 0.1-0.55; Softening water 5-15; Dispersion agent 0.2-0.4 part; Wetting agent 0.3-0.5 part, flow agent 0.15-0.25 part, defoamer 0.3-0.5 part, sanitas and mould inhibitor 0.2-0.3 part.
2. a kind of aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish according to claim 1, it is characterized in that, described aqueous acrylic modified epoxy ester resin is to carry out grafting under the action of evocating by the acrylic monomer of the vinyl monomer of the epoxy ester performed polymer of 20-30 weight part and 5-15 part, 5-15 part, 0.5-1 part, again through the resulting water-soluble products of Water-borne modification; Its acid number is 20-40mgKOH/g, and solid part is 30-50%.
3. a kind of aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish according to claim 1, it is characterized in that, described aminoresin comprise following one or more: the pure etherificate melamine resin of first (fourth, isobutyl), the pure etherificate trimeric cyanamide methylal resin of first (fourth, isobutyl), the pure etherificate trimeric cyanamide of first (fourth, isobutyl)-urea methylal resin, its consumption is the 3-8 weight part.
4. a kind of aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish according to claim 1 is characterized in that, described PH conditioning agent is following one or more: ammoniacal liquor, triethylamine, N, N-dimethylethanolamine, its optimum amount are 0.2-0.5 part.
5. the preparation method of an aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish is characterized in that, may further comprise the steps:
(1) presses aqueous acrylic modified epoxy ester resin 45-65, aminoresin 2-20, pigment 5-35, filler 0-15, dispersion agent 0.2-0.4 part; Wetting agent 0.3-0.5 part, flow agent 0.15-0.25 part, defoamer 0.3-0.5 part, sanitas and mould inhibitor 0.2-0.3 part, siccative 1-3, PH conditioning agent 0.1-0.55, softening water 5-15 get the raw materials ready;
(2) in Scattered Kettle, add the softening water, the dispersion agent in the formula ratio auxiliary agent, wetting agent of formula ratio, 2/3 defoamer, stir with the adjustable high-speed dispersion machine;
(2) add the aqueous acrylic modified epoxy ester resin of formula ratio 1/2 and the aminoresin of formula ratio, under the rotating speed of 400-500rpm, stir;
(3) pigment, the filler of adding formula ratio stir, and keep 1-2 hour, get slurry;
(4) above-mentioned slurry is ground by shredder,, get mill base until fineness≤45um;
(5) be transferred to proportion container at above-mentioned mill base, add second half aqueous acrylic modified epoxy ester resin again, flow agent, sanitas, mould inhibitor and the remaining defoamer of formula ratio stirs;
(6) detect pH value, add an amount of PH conditioning agent, regulating PH is between 8 to 10;
(7) filter, the packing back is a finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010215899 CN101864236A (en) | 2010-07-02 | 2010-07-02 | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010215899 CN101864236A (en) | 2010-07-02 | 2010-07-02 | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101864236A true CN101864236A (en) | 2010-10-20 |
Family
ID=42956174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010215899 Pending CN101864236A (en) | 2010-07-02 | 2010-07-02 | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101864236A (en) |
Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627902A (en) * | 2012-03-20 | 2012-08-08 | 上海暄洋化工材料科技有限公司 | Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof |
| CN102746768A (en) * | 2012-08-02 | 2012-10-24 | 西北永新化工股份有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN102827544A (en) * | 2012-09-17 | 2012-12-19 | 吴江市物华五金制品有限公司 | Thermosetting water soluble resin antibacterial coating |
| CN102925039A (en) * | 2012-11-30 | 2013-02-13 | 刘凯 | Stoving varnish and preparation method thereof |
| CN103045053A (en) * | 2013-01-04 | 2013-04-17 | 高文升 | Water-based industrial anticorrosion paint and preparation method |
| CN103436124A (en) * | 2013-08-28 | 2013-12-11 | 广西梧州龙鱼漆业有限公司 | Special stoving varnish for oil drum and preparation method of special stoving varnish |
| CN103467748A (en) * | 2013-08-13 | 2013-12-25 | 嘉兴市清河高力绝缘有限公司 | Preparation method for waterborne acrylic acid modified epoxy ester emulsion and its amino baking varnish |
| CN103540230A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-corrosion paint for switch cabinet and preparation method thereof |
| CN103540224A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-corrosion paint for switch cabinet and preparation method thereof |
| CN103540231A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-rust paint for switch cabinet body and preparation method thereof |
| CN103788846A (en) * | 2014-01-27 | 2014-05-14 | 厦门双瑞船舶涂料有限公司 | Anticorrosive top-coat and preparation method thereof |
| CN104087128A (en) * | 2014-07-27 | 2014-10-08 | 广西梧州龙鱼漆业有限公司 | Water-based primer composition |
| CN104087799A (en) * | 2014-08-07 | 2014-10-08 | 兰宝琴 | Manufacturing method of aluminum-plastic plate |
| CN105261974A (en) * | 2015-11-10 | 2016-01-20 | 鼎圣电气有限公司 | Constant-temperature high-low voltage switch cabinet |
| CN105349000A (en) * | 2015-12-10 | 2016-02-24 | 董晓娜 | Metallic surface anti-corrosion paint and preparing method thereof |
| CN105885635A (en) * | 2016-06-10 | 2016-08-24 | 洪其祥 | Water-based plate coating and preparation method thereof |
| CN106634382A (en) * | 2016-12-23 | 2017-05-10 | 珠海市立州涂料有限公司 | Environment-friendly anticorrosion quick-drying type primer-topcoat integrated air-dry paint and preparation method thereof |
| CN106674441A (en) * | 2017-01-24 | 2017-05-17 | 湘江涂料科技有限公司 | Water-soluble acrylate modified epoxy ester resin and preparation method thereof |
| CN107245288A (en) * | 2016-11-07 | 2017-10-13 | 中山蓝海洋水性涂料有限公司 | High-alkali-resistance strong-adhesion water-based metal matte baking paint and preparation and use methods thereof |
| CN107337981A (en) * | 2016-08-08 | 2017-11-10 | 宁波全盛世纪气动科技有限公司 | A kind of modified epoxy baking vanish |
| CN107586493A (en) * | 2016-07-06 | 2018-01-16 | 赫普有限公司 | Water based primer compositions, the priming paint obtained by it and the double-deck system containing the priming paint |
| CN107629640A (en) * | 2017-10-24 | 2018-01-26 | 河北晨阳工贸集团有限公司 | A kind of agricultural machinery anti-corrosive primer and preparation method thereof |
| CN107858079A (en) * | 2017-10-11 | 2018-03-30 | 湖南文理学院 | A kind of water-based single group can be with rust construction steel construction priming paint and its preparation method and application |
| CN108587414A (en) * | 2018-03-14 | 2018-09-28 | 河北晨阳工贸集团有限公司 | A kind of water-repellent preservation amino-stoving varnish |
| CN109535907A (en) * | 2018-12-03 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of water soluble acrylic acid epoxy amino baking white primer |
| CN109535906A (en) * | 2018-12-03 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of water soluble acrylic acid epoxy amino baking black primer |
| CN109553233A (en) * | 2018-12-25 | 2019-04-02 | 南通理工学院 | A kind of ship sanitary system using air-conditioning condensate |
| CN109627927A (en) * | 2018-12-17 | 2019-04-16 | 佛山市凡恩金属制品有限公司 | A kind of coating for aluminum profile shipborne equipment |
| CN110093094A (en) * | 2019-04-11 | 2019-08-06 | 广州集泰化工股份有限公司 | A kind of axle vehicle sedan-chair bottom surface unification aqueous anticorrosion paint and preparation method thereof |
| CN110396353A (en) * | 2019-08-27 | 2019-11-01 | 金生龙 | A kind of anti-corrosion gas defence water paint and preparation method thereof |
| CN110894394A (en) * | 2019-11-12 | 2020-03-20 | 无锡华东锌盾科技有限公司 | Water-based polyester amino baking varnish coating and preparation method and application thereof |
| CN111440495A (en) * | 2020-04-17 | 2020-07-24 | 山东七维新材料有限公司 | Water-based amino baking paint and preparation method thereof |
| CN111574895A (en) * | 2019-02-18 | 2020-08-25 | 蓝伟荣 | Metal rusty anticorrosive primer |
| CN112251117A (en) * | 2020-11-05 | 2021-01-22 | 丹东安邦涂料有限公司 | Preparation method of water-based dip-coating primer-topcoat paint capable of being baked at low temperature |
| CN114181625A (en) * | 2022-01-05 | 2022-03-15 | 嘉兴泰格高新材料股份有限公司 | Methylene chloride and ketone solvent resistant high-temperature water-based amino baking paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1640968A (en) * | 2004-01-05 | 2005-07-20 | 重庆亿隆漆业有限公司 | Water-soluble acroleic-acid modified epoxy ester anti-rast paint |
| CN101177518A (en) * | 2006-11-09 | 2008-05-14 | 上海涂料有限公司技术中心 | Epoxy ester resin water dispersion and method for manufacturing rust-inhibiting primer using the same as foundation |
| CN101423724B (en) * | 2008-12-23 | 2010-12-08 | 泉州市信和涂料有限公司 | Roasting reactive dermatoglyph paint and preparation method thereof |
-
2010
- 2010-07-02 CN CN 201010215899 patent/CN101864236A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1640968A (en) * | 2004-01-05 | 2005-07-20 | 重庆亿隆漆业有限公司 | Water-soluble acroleic-acid modified epoxy ester anti-rast paint |
| CN101177518A (en) * | 2006-11-09 | 2008-05-14 | 上海涂料有限公司技术中心 | Epoxy ester resin water dispersion and method for manufacturing rust-inhibiting primer using the same as foundation |
| CN101423724B (en) * | 2008-12-23 | 2010-12-08 | 泉州市信和涂料有限公司 | Roasting reactive dermatoglyph paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《中国涂料》 20060215 周小勇等 水性丙烯酸-环氧接枝共聚型树脂的制备 第21卷, 第02期 2 * |
Cited By (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627902B (en) * | 2012-03-20 | 2014-10-15 | 上海暄洋化工材料科技有限公司 | Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof |
| CN102627902A (en) * | 2012-03-20 | 2012-08-08 | 上海暄洋化工材料科技有限公司 | Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof |
| CN102746768A (en) * | 2012-08-02 | 2012-10-24 | 西北永新化工股份有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN102746768B (en) * | 2012-08-02 | 2014-12-10 | 西北永新涂料有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN102827544A (en) * | 2012-09-17 | 2012-12-19 | 吴江市物华五金制品有限公司 | Thermosetting water soluble resin antibacterial coating |
| CN102925039A (en) * | 2012-11-30 | 2013-02-13 | 刘凯 | Stoving varnish and preparation method thereof |
| CN103045053A (en) * | 2013-01-04 | 2013-04-17 | 高文升 | Water-based industrial anticorrosion paint and preparation method |
| CN103467748A (en) * | 2013-08-13 | 2013-12-25 | 嘉兴市清河高力绝缘有限公司 | Preparation method for waterborne acrylic acid modified epoxy ester emulsion and its amino baking varnish |
| CN103436124A (en) * | 2013-08-28 | 2013-12-11 | 广西梧州龙鱼漆业有限公司 | Special stoving varnish for oil drum and preparation method of special stoving varnish |
| CN103540230A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-corrosion paint for switch cabinet and preparation method thereof |
| CN103540224A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-corrosion paint for switch cabinet and preparation method thereof |
| CN103540231A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Anti-rust paint for switch cabinet body and preparation method thereof |
| CN103788846A (en) * | 2014-01-27 | 2014-05-14 | 厦门双瑞船舶涂料有限公司 | Anticorrosive top-coat and preparation method thereof |
| CN104087128A (en) * | 2014-07-27 | 2014-10-08 | 广西梧州龙鱼漆业有限公司 | Water-based primer composition |
| CN104087799A (en) * | 2014-08-07 | 2014-10-08 | 兰宝琴 | Manufacturing method of aluminum-plastic plate |
| CN105261974A (en) * | 2015-11-10 | 2016-01-20 | 鼎圣电气有限公司 | Constant-temperature high-low voltage switch cabinet |
| CN105349000A (en) * | 2015-12-10 | 2016-02-24 | 董晓娜 | Metallic surface anti-corrosion paint and preparing method thereof |
| CN105349000B (en) * | 2015-12-10 | 2017-11-07 | 浙江德利福科技股份有限公司 | A kind of metal surface anticorrosive paint and preparation method thereof |
| CN105885635A (en) * | 2016-06-10 | 2016-08-24 | 洪其祥 | Water-based plate coating and preparation method thereof |
| CN107586493A (en) * | 2016-07-06 | 2018-01-16 | 赫普有限公司 | Water based primer compositions, the priming paint obtained by it and the double-deck system containing the priming paint |
| CN107337981A (en) * | 2016-08-08 | 2017-11-10 | 宁波全盛世纪气动科技有限公司 | A kind of modified epoxy baking vanish |
| CN107245288A (en) * | 2016-11-07 | 2017-10-13 | 中山蓝海洋水性涂料有限公司 | High-alkali-resistance strong-adhesion water-based metal matte baking paint and preparation and use methods thereof |
| CN107245288B (en) * | 2016-11-07 | 2019-09-06 | 中山蓝海洋水性涂料有限公司 | High-alkali-resistance strong-adhesion water-based metal matte baking paint and preparation and use methods thereof |
| CN106634382A (en) * | 2016-12-23 | 2017-05-10 | 珠海市立州涂料有限公司 | Environment-friendly anticorrosion quick-drying type primer-topcoat integrated air-dry paint and preparation method thereof |
| CN106634382B (en) * | 2016-12-23 | 2019-08-20 | 珠海市立州水性涂料有限公司 | A kind of bottom surface unification self-drying paint of environment friendly corrosion protection quick-dry type and preparation method thereof |
| CN106674441B (en) * | 2017-01-24 | 2019-07-23 | 湘江涂料科技有限公司 | A kind of water-soluble acrylic modified epoxy ester resin and preparation method thereof |
| CN106674441A (en) * | 2017-01-24 | 2017-05-17 | 湘江涂料科技有限公司 | Water-soluble acrylate modified epoxy ester resin and preparation method thereof |
| CN107858079A (en) * | 2017-10-11 | 2018-03-30 | 湖南文理学院 | A kind of water-based single group can be with rust construction steel construction priming paint and its preparation method and application |
| CN107629640A (en) * | 2017-10-24 | 2018-01-26 | 河北晨阳工贸集团有限公司 | A kind of agricultural machinery anti-corrosive primer and preparation method thereof |
| CN108587414A (en) * | 2018-03-14 | 2018-09-28 | 河北晨阳工贸集团有限公司 | A kind of water-repellent preservation amino-stoving varnish |
| CN109535906A (en) * | 2018-12-03 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of water soluble acrylic acid epoxy amino baking black primer |
| CN109535907A (en) * | 2018-12-03 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of water soluble acrylic acid epoxy amino baking white primer |
| CN109627927A (en) * | 2018-12-17 | 2019-04-16 | 佛山市凡恩金属制品有限公司 | A kind of coating for aluminum profile shipborne equipment |
| CN109553233A (en) * | 2018-12-25 | 2019-04-02 | 南通理工学院 | A kind of ship sanitary system using air-conditioning condensate |
| CN111574895A (en) * | 2019-02-18 | 2020-08-25 | 蓝伟荣 | Metal rusty anticorrosive primer |
| CN110093094A (en) * | 2019-04-11 | 2019-08-06 | 广州集泰化工股份有限公司 | A kind of axle vehicle sedan-chair bottom surface unification aqueous anticorrosion paint and preparation method thereof |
| CN110396353A (en) * | 2019-08-27 | 2019-11-01 | 金生龙 | A kind of anti-corrosion gas defence water paint and preparation method thereof |
| CN110894394A (en) * | 2019-11-12 | 2020-03-20 | 无锡华东锌盾科技有限公司 | Water-based polyester amino baking varnish coating and preparation method and application thereof |
| CN111440495A (en) * | 2020-04-17 | 2020-07-24 | 山东七维新材料有限公司 | Water-based amino baking paint and preparation method thereof |
| CN112251117A (en) * | 2020-11-05 | 2021-01-22 | 丹东安邦涂料有限公司 | Preparation method of water-based dip-coating primer-topcoat paint capable of being baked at low temperature |
| CN114181625A (en) * | 2022-01-05 | 2022-03-15 | 嘉兴泰格高新材料股份有限公司 | Methylene chloride and ketone solvent resistant high-temperature water-based amino baking paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101864236A (en) | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish | |
| CN101104764B (en) | Double-anticorrosion paint for steel and preparing method thereof | |
| CN102108245B (en) | Waterborne polyester modified epoxy polyurethane anticorrosive paint and preparation method thereof | |
| CN101104770A (en) | Water-based epoxy intermediate paint | |
| CN102010648A (en) | Floating coat-free shining base coat used for metal pieces and preparation method thereof | |
| CN100345922C (en) | High-saline-resistance lead red alcohol acid antirust paint and its preparing method | |
| CN102559026A (en) | High-performance aqueous non-toxic and anti-corrosion coating and preparation method thereof | |
| CN110564234A (en) | water-based PVDF (polyvinylidene fluoride) fluorocarbon coating for coiled material as well as preparation method and application thereof | |
| CN105218752A (en) | The preparation method of the polyurethane-acrylate water dispersion of epoxy-silicone resin modification and water-based epoxy zinc-rich primer | |
| CN103305101A (en) | Quick-drying anticorrosive and anti-rust primer and preparation method thereof | |
| CN101629045A (en) | High solid metal inner cavity anticorrosive paint and production method thereof | |
| CN105885645A (en) | Preparation method of waterborne rusty epoxy coating | |
| CN108276864B (en) | Phosphate/polyurethane modified waterborne alkyd anticorrosive paint | |
| CN101613560B (en) | Mirror back protective coating based on priming-finishing paint coupling technology, manufacture method and construction method | |
| CN103305096A (en) | Multifunctional undercoat and preparation method thereof | |
| CN109762439A (en) | A kind of waterborne epoxy coatings and preparation method thereof | |
| CN1159399C (en) | Water-based acrylic acid modified alcoholic acid amino baking paint | |
| CN109517459A (en) | A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint | |
| CN104293111A (en) | High-efficiency anti-rusting epoxy finishing paint loaded with silicon dioxide nano spheres and preparation method of high-efficiency anti-rusting epoxy finishing paint | |
| CN104629586A (en) | Roasting-free energy-saving high salt spray resistant epoxy primer and preparation method thereof | |
| CN115466557A (en) | Anti-rust and anti-corrosion primer and preparation method thereof | |
| CN101451043A (en) | Novel acrylic resin bottom face synthetic lacquer | |
| CN103666163A (en) | Water-based metal rust-proof white paint and preparation method thereof | |
| CN106010025A (en) | Rust inhibiting coating for steel and preparation method of rust inhibiting coating | |
| CN104387906A (en) | Air-resistant antioxidative rust-proof epoxy finish coat and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20101020 |