CN110669379A - Quick-drying water-based ink composition and preparation method and application thereof - Google Patents
Quick-drying water-based ink composition and preparation method and application thereof Download PDFInfo
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- CN110669379A CN110669379A CN201910981656.9A CN201910981656A CN110669379A CN 110669379 A CN110669379 A CN 110669379A CN 201910981656 A CN201910981656 A CN 201910981656A CN 110669379 A CN110669379 A CN 110669379A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/10—Intaglio printing ; Gravure printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a quick-drying water-based ink composition which is characterized by comprising the following components in percentage by mass: 10-15% of colorless inorganic infrared absorption material, 30-50% of water-based emulsion resin, 5-10% of pigment, 1-5% of additive, 5-10% of cosolvent and 20-35% of water. The preparation method comprises the following steps: weighing a colorless inorganic infrared absorption material, water-based emulsion resin, a pigment, an additive, a cosolvent and water according to a mass ratio, uniformly mixing, grinding at a rotating speed of 500-2500 r/min for 2-6 hours, and filtering by using a polyvinylidene fluoride filter membrane with the aperture of less than 10 mu m to obtain the quick-drying water-based ink composition. The ink has high drying speed, and compared with water-based ink without color inorganic infrared absorption materials, the gravure printing speed is greatly improved.
Description
Technical Field
The invention relates to the field of printing ink, in particular to a quick-drying water-based ink composition and a preparation method and application thereof.
Background
The water-based ink solves the problem that organic solvent volatilizes to pollute the atmospheric environment in the printing process of the ink. However, due to the particularity of water molecules, hydrogen bonds exist among the water molecules, association occurs among the molecules, the acting force of the molecular time is increased, the drying speed of the water molecules is slow, the printing, particularly the drying speed of gravure printing ink is influenced, and the production efficiency is greatly influenced.
In order to solve the drying problem of the aqueous ink, various methods such as increasing the drying length of the apparatus, increasing the air volume of the apparatus, decreasing the depth of the pattern of the gravure roll, and increasing the drying speed by adding an external accelerator have been tried. These measures solve the problem of partial drying to some extent, but the effect is still not ideal.
The drying temperature of the general gravure printing equipment is up to 85 ℃, and some printing films deform to influence the printing quality, so that the method for increasing the temperature to improve the printing drying speed is limited by the technology. In addition, since the aqueous printing ink has a limited effective temperature utilization for the temperature field provided by the equipment, it cannot sufficiently absorb the heat generated by the equipment, thereby promoting drying and volatilization of the water.
Disclosure of Invention
In view of the above, an object of the present invention is to provide a quick-drying type aqueous ink composition. The specific technical scheme is as follows:
a quick-drying water-based ink composition comprises the following components in percentage by mass: 10-15% of colorless inorganic infrared absorption material30-50% of water-based emulsion resin, 5-10% of pigment, 1-5% of additive, 5-10% of cosolvent and 20-35% of water; the colorless inorganic infrared absorption material is MxOy、MxCy、MxByWherein M is metal elements Mg, Al, Ce or Zr (metal ions of the metal elements are colorless ions), O is oxygen, C is carbon, B is boron, x is less than or equal to 3, and y is less than or equal to 3.
Preferably, the inorganic infrared absorbing material is magnesium oxide, zirconium oxide or aluminum oxide.
Preferably, the aqueous emulsion resin is aqueous polyurethane, aqueous acrylic resin, aqueous chlorinated polypropylene resin or water-soluble acetate.
Preferably, the pigment is iron red, iron yellow, iron black, iron blue, chromium green, chromium yellow or azo compounds.
Preferably, the additive consists of the following substances in percentage by mass: 20% of film forming additive, 50% of defoaming agent and wetting agent, 10% of thickening agent and 20% of dispersing agent;
more preferably, the film-forming assistant is methyl cyclohexanoate, ethyl cyclohexanoate, dimethyl adipate or diethyl adipate, the defoaming agent and the wetting agent are acetylene glycol, the thickener is ethoxylated alcohol, and the dispersant is phosphate.
Preferably, the cosolvent is ethanol, propanol, butanol, ethylene glycol, propylene glycol methyl ether, propylene glycol ethyl ether, or propylene glycol methyl ethyl ether.
The invention also aims to provide a preparation method of the quick-drying water-based ink composition. The specific technical scheme is as follows:
a preparation method of the quick-drying water-based ink composition comprises the following steps: weighing a colorless inorganic infrared absorption material, water-based emulsion resin, a pigment, an additive, a cosolvent and water according to a mass ratio, uniformly mixing, grinding at a rotating speed of 500-2500 r/min for 2-6 hours, and filtering by using a polyvinylidene fluoride filter membrane with the aperture of less than 10 mu m to obtain the quick-drying water-based ink composition.
The invention also provides application of the quick-drying water-based ink composition. The specific technical scheme is as follows:
the quick-drying water-based ink composition is applied to gravure printing.
Preferably, the specific application method is as follows: the printing substrate is PET film, and the pattern depth of the rolling plate is 30-50 μm.
Has the advantages that:
according to the quick-drying water-based ink composition provided by the invention, the colorless inorganic material capable of absorbing infrared rays is utilized, so that the heat of equipment is effectively absorbed during printing under the condition of not interfering the color mixing of the ink, the quick drying of the water-based ink is accelerated, the gravure printing speed is greatly increased, and the speed is increased from 60m/min to more than 100 m/min.
Detailed Description
Example 1
The ingredients of the aqueous quick-drying ink composition of this example are shown in table 1, and the preparation method is as follows:
1. colorless inorganic infrared absorbing material (magnesium oxide), waterborne emulsion resin (waterborne polyurethane), pigment (iron blue), additive, cosolvent (ethanol) and water are weighed according to the mixture ratio in the table 1. Wherein, the additive (added in the form of an additive package) comprises the following components: 20% of methyl cyclohexanoate (film-forming aid), 50% of acetylene glycol (defoaming agent and wetting agent), 10% of ethoxylated alcohol (thickening agent) and 20% of phosphate (dispersing agent).
2. Stirring the raw materials for 3 hours by using a mixer at 2500rpm, uniformly stirring, and then transferring into a high-speed grinding dispersion machine for grinding at the rotating speed of 1500r/min for 4 hours; then, the obtained mixture was put into a disposable plastic syringe and filtered using a polyvinylidene fluoride filter having a pore size of 5 μm, thereby obtaining the quick-drying type aqueous ink composition.
Table 1 example 1 formulation (mass%,%)
| Examples 1 to 1 | Examples 1 to 2 | Examples 1 to 3 | Examples 1 to 4 | Examples 1 to 5 | |
| Magnesium oxide | 10 | 10 | 15 | 15 | 10 |
| Polyurethane | 30 | 50 | 30 | 35 | 40 |
| Ethanol | 10 | 5 | 10 | 10 | 5 |
| Additive package | 5 | 5 | 5 | 1 | 2 |
| Pigment (I) | 10 | 10 | 5 | 10 | 10 |
| Water (W) | 35 | 20 | 35 | 29 | 33 |
Example 2
The ingredients of the aqueous quick-drying ink composition of this example are shown in table 2, and the preparation method is as follows:
1. colorless inorganic infrared absorbing material (alumina), water-based emulsion resin (water-based acrylic resin), pigment (iron blue), additive, cosolvent (ethanol) and water are weighed according to the mixture ratio in the table 2. Wherein, the additive (added in the form of an additive package) comprises the following components: 20% of methyl cyclohexanoate (film-forming aid), 50% of acetylene glycol (defoaming agent and wetting agent), 10% of ethoxylated alcohol (thickening agent) and 20% of phosphate (dispersing agent).
2. Stirring the raw materials for 3 hours by using a mixer at 2500rpm, uniformly stirring, and then transferring into a high-speed grinding dispersion machine for grinding at the rotating speed of 1500r/min for 4 hours; then, the obtained mixture was put into a disposable plastic syringe and filtered using a polyvinylidene fluoride filter having a pore size of 5 μm, thereby obtaining the quick-drying type aqueous ink composition.
Table 2 example 2 formulation (mass%,%)
| Example 2-1 | Examples 2 to 2 | Examples 2 to 3 | Examples 2 to 4 | Examples 2 to 5 | |
| Alumina oxide | 10 | 10 | 15 | 15 | 10 |
| Acrylic resin | 30 | 50 | 30 | 35 | 40 |
| Ethanol | 10 | 5 | 10 | 10 | 5 |
| Additive package | 5 | 5 | 5 | 1 | 2 |
| Pigment (I) | 10 | 10 | 5 | 10 | 10 |
| Water (W) | 35 | 20 | 35 | 29 | 33 |
Example 3
The ingredients of the aqueous quick-drying ink composition of this example are shown in table 3, and the preparation method is as follows:
1. colorless inorganic infrared absorbing material (zirconia), aqueous emulsion resin (aqueous chlorinated polypropylene), pigment (iron blue), additive, cosolvent (ethanol) and water were weighed according to the mixture ratio in table 3. Wherein, the additive (added in the form of an additive package) comprises the following components: 20% of methyl cyclohexanoate (film-forming aid), 50% of acetylene glycol (defoaming agent and wetting agent), 10% of ethoxylated alcohol (thickening agent) and 20% of phosphate (dispersing agent).
2. Stirring the raw materials for 3 hours by using a mixer at 2500rpm, uniformly stirring, and then transferring into a high-speed grinding dispersion machine for grinding at the rotating speed of 1500r/min for 4 hours; then, the obtained mixture was put into a disposable plastic syringe and filtered using a polyvinylidene fluoride filter having a pore size of 5 μm, thereby obtaining the quick-drying type aqueous ink composition.
Table 3 formulation (mass%)
| Example 3-1 | Examples 3 to 2 | Examples 3 to 3 | Examples 3 to 4 | Examples 3 to 5 | |
| Zirconium oxide | 10 | 10 | 15 | 15 | 10 |
| Chlorinated polypropylene | 30 | 50 | 30 | 35 | 40 |
| Ethanol | 10 | 5 | 10 | 10 | 5 |
| Additive package | 5 | 5 | 5 | 1 | 2 |
| Pigment (I) | 10 | 10 | 5 | 10 | 10 |
| Water (W) | 35 | 20 | 35 | 29 | 33 |
Example 4 (comparative example)
The ingredients of the aqueous quick-drying ink composition of this comparative example are shown in table 4, and the preparation method is as follows:
1. the water-based emulsion resin (water-based polyurethane), the pigment (iron blue), the additive, the cosolvent (ethanol) and water are weighed according to the mixture ratio in the table 4. Wherein, the additive (added in the form of an additive package) comprises the following components: 20% of methyl cyclohexanoate (film-forming aid), 50% of acetylene glycol (defoaming agent and wetting agent), 10% of ethoxylated alcohol (thickening agent) and 20% of phosphate (dispersing agent).
2. Stirring the raw materials for 3 hours by using a mixer at 2500rpm, uniformly stirring, and then transferring into a high-speed grinding dispersion machine for grinding at the rotating speed of 1500r/min for 4 hours; then, the obtained mixture was put into a disposable plastic syringe and filtered using a polyvinylidene fluoride filter having a pore size of 5 μm, thereby obtaining the quick-drying type aqueous ink composition.
Table 4 example 4 formulation (mass%,%)
| Example 4-1 | Example 4 to 2 | Examples 4 to 3 | Examples 4 to 4 | Examples 4 to 5 | |
| Polyurethane | 30 | 50 | 35 | 45 | 40 |
| Ethanol | 15 | 10 | 15 | 10 | 15 |
| Additive package | 5 | 5 | 5 | 1 | 2 |
| Pigment (I) | 15 | 10 | 15 | 10 | 10 |
| Water (W) | 35 | 25 | 30 | 34 | 33 |
All of the prepared aqueous ink compositions in the above examples were tested, and then printed on a commercially available gravure printing machine (the ink was printed on a substrate, the printing substrate used was a PET film, and the pattern depth of the clich é was 40 μm), to form images, respectively, to thereby obtain prints for evaluation. The test results are shown in table 5 below:
TABLE 5 printing speeds of Water-based inks obtained in examples and comparative examples
| Gravure printing speed (m/min) | |
| Examples 1 to 1 | 110 |
| Examples 1 to 2 | 95 |
| Examples 1 to 3 | 120 |
| Examples 1 to 4 | 100 |
| Examples 1 to 5 | 90 |
| Example 2-1 | 118 |
| Examples 2 to 2 | 105 |
| Examples 2 to 3 | 98 |
| Examples 2 to 4 | 110 |
| Examples 2 to 5 | 99 |
| Example 3-1 | 93 |
| Examples 3 to 2 | 113 |
| Examples 3 to 3 | 105 |
| Examples 3 to 4 | 108 |
| Examples 3 to 5 | 112 |
| Comparative example 4-1 | 60 |
| Comparative examples 4 to 2 | 55 |
| Comparative examples 4 to 3 | 54 |
| Comparative examples 4 to 4 | 63 |
| Comparative examples 4 to 5 | 65 |
The water-based ink composition provided by the invention has excellent drying property in gravure printing, and the drying speed is greatly improved. The gravure printing speed (up to 120m/min) of the aqueous inks obtained in examples 1 to 3 was greatly improved compared to that of the aqueous ink obtained in comparative example (up to 65 m/min).
Claims (10)
1. The quick-drying water-based ink composition is characterized by comprising the following components in percentage by mass: 10-15% of colorless inorganic infrared absorption material, 30-50% of water-based emulsified resin, 5-10% of pigment, 1-5% of additive, 5-10% of cosolvent and 20-35% of water; the colorless inorganic infrared absorption material is MxOy、MxCy、MxByAny one or a mixture of more than two of the above in any mass ratio, wherein M is metal element Mg, Al, Ce or Zr, O is oxygen element, and C is carbon elementElement, B is boron element, x ≦ 3, y ≦ 3.
2. The quick-drying aqueous ink composition according to claim 1, wherein the inorganic infrared absorbing material is magnesium oxide, zirconium oxide, or aluminum oxide.
3. The quick-drying aqueous ink composition according to claim 1, wherein the aqueous emulsion resin is aqueous polyurethane, aqueous acrylic resin, aqueous chlorinated polypropylene resin, or water-soluble acetate.
4. The quick-drying aqueous ink composition according to claim 1, wherein the pigment is iron red, iron yellow, iron black, iron blue, chromium green, chromium yellow, or an azo compound.
5. The quick-drying water-based ink composition according to claim 1, wherein the additive comprises the following substances in percentage by mass: 20% of film forming additive, 50% of defoaming agent and wetting agent, 10% of thickening agent and 20% of dispersing agent.
6. The quick-drying aqueous ink composition according to claim 5, wherein the coalescing agent is methyl cyclohexanoate, ethyl cyclohexanoate, dimethyl adipate, or diethyl adipate, the defoaming agent and wetting agent is acetylene glycol, the thickener is an ethoxylated alcohol, and the dispersant is a phosphate ester.
7. The quick-drying aqueous ink composition according to claim 1, wherein the cosolvent is ethanol, propanol, butanol, ethylene glycol, propylene glycol methyl ether, propylene glycol ethyl ether, or propylene glycol methyl ethyl ether.
8. A method for producing a quick-drying aqueous ink composition according to any one of claims 1 to 7, comprising the steps of: weighing a colorless inorganic infrared absorption material, water-based emulsion resin, a pigment, an additive, a cosolvent and water according to a mass ratio, uniformly mixing, grinding at a rotating speed of 500-2500 r/min for 2-6 hours, and filtering by using a polyvinylidene fluoride filter membrane with the aperture of less than 10 mu m to obtain the quick-drying water-based ink composition.
9. The quick-drying type aqueous ink composition according to any one of claims 1 to 7, which is applied to gravure printing.
10. The method according to claim 9, wherein the printing substrate is a PET film, and the embossing depth of the embossing plate is 30 to 50 μm.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112126276A (en) * | 2020-09-21 | 2020-12-25 | 台昌彩艺工业股份有限公司 | Water-based ink and printing film comprising same |
| CN114940841A (en) * | 2022-07-13 | 2022-08-26 | 山东盛驰新材料有限公司 | Pigment for water-based ink and preparation method thereof |
| CN115595013A (en) * | 2022-10-27 | 2023-01-13 | 张红生（Cn） | Quick-drying water-based ink and preparation method thereof |
| US11623997B2 (en) | 2020-09-14 | 2023-04-11 | Tai Chang Colorful Press Industrial Co., Ltd. | Water-based ink and printing film comprising the same |
| CN116635490A (en) * | 2020-12-21 | 2023-08-22 | 爱克发-格法特公司 | NIR absorbing inkjet ink and method of recording |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN102516845A (en) * | 2011-12-05 | 2012-06-27 | 义乌市伟航水性油墨有限公司 | Plastic gravure waterborne ink |
| CN102952431A (en) * | 2012-11-20 | 2013-03-06 | 义乌市伟航水性油墨有限公司 | Cigarette tipping paper water-based ink and preparation method |
| CN103183985A (en) * | 2013-03-18 | 2013-07-03 | 福建省利得彩环保科技有限公司 | Water-based printing ink and application thereof |
| CN103555065A (en) * | 2013-11-18 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Quick-drying type water-based ink-jet ink and preparation method thereof |
| CN108641472A (en) * | 2018-04-09 | 2018-10-12 | 天津科技大学 | General plastic intaglio printing water-based ink and preparation method |
-
2019
- 2019-10-16 CN CN201910981656.9A patent/CN110669379A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN102516845A (en) * | 2011-12-05 | 2012-06-27 | 义乌市伟航水性油墨有限公司 | Plastic gravure waterborne ink |
| CN102952431A (en) * | 2012-11-20 | 2013-03-06 | 义乌市伟航水性油墨有限公司 | Cigarette tipping paper water-based ink and preparation method |
| CN103183985A (en) * | 2013-03-18 | 2013-07-03 | 福建省利得彩环保科技有限公司 | Water-based printing ink and application thereof |
| CN103555065A (en) * | 2013-11-18 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Quick-drying type water-based ink-jet ink and preparation method thereof |
| CN108641472A (en) * | 2018-04-09 | 2018-10-12 | 天津科技大学 | General plastic intaglio printing water-based ink and preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 郭学益: "《高纯金属材料》", 31 January 2010, 冶金工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11623997B2 (en) | 2020-09-14 | 2023-04-11 | Tai Chang Colorful Press Industrial Co., Ltd. | Water-based ink and printing film comprising the same |
| CN112126276A (en) * | 2020-09-21 | 2020-12-25 | 台昌彩艺工业股份有限公司 | Water-based ink and printing film comprising same |
| CN116635490A (en) * | 2020-12-21 | 2023-08-22 | 爱克发-格法特公司 | NIR absorbing inkjet ink and method of recording |
| CN114940841A (en) * | 2022-07-13 | 2022-08-26 | 山东盛驰新材料有限公司 | Pigment for water-based ink and preparation method thereof |
| CN115595013A (en) * | 2022-10-27 | 2023-01-13 | 张红生（Cn） | Quick-drying water-based ink and preparation method thereof |
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