CN102151930A - Dissimilar metal material brazing method - Google Patents

Dissimilar metal material brazing method Download PDF

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Publication number
CN102151930A
CN102151930A CN2011100663699A CN201110066369A CN102151930A CN 102151930 A CN102151930 A CN 102151930A CN 2011100663699 A CN2011100663699 A CN 2011100663699A CN 201110066369 A CN201110066369 A CN 201110066369A CN 102151930 A CN102151930 A CN 102151930A
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mother metal
welding
metal
solder
base metal
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CN102151930B (en
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李明雨
计红军
肖勇
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Shenzhen Graduate School Harbin Institute of Technology
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Shenzhen Graduate School Harbin Institute of Technology
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Abstract

The invention discloses a dissimilar metal material brazing method. The dissimilar metal material includes a first base metal and a second base metal different from each other. The method comprises the following steps: clamping the first base metal on a telescopic fixture and clamping the second base metal on a fixed fixture in such a manner that the welding surfaces of the first base metal and the second base metal face to each other, and placing a solder between the welding surfaces; applying a pre-pressure on the first base metal relative to the welding surface; locally rapidly heating the welding parts of the first base metal and the second base metal to a preset temperature and keeping the temperature; increasing the pre-pressure to a welding pressure; applying ultrasonic vibration to the first base metal relative to the welding surfaces by an ultrasonic compression bar; and continuously keeping the temperature and the pressure after the ultrasonic vibration completes, stopping heating, and further keeping the pressure until the welding parts are cooled. The method can improve the strength of a brazed joint of dissimilar metal materials by reducing the formation of laminar brittle intermetallic compounds and the like.

Description

Method for welding between different metal materials
Technical field
The present invention relates to the method for welding between a kind of metal material, especially a kind of method for welding that welds between different metal materials such as copper or copper alloy and aluminum or aluminum alloy, stainless steel and aluminum or aluminum alloy, stainless steel and the magnesium alloy that is applicable to.
Background technology
In recent years, the copper valency is constantly soaring both at home and abroad, and this has brought very big cost pressure for manufacturings such as refrigeration, electronics, automobile.The main using value of copper is that this material has good conduction, thermal conductivity.Because copper storage capacity in the earth's crust is less, the continuous rise of copper valency is not ccontaining doubtful, therefore seek a kind of performance and copper material near and the relatively low material of price substitute the common starting point that copper material becomes enterprise's saving cost.The conduction and the heat conductivility of aluminum metal are only second to copper, replace the serviceability that copper material can't be crossed the earth effect product in a lot of occasions with aluminium.With regard to production cost, the market price of aluminium is about the l/3 of copper, and the density of aluminium also has only the l/3 of copper, and the aluminum member material cost is 1/9 of an identical copper member.Therefore, people adopt the technology of " with aluminium for copper " to reduce production costs in a lot of industries.
Yet, the use of copper material is still irreplaceable in some members, as the device for drying and filtering in the refrigeration member, capillary, compressor three pipes etc., still will adopt copper pipe to make, in refrigeration pipe, not only aluminum pipe is arranged but also copper pipe is arranged like this, must bring copper aluminum pipe connectivity problem.In addition, because there is the thicker oxide-film of one deck on the aluminium surface, so in some aluminum electronic devices, occur contact heating that causes greatly because of device contacts resistance and the creep failure that causes material easily; Especially also can make the aluminum contact produce discharge spark under the high voltage situation and cause the accident, therefore common way all is at the aluminium material surface soldering copper, reduces contact resistance.
Copper aluminium dissimilar materials interconnection technique there has been more research both at home and abroad, but never very big breakthrough on albronze bonding strength and reduction link cost.The difficult point that copper aluminium dissimilar materials connects is: the fusing point of copper and aluminium differs the thermal conductivity of big (near 400 ℃), copper and is about 3 times of aluminium, their linear expansion coefficient and melting heat very big-difference is also arranged, and direct connection will produce very big welding stress; In addition, more main is that when copper aluminium dissimilar materials connected, the mutual diffusion of atom caused CuAl easily between heterogeneous mother metal 2The formation of compound between the stratiform brittle metal, the thickness of this brittle compound layer will greatly influence the mechanical property of joint when surpassing certain value (10um).Therefore, alleviate the difference of physical property between heterogeneous mother metal as far as possible, and the formation of compound between less stratiform brittle metal, be the key that obtains high-quality copper and aluminium welding joint.
Use more copper aluminium dissimilar materials method of attachment at present and mainly contain friction butt welding, friction stir welding and soldering.The butt welding that wherein rubs is mainly used in the butt joint of pipe or club-shaped material, and friction stir welding is mainly used in the connection of board-like material, these two kinds of methods all belong to the category of Solid-State Welding, equipment is had relatively high expectations, technological parameter is strict, and the production that is not suitable for particular surroundings or complicated joint also is not suitable for the welding of slim member.In addition, Solid-State Welding plumb joint intensity is subjected to CuAl easily 2The thickness of compound layer and hardness influence between brittle metal, joint fatigue durability and air-tightness are relatively poor.
Soldering is used comparatively general in the connection of dissimilar materials, and for example copper aluminium soldering is compared with Solid-State Welding, and the difference of physical property between heterogeneous mother metal has been alleviated in the use of solder in the soldering, and the endurance load-carrying ability of joint is stronger; In addition, it is low that soldering also has a production cost, strong to the adaptability of complex part, strength of joint and air-tightness height, and numerous advantages such as the online production ability is strong, thereby be a kind of very promising copper aluminium interconnection technique.Common method for welding mainly contains vacuum brazing, gas brazing and induction brazing etc.Wherein vacuum brazing is generally carried out under high vacuum environment, and this method has higher requirements to the cleanliness factor of mother metal linkage interface, is not suitable for complicated joint welding and production in enormous quantities.In addition, the vacuum brazing temperature retention time is longer, forms thicker CuAl easily at the copper material interface 2Layer, thus worsened joint performance.Gas brazing and induction brazing all are the modes that adopts local heat, and the heat affected area is little, and weld interval is short, uses comparatively general.Yet these two kinds of method for welding need cooperate brazing flux to use, and to remove the oxide-film of mother metal epidermis, promote the wetting expansion of solder on the mother metal surface.The use of brazing flux has increased the cost of welding on the one hand; In joint, produce pore on the other hand easily; And the brazing flux residue in the postwelding weld seam reduces Joint Reliability if clean out the electrochemical corrosion that also causes joint easily.In addition, gas brazing and induction brazing can not be avoided stratiform CuAl fully 2Generation, have only strict control firing rate and welding temperature could reduce CuAl as far as possible 2The thickness of layer.Same for the soldering between stainless steel and aluminum or aluminum alloy, stainless steel and the magnesium alloy, owing to form compounds affect welding quality between the stratiform brittle metal easily, existing method for welding difficulty has realized the welding of high-efficiency high-quality.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, the invention provides the method for welding between a kind of different metal materials, the inventive method is applicable to the welding between copper alloy or Cu-base composites and aluminium alloy or aluminum matrix composite, stainless steel and aluminium alloy or the dissimilar materials such as aluminum matrix composite, stainless steel and magnesium alloy or magnesium base composite material.
The technical solution used in the present invention is: the method for welding between a kind of different metal materials, described different metal materials comprise first mother metal and second mother metal that material is different, and described method for welding may further comprise the steps:
A, first mother metal is installed on the scalable anchor clamps, second mother metal is installed on the stationary fixture, and solder side first mother metal, second mother metal is placed between the described solder side relatively and with solder;
B, apply the precompression with respect to described solder side on first mother metal, the precompression size is 0.01MPa~0.5MPa;
C, to the welding position local heat of described first mother metal and second mother metal, heat temperature raising speed is 5 ℃/s~50 ℃/s, is incubated after reaching design temperature;
D, described precompression is risen to welding pressure, described welding pressure is higher than described precompression, and more than or equal to 0.1MPa smaller or equal to 3MPa;
E, apply ultrasonic vibration with respect to described second mother metal with excess sound pressure pole pair first mother metal;
Follow-up continuation of insurance temperature pressurize 1~60 second is finished in f, ultrasonic vibration, stops heating then and continues pressurize to the cooling of described welding position.
Preferably, described first mother metal is that copper alloy or Cu-base composites, second mother metal are aluminium alloy or aluminum matrix composite; Perhaps described first mother metal is that aluminium alloy or aluminum matrix composite, second mother metal are copper alloy or Cu-base composites; Perhaps described first mother metal is that stainless steel, second mother metal are selected from a kind of in aluminium alloy, aluminum matrix composite, magnesium alloy, the magnesium base composite material; Perhaps first mother metal is selected from a kind of in aluminium alloy, aluminum matrix composite, magnesium alloy, the magnesium base composite material, and second mother metal is a stainless steel.
Preferably, the mode of heating among the described step c is intermediate frequency or high-frequency induction heating.Certainly mode of heating also can be selected flame heat, LASER HEATING or hot blast heating for use.
Preferably, the design temperature among the described step c is higher than 5 ℃~100 ℃ of the solidus temperatures of described solder or is higher than 0 ℃~80 ℃ of the liquidus temperatures of described solder.Design temperature among the more preferably described step c is higher than 10 ℃~50 ℃ of the solidus temperatures of described solder or is higher than 5 ℃~30 ℃ of the liquidus temperatures of described solder.
Preferably, the frequency of ultrasonic vibration is that 10kHz~40kHz, amplitude are 5 μ m~25 μ m among the described step e, and the ultrasonic vibration time is 0.5~60 second.
Preferably, to rise to welding pressure be when step c eddy-current heating reaches design temperature to described steps d or carry out afterwards with precompression, perhaps begins steps d at step c eddy-current heating during near design temperature precompression is risen to welding pressure.
Preferably, precompression is risen to welding pressure begins step e after 0~5 second the ultrasonic vibration that applies in steps d.Preferably, described mother metal is tubulose, bar-shaped or strip.Wherein the welding point mode can be butt joint, overlap joint or corner connection
As further improvement, described first mother metal, when second mother metal is tubulose, further comprising the steps of before described step a:
a 0, with the end mouth of pipe enlarging of reamer with second mother metal, according to the same angle in described enlarging inclined-plane one end of first mother metal being processed a chamfering, the enlarging inclined-plane of the fillet surface of described first mother metal and second mother metal is a solder side; Perhaps, with the end mouth of pipe enlarging of reamer with first mother metal, according to the same angle in described enlarging inclined-plane one end of second mother metal being processed a chamfering, the enlarging inclined-plane of described first mother metal and the fillet surface of second mother metal are solder side.Preferred 15 °~45 ° of angle between the inclined-plane of described enlarging and chamfering and the tube hub line; The length on enlarging inclined-plane increases with the increase of tubing caliber, preferably is not less than 3mm; The length on preferred chamfering inclined-plane is slightly less than the length on enlarging inclined-plane, and for example less than 0.5~3mm, the above straight tube face portion relative with the enlarging inclined-plane of chamfering this moment also is solder side
Preferably, first mother metal and second mother metal are vertically placed among described step a~f, applying ultrasonic vibration among the step e can apply also from the top and can apply from the below, when the top applies ultrasonic vibration, the top mother metal is installed on scalable anchor clamps upper and lower mother metal and is installed on the stationary fixture, and if applied ultrasonic vibration from the below with the below mother metal be installed on the scalable anchor clamps, the top mother metal is installed on the stationary fixture.Certainly described mother metal horizontal positioned is welded also and be fine.
Preferably, described solder is that Sn-Zn system, Zn-Al system, Al-Si are one or more in the alloy.
Preferably, described solder is a paste, strip, bar-shaped or powdery.
As further improvement, described precompression and welding pressure are direct acting by described ultrasonic depression bar.
As further improvement, intermediate frequency among the described step c or HF induction heating apparatus comprise the attemperating unit of infrared measurement of temperature or thermocouple temperature measurement, by described attemperating unit the welding position that heats are carried out temperature control.
Method for welding has following useful technique effect between different metal materials of the present invention:
1, the method for welding between different metal materials of the present invention adopts middle and high frequency eddy-current heating to combine with ultrasonic vibration, shortened the time of soldering effectively, and ultrasonic cavitation in liquid solder has played good stirring action to solder, thereby reduced the interatomic diffusion of dissimilar metal, reduced (the CuAl that forms during the copper aluminium soldering for example of compound between the stratiform brittle metal 2) formation; Local fast heating has also been dwindled the scope of heat affected area in addition, and influence reduces to strength of parent; Also have ultrasonic vibration to accelerate the filling of solder butt welded seam and, discharged pore and residue in the wetting expansion on mother metal surface.Therefore improved the intensity of welding point from many aspects.
2, this method for welding need not to use any brazing flux, has reduced production cost, has also avoided the halogen in the brazing flux to the pollution of environment and the harm that operator ' s health is caused; In addition, the air holes when electrochemical corrosion of the joint that has produced when also having avoided using brazing flux and brazing flux reaction, thus increased the reliability of welding point.
3, because welding pressure is little, brazing temperature is low and weld interval short, so this method is specially adapted to the connection of thin wall copper aluminum pipe.
4, can under antivacuum situation, carry out soldering, less demanding to weldment surface roughness and cleannes, simplified technology; Welding interval is short, the productivity effect height; Because heat time heating time is short, heated perimeter is little, required welding pressure and ultrasonic vibration power are low, thereby consumes energy is less, makes the cost of welding lower.
Description of drawings
Fig. 1 is copper, the aluminum pipe induction-ULTRASONIC COMPLEX soldering schematic diagram of one embodiment of the invention;
Fig. 2 is copper, the aluminium bar material induction-ULTRASONIC COMPLEX soldering schematic diagram of another embodiment of the present invention.
The specific embodiment
Below be embodiments of the invention, also can further be well understood to the present invention in conjunction with the accompanying drawings by these embodiment, but they be not limitation of the invention.
Embodiment 1
Referring to Fig. 1, select 6061 aluminum pipes 1 and T2 copper pipe 2 for use, their external diameter is 8mm, wall thickness is 1mm.Used solder is the no brazing flux solder paste 3 of Zn-4.7Al-0.5Cu (wt.%), and the solidus temperature of this solder is that 380 ℃, liquidus temperature are 397 ℃.Adopt reamer to make an end mouth of pipe enlarging of aluminum pipe 1 V-shaped, angle between enlarging inclined-plane and the tube hub line is 30 °, chamfer length is 5mm, go out chamfering by same angle at an end mouth of pipe car of copper pipe 2, the above straight tube face relative with the enlarging inclined-plane in chamfering inclined-plane is divided into solder side when enlarging inclined-plane, chamfering inclined-plane and welding.
Referring to Fig. 1, the flared end of aluminum pipe 1 vertically is installed on the stationary fixture 7 up, the chamfered end of copper pipe 2 vertically is installed on the scalable anchor clamps 8 down and to the flared end of good aluminum pipe 1, solder paste 3 evenly is filled in the V-type groove of copper pipe 2 and the joint of aluminum pipe 1.The other end by 6 pairs of copper pipes 2 of ultrasonic depression bar applies precompression with respect to aluminum pipe 1 downwards, and precompression also can apply by other pressurized equipments, and the precompression size is 0.1MPa.Open induction heating equipment, by the speed Fast Heating that 4 pairs of radio-frequency induction coils are intended the welding position with 10 ℃/s, the number of turns of induction coil 4 is good with 1~3 circle.Induction heating equipment also is provided with infrared attemperating unit 5, and the control of thermometric and temperature is carried out at the heating position, when intending beginning insulation when the welding position temperature rises to 410 ℃ of design temperatures, and the precompression of 6 pairs of copper pipes 2 of ultrasonic depression bar is increased to welding pressure 0.5MPa; 0.5 second back starts ultrasonic vibration by ultrasonic depression bar 6, ultrasonic vibration power is that 120W, frequency are that 28kHz, time of vibration are 4 seconds.Ultrasonic vibration finishes to continue to keep welding pressure 0.5MPa and be incubated down for 410 ℃ at design temperature, temperature retention time is 2 seconds, weldment cooling (also can adopt water-cooled) naturally in air after insulation is finished, to-be-welded pieces welding position temperature stops pressurize when reducing to room temperature, and from anchor clamps, take out weldment, finish welding.The section of weld joint microscopic analysis shows that seam organization is evenly distributed, no stratiform CuAl 2Form, and do not find pore and crackle; Welding point has higher mechanical property and sealing.
Embodiment 2
Referring to Fig. 2, select for use T2 copper rod 1 and 6061 aluminium alloy bars 2 to be mother metal, the mother metal diameter is 6mm, length is 40mm.Selecting composition for use is Zn-4.7Al-0.5Cu(wt.%), diameter is that 6mm, thickness are the disk solder 3 of 400 μ m, the solidus temperature of this solder is that 380 ℃, liquidus temperature are 397 ℃.With No. 400 silicon carbide papers end face of mother metal is polished as solder side, and adopt ethanol that mother metal and disk solder 3 are carried out ultrasonic cleaning.
Referring to Fig. 2, the end face that polishes of copper rod 1 vertically is installed on the stationary fixture 7 up, aluminium alloy bars 2 polishes end face and vertically is installed on the scalable anchor clamps 8 down and to the end face that polishes of good copper rod 1, with disk solder 3 be preset at copper, aluminium bar polishes between the end face.The other end by 6 pairs of aluminium alloy bars 2 of ultrasonic depression bar applies precompression with respect to copper rod 1, and precompression also can apply by other pressurized equipments, and the precompression size is 0.2MPa.Open induction heating equipment, by the speed Fast Heating that 4 pairs of radio-frequency induction coils are intended the welding position with 10 ℃/s, the number of turns of induction coil 4 is good with 1~3 circle.Induction heating equipment also is provided with infrared attemperating unit 5, thermometric and temperature control are carried out in the heating position, when intending beginning insulation when the welding position temperature rises to 410 ℃ of design temperatures, and the precompression of 6 pairs of aluminium alloy bars 2 of ultrasonic depression bar is increased to welding pressure 0.5MPa; 0.5 second back starts ultrasonic vibration by ultrasonic depression bar 6, ultrasonic vibration power is that 270W, frequency are that 28kHz, time of vibration are 6 seconds.Ultrasonic vibration finishes to continue to keep welding pressure 0.5MPa and be incubated down for 410 ℃ at design temperature, temperature retention time is 2 seconds, weldment cooling (also can adopt water-cooled) naturally in air after insulation is finished, to-be-welded pieces welding position temperature stops pressurize when reducing to room temperature, and from anchor clamps, take out weldment, finish welding.The section of weld joint microscopic analysis shows that seam organization is evenly distributed, no stratiform CuAl 2Form, and do not find pore and crackle; Welding point has higher mechanical property and sealing.

Claims (10)

1. the method for welding between a different metal materials, described different metal materials comprises first mother metal and second mother metal that material is different, first mother metal and second mother metal have solder side, it is characterized in that: described method for welding may further comprise the steps:
A, first mother metal is installed on the scalable anchor clamps, second mother metal is installed on the stationary fixture, and solder side first mother metal, second mother metal is placed between the described solder side relatively and with solder;
B, apply the precompression with respect to described solder side on first mother metal, the precompression size is 0.01MPa~0.5MPa;
C, to the welding position local heat of described first mother metal and second mother metal, heat temperature raising speed is 5 ℃/s~50 ℃/s, is incubated after reaching design temperature;
D, described precompression is risen to welding pressure, described welding pressure is higher than described precompression, and more than or equal to 0.1MPa smaller or equal to 3MPa;
E, apply ultrasonic vibration with respect to described second mother metal with excess sound pressure pole pair first mother metal;
Follow-up continuation of insurance temperature pressurize 1~60 second is finished in f, ultrasonic vibration, stops heating then and continues pressurize to the cooling of described welding position.
2. the method for welding between different metal materials according to claim 1 is characterized in that: described first mother metal is that copper alloy or Cu-base composites, second mother metal are aluminium alloy or aluminum matrix composite; Perhaps described first mother metal is that aluminium alloy or aluminum matrix composite, second mother metal are copper alloy or Cu-base composites; Perhaps described first mother metal is that stainless steel, second mother metal are selected from a kind of in aluminium alloy, aluminum matrix composite, magnesium alloy, the magnesium base composite material; Perhaps first mother metal is selected from a kind of in aluminium alloy, aluminum matrix composite, magnesium alloy, the magnesium base composite material, and second mother metal is a stainless steel.
3. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: mode of heating is intermediate frequency or high-frequency induction heating among the described step c.
4. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: the design temperature among the described step c is higher than 5 ℃~100 ℃ of the solidus temperatures of described solder or is higher than 0 ℃~80 ℃ of the liquidus temperatures of described solder.
5. according to the method for welding between each described different metal materials of claim 1~4, it is characterized in that: the frequency of ultrasonic vibration is that 10kHz~40kHz, amplitude are 5 μ m~25 μ m among the described step e, and the ultrasonic vibration time is 0.5~60 second.
6. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: precompression is risen to welding pressure begins step e after 0~5 second the ultrasonic vibration that applies in steps d.
7. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: described first mother metal, second mother metal are tubular material, and be further comprising the steps of before described step a:
a 0, with the end mouth of pipe enlarging of reamer with second mother metal, according to the same angle in described enlarging inclined-plane one end of first mother metal being processed a chamfering, the enlarging inclined-plane of the fillet surface of described first mother metal and second mother metal is a solder side; Perhaps, with the end mouth of pipe enlarging of reamer with first mother metal, according to the same angle in described enlarging inclined-plane one end of second mother metal being processed a chamfering, the enlarging inclined-plane of described first mother metal and the fillet surface of second mother metal are solder side.
8. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: described solder is that Sn-Zn system, Zn-Al system, Al-Si are one or more in the alloy.
9. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: described solder is a paste, sheet, bar-shaped or powdery.
10. the method for welding between different metal materials according to claim 1 and 2 is characterized in that: directly apply precompression and welding pressure by described ultrasonic depression bar.
CN2011100663699A 2011-03-18 2011-03-18 Dissimilar metal material brazing method Expired - Fee Related CN102151930B (en)

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