CN102516845B - Plastic gravure waterborne ink - Google Patents
Plastic gravure waterborne ink Download PDFInfo
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- CN102516845B CN102516845B CN 201110397532 CN201110397532A CN102516845B CN 102516845 B CN102516845 B CN 102516845B CN 201110397532 CN201110397532 CN 201110397532 CN 201110397532 A CN201110397532 A CN 201110397532A CN 102516845 B CN102516845 B CN 102516845B
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Abstract
The invention discloses plastic gravure waterborne ink, which belongs to the technical field of waterborne ink, and is characterized in that: water-soluble synthetic resin is prepared from the following components in percentage by weight: 25-35 parts of polyamide, 7-15 parts of an acrylic monomer, 5-15 parts of soybean oil, 1-6 parts of pentaerythritol, 8-15 pats of maleic anhydride, 0.0-1 part of magnesia, 30-40 parts of rosin and 1-3 parts of a crosslinking agent; water-soluble oleoresin is prepared form the following components in parts by weight: 45-50 parts of water-soluble synthetic resin, 15-20 parts of ethanol, 30-40 parts of water and 3-6 parts of ammonia water; and a plastic gravure waterborne ink product is prepared from the following components in parts by weight: 50-60 parts of water-soluble oleoresin, 10-30 parts of a pigment, 10-20 parts of water and 1-8 parts of an aid consisting of an active agent, a deforming agent, a stabilizing agent, a dispersing agent, a flatting agent and a slipping agent. The plastic gravure waterborne ink is environmentally-friendly, safe, nontoxic, harmless, noncombustible and non-explosive, does not pollute the atmospheric environment, is accordant with the food sanitation safety, and has high adhesive firmness, i.e., high adhesion.
Description
Technical field
The invention belongs to the water color ink technical field, be specifically related to a kind of plastic gravure waterborne ink.
Background technology
Subsequently Social Culture, science and technology, expanding economy, Printing industry develops at a speed unheard of before, and printing ink is the greatest contamination source of Printing industry, world's printing ink output reached 350 all ages ton, annual organic volatile (VOC) discharge amount of pollution caused by printing ink reaches more than 500,000 tons, major polluting atmosphere environment, directly harm humans health.Along with improving constantly of people's environmental consciousness, environmental protection becomes the development topic of 21 century.Therefore research, development and application harm is little, it is few to pollute, so that non-harmful Green Packaging printing material becomes the inevitable requirement of Green Packaging development.Thus, the research and development of water color ink have become the main flow of printing industry.For this reason, people have worked out the technical scheme of many water color inks, as: as notification number: CN101029194, the patent No.: 200610057929.3 " plastic-film water intaglio printing inks "; Notification number: CN 101613472, the patent No.: 200910032093.5 " preparation methods of polyamide resin used for water color ink "; Publication number: CN 101613545, number of patent application: 200910162097.5 " a kind of water color ink for intaglio printing and making methods "; But existing technical scheme all also exists in various degree can not alkali resistant, not anti-acetic acid, non-water resistant, dry slow, low in glossiness, poor adhesive force, water color ink really in plastics intaglio printing industry actual application in batches also fail to appear in the newspapers.
Summary of the invention
The objective of the invention is to provide a kind of plastic gravure waterborne ink, its environmental protection, safe, nontoxic, harmless, do not fire not quick-fried, almost non-volatility organic gas, not pollutant atmosphere; Significantly reduce the printed matter surface residual contaminants, met food sanitation safe; Attachment fastness is strong adhesion, anti-rubbing, and scratch resistant, glossiness are high, and wear resistance is good, and rate of drying is fast; Its production process, the waste gas of discharging from reactor drenches purifying treatment through water, reaches emission standard.
Above-mentioned goal of the invention is achieved through the following technical solutions, a kind of plastic gravure waterborne ink, its main points are the component by following weight proportion: 25～35 parts of polymeric amide, 7～15 parts of Acrylic Acid Monomers, 5～15 parts of soybean oil, 1～6 part of tetramethylolmethane, 8～15 parts of MALEIC ANHYDRIDE, 0.01～1 part, magnesium oxide, 1～3 part of 30～40 parts of rosin, linking agent prepare water-soluble synthetic resin; By the component of following weight proportion: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts, water, 3～6 parts of ammoniacal liquor prepare water soluble resin oil; Component by following weight proportion: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, the auxiliary agent 1-8 part be comprised of promoting agent, defoamer, stablizer, dispersion agent, flow agent, slip(ping)agent makes the plastic gravure waterborne ink product.
Above-mentioned plastic gravure waterborne ink, one of its technical scheme is the component by following weight proportion: 0 part of kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent prepare water-soluble synthetic resin.
Above-mentioned plastic gravure waterborne ink, one of its technical scheme is that polymeric amide is selected unsaturated diamines and MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000.
A kind of method for preparing plastic gravure waterborne ink, its main points are:
A, by the component of following weight proportion: 25～35 parts of polymeric amide, 7～15 parts of Acrylic Acid Monomers, 5～15 parts of soybean oil, 1～6 part of tetramethylolmethane, 8～15 parts of MALEIC ANHYDRIDE, 0.01～1 part, magnesium oxide, 1～3 part of 30～40 parts of rosin, linking agent by reactor at the temperature of 250-270 ℃, stirred, reaction and polymerization, make water-soluble synthetic resin;
B, by the component of following weight proportion: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts, water, 3～6 parts of ammoniacal liquor are stirred, are reacted at the temperature of 70-80 ℃ by reactor, water soluble resin oil is made in emulsification;
C, by the component of following weight proportion: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, the auxiliary agent 1-8 part be comprised of promoting agent, defoamer, stablizer, dispersion agent, flow agent, slip(ping)agent is through disperseing, grind, filter, finally make the plastic gravure waterborne ink product.
The above-mentioned method for preparing plastic gravure waterborne ink, one of its method is by the component of following weight proportion: 0 part of kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent by reactor at the temperature of 260-265 ℃, stirred, reaction and polymerization, make water-soluble synthetic resin.
The above-mentioned method for preparing plastic gravure waterborne ink, one of its method is that polymeric amide is selected unsaturated diamines and MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000.
Beneficial effect of the present invention: its product environmental protection, safe, nontoxic, harmless, do not fire not quick-fried, almost non-volatility organic gas, not pollutant atmosphere; Significantly reduce the printed matter surface residual contaminants, met the food sanitation safe requirement; Attachment fastness is strong adhesion, anti-rubbing, and scratch resistant, glossiness is high, and wear resistance is good, and rate of drying is fast; Its production process, the waste gas of discharging from reactor drenches purifying treatment through water, reaches emission standard.
Embodiment
Be below an embodiment of the present invention-plastic gravure waterborne ink, it presses the component of following weight proportion:
0 part of kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent prepare water-soluble synthetic resin, and polymeric amide is selected unsaturated diamines MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000; By the component of following weight proportion: 48 parts of water-soluble synthetic resins, 17 parts of ethanol, 35 parts, water, 4 parts of ammoniacal liquor prepare water soluble resin oil; By the component of following weight proportion: 55 parts of water soluble resin oil, 20 parts of pigment, 15 parts, water, by promoting agent, defoamer, stablizer, dispersion agent,, 3 parts of the auxiliary agents that form of flow agent, slip(ping)agent make the plastic gravure waterborne ink product.
Be below the present invention-prepare embodiment of the method for plastic gravure waterborne ink, with the present embodiment, produce above-described embodiment product:
A, by the component of following weight proportion: 0 part of kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent by reactor at the temperature of 260-265 ℃, stirred, reaction and polymerization, make water-soluble synthetic resin; Polymeric amide is wherein selected unsaturated diamines MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000.
B, by the component of following weight proportion: 48 parts of water-soluble synthetic resins, 17 parts of ethanol, 35 parts, water, 4 parts of ammoniacal liquor by reactor at the temperature of 70-80 ℃, stirred, reaction, emulsification make water soluble resin oil;
C, by the component of following weight proportion: 55 parts of water soluble resin oil, 20 parts of pigment, 15 parts, water, by promoting agent, defoamer, stablizer, dispersion agent,, 3 parts of the auxiliary agents that form of flow agent, slip(ping)agent, through in high speed dispersor, sand mill equipment, being disperseed, grind, filter, finally make the plastic gravure waterborne ink product.
Above-described embodiment, through " national chemical building material quality surveillance " center " detects, and its examining report is as follows:
Examining report
Claims (4)
1. a plastic gravure waterborne ink, it is characterized in that the component by following weight proportion: 25～35 parts of polymeric amide, 7～15 parts of Acrylic Acid Monomers, 5～15 parts of soybean oil, 1～6 part of tetramethylolmethane, 8～15 parts of MALEIC ANHYDRIDE, 0.01～1 part, magnesium oxide, 1～3 part of 30～40 parts of rosin, linking agent prepare water-soluble synthetic resin; By the component of following weight proportion: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts, water, 3～6 parts of ammoniacal liquor prepare water soluble resin oil; Component by following weight proportion: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, the auxiliary agent 1-8 part be comprised of promoting agent, defoamer, stablizer, dispersion agent, flow agent, slip(ping)agent makes the plastic gravure waterborne ink product; Described polymeric amide is selected unsaturated diamines MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000.
2. plastic gravure waterborne ink according to claim 1, it is characterized in that the component by following weight proportion: polymeric amide is selected unsaturated diamines MALEIC ANHYDRIDE, C
16dimeracid reaction is synthetic, and the molecular weight that band contains unsaturated link(age) is less than 0 part of 10,000 kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent prepare water-soluble synthetic resin.
3. a method for preparing plastic gravure waterborne ink is characterized in that:
A, by the component of following weight proportion: 25～35 parts of polymeric amide, described polymeric amide is selected unsaturated diamines MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the polymeric amide that the molecular weight that band contains unsaturated link(age) is less than 10,000,7～15 parts of Acrylic Acid Monomers, 5～15 parts of soybean oil, 1～6 part of tetramethylolmethane, 8～15 parts of MALEIC ANHYDRIDE, 0.01～1 part, magnesium oxide, 1～3 part of 30～40 parts of rosin, linking agent by reactor at the temperature of 250-270 ℃, stirred, reaction and polymerization, make water-soluble synthetic resin;
B, by the component of following weight proportion: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts, water, 3～6 parts of ammoniacal liquor are stirred, are reacted at the temperature of 70-80 ℃ by reactor, water soluble resin oil is made in emulsification;
C, by the component of following weight proportion: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, the auxiliary agent 1-8 part be comprised of promoting agent, defoamer, stablizer, dispersion agent, flow agent, slip(ping)agent is through disperseing, grind, filter, finally make the plastic gravure waterborne ink product.
4. the method for preparing plastic gravure waterborne ink according to claim 3, it is characterized in that the component of following weight proportion: polymeric amide is selected unsaturated diamines MALEIC ANHYDRIDE, C
16the dimeracid reaction is synthetic, the molecular weight that band contains unsaturated link(age) is less than 0 part of 10,000 kymene, 10 parts of Acrylic Acid Monomers, 10 parts of soybean oil, 2 parts of tetramethylolmethanes, 11 parts of MALEIC ANHYDRIDE, 0.03 part, magnesium oxide, 2 parts of 35 parts of rosin, linking agent by reactor at the temperature of 260-265 ℃, stirred, reaction and polymerization, make water-soluble synthetic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201110397532 CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110397532 CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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| CN102516845A CN102516845A (en) | 2012-06-27 |
| CN102516845B true CN102516845B (en) | 2013-12-18 |
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| CN 201110397532 Active CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031468A (en) * | 2014-06-30 | 2014-09-10 | 柳江县联华纸制品厂 | Water-based gravure ink |
| CN104292966A (en) * | 2014-11-11 | 2015-01-21 | 合肥皖为电气设备工程有限责任公司 | Printing ink with good oxidation resistance and high color and lustrousness as well as preparation method for printing ink |
| CN104804528A (en) * | 2015-03-31 | 2015-07-29 | 安徽省嘉信包装印务有限公司 | Water-based plastic printing ink |
| CN111373003B (en) * | 2017-08-17 | 2022-03-29 | 太阳化学公司 | Water-based inks with high renewable content |
| CN109593398A (en) * | 2017-11-22 | 2019-04-09 | 广东华年颖异新材料科技有限责任公司 | Composite water soluble ink and preparation method thereof is printed in a kind of PE, OPP intaglio plate |
| CN109321031B (en) * | 2018-05-23 | 2021-12-07 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure printing ink for heat shrinkable film and preparation method thereof |
| CN110669379A (en) * | 2019-10-16 | 2020-01-10 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
| CN110643219A (en) * | 2019-11-14 | 2020-01-03 | 云南开放大学 | Gravure ink for printing PET aluminum-plated film |
| CN111334119A (en) * | 2020-04-16 | 2020-06-26 | 佛山市珂宁装饰材料有限公司 | Water-based ink for paper cup |
| CN115477872A (en) * | 2022-10-11 | 2022-12-16 | 深圳市四鼎华悦科技有限公司 | Environment-friendly ink paint for water-based paint |
| CN116376356A (en) * | 2023-05-09 | 2023-07-04 | 张家港市黎明化工有限公司 | Gravure printing ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6734280B1 (en) * | 2000-09-14 | 2004-05-11 | Meadwestvaco Corporation | Rosin-fatty acid vinylic polyamide polymer resins |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
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- 2011-12-05 CN CN 201110397532 patent/CN102516845B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6734280B1 (en) * | 2000-09-14 | 2004-05-11 | Meadwestvaco Corporation | Rosin-fatty acid vinylic polyamide polymer resins |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
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| CN102516845A (en) | 2012-06-27 |
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Effective date of registration: 20191218 Address after: 312000 Paitou Zhen Xin Sheng Cun, Zhuji City, Shaoxing City, Zhejiang Province Patentee after: Zhejiang Weihang New Material Technology Co., Ltd Address before: Yiwu City, Zhejiang province 322000 Chouzhou West Road, Jinhua City, No. 176 (Yiwu wellhand Water Ink Co. Ltd.) Patentee before: Yiwu Weihang Water-based Ink Co., Ltd. |