CN102326534A - Method for preparing chlorine-containing disinfectant fluid - Google Patents
Method for preparing chlorine-containing disinfectant fluid Download PDFInfo
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- CN102326534A CN102326534A CN2010102265009A CN201010226500A CN102326534A CN 102326534 A CN102326534 A CN 102326534A CN 2010102265009 A CN2010102265009 A CN 2010102265009A CN 201010226500 A CN201010226500 A CN 201010226500A CN 102326534 A CN102326534 A CN 102326534A
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- chlorine
- containing disinfectant
- water
- polyvinylpyrrolidone
- ammonium sulfate
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Abstract
The invention provides a method for preparing a chlorine-containing disinfectant fluid. The chlorine-containing disinfectant fluid comprises a compound complexing agent, a chlorine-containing disinfectant and a stabilizer, wherein the compound complexing agent is a mixture of nonylphenol polyoxyethylene ether ammonium sulfate and polyvinylpyrrolidone; the chlorine-containing disinfectant comprises sodium hypochlorite, trichloroisocyanuric acid and sodium dichloroisocyanurate; and the stabilizer is amino sulfanilic acid. The components are dissolved and diluted in water according to the proportion specified in specifications and the method. The prepared chlorine-containing disinfectant fluid has high disinfecting capability and stable effective chlorine, and can be widely applied in the fields of indoor air disinfection, skin disinfectants and the like.
Description
Technical field
The present invention relates to environmental protection and health care disinfection technology field, specifically be meant a kind of preparation method of chlorine-containing disinfecting water.
Technical background
Chlorine-containing disinfectant is the most widely used a kind of disinfectant, comprises polytype, like clorox, chlorine ammonia-T, sym-closene, sodium dichloro cyanurate etc.Because chlorine-containing disinfectant has cheapness, advantage such as efficient, is widely used in drinking water disinfection, environment disinfected, fields such as health care sterilization, be use in the world at present one type of disinfectant the most widely.
Chlorine-containing disinfectant mainly contains two kinds of formulations: solid dosage forms and liquid dosage form.Solid dosage forms most species, available chlorine content are generally in the 20-90% scope.Liquid dosage form is less, and main component is a clorox, available chlorine content 5-12%.
The sterilization of dissimilar chlorine-containing disinfectants is similar basically with sterilizing mechanisms, and these disinfectants dissolve or dilute the back and produce the hypochlorous acid molecule in water, generates active chlorine (also claiming available chlorine) and carries out disinfection.
At present, the greatest problem of chlorine-containing disinfectant existence is:
(1) chlorine-containing disinfectant is after dissolving or dilution, and available chlorine is unstable in the aqueous solution, and especially under neutrality and acid medium condition, the half life period generally has only tens hours.Therefore, chlorine-containing disinfectant can not long preservation after dissolving and dilution, is inconvenient to use.
(2) the hypochlorous acid molecule decomposes in water and discharges gas Cl
2, gas Cl
2Contaminated environment not only, but also can cause shed tears, cough, chafe and mucous membrane, severe patient causes poisoning, is choked to death and dies.When working concentration was big, the people was unsuitable on the scene.Therefore, chlorine-containing disinfectant generally should not be applied to disinfection of indoor air.
(3) chlorine-containing disinfectant is a kind of high effect disinfectants, and stronger excitant is arranged, and generally should not be applied to the sterilization of human body skin and mucous membrane.
For above-mentioned reasons, the application of chlorine-containing disinfectant is very limited.Though, developed some quite more stable chlorine-containing disinfection liquids in recent years, all be that hypochlorous sodium solution is main sterilization composition.Its stability is similar with traditional clorox, has both made under lucifuge, sealing condition, in 1 year about available chlorine decline 20-35%.But after being diluted to working concentration (is 100-1000mg/L like effective cl concn), available chlorine is unstable equally, and the half life period of available chlorine generally has only several days.In recent years, the report of complexing chlorhexidine-containing disinfectant is arranged also, but available chlorine stability or undesirable, deposited 78 days in the darkroom, its available chlorine percent of loss is 62-67%, and obvious gas Cl is in use arranged
2Taste.
Therefore, if can solve the stability problem of chlorine-containing disinfectant aqueous solution available chlorine, alleviate its excitant; With the range of application that further enlarges chlorine-containing disinfectant; Can chlorine-containing disinfectant be applied to fields such as disinfection of indoor air, skin degerming, market prospects are wide, and to the protection environment; Human body health has great importance, and social benefit is far-reaching.
Chinese invention patent CN101006782A discloses a kind of preparation method of stable high potential chlorine-containing disinfection liquid, and the complexing agent of employing is the alkyl amino sulfonic compound.The shortcoming of this method is: the disinfecting power of the thimerosal of being prepared is influenced greatly by the pH value of system, and the pH value of system increases after the several times dilution, and disinfecting power obviously descends; Stationary phase is generally less than 1 year; Alkyl amino sulfonic compound large usage quantity has stimulation to skin, influences its range of application.
Summary of the invention
The objective of the invention is provides a kind of preparation method of chlorine-containing disinfecting water in order to solve the above-mentioned deficiency that existing chlorine-containing disinfection liquid and chlorine-containing disinfectant exist.This method is used a kind of compound complex agent, a kind of chlorine-containing disinfectant, a kind of stabilizing agent and water by certain proportioning preparation.Not only the available chlorine retention period is long for the chlorine-containing disinfecting water of being prepared, and has stronger disinfecting power.
Compound complex agent according to the invention is the mixture of NPE ammonium sulfate and polyvinylpyrrolidone, and both weight ratios are: polyoxyethylene ether ammonium sulfate: polyvinylpyrrolidone is 4: 1-1: 2, preferred 2: 1-1: 1.Stabilizing agent according to the invention is a sulfamic acid amine; The not special restriction of said chlorine-containing disinfectant; Can be chlorine-containing disinfectants such as clorox, calcium hypochlorite, Efficacious Disinfeitant, sym-closene, sodium dichloro cyanurate, but preferred available chlorine content be higher, water-soluble better, the malicious lower sodium dichloro cyanurate of property.These three kinds of components unit are by weight counted: NPE ammonium sulfate+polyvinylpyrrolidone 30-40%, and chlorine-containing disinfectant (by available chlorine) 20-25%, sulfamic acid amine 30-40%.
The not special restriction of institute of the present invention water can be adopted distilled water, pure water or running water, preferred pure water.
The preparation method of a kind of chlorine-containing disinfecting water according to the invention; Its compound method is with after polyvinylpyrrolidone mixes by a certain percentage with NPE ammonium sulfate; In 45-50 ℃ water, dissolve; Add chlorine-containing disinfectant then, add stabilizing agent again, be diluted with water to needed concentration at last.These four kinds of components unit are by weight counted: complexing agent 0.05-2.0%; Chlorine-containing disinfectant (in available chlorine content) 0.02-0.6%; Stabilizing agent 0.05-2.0%; Water 95-99%.The effective chlorine density of the chlorine-containing disinfecting water of preparation is 0.02%-0.6% (but not receiving this concentration limit).
Principle of the present invention is: the good dispersion that NPE ammonium sulfate and polyvinylpyrrolidone all have and water-soluble; They dissolve the back in water can form the indefinite form complex compound with the hypochlorous acid molecule that the chlorine-containing disinfectant hydrolysis forms, and both mix the back and have the obvious synergistic effect for this complexing; The adding of sulfamic acid amine can be stablized this indefinite form complex compound more, makes that available chlorine is highly stable in the aqueous solution; In use, this chloro-complex that contains discharges free hypochlorous acid molecule gradually, thereby carries out disinfection and sterilization.
Chlorine-containing disinfecting water of the present invention compared with prior art has following advantage and effect:
(1) chlorine-containing disinfecting water of the present invention has basically no the chlorine flavor, and environmentally safe is easy to accept;
(2) chlorine-containing disinfecting water available chlorine of the present invention is stable, and the half life period was more than 1.5 years, in preserving and using, need not lucifuge and sealing, the convenient use;
(3) a little less than the excitant of chlorine-containing disinfecting water of the present invention to skin, the disinfective action longer duration can be applicable to the sterilization of skin and mucous membrane.
Because chlorine-containing disinfecting water of the present invention has overcome the technical problem of traditional chlorine-containing disinfection liquid or disinfectant existence, can be applicable to skin, mucous membrane sterilization, people and animals fields such as disinfection of indoor air on the scene are arranged.
Embodiment
Below in conjunction with embodiment, the present invention is done to specify further:
Embodiment 1: take by weighing NPE ammonium sulfate 15g and polyvinylpyrrolidone 10g; Be dissolved in 500 milliliters of temperature and be in 50 ℃ the pure water; Add sodium dichloro cyanurate 9g (containing available chlorine 63%) then, treat to add sulfamic acid amine 10g again after it fully dissolves; Be diluted to 1 liter with pure water at last.The effective chlorine density of the chlorine-containing disinfecting water of preparation is 0.53%.Preserved 180 days sealing under the condition of lucifuge not, effective chlorine density is 0.49%.
Embodiment 2: take by weighing NPE ammonium sulfate 3g and polyvinylpyrrolidone 2g; Being dissolved in 200 milliliters of temperature is in 50 ℃ of pure water; Add sodium dichloro cyanurate 2g (containing available chlorine 63%) then; Treat to add sulfamic acid amine 2g again after it fully dissolves, last, be diluted to 1 liter with pure water.The effective chlorine density of the chlorine-containing disinfecting water of preparation is 0.11%.Preserved 180 days sealing under the condition of lucifuge not, effective chlorine density is 0.11%.
Embodiment 3: take by weighing NPE ammonium sulfate 0.5g, polyvinylpyrrolidone 0.4g; Being dissolved in 100 milliliters of temperature is in 50 ℃ of pure water; Add sodium dichloro cyanurate 0.4g (containing available chlorine 63%) then; Treat to add sulfamic acid amine 0.5g again after it fully dissolves, be diluted to 1 liter with pure water at last.The effective chlorine density of the chlorine-containing disinfecting water of preparation is 0.021%.Preserved 180 days sealing under the condition of lucifuge not, effective chlorine density is 0.020%.
Claims (3)
1. the preparation method of a chlorine-containing disinfecting water is characterized in that by a kind of compound complex agent, chlorine-containing disinfectant, stabilizing agent and water by certain weight ratio preparation.Said compound complex agent is the mixture of NPE ammonium sulfate and polyvinylpyrrolidone; Said stabilizing agent is a sulfamic acid amine.The weight proportion of these four kinds of components is: compound complex agent 0.05-2.0%; Chlorine-containing disinfectant (in available chlorine content) 0.02-0.6%; Stabilizing agent 0.05-2.0%; Water 95-99%.
2. compound complex agent according to claim 1 is the mixture of NPE ammonium sulfate and polyvinylpyrrolidone, and both weight proportions are polyoxyethylene ether ammonium sulfate: polyvinylpyrrolidone is 4: 1-1: 2, preferred 2: 1-1: 1.
3. the preparation method of a kind of chlorine-containing disinfecting water according to claim 1; Its preparation method is with after polyvinylpyrrolidone mixes by a certain percentage with NPE ammonium sulfate; In 45-50 ℃ water, dissolve; Add chlorine-containing disinfectant then, treat to add stabilizing agent again after it fully dissolves, be diluted with water to needed concentration at last.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104430577A (en) * | 2014-11-13 | 2015-03-25 | 蚌埠金宇印刷物资有限公司 | Air disinfectant and preparation method thereof |
CN107467070A (en) * | 2017-08-23 | 2017-12-15 | 太仓优活生物技术有限公司 | A kind of sterilized articles therefrom having no toxic side effect |
CN107691471A (en) * | 2017-09-29 | 2018-02-16 | 广州闪电生物科技有限公司 | Antiseptic solution and sterilization method |
CN112825851A (en) * | 2021-01-11 | 2021-05-25 | 山东安捷高科消毒科技有限公司 | High-stability 84 disinfectant with corrosion inhibition effect and preparation method thereof |
CN113598168A (en) * | 2021-08-18 | 2021-11-05 | 首都医科大学附属北京朝阳医院 | Stabilizer, preparation method thereof and application thereof in chlorine-containing disinfectant |
CN114868762A (en) * | 2022-04-23 | 2022-08-09 | 杭州西子卫生消毒药械有限公司 | Composite intermediate-effect disinfectant and preparation method thereof |
CN115152756A (en) * | 2022-06-07 | 2022-10-11 | 沈阳化工大学 | Clathrate compound disinfection tablet and preparation method thereof |
CN116058383A (en) * | 2023-03-29 | 2023-05-05 | 山东利尔康医疗科技股份有限公司 | High-level disinfection wet tissue and preparation method thereof |
-
2010
- 2010-07-14 CN CN2010102265009A patent/CN102326534A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104430577A (en) * | 2014-11-13 | 2015-03-25 | 蚌埠金宇印刷物资有限公司 | Air disinfectant and preparation method thereof |
CN107467070A (en) * | 2017-08-23 | 2017-12-15 | 太仓优活生物技术有限公司 | A kind of sterilized articles therefrom having no toxic side effect |
CN107691471A (en) * | 2017-09-29 | 2018-02-16 | 广州闪电生物科技有限公司 | Antiseptic solution and sterilization method |
CN112825851A (en) * | 2021-01-11 | 2021-05-25 | 山东安捷高科消毒科技有限公司 | High-stability 84 disinfectant with corrosion inhibition effect and preparation method thereof |
CN112825851B (en) * | 2021-01-11 | 2022-03-25 | 山东安捷高科消毒科技有限公司 | High-stability 84 disinfectant with corrosion inhibition effect and preparation method thereof |
CN113598168A (en) * | 2021-08-18 | 2021-11-05 | 首都医科大学附属北京朝阳医院 | Stabilizer, preparation method thereof and application thereof in chlorine-containing disinfectant |
CN114868762A (en) * | 2022-04-23 | 2022-08-09 | 杭州西子卫生消毒药械有限公司 | Composite intermediate-effect disinfectant and preparation method thereof |
CN115152756A (en) * | 2022-06-07 | 2022-10-11 | 沈阳化工大学 | Clathrate compound disinfection tablet and preparation method thereof |
CN115152756B (en) * | 2022-06-07 | 2024-01-16 | 沈阳化工大学 | Clathrate disinfection tablet and preparation method thereof |
CN116058383A (en) * | 2023-03-29 | 2023-05-05 | 山东利尔康医疗科技股份有限公司 | High-level disinfection wet tissue and preparation method thereof |
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