CN102181196A - Water-in-water colorful stone simulated paint - Google Patents
Water-in-water colorful stone simulated paint Download PDFInfo
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- CN102181196A CN102181196A CN 201110025163 CN201110025163A CN102181196A CN 102181196 A CN102181196 A CN 102181196A CN 201110025163 CN201110025163 CN 201110025163 CN 201110025163 A CN201110025163 A CN 201110025163A CN 102181196 A CN102181196 A CN 102181196A
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Abstract
The invention provides a novel water-in-water colorful stone simulated paint, and belongs to the technical field of coating preparation. In the process of preparing a dispersion phase, a surface treated calcium carbonate is added, and the dispersion phase prepared from the calcium carbonate can be obviously separated from the aqueous phase; the protective glue component mainly consists of cellulose, water, water-soluble resin, defoaming agent, dispersant and preservative; by adding the protective glue component, the dispersion phase is coated by the protective glue, so that the prepared colorful paint has good stability and the dispersion phase is obviously separated from the dispersion medium; and the aqueous dispersion medium mainly consists of water, organic bentonite, aluminum sulfate and magnesium chloride. On the process design, secondary reaction of base paints is adopted to improve the viscosity of the base paints and the strength of cohesion; and on the formula design, protective solution with polarity is added among the base paints of different colors, and granules are uniformly distributed in the protective solution under mechanical action.
Description
Technical field
The present invention relates to a kind of house paint or coating for internal and external wall, the profound color stone similar paint of specifically a kind of water-in-water type.
Background technology
Along with growth in the living standard, people have been not only to have solved the basic living problems to the pursuit of life, but rise to the spirit and the pursuit of goods and materials, simultaneously, people begin to embody style simple, individual character gradually on the finishing of interior exterior wall, and the construction of profound color coating material is fairly simple, can satisfy the demands of consumers in the personalization of product and variation, has therefore also attracted people's attention gradually.
Last century the eighties, profound color coating material was once fashionable for a time in China, but contained organic solvents such as toluene, dimethylbenzene because of it, producing, all can discharging a large amount of poisonous organic solvents in the construction process, environment and HUMAN HEALTH had all been constituted great threat.
Along with people improve the cognition degree of environmental protection, the use of solvent in coating reduced day by day, development is the developing direction of the low pollutionization of coating as the water-borne coatings of medium replace organic solvent with water, the raising of the application percentage that profound color coating material of while is fitted up in interior exterior wall, the water Bao Shui of novel environment-friendly is to be disperse phase with various emulsion paints, with water is external phase, so it is nontoxic, tasteless, pollution-free, and have performances such as good water tolerance, abrasion resistance and fire prevention, be current ideal finishing material therefore.
Traditional profound color coating material all is based on oil-in-water-type or water-in-oil, because environmental protection becomes more and more important, the application of solvent in coating is day by day reduced, so the profound color coating material of water-in-water type arises at the historic moment.The profound color system component of water-in-water type is made up of dispersion medium and disperse phase two portions, different with the profound color coating material of oil-in-water-type is that two portions are water-based system, when disperse phase mixes in dispersion medium, no matter be original disperse phase and dispersion medium, still both mix post-reacted resultant, have only seldom dissolving each other or mutual miscible fluid of degree.Thereby form comparatively clearly two-phase, one mutually for containing dispersing of pigments phase drop, and one is the dispersion medium aqueous solution mutually.So nontoxic, tasteless, pollution-free, and have performances such as good water tolerance, abrasion resistance and fire prevention, be current ideal house decorative material.The patent of the profound color coating material of initial water-in-water type is from the Japan and the U.S., and Japanese Patent is that the coating with polyvinyl alcohol makes it gelation with the borax substance reaction earlier and is being distributed to aqueous phase then.The patent of the U.S. then is that multiple material such as polyvinyl alcohol, casein is added in the polymer emulsion, then it is being dispersed in the aqueous solution that contains jello.
The existing in the market profound color coating material of a spot of water-in-water type product is sold; but it is relatively poor that ubiquity package stability; after storage after a while; decorative pattern particle wherein can sink; have one deck protection glue solution above and be cloudy state, present significantly and the same color of the color grain of decorative pattern.And the force of cohesion of decorative pattern particle is not enough, after the storage of for some time, has greatly changed thereby the decorative pattern particle becomes the broken profound color coating material that spraying is come out easily.Therefore be badly in need of the profound color coating material of a kind of novel water-in-water type of research, solve problems such as current ubiquitous package stability is relatively poor, decorative pattern particle force of cohesion is relatively poor.
Summary of the invention
The purpose of this invention is to provide the profound color stone similar paint of a kind of water-in-water type.
The objective of the invention is to realize in the following manner, preparation technology comprises 1) preparation of water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 40-45 part, film coalescence aid: 1-2 part, titanium dioxide: 4-6 part, lime carbonate: 4-6 part, dispersion agent: 0.4-0.6 part, defoamer: 0.25-0.35 part, thickening material: 0.1-0.2 part, ammoniacal liquor: 0.02 part-0.03 part, sanitas: 0.2-0.3 part, water: 35-45 part;
Preparation technology: in dispersion tank, add film coalescence aid, titanium dioxide, lime carbonate, dispersion agent, thickening material, ammoniacal liquor and sanitas and water successively by formula ratio, mix, and be ground to suitable fineness by sand mill, add synthetic resin emulsion and defoamer at last, regulate viscosity with thickening material, viscosity controller promptly makes the water-dispersion phase at 50-500CPS;
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 65-75 part; Dispersion agent: 1-1.5 part; Defoamer: 0.5-1 part; Mierocrystalline cellulose: 0.5-1 part; Sanitas: 0.1-0.2 part; Water: 25-35 part;
Preparation technology is as follows:
In stirred pot, add entry, dispersion agent, defoamer, Mierocrystalline cellulose, sanitas successively by formula rate, treat that Mierocrystalline cellulose dissolves fully, after stirring, add water soluble resin at last, stir, promptly make the protection sol solution;
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 90-95 part; Organobentonite: 0.5-2 part; Tai-Ace S 150: 3-6 part; Magnesium chloride: 0.5-2 part;
Preparation technology is as follows:
Press formula rate, earlier with Tai-Ace S 150, magnesium chloride water dissolution, organobentonite is added be stirred to glue in the entry again, Tai-Ace S 150, the magnesium chloride that adds after dissolving stirs then, promptly makes water dispersion medium;
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 25-35 part; Protection glue: 20-25 part; Water dispersion medium: 40-60 part;
The preparation method is as follows:
Formula rate is added water dispersion medium in the mixing tank, add water-dispersion phase and protection glue while stirring,, slowly stir then, obtain the profound color coating material of water-in-water type of the surperficial gel of shades of colour blended dispersed particle at last with screen cloth cutting not of uniform size;
In the above-mentioned prescription
Defoamer is: the W-090, the W-092 that adopt the modest company of moral to produce, the mixture of one or more in the Defoamer 121 SN-345 products that Haichuan Company is produced;
Dispersion agent is: adopt WP-5040, WP-5060 that Qingzhou shellfish specialization worker company limited produces, one or more the mixture in the WP-19 product;
Thickening material is: use alkali swelling type thickening material, adopt ATW-60, ATW-2000 that Bei Te company produces, one or more the mixture in the DC-8 product;
Synthetic resin emulsion: the GK-503 that adopts Qingzhou shellfish specialization worker company limited to produce, GK-504, the mixture of one or more in the GK-507 product;
Film coalescence aid is: the mixture of one or more in alcohol ester 12, Diethylene Glycol butyl ether, the butyl glycol ether;
Sanitas is: SPX is the original-pack a kind of raw material of U.S. Sol company.
Excellent effect of the present invention is: profound firework line coating for internal and external wall is a kind of coating that once just can obtain multiple color and decorative pattern with common spraying method.Profound firework line coating for internal and external wall can not only give buildings appearance attractive in appearance, but also has the protection building masonry wall and prolong function such as buildings work-ing life.Raising along with living standards of the people, people require also more and more to pay attention to the decoration in house, original low-grade coating variety can not satisfy the demand of people to the flawless finish material far away, the appearance of profound firework line coating for internal and external wall, changed China's coating for internal and external wall kind dullness, of low grade, the situation of decorative effect difference.And with its decorative pattern gracefulness, three-dimensional puzzled strong, rich color, unique and good water-fast, alkaline-resisting of decorative effect, excellent performances such as washability become the high-grade interior and exterior decoration material of the most attractive at present and competitive power.
Embodiment
Embodiment 1:
Preparation technology comprises 1) preparation of water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 40 parts, film coalescence aid: 1 part, titanium dioxide: 4 parts, lime carbonate: 4 parts, dispersion agent: 0.4 part, defoamer: 0.25 part, thickening material: 0.1 part, ammoniacal liquor: 0.022, sanitas: 0.2 part, water: 35 parts;
Preparation technology: in dispersion tank, add film coalescence aid, titanium dioxide, lime carbonate, dispersion agent, thickening material, ammoniacal liquor and sanitas and water successively by formula ratio, mix, and be ground to suitable fineness by sand mill, add synthetic resin emulsion and defoamer at last, regulate viscosity with thickening material, viscosity controller promptly makes the water-dispersion phase at 50-500CPS;
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 65 parts; Dispersion agent: 1 part; Defoamer: 0.5 part; Mierocrystalline cellulose: 0.5-part; Sanitas: 0.1 part; Water: 25 parts;
Preparation technology is as follows:
In stirred pot, add entry, dispersion agent, defoamer, Mierocrystalline cellulose, sanitas successively by formula rate, treat that Mierocrystalline cellulose dissolves fully, after stirring, add water soluble resin at last, stir, promptly make the protection sol solution;
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 90 parts; Organobentonite: 0.5 part; Tai-Ace S 150: 3 parts; Magnesium chloride: 0.5 part;
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 25 parts; Protection glue: 20 parts; Water dispersion medium: 40 parts;
The preparation method is as follows:
Formula rate is added water dispersion medium in the mixing tank, add water-dispersion phase and protection glue while stirring,, slowly stir then, obtain the profound color coating material of water-in-water type of the surperficial gel of shades of colour blended dispersed particle at last with screen cloth cutting not of uniform size;
Embodiment 2
Preparation technology comprises 1) preparation of water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 45 parts, film coalescence aid: 2 parts, titanium dioxide: 6 parts, lime carbonate: 6 parts, dispersion agent: 0.6 part, defoamer: 0.35 part, thickening material: 0.2 part, ammoniacal liquor: 0.02 part, sanitas: 0.3 part, water: 45 parts;
Preparation technology is identical with embodiment 1.
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 75 parts; Dispersion agent: 1.5 parts; Defoamer: 1 part; Mierocrystalline cellulose: 1 part; Sanitas: 0.2 part; Water: 35 parts;
Preparation technology is identical with embodiment 1.
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 95 parts; Organobentonite: 2 parts; Tai-Ace S 150: 6 parts; Magnesium chloride: 2 parts;
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 35 parts; Protection glue: 25 parts; Water dispersion medium: 60 parts;
Preparation technology is identical with embodiment 1.
Embodiment 3
Technology comprises: the preparation of 1) water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 44 parts, film coalescence aid: 1.8 parts, titanium dioxide: 5.5 parts, lime carbonate: 5.5 parts, dispersion agent: 0.55 part, defoamer: 0.32 part, thickening material: 0.18 part, ammoniacal liquor: 0.03 part, sanitas: 0.28 part, water: 43 parts;
Preparation technology is identical with embodiment 1.
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 72 parts; Dispersion agent: 1.3 parts; Defoamer: 0.9 part; Mierocrystalline cellulose: 0.8 part; Sanitas: 0.19 part; Water: 32 parts
Preparation technology is identical with embodiment 1.
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 94 parts; Organobentonite: 0.8 part; Tai-Ace S 150: 5 parts; Magnesium chloride: 0.8 part;
Preparation technology is identical with embodiment 1.
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 33 parts; Protection glue: 24 parts; Water dispersion medium: 55 parts.
Preparation technology is identical with embodiment 1.
Embodiment 4
Technology comprises: the preparation of 1) water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 42 parts, film coalescence aid: 1.1 parts, titanium dioxide: 4.5 parts, lime carbonate: 4.5 parts, dispersion agent: 0.42 part, defoamer: 0.27 part, thickening material: 0.12 part, ammoniacal liquor: 0.025 part, sanitas: 0.22 part, water: 38 parts;
Preparation technology is identical with embodiment 1.
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 68 parts; Dispersion agent: 1.1 parts; Defoamer: 0.6 part; Mierocrystalline cellulose: 0.6 part; Sanitas: 0.15 part; Water: 28 parts;
Preparation technology is identical with embodiment 1.
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 91 parts; Organobentonite: 0.6 part; Tai-Ace S 150: 4 parts; Magnesium chloride: 0.6 part;
Preparation technology is identical with embodiment 1.
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 29 parts; Protection glue: 22 parts; Water dispersion medium: 45 parts.
Preparation technology is identical with embodiment 1.
Embodiment 5
Technology comprises: the preparation of 1) water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 43 parts, film coalescence aid: 1.6 parts, titanium dioxide: 5 parts, lime carbonate: 5 parts, dispersion agent: 0.5 part, defoamer: 0.3 part, thickening material: 0.16 part, ammoniacal liquor: 0.028 part, sanitas: 0.27 part, water: 40 parts;
Preparation technology is identical with embodiment 1.
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 70 parts; Dispersion agent: 1.2 parts; Defoamer: 0.8 part; Mierocrystalline cellulose: 0.7 part; Sanitas: 0.18 part; Water: 30 parts;
Preparation technology is identical with embodiment 1.
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 92 parts; Organobentonite: 0.7 part; Tai-Ace S 150: 4.5 parts; Magnesium chloride: 0.7 part;
Preparation technology is identical with embodiment 1.
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 30 parts; Protection glue: 23 parts; Water dispersion medium: 50 parts.
Preparation technology is identical with embodiment 1.
The allotment of color is to mix colours according to requirement of client or according to the requirement of real marmorean color, and mixing colours is current techique.
Claims (3)
1. the profound color stone similar paint of water-in-water type is characterized in that comprising: the preparation of 1) water-dispersion phase; 2) preparation of protection glue; 3) water dispersion medium preparation and the 4) preparation of the profound color stone similar paint of water-in-water type: wherein:
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 40-45 part, film coalescence aid: 1-2 part, titanium dioxide: 4-6 part, lime carbonate: 4-6 part, dispersion agent: 0.4-0.6 part, defoamer: 0.25-0.35 part, thickening material: 0.1-0.2 part, ammoniacal liquor: 0.02 part-0.03 part, sanitas: 0.2-0.3 part, water: 35-45 part;
Preparation technology: in dispersion tank, add film coalescence aid, titanium dioxide, lime carbonate, dispersion agent, thickening material, ammoniacal liquor, sanitas and water successively by formula ratio, mix, and be ground to＜fineness of 50um by sand mill, add synthetic resin emulsion and defoamer at last, regulate viscosity with thickening material, it is mutually standby that viscosity controller promptly makes water-dispersion at 50-500CPS;
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 65-75 part; Dispersion agent: 1-1.5 part; Defoamer: 0.5-1 part; Mierocrystalline cellulose: 0.5-1 part; Sanitas: 0.1-0.2 part; Water: 25-35 part;
Preparation technology is as follows:
Add entry, dispersion agent, defoamer, Mierocrystalline cellulose, sanitas successively by formula rate in stirred pot, treat that Mierocrystalline cellulose dissolves fully, after stirring, add water soluble resin at last, stir, it is standby promptly to make the protection sol solution;
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 90-95 part; Organobentonite: 0.5-2 part; Tai-Ace S 150: 3-6 part; Magnesium chloride: 0.5-2 part;
Preparation technology is as follows:
Press formula rate, earlier with Tai-Ace S 150, magnesium chloride water dissolution, organobentonite is added be stirred to glue in the entry again, Tai-Ace S 150, the magnesium chloride that adds after dissolving stirs then, and it is standby promptly to make water dispersion medium;
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water dispersion medium: 40-60 part; Water-dispersion phase: 25-35 part; Protection glue: 20-25 part;
The preparation method is as follows:
Formula rate is added water dispersion medium in the mixing tank, add water-dispersion phase and protection glue while stirring,, slowly stir then, obtain the profound color coating material of water-in-water type of the surperficial gel of shades of colour blended dispersed particle at last with the screen cloth cutting;
In the above-mentioned prescription
Defoamer is: the W-090, the W-092 that adopt the modest company of moral to produce, the mixture of one or more in the Defoamer 121 SN-345 products that Haichuan Company is produced;
Dispersion agent is: adopt WP-5040, WP-5060 that Qingzhou shellfish specialization worker company limited produces, one or more the mixture in the WP-19 product;
Thickening material is: use alkali swelling type thickening material, adopt ATW-60, ATW-2000 that Bei Te company produces, one or more the mixture in the DC-8 product;
Synthetic resin emulsion: the GK-503 that adopts Qingzhou shellfish specialization worker company limited to produce, GK-504, the mixture of one or more in the GK-507 product;
Film coalescence aid is: the mixture of one or more in alcohol ester 12, Diethylene Glycol butyl ether, the butyl glycol ether;
Sanitas is: SPX is the mixture of the original-pack two kinds of raw materials of U.S. Sol company.
2. the profound color stone similar paint of water-in-water type according to claim 1: it is characterized in that,
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 42-44 part, film coalescence aid: 1.1-1.8 part, titanium dioxide: 4.5-5.5 part, lime carbonate: 4.5-5.5 part, dispersion agent: 0.42-0.55 part, defoamer: 0.27-0.32 part, thickening material: 0.12-0.18 part, ammoniacal liquor: 0.022 part-0.028 part, sanitas: 0.22-0.28 part, water: 38-43 part;
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 68-72 part; Dispersion agent: 1.1-1.3 part; Defoamer: 0.6-0.9 part; Mierocrystalline cellulose: 0.6-0.8 part; Sanitas: 0.15-0.19 part; Water: 28-32 part
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 91-94 part; Organobentonite: 0.6-0.8 part; Tai-Ace S 150: 4-5 part; Magnesium chloride: 0.6-0.8 part;
4) water-dispersion phase: 29-33 part; Protection glue: 22-24 part; Water dispersion medium: 45-55 part.
3. the profound color stone similar paint of water-in-water type according to claim 1: it is characterized in that,
1) water-dispersion is to be made by following materials of weight proportions mutually:
Synthetic resin emulsion: 43 parts, film coalescence aid: 1.6 parts, titanium dioxide: 5 parts, lime carbonate: 5 parts, dispersion agent: 0.5 part, defoamer: 0.3 part, thickening material: 0.16 part, ammoniacal liquor: 0.025 part, sanitas: 0.27 part, water: 40 parts;
2) protection glue is to be made by following materials of weight proportions:
Synthetic resin emulsion: 70 parts; Dispersion agent: 1.2 parts; Defoamer: 0.8 part; Mierocrystalline cellulose: 0.7 part; Sanitas: 0.18 part; Water: 30 parts
3) water dispersion medium is to be made by following materials of weight proportions:
Water: 92 parts; Organobentonite: 0.7 part; Tai-Ace S 150: 4.5 parts; Magnesium chloride: 0.7 part;
4) the profound color stone similar paint of water-in-water type is to be made by following materials of weight proportions:
Water-dispersion phase: 30 parts; Protection glue: 23 parts; Water dispersion medium: 50 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110025163 CN102181196A (en) | 2011-01-24 | 2011-01-24 | Water-in-water colorful stone simulated paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110025163 CN102181196A (en) | 2011-01-24 | 2011-01-24 | Water-in-water colorful stone simulated paint |
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| CN102181196A true CN102181196A (en) | 2011-09-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN 201110025163 Pending CN102181196A (en) | 2011-01-24 | 2011-01-24 | Water-in-water colorful stone simulated paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104513039A (en) * | 2013-09-29 | 2015-04-15 | 立邦涂料（中国）有限公司 | Aqueous imitation stone coating, coat and product |
| CN104559789A (en) * | 2015-01-23 | 2015-04-29 | 安徽本雅明涂料有限公司 | Water-in-water sand-containing multicolor paint and manufacturing method thereof |
| CN105440811A (en) * | 2014-09-02 | 2016-03-30 | 立邦涂料（中国）有限公司 | Aqueous liquid simulation wallpaper coating, coating layer and product |
| CN108102500A (en) * | 2017-12-31 | 2018-06-01 | 长沙善道新材料科技有限公司 | A kind of aqueous imitation marble paint and preparation method thereof |
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| WO2004096925A1 (en) * | 2003-04-25 | 2004-11-11 | Eco Chemical, Inc. | Marking and removing turf lines method and composition |
| CN101343436A (en) * | 2008-08-06 | 2009-01-14 | 窦俊英 | Novel water-covering water gorgeous paint and preparation thereof |
| CN101845260A (en) * | 2010-03-10 | 2010-09-29 | 杭州德尔福涂料有限公司 | Full-aqueous multicolour paint and preparation method thereof |
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2011
- 2011-01-24 CN CN 201110025163 patent/CN102181196A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004096925A1 (en) * | 2003-04-25 | 2004-11-11 | Eco Chemical, Inc. | Marking and removing turf lines method and composition |
| CN101343436A (en) * | 2008-08-06 | 2009-01-14 | 窦俊英 | Novel water-covering water gorgeous paint and preparation thereof |
| CN101845260A (en) * | 2010-03-10 | 2010-09-29 | 杭州德尔福涂料有限公司 | Full-aqueous multicolour paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104513039A (en) * | 2013-09-29 | 2015-04-15 | 立邦涂料（中国）有限公司 | Aqueous imitation stone coating, coat and product |
| CN104513039B (en) * | 2013-09-29 | 2017-01-18 | 立邦涂料（中国）有限公司 | Aqueous imitation stone coating, coat and product |
| CN105440811A (en) * | 2014-09-02 | 2016-03-30 | 立邦涂料（中国）有限公司 | Aqueous liquid simulation wallpaper coating, coating layer and product |
| CN104559789A (en) * | 2015-01-23 | 2015-04-29 | 安徽本雅明涂料有限公司 | Water-in-water sand-containing multicolor paint and manufacturing method thereof |
| CN108102500A (en) * | 2017-12-31 | 2018-06-01 | 长沙善道新材料科技有限公司 | A kind of aqueous imitation marble paint and preparation method thereof |
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Application publication date: 20110914 |