CN102637922A - 一种锂空气电池的制备方法 - Google Patents
一种锂空气电池的制备方法 Download PDFInfo
- Publication number
- CN102637922A CN102637922A CN2012101100188A CN201210110018A CN102637922A CN 102637922 A CN102637922 A CN 102637922A CN 2012101100188 A CN2012101100188 A CN 2012101100188A CN 201210110018 A CN201210110018 A CN 201210110018A CN 102637922 A CN102637922 A CN 102637922A
- Authority
- CN
- China
- Prior art keywords
- lithium
- film
- thin film
- preparation
- air battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 22
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000005245 sintering Methods 0.000 claims abstract description 17
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 17
- 238000007731 hot pressing Methods 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000000498 ball milling Methods 0.000 claims abstract description 10
- 239000003792 electrolyte Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000006230 acetylene black Substances 0.000 claims abstract description 7
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 7
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 7
- 230000001681 protective effect Effects 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052582 BN Inorganic materials 0.000 claims abstract description 6
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005030 aluminium foil Substances 0.000 claims abstract description 6
- -1 polyoxyethylene Polymers 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229910005793 GeO 2 Inorganic materials 0.000 claims description 8
- 239000000428 dust Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 101000598921 Homo sapiens Orexin Proteins 0.000 claims description 2
- 101001123245 Homo sapiens Protoporphyrinogen oxidase Proteins 0.000 claims description 2
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 2
- 229910013398 LiN(SO2CF2CF3)2 Inorganic materials 0.000 claims description 2
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 2
- 102100029028 Protoporphyrinogen oxidase Human genes 0.000 claims description 2
- 230000000994 depressogenic effect Effects 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 8
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 239000010409 thin film Substances 0.000 abstract 8
- 238000002156 mixing Methods 0.000 abstract 5
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 abstract 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 238000000227 grinding Methods 0.000 abstract 2
- 238000002844 melting Methods 0.000 abstract 2
- 230000008018 melting Effects 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 239000010408 film Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 229910001220 stainless steel Inorganic materials 0.000 abstract 1
- 239000010935 stainless steel Substances 0.000 abstract 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 13
- 229910001416 lithium ion Inorganic materials 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 238000007599 discharging Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910013872 LiPF Inorganic materials 0.000 description 2
- 101150058243 Lipf gene Proteins 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 1
- 206010036590 Premature baby Diseases 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Hybrid Cells (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210110018.8A CN102637922B (zh) | 2012-04-16 | 2012-04-16 | 一种锂空气电池的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210110018.8A CN102637922B (zh) | 2012-04-16 | 2012-04-16 | 一种锂空气电池的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102637922A true CN102637922A (zh) | 2012-08-15 |
CN102637922B CN102637922B (zh) | 2015-02-11 |
Family
ID=46622224
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210110018.8A Active CN102637922B (zh) | 2012-04-16 | 2012-04-16 | 一种锂空气电池的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102637922B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016141765A1 (zh) * | 2015-03-06 | 2016-09-15 | 中国科学院上海硅酸盐研究所 | 一种基于高致密度固体电解质的新型锂空气电池 |
CN106654172A (zh) * | 2016-12-28 | 2017-05-10 | 中天储能科技有限公司 | 一种多重保护的锂金属负极片 |
CN106910965A (zh) * | 2017-03-24 | 2017-06-30 | 中国人民解放军国防科学技术大学 | 锂空气电池及其制备方法 |
CN111244427A (zh) * | 2020-01-21 | 2020-06-05 | 浙江理工大学 | 应用于锂金属电池的无机GeO2-Li复合负极及其制备方法 |
CN113380980A (zh) * | 2020-02-25 | 2021-09-10 | 株式会社理光 | 电极用混合层,电极,及电化学元件 |
CN114639797A (zh) * | 2021-06-26 | 2022-06-17 | 宁德时代新能源科技股份有限公司 | 负极极片的处理方法、钠金属负极极片及相关装置 |
-
2012
- 2012-04-16 CN CN201210110018.8A patent/CN102637922B/zh active Active
Non-Patent Citations (1)
Title |
---|
BINOD KUMAR, ET AL.: "A Solid-state,Rechargeable,long Cycle Life Lithium-Air Battery", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016141765A1 (zh) * | 2015-03-06 | 2016-09-15 | 中国科学院上海硅酸盐研究所 | 一种基于高致密度固体电解质的新型锂空气电池 |
CN106654172A (zh) * | 2016-12-28 | 2017-05-10 | 中天储能科技有限公司 | 一种多重保护的锂金属负极片 |
CN106910965A (zh) * | 2017-03-24 | 2017-06-30 | 中国人民解放军国防科学技术大学 | 锂空气电池及其制备方法 |
CN106910965B (zh) * | 2017-03-24 | 2019-03-12 | 中国人民解放军国防科学技术大学 | 锂空气电池及其制备方法 |
CN111244427A (zh) * | 2020-01-21 | 2020-06-05 | 浙江理工大学 | 应用于锂金属电池的无机GeO2-Li复合负极及其制备方法 |
CN113380980A (zh) * | 2020-02-25 | 2021-09-10 | 株式会社理光 | 电极用混合层,电极,及电化学元件 |
CN114639797A (zh) * | 2021-06-26 | 2022-06-17 | 宁德时代新能源科技股份有限公司 | 负极极片的处理方法、钠金属负极极片及相关装置 |
CN114639797B (zh) * | 2021-06-26 | 2023-12-29 | 宁德时代新能源科技股份有限公司 | 负极极片的处理方法、钠金属负极极片及制备装置 |
Also Published As
Publication number | Publication date |
---|---|
CN102637922B (zh) | 2015-02-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105355886B (zh) | 一种钠离子电池正极Na2+2xFe2‑x(SO4)3@碳复合材料及其制备方法 | |
CN102637922B (zh) | 一种锂空气电池的制备方法 | |
CN102088086B (zh) | 一种高电压锂离子电池正极制备方法 | |
CN108172903A (zh) | 电解液、钠离子二次电池及其制备方法 | |
CN104600247B (zh) | 一种锂硫电池用硫‑碳复合正极材料及其制备方法 | |
CN108963205A (zh) | 一种新型复合正极及其制备方法和应用的固态锂电池 | |
YANG et al. | Next-generation energy storage technologies and their key electrode materials | |
CN102394305A (zh) | 一种泡沫铜氧化物/铜锂离子电池负极及其制备方法 | |
CN101221853A (zh) | 一种半固态或全固态水系超级电容器 | |
CN104592541B (zh) | 微孔聚苯并咪唑膜及改性聚苯并咪唑为隔膜的锂硫电池 | |
CN104600349B (zh) | 一种高安全性的软包装锂硫电池及其正极材料 | |
CN103855389A (zh) | 三氟化铁/碳复合材料及其制备方法和应用 | |
CN108242540A (zh) | 一种碳包覆磷酸钒钠微球及其制备方法和作为钠离子电池正极材料的应用 | |
CN106920930A (zh) | 一种用于锂硫电池正极的复合材料及其制备方法和应用 | |
CN103296312A (zh) | 一种大功率高倍率磷酸铁锂电池的制备方法 | |
CN104617247A (zh) | 一种串接叠层锂硫电池的制备方法 | |
CN108711636A (zh) | 一种组合电解液型双离子摇椅式二次电池及其制备方法 | |
CN105390683A (zh) | 一种锂离子电池硫基负极材料及其应用 | |
CN103985851A (zh) | 一类钠离子电池正极材料及包括该正极材料的钠离子电池 | |
CN111987348A (zh) | 一种nasicon型固态电池的制备方法 | |
CN111224155A (zh) | 可凝胶体系、凝胶态/固态电解质、锂硫电池及制备方法 | |
CN112151874A (zh) | 一种无集流体的电池及其制备方法 | |
Xiao et al. | Zn-based batteries for energy storage | |
CN104332637B (zh) | 一种贵金属纳米颗粒负载于多孔石墨烯的催化剂制备方法 | |
CN102655250B (zh) | 锂空气电池的固态电解质及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information |
Address after: Nanhai District of Guangdong province water sand 528200 Foshan Bay Industrial Zone Applicant after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Address before: Nanhai District of Guangdong province water sand 528200 Foshan Bay Industrial Zone Applicant before: GUANGDONG BANGPU CYCLE TECHNOLOGY CO.,LTD. Address after: Nanhai District of Guangdong province water sand 528200 Foshan Bay Industrial Zone Applicant after: GUANGDONG BANGPU CYCLE TECHNOLOGY CO.,LTD. Address before: Nanhai District of Guangdong province water sand 528200 Foshan Bay Industrial Zone Applicant before: FOSHAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. |
|
CB02 | Change of applicant information | ||
COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: GUANGDONG BRUNP RECYCLING CO., LTD. TO: GUANGDONG BANGPU CIRCULATION TECHNOLOGY CO., LTD. Free format text: CORRECT: APPLICANT; FROM: FOSHAN BRUNP RECYCLING TECHNOLOGY CO., LTD. TO: GUANGDONG BRUNP RECYCLING CO., LTD. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171114 Address after: 528248 Guangdong province Lishui Town Nanhai District Foshan City Industrial Zone, Sha Co-patentee after: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Address before: Nanhai District of Guangdong province water sand 528200 Foshan Bay Industrial Zone Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
CP02 | Change in the address of a patent holder |
Address after: No.6 Zhixin Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Address before: 528248 Guangdong province Lishui Town Nanhai District Foshan City Industrial Zone, Sha Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. |
|
CP02 | Change in the address of a patent holder |