CN102911409A - Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof - Google Patents
Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof Download PDFInfo
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- CN102911409A CN102911409A CN2012103461369A CN201210346136A CN102911409A CN 102911409 A CN102911409 A CN 102911409A CN 2012103461369 A CN2012103461369 A CN 2012103461369A CN 201210346136 A CN201210346136 A CN 201210346136A CN 102911409 A CN102911409 A CN 102911409A
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- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 poly(styrene-butadiene-styrene) Polymers 0.000 claims abstract description 19
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 12
- 239000011858 nanopowder Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 7
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 6
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 6
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011593 sulfur Substances 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 6
- 229940126062 Compound A Drugs 0.000 claims description 17
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229920013649 Paracril Polymers 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000003712 anti-aging effect Effects 0.000 claims description 5
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000000052 vinegar Substances 0.000 claims description 5
- 235000021419 vinegar Nutrition 0.000 claims description 5
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 229910052923 celestite Inorganic materials 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000010433 feldspar Substances 0.000 claims description 3
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 claims description 3
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 abstract description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 239000000779 smoke Substances 0.000 abstract description 3
- 229920000459 Nitrile rubber Polymers 0.000 abstract 2
- 229920000058 polyacrylate Polymers 0.000 abstract 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- POZJYKKVMDSOMO-UHFFFAOYSA-N dimethyltin;6-methylheptyl 2-sulfanylacetate Chemical compound C[Sn]C.CC(C)CCCCCOC(=O)CS POZJYKKVMDSOMO-UHFFFAOYSA-N 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 229920001610 polycaprolactone Polymers 0.000 abstract 1
- 239000004632 polycaprolactone Substances 0.000 abstract 1
- 229920000306 polymethylpentene Polymers 0.000 abstract 1
- 239000011116 polymethylpentene Substances 0.000 abstract 1
- 239000006235 reinforcing carbon black Substances 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 206010000369 Accident Diseases 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Inorganic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses an environment-friendly tensile high-temperature-resistant control cable material and a preparation method thereof. The cable material is composed of a mixture A and a mixture B, wherein the mixture A comprises, by weight, 30-40 parts of nitrile rubber, 20-30 parts of silicon rubber, 10-20 parts of polyacrylate, 10-20 parts of poly(styrene-butadiene-styrene), 1-3 parts of semi-reinforcing carbon black, 40-60 parts of modified nano-powder, 1-3 parts of insoluble sulfur, 1.5-2.5 parts of methyltrimethoxysilane, 1-3 parts of zinc stearate, 3-4 parts of antioxidant 1035, 1-3 parts of bi-texanol, 10-20 parts of magnesium hydroxide and 1-3 parts of dioctyl phthalate; the mixture B comprises, by weight, 30-50 parts of nitrile rubber, 20-40 parts of silicon rubber, 20-30 parts of polyacrylate, 0.3-0.5 part of poly(4-methyl-1-pentene) , 2-4 parts of antiager RD, 5-10 parts of polycaprolactone, 2-3 part of crosslinking agents TAIC, 1-3 part of chlorinated paraffin, 5-8 parts of ammonium dihydrogen phosphate and 1-3 parts of isooctyl thioglycolate dimethyl tin. The preparation method is simple, the composite formula is reasonable, the performance of the cable material is improved greatly, thermal resistance, aging resistance and wear resistance of the cable material are good, expansion deformation under high temperature is small, secondary vulcanization is facilitated, and the cable material is low-smoke, flame-retardant, environment-friendly and safe.
Description
Technical field
The present invention relates to a kind of environment-friendly type tension high temperature resistance control cable material and preparation method thereof, belong to the CABLE MATERIALS technical field.
Background technology
Along with developing rapidly of economy, electric wire is at industry-by-industry, all be widely used in the field, frequent occurrence along with the electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, discharge a large amount of smog and poisonous during cable fire, corrosive gas is Hazard Factor in the fire, people's safe escape and fire-fighting work in fire, have been hindered, make lives and properties suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, wire peculiar to vessel particularly, line for cars, the high temperature instrument cable, many occasions such as oil drilling platform cable, environment-friendly type tension high temperature resistance control cable material also is absolutely necessary certainly.
Summary of the invention
The purpose of this invention is to provide a kind of environment-friendly type tension high temperature resistance control cable material and preparation method thereof, preparation method of the present invention is simple, the constitutive material prescription is reasonable, performance improves greatly, the heat-resisting ageing-resisting wear resisting property is good, and dilatational strain is little under the high temperature, is conducive to post cure processing, low-smoke and flame retardant, Environmental Safety.
The following technical scheme of employing of the present invention for achieving the above object:
Environment-friendly type tension high temperature resistance control cable material, the weight part of its constitutive material is:
Compound A: paracril 30-40, silicon rubber 20-30, polyacrylic ester 10-20, SBS 10-20, semi-reinforcing hydrocarbon black 1-3, modified Nano powder 40-60, insoluble sulfur 1-3, methyltrimethoxy silane 1.5-2.5, Zinic stearas 1-3, oxidation inhibitor 1035 3-4, two Lauryl Alcohol ester 1-3, magnesium hydroxide 10-20 and dioctyl ester 1-3;
Compound B: vinegar 5-10, linking agent TAIC 2-3, clorafin 1-3, primary ammonium phosphate 5-8 and dimethyl dimercapto 2-ethyl hexyl ethanoate tin 1-3 in paracril 30-50, silicon rubber 20-40, polyacrylic ester 20-30, poly--4-methyl-1-pentene 0.3-0.5, anti-aging agent RD 2-4, the poly-caproic acid.
Environment-friendly type tension high temperature resistance control cable material, the weight part of its constitutive material is:
Compound A: paracril 35, silicon rubber 25, polyacrylic ester 15, SBS 15, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, insoluble sulfur 2, methyltrimethoxy silane 2, Zinic stearas 2, oxidation inhibitor 1,035 3.5, two Lauryl Alcohol ester 2, magnesium hydroxide 15 and dioctyl ester 2;
Compound B: vinegar 8, linking agent TAIC 2.5, clorafin 2, primary ammonium phosphate 7 and dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2 in paracril 40, silicon rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent RD 3, the poly-caproic acid.
The preparation method of environment-friendly type tension high temperature resistance control cable material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 15-25 minute again, the control temperature was plasticated 3-5 minute discharging at last at 132-140 ℃ under 145-155 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 600-700 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
Advantage of the present invention:
Preparation method of the present invention is simple, and the constitutive material prescription is reasonable, and performance improves greatly, and the heat-resisting ageing-resisting wear resisting property is good, and dilatational strain is little under the high temperature, is conducive to post cure processing, low-smoke and flame retardant, Environmental Safety.
Embodiment
Embodiment 1:Environment-friendly type tension high temperature resistance control cable material, the weight part of its constitutive material is:
Compound A: paracril 35, silicon rubber 25, polyacrylic ester 15, SBS 15, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, insoluble sulfur 2, methyltrimethoxy silane 2, Zinic stearas 2, oxidation inhibitor 1,035 3.5, two Lauryl Alcohol ester 2, magnesium hydroxide 15 and dioctyl ester 2;
Compound B: vinegar 8, linking agent TAIC 2.5, clorafin 2, primary ammonium phosphate 7 and dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2 in paracril 40, silicon rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent RD 3, the poly-caproic acid.
The preparation method of environment-friendly type tension high temperature resistance control cable material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 15-25 minute again, the control temperature was plasticated 3-5 minute discharging at last at 132-140 ℃ under 145-155 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 600-700 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
The environment-friendly type tension high temperature resistance control cable material performance that the present invention makes:
| Sequence number | Project name | Unit | Test value |
| 1 | Tensile strength | Mpa | 7.8 |
| 2 | Elongation at break | % | 560 |
| 3 | 200 ℃, tensile strength after 240h is aging | Mpa | 7.9 |
| 4 | 200 ℃, elongation at break after 240h is aging | % | 550 |
| 5 | 20 ℃ of volume specific resistances | Ω·m | 9.7×10 12 |
| 6 | Relative permittivity | / | 3.5 |
| 7 | Insulation resistance under the 1000 ℃ * 90min high temperature | MΩ | 1.3 |
Claims (4)
1. environment-friendly type tension high temperature resistance control cable material is characterized in that the weight part of its constitutive material is:
Compound A: paracril 30-40, silicon rubber 20-30, polyacrylic ester 10-20, SBS 10-20, semi-reinforcing hydrocarbon black 1-3, modified Nano powder 40-60, insoluble sulfur 1-3, methyltrimethoxy silane 1.5-2.5, Zinic stearas 1-3, oxidation inhibitor 1035 3-4, two Lauryl Alcohol ester 1-3, magnesium hydroxide 10-20 and dioctyl ester 1-3;
Compound B: vinegar 5-10, linking agent TAIC 2-3, clorafin 1-3, primary ammonium phosphate 5-8 and dimethyl dimercapto 2-ethyl hexyl ethanoate tin 1-3 in paracril 30-50, silicon rubber 20-40, polyacrylic ester 20-30, poly--4-methyl-1-pentene 0.3-0.5, anti-aging agent RD 2-4, the poly-caproic acid.
2. environment-friendly type tension high temperature resistance control cable material according to claim 1 is characterized in that the weight part of its constitutive material is:
Compound A: paracril 35, silicon rubber 25, polyacrylic ester 15, SBS 15, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, insoluble sulfur 2, methyltrimethoxy silane 2, Zinic stearas 2, oxidation inhibitor 1,035 3.5, two Lauryl Alcohol ester 2, magnesium hydroxide 15 and dioctyl ester 2;
Compound B: vinegar 8, linking agent TAIC 2.5, clorafin 2, primary ammonium phosphate 7 and dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2 in paracril 40, silicon rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent RD 3, the poly-caproic acid.
3. the preparation method of an environment-friendly type tension high temperature resistance control cable material as claimed in claim 1 or 2 is characterized in that may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 15-25 minute again, the control temperature was plasticated 3-5 minute discharging at last at 132-140 ℃ under 145-155 ℃.
4. environment-friendly type tension high temperature resistance control cable material according to claim 1 and 2, it is characterized in that: described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 600-700 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210346136.9A CN102911409B (en) | 2012-09-18 | 2012-09-18 | Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof |
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| CN201210346136.9A CN102911409B (en) | 2012-09-18 | 2012-09-18 | Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof |
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| CN102911409A true CN102911409A (en) | 2013-02-06 |
| CN102911409B CN102911409B (en) | 2015-03-11 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103554894A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Environment-friendly type flame-retardant polyurethane rubber cable material |
| CN103554597A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Temperature-resistant and corrosion-resistant modified silicone rubber cable material |
| CN104008800A (en) * | 2014-04-23 | 2014-08-27 | 晶锋集团股份有限公司 | Shock-absorption cable |
| CN104262693A (en) * | 2014-08-29 | 2015-01-07 | 朱其贵 | High-hardness inorganic enhanced rubber material |
| CN105860301A (en) * | 2016-05-18 | 2016-08-17 | 张翔 | Formula and preparation method of oil-proof and anti-ageing cable sheath |
| CN105885433A (en) * | 2016-06-26 | 2016-08-24 | 安徽我要遛遛信息技术有限公司 | Preparation method of high-flame-retardant and fireproof communication cable material |
| CN105885434A (en) * | 2016-06-26 | 2016-08-24 | 安徽我要遛遛信息技术有限公司 | Fireproof and flame-retardant communication cable material and preparation method thereof |
| CN105968546A (en) * | 2016-05-18 | 2016-09-28 | 张翔 | Formula of environment-friendly flame-retardant cable sheath and preparation method thereof |
| CN107151357A (en) * | 2017-04-19 | 2017-09-12 | 安徽华电线缆集团有限公司 | A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS |
| CN107434899A (en) * | 2017-08-31 | 2017-12-05 | 安徽华海特种电缆集团有限公司 | A kind of anti-corrosion heat-resisting tension controls CABLE MATERIALS |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103554894A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Environment-friendly type flame-retardant polyurethane rubber cable material |
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| CN105885434A (en) * | 2016-06-26 | 2016-08-24 | 安徽我要遛遛信息技术有限公司 | Fireproof and flame-retardant communication cable material and preparation method thereof |
| CN107151357A (en) * | 2017-04-19 | 2017-09-12 | 安徽华电线缆集团有限公司 | A kind of floating power station vibration resistance tension UV resistant high-low temperature resistant CABLE MATERIALS |
| CN107434899A (en) * | 2017-08-31 | 2017-12-05 | 安徽华海特种电缆集团有限公司 | A kind of anti-corrosion heat-resisting tension controls CABLE MATERIALS |
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| CN102911409B (en) | 2015-03-11 |
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