CN102746546B - A kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof - Google Patents
A kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof Download PDFInfo
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- CN102746546B CN102746546B CN201210196886.2A CN201210196886A CN102746546B CN 102746546 B CN102746546 B CN 102746546B CN 201210196886 A CN201210196886 A CN 201210196886A CN 102746546 B CN102746546 B CN 102746546B
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Abstract
The invention discloses a kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof, the weight portion of its constitutive material is: polyolefin elastomer 8450/ Dupont 90 110, PVC resin powder 50 60, wollastonite in powder 40 60, nano-attapulgite 60 80, ethylene propylene diene rubber 50 80, nitrile rubber 40 50, nanoclay 20 30, aluminium hydroxide 30 40, precipitated silica 14, precipitated calcium carbonate 60 80, insoluble sulfur 35, iso-cyanuric acid triallyl ester 14, age resistor TPPD3 5, cumyl peroxide DCP4 6, dibasic lead phosphite 38, antioxidant 1010 57, stearic acid monoglyceride 25 and antimony trioxide 50 70.Preparation method of the present invention is simple, excellent electrical property, and heat-resisting ageing-resisting anti-wear performance is good, and under high temperature, dilatancy is little, beneficially post-cure processing, low-smoke and flame retardant, Environmental Safety.
Description
Technical field
The present invention relates to a kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof, belong to CABLE MATERIALS skill
Art field.
Background technology
Along with economic develops rapidly, electric wire is widely used in industry-by-industry, field.Along with electrically
The frequent generation of fire incident, the fire-retardant problem of electric wire gradually causes the attention of countries in the world.Discharge during cable fire
A large amount of smog and poisonous, corrosive gas are risk factors in fire, hamper in a fire people safe escape and
Fire-fighting work, makes lives and properties suffer heavy losses.Simultaneously along with the development of communication career, auto industry and computer industry,
Particularly many occasions such as aviation wire, line for cars, high temperature instrument cable, oil drilling platform cable, have increasing need for making
With halogen-free environment-friendly type power cable for wind power generation material.
Summary of the invention
It is an object of the invention to provide a kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof, this
Bright preparation method is simple, excellent electrical property, and heat-resisting ageing-resisting anti-wear performance is good, and under high temperature, dilatancy is little, beneficially secondary
Sulfuration processing, low-smoke and flame retardant, Environmental Safety.
The adopting the following technical scheme that of the present invention for achieving the above object
Halogen-free environment-friendly type power cable for wind power generation material, the weight portion of its constitutive material is: polyolefin elastomer
8450/ Dupont 90-110, PVC resin powder 50-60, wollastonite in powder 40-60, nano-attapulgite 60-80, EPDM
Rubber 50-80, nitrile rubber 40-50, nanoclay 20-30, aluminium hydroxide 30-40, precipitated silica 1-4, lightweight
Calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, age resistor TPPD 3-5, peroxidating two are different
Propyl benzene DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, stearic acid monoglyceride 2-5 and antimony trioxide 50-
70。
Halogen-free environment-friendly type power cable for wind power generation material, the weight portion of its constitutive material is: polyolefin elastomer
8450/ Dupont 100, PVC resin powder 55, wollastonite in powder 50, nano-attapulgite 70, ethylene propylene diene rubber 65, butyronitrile
Rubber 45, nanoclay 25, aluminium hydroxide 35, precipitated silica 3, precipitated calcium carbonate 70, insoluble sulfur 4, triolefin
Propyl group fulminuric acid ester 3, age resistor TPPD 4, cumyl peroxide DCP 5, dibasic lead phosphite 5, antioxidant 1010
6, stearic acid monoglyceride 3.5 and antimony trioxide 60.
The preparation method of halogen-free environment-friendly type power cable for wind power generation material, comprises the following steps: by the weight of constitutive material
Amount part weighs each raw material, then in temperature 100-120 DEG C after banburying 5-7 minute, mixed at temperature 150-170 DEG C again after banburying
Refine and obtain finished product in 20-30 minute.
Beneficial effects of the present invention:
Preparation method of the present invention is simple, excellent electrical property, and heat-resisting ageing-resisting anti-wear performance is good, dilatancy under high temperature
Little, beneficially post-cure processing, low-smoke and flame retardant, Environmental Safety.
Detailed description of the invention
Embodiment 1: halogen-free environment-friendly type power cable for wind power generation material, the weight portion of its constitutive material is: polyolefin bullet
Gonosome POE 8450/ Dupont 90-110, PVC resin powder 50-60, wollastonite in powder 40-60, nano-attapulgite 60-80,
Ethylene propylene diene rubber 50-80, nitrile rubber 40-50, nanoclay 20-30, aluminium hydroxide 30-40, precipitated silica 1-
4, precipitated calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, age resistor TPPD 3-5, peroxide
Change diisopropylbenzene (DIPB) DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, stearic acid monoglyceride 2-5 and three oxidations
Antimony 50-70.
The preparation method of halogen-free environment-friendly type power cable for wind power generation material, comprises the following steps: by the weight of constitutive material
Amount part weighs each raw material, then in temperature 100-120 DEG C after banburying 5-7 minute, mixed at temperature 150-170 DEG C again after banburying
Refine and obtain finished product in 20-30 minute.
The CABLE MATERIALS performance data prepared by embodiments of the invention 1:
Temperature resistant grade is high, continuous long-time stable work at 110 DEG C;
Before aging: elongation at break 283%, tensile strength 14N/mm2;
After aging: (120 DEG C, 240h) elongation at break 240%, tensile strength 13N/mm2;
Electrical property: specific insulation 1.92*1012Ohm-meter, breakdown strength 19Kv/mm.
Single vertical combustion test, after flame time is 7 seconds, and burning end away from upper fixture lower edge distance is 280 millimeters;Bunchy fires
Burning test, char length is 1.5 meters.
Claims (3)
1. an environment-friendly type power cable for wind power generation material, it is characterised in that the weight portion of its constitutive material is: polyolefin bullet
Gonosome POE 8450/ Dupont 90-110, PVC resin powder 50-60, wollastonite in powder 40-60, nano-attapulgite 60-80, three
Unit EP rubbers 50-80, nitrile rubber 40-50, nanoclay 20-30, aluminium hydroxide 30-40, precipitated silica 1-4, light
Matter calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, age resistor TPPD 3-5, peroxidating two are different
Propyl benzene DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, stearic acid monoglyceride 2-5 and antimony oxide 50-
70。
Environment-friendly type power cable for wind power generation material the most according to claim 1, it is characterised in that the weight of its constitutive material
Amount part is: polyolefin elastomer 8450/ Dupont 100, PVC resin powder 55, wollastonite in powder 50, nano-attapulgite
70, ethylene propylene diene rubber 65, nitrile rubber 45, nanoclay 25, aluminium hydroxide 35, precipitated silica 3, precipitated calcium carbonate
70, insoluble sulfur 4, iso-cyanuric acid triallyl ester 3, age resistor TPPD 4, cumyl peroxide DCP 5, dibasic
Lead phosphite 5, antioxidant 1010 6, stearic acid monoglyceride 3.5 and antimony oxide 60.
3. the preparation method of an environment-friendly type power cable for wind power generation material as claimed in claim 1, it is characterised in that bag
Include following steps: weigh each raw material by the weight portion of constitutive material, then in temperature 100-120 DEG C after banburying 5-7 minute, close
Within mixing 20-30 minute at temperature 150-170 DEG C, finished product is obtained again after refining.
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CN201210196886.2A CN102746546B (en) | 2012-06-15 | 2012-06-15 | A kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof |
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CN201210196886.2A CN102746546B (en) | 2012-06-15 | 2012-06-15 | A kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof |
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CN102746546B true CN102746546B (en) | 2016-08-03 |
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Effective date of registration: 20201016 Address after: Suzhou City, Jiangsu province 215600 Zhangjiagang Yang Donglai Huayu Road No. 6 Patentee after: SUZHOU YIPUDUN NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 238339 Anhui city of Wuhu province Wuwei County New Industrial Park Patentee before: ANHUI HUATONG CABLE GROUP Co.,Ltd. |