CN102664270B - Lithium ion paper battery - Google Patents

Lithium ion paper battery Download PDF

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Publication number
CN102664270B
CN102664270B CN201210106327.8A CN201210106327A CN102664270B CN 102664270 B CN102664270 B CN 102664270B CN 201210106327 A CN201210106327 A CN 201210106327A CN 102664270 B CN102664270 B CN 102664270B
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China
Prior art keywords
paper
carbon nano
battery
conductive paper
lithium ion
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CN201210106327.8A
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Chinese (zh)
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CN102664270A (en
Inventor
孙晓刚
姚军
曹宏辉
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Henan Calway Nano Carbon Materials Co Ltd
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Nanchang University
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Priority to CN201210106327.8A priority Critical patent/CN102664270B/en
Publication of CN102664270A publication Critical patent/CN102664270A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

A lithium ion paper battery contains an anode mass flow electrode (2), a cathode mass flow electrode (6), an anode active material (3), a diaphragm (4), a cathode material (5), an anode tab (1) and a cathode tab (7), and is characterized in that the anode mass flow electrode and the cathode mass flow electrode are carbon nanotube conducting paper. The thickness of the battery provided by the invention is no more than 0.5mm. The battery can be widely applied in the fields such as intelligent card, music greeting card, electronic tag, electronic newspaper, RF Reader (RFID) and the like.

Description

Lithium ion paper battery
Technical field
The present invention relates to a kind of carbon nano tube conductive paper is the ultrathin lithium ion paper battery of the afflux utmost point.
Background technology
Paper battery is ultra-thin battery, can embed in paper, is desirable compact power.Paper battery is once used and chargeable two class batteries.The part of this novel battery comprises electrode, electrolyte and barrier film.This paper battery can fold, and can produce by mode of printing, a kind of novel energy storage device.
Summary of the invention
The present invention relates to a kind of carbon nano-tube of using as the chargeable lithium ion paper battery of the afflux utmost point.
The present invention is achieved by the following technical solutions.
Battery is comprised of the anode collection utmost point (2), the negative pole currect collecting utmost point (6), positive electrode active materials (3), barrier film (4), negative material (5), positive pole ear (1) and negative lug (7).The anode collection utmost point adopts carbon nano tube conductive paper to make, after surface-coated positive electrode active materials, make positive pole, negative pole be take carbon nano tube conductive paper as the afflux utmost point, surface-coated graphite cathode slurry is made negative pole, after vacuumize, by the order of positive pole, barrier film and negative pole, stacks, then with aluminum plastic film, pack envelope in fact, from reserved opening part vacuumizes, inject electrolyte, then sealing.Two lugs remain on package outside, as positive and negative electrode tie point.
The thickness of battery is no more than 0.5mm, and the application of paper battery is very extensive.This battery can be used for the fields such as smart card, music greeting card, electronic tag, electronic newspaper, RF Reader (RFID).
Accompanying drawing explanation
Fig. 1 is the ultrathin lithium ion paper battery of the present invention structural representation.Wherein 1 is positive pole ear, and 2 is the anode collection utmost point, and 3 is positive electrode active materials, and 4 is barrier film, and 5 is negative material, and 6 is the negative pole currect collecting utmost point, and 7 is negative lug.
Embodiment
The present invention will be described further by following examples.
Being prepared as follows of the carbon nano tube conductive paper of embodiment of the present invention: carbon nano-tube and dispersant SDBS are joined in concentration 50% ethanolic solution, every liter of solution adds carbon nano-tube 2-8 gram, SDBS addition 5-10 gram, after ultrasonic 10 minutes, rice paper is launched to put into solution, continue ultrasonic 20 minutes, carbon nanotube adsorption and being penetrated in paper, take out and with twin rollers, to offset after conductive paper vacuumize wholely, be cut into the specification needing.
Embodiment 1.
Then work material of lithium cobalt acid slurry coating is made to positive pole on carbon nano tube conductive paper surface, conductive paper coated graphite cathode size is made negative pole.Between both positive and negative polarity, put into barrier film and be assembled into paper battery, after encapsulation, vacuumize and inject electrolyte LiPF6, then seal.
Embodiment 2.
Then the material lithium manganate slurry coating of positive pole being lived is made positive pole on carbon nano tube conductive paper surface, and conductive paper coated graphite cathode size is made negative pole.Between both positive and negative polarity, put into barrier film and be assembled into paper battery, after encapsulation, vacuumize and inject electrolyte LiPF6, then seal.
Embodiment 3.
Then the material LiFePO 4 of lithium slurry coating of positive pole being lived is made positive pole on carbon nano tube conductive paper surface, and conductive paper coated graphite cathode size is made negative pole.Between both positive and negative polarity, put into barrier film and be assembled into paper battery, after encapsulation, vacuumize and inject electrolyte LiPF6, then seal.

Claims (1)

1. a lithium ion paper battery, comprise the anode collection utmost point (2) of carbon nano tube conductive paper, the negative pole currect collecting utmost point (6) of carbon nano tube conductive paper, positive electrode active materials (3), barrier film (4), negative material (5), positive pole ear (1) and negative lug (7) is characterized in that:
Described carbon nano tube conductive paper preparation method is: carbon nano-tube and dispersant SDBS are joined in concentration 50% ethanolic solution, every liter of solution adds carbon nano-tube 2-8 gram, SDBS addition 5-10 gram, after ultrasonic 10 minutes, rice paper is launched to put into solution, continue ultrasonic 20 minutes, take out and with twin rollers, to offset after conductive paper vacuumize wholely, be cut into the specification needing.
CN201210106327.8A 2012-04-12 2012-04-12 Lithium ion paper battery Active CN102664270B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210106327.8A CN102664270B (en) 2012-04-12 2012-04-12 Lithium ion paper battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210106327.8A CN102664270B (en) 2012-04-12 2012-04-12 Lithium ion paper battery

Publications (2)

Publication Number Publication Date
CN102664270A CN102664270A (en) 2012-09-12
CN102664270B true CN102664270B (en) 2014-10-29

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210106327.8A Active CN102664270B (en) 2012-04-12 2012-04-12 Lithium ion paper battery

Country Status (1)

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CN (1) CN102664270B (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6605385B2 (en) * 2001-03-22 2003-08-12 Wilson Greatbatch Ltd. Electrochemical cell having an electrode with a carbonate additive in the electrode active mixture
KR100669456B1 (en) * 2004-11-26 2007-01-15 삼성에스디아이 주식회사 Electrode for fuel cell, fuel cell comprising the same, and method for preparing the smme
EP2143164A1 (en) * 2007-04-24 2010-01-13 TEMIC Automotive Electric Motors GmbH Electrochemical cell with a non-graphitizable carbon electrode and energy storage assembly

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Publication number Publication date
CN102664270A (en) 2012-09-12

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TR01 Transfer of patent right

Effective date of registration: 20160713

Address after: 330103 Nanchang Changleng Industrial Park in Jiangxi Province Huang Xi Road

Patentee after: Nanchang Weisike Nano Technology Co. Ltd.

Address before: 999 No. 330031 Jiangxi province Nanchang Honggutan University Avenue

Patentee before: Nanchang University

TR01 Transfer of patent right

Effective date of registration: 20180619

Address after: 330052 Nanchang County Xiaolan economic and Technological Development Zone, Nanchang County, Nanchang, Jiangxi, west of Jinsha three road, south of Toyama

Patentee after: Jiangxi Kelaiwei carbon nano materials Co. Ltd.

Address before: 330103 Huangxi Road, mayor's Industrial Park, Nanchang, Jiangxi

Patentee before: Nanchang Weisike Nano Technology Co. Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190626

Address after: 452470 Henan Xinbo Mine Equipment Technology Co., Ltd. (Jiaohe Village, Zhongyue District)

Patentee after: Henan Calway nano carbon materials Co., Ltd.

Address before: 330052 Nanchang County Xiaolan economic and Technological Development Zone, Nanchang County, Nanchang, Jiangxi, west of Jinsha three road, south of Toyama

Patentee before: Jiangxi Kelaiwei carbon nano materials Co. Ltd.

TR01 Transfer of patent right