Ultrathin lithium ion battery
Technical field
The present invention relates to a kind of carbon nano tube conductive paper is the ultrathin lithium ion paper battery of negative pole.
Background technology
Paper battery is ultra-thin battery, can embed in paper, is desirable compact power.Paper battery once uses and chargeable two class batteries.The part of this novel battery comprises electrode, electrolyte and barrier film.This paper battery can fold, and can produce by mode of printing, a kind of novel energy storage device.
Summary of the invention
The present invention relates to a kind of with the chargeable lithium ion paper battery of carbon nano tube conductive paper while as negative pole and the afflux utmost point.The structure of battery is further simplified than common paper battery.
The present invention is achieved by the following technical solutions.
Ultrathin lithium ion battery of the present invention is made up of the anode collection utmost point (1), positive electrode active materials (2), barrier film (3), negative pole (4), negative lug (5) and anodal level ear (6).The anode collection utmost point (1) adopts aluminium foil, and surface-coated positive electrode active materials (2) final vacuum is dry; Negative pole (4) is carbon nano tube conductive paper, after vacuumize, stacks by barrier film (3) and anodal active material face, then packs envelope in fact with aluminum plastic film, after vacuumizing, injects electrolyte, sealing.Two lugs remain on package outside, as positive and negative electrode tie point.
The thickness of ultrathin lithium ion battery of the present invention is no more than 0.5mm, and application is very extensive.Can be used for the fields such as smart card, music greeting card, electronic tag, electronic newspaper, RF Reader (RFID).
Brief description of the drawings
Fig. 1 is the ultrathin lithium ion paper battery of the present invention structural representation.1 is the anode collection utmost point, and 2 is positive electrode active materials, and 3 is barrier film, and 4 is negative pole, 5 negative lug, and 6 is positive pole ear.
Embodiment
The present invention will be described further by following examples.
Being prepared as follows of carbon nano tube conductive paper in described embodiment: carbon nano-tube and dispersant SDBS are joined in concentration 50% ethanolic solution, every liter of solution adds carbon nano-tube 2-8 gram, SDBS addition 5-10 gram, after ultrasonic 10 minutes, rice paper is deployed in solution, continues ultrasonic 20 minutes, carbon nanotube adsorption and being penetrated in paper, after the vacuumize of taking-up conductive paper, offset with twin rollers, be cut into the specification needing.
Embodiment 1.
Material lithium manganate slurry coating alive positive pole is being made to positive pole on the aluminium foil of the anode collection utmost point, and carbon nano tube conductive paper, as negative pole, is put into barrier film and is assembled into paper battery between positive and negative electrode, vacuumizes and inject electrolyte LiPF6 after encapsulation, then seals.
Embodiment 2.
Material ferric lithium phosphate slurry coating alive positive pole is being made to positive pole on the aluminium foil of the anode collection utmost point, carbon nano tube conductive paper is as negative pole, puts into barrier film assembling between positive and negative electrode, vacuumizes and inject electrolyte LiPF6 after encapsulation, then sealing, makes ultra-thin lithium ion paper battery.
Embodiment 3.
Material of lithium cobalt acid slurry coating alive positive pole is being made to positive pole on the aluminium foil of the anode collection utmost point, and carbon nano tube conductive paper, as negative pole, is put into barrier film and is assembled into paper battery between positive and negative electrode, vacuumizes and inject electrolyte LiPF6 after encapsulation, then seals.