CN102378647A - 使用双金属催化剂由乙酸制备乙醇或乙酸乙酯的方法 - Google Patents

使用双金属催化剂由乙酸制备乙醇或乙酸乙酯的方法 Download PDF

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Publication number
CN102378647A
CN102378647A CN2010800062309A CN201080006230A CN102378647A CN 102378647 A CN102378647 A CN 102378647A CN 2010800062309 A CN2010800062309 A CN 2010800062309A CN 201080006230 A CN201080006230 A CN 201080006230A CN 102378647 A CN102378647 A CN 102378647A
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China
Prior art keywords
catalyst
hydrogenation
carrier
acetate
modification agent
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Pending
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CN2010800062309A
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English (en)
Chinese (zh)
Inventor
V·J·约翰斯顿
L·陈
B·F·金米奇
J·T·查普曼
J·H·津克
H·魏纳
J·L·波茨
R·耶夫蒂奇
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Celanese International Corp
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Celanese International Corp
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Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese International Corp filed Critical Celanese International Corp
Publication of CN102378647A publication Critical patent/CN102378647A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2010800062309A 2009-10-26 2010-02-02 使用双金属催化剂由乙酸制备乙醇或乙酸乙酯的方法 Pending CN102378647A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
US12/588,727 2009-10-26
PCT/US2010/022954 WO2011056248A2 (fr) 2009-10-26 2010-02-02 Procédés pour fabriquer de l'éthanol ou de l'acétate d'éthyle à partir d'acide acétique en utilisant des catalyseurs bimétalliques

Publications (1)

Publication Number Publication Date
CN102378647A true CN102378647A (zh) 2012-03-14

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CN2010800062309A Pending CN102378647A (zh) 2009-10-26 2010-02-02 使用双金属催化剂由乙酸制备乙醇或乙酸乙酯的方法

Country Status (3)

Country Link
EP (1) EP2493611A2 (fr)
CN (1) CN102378647A (fr)
WO (1) WO2011056248A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358752A (zh) * 2018-04-18 2018-08-03 肖锦 一种乙酸加氢制乙醇的方法
CN111298780A (zh) * 2018-12-12 2020-06-19 国家能源投资集团有限责任公司 复合粘结剂和载体及其制备方法和应用以及乙酸加氢制乙醇催化剂及其应用

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8211821B2 (en) * 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6294703B1 (en) * 1998-06-22 2001-09-25 Mitsubishi Chemical Company Process for the manufacture of cycloalkyldimethanol
CN1549851A (zh) * 2001-07-18 2004-11-24 ���з����о���˾ 氢化反应和脱氢反应方法及用于该方法的催化剂

Family Cites Families (12)

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US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
US4399305A (en) 1982-10-18 1983-08-16 Union Carbide Corporation Production of ethylene by the pyrolysis of ethyl acetate
FR2570370B1 (fr) 1984-09-17 1987-03-20 Atochem Procede de fabrication d'ethylene a partir d'esters ethyliques
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6294703B1 (en) * 1998-06-22 2001-09-25 Mitsubishi Chemical Company Process for the manufacture of cycloalkyldimethanol
CN1549851A (zh) * 2001-07-18 2004-11-24 ���з����о���˾ 氢化反应和脱氢反应方法及用于该方法的催化剂

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
RAFAEL ALCALA,ET AL.: "Experimental and DFT Studies of the Conversion of Ethanol and Acetic Acid on PtSn-Based Catalysts", 《J.PHYS.CHEM.B》 *
朱洪法: "《催化剂手册》", 31 December 2008 *
陈性勇等: "《基本有机化工生产及工艺》", 31 December 1985 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358752A (zh) * 2018-04-18 2018-08-03 肖锦 一种乙酸加氢制乙醇的方法
CN111298780A (zh) * 2018-12-12 2020-06-19 国家能源投资集团有限责任公司 复合粘结剂和载体及其制备方法和应用以及乙酸加氢制乙醇催化剂及其应用

Also Published As

Publication number Publication date
WO2011056248A2 (fr) 2011-05-12
EP2493611A2 (fr) 2012-09-05
WO2011056248A3 (fr) 2011-11-17

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