CN102069141A - 用于铸造型芯模的粘结剂 - Google Patents
用于铸造型芯模的粘结剂 Download PDFInfo
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- CN102069141A CN102069141A CN 201010176020 CN201010176020A CN102069141A CN 102069141 A CN102069141 A CN 102069141A CN 201010176020 CN201010176020 CN 201010176020 CN 201010176020 A CN201010176020 A CN 201010176020A CN 102069141 A CN102069141 A CN 102069141A
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- 229920001568 phenolic resin Polymers 0.000 claims description 30
- 239000005011 phenolic resin Substances 0.000 claims description 30
- 125000001743 benzylic group Chemical group 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 8
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- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 239000004305 biphenyl Substances 0.000 claims description 6
- 125000006267 biphenyl group Chemical group 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 6
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- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
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- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 3
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 3
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims description 3
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- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 3
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 claims description 3
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000004843 novolac epoxy resin Substances 0.000 claims description 3
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
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- BDLWRIAFNYVGTC-UHFFFAOYSA-N 2-[bis(2-chloroethyl)amino]ethyl 3-(acridin-9-ylamino)propanoate Chemical compound C1=CC=C2C(NCCC(=O)OCCN(CCCl)CCCl)=C(C=CC=C3)C3=NC2=C1 BDLWRIAFNYVGTC-UHFFFAOYSA-N 0.000 claims 1
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- 239000004291 sulphur dioxide Substances 0.000 abstract 3
- CRKDNNLDFYKBEE-RMKNXTFCSA-N (e)-benzylidenehydrazine Chemical compound N\N=C\C1=CC=CC=C1 CRKDNNLDFYKBEE-RMKNXTFCSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
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- 238000004519 manufacturing process Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
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- 150000002978 peroxides Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 2
- 102100025222 CD63 antigen Human genes 0.000 description 2
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- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
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- 229910052753 mercury Inorganic materials 0.000 description 2
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- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 230000007613 environmental effect Effects 0.000 description 1
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- 230000002349 favourable effect Effects 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 238000006068 polycondensation reaction Methods 0.000 description 1
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- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Mold Materials And Core Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
Description
实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 实例6 | 实例7 | 实例8 | |
苄基醚酚醛树脂*(g) | 101.3% | 26050% | 307.5% | 8215.8% | 90(20%) | 508.3% | 185.535% | 100.819.5% |
聚异氰酸酯*(g) | 7.51% | 81.54% | 10025% | 9.61.85% | 8018% | 8013% | 26.55% | 42.68.2% |
环氧树脂(g) | 750 | 520 | 400 | 518.4 | 450 | 600 | 530 | 516.6 |
丙烯酸酯(g) | 200 | 200 | 300 | 220 | 210 | 200 | 200 | 200 |
高沸点酯(g) | 22.5 | 12 | 100 | 140 | 130 | -- | 38 | 110 |
烃稀释剂(g) | 10 | -- | 70 | 30 | 40 | 90 | 20 | 30 |
射砂压力 | 吹SO2压力 | 洗涤压力 | 吹SO2时间 | 洗涤时间 |
0.4MPa | 0.2MPa | 0.2MPa | 15.0秒 | 10.0秒 |
Claims (9)
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CN2010101760206A CN102069141B (zh) | 2009-11-24 | 2010-05-11 | 用于铸造型芯模的粘结剂 |
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CN200910223682.1 | 2009-11-24 | ||
CN200910223682 | 2009-11-24 | ||
CN2010101760206A CN102069141B (zh) | 2009-11-24 | 2010-05-11 | 用于铸造型芯模的粘结剂 |
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CN102069141A true CN102069141A (zh) | 2011-05-25 |
CN102069141B CN102069141B (zh) | 2012-10-03 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102717025A (zh) * | 2012-06-29 | 2012-10-10 | 济南圣泉集团股份有限公司 | 冷芯盒法环氧树脂单组份粘结剂、铸造混合物、铸造成型体 |
CN103302234A (zh) * | 2013-06-13 | 2013-09-18 | 济南圣泉集团股份有限公司 | 一种易脱模的胺法冷芯盒粘结剂 |
CN103317083A (zh) * | 2013-06-13 | 2013-09-25 | 济南圣泉集团股份有限公司 | 一种提高胺法冷芯盒砂芯脱模性的方法 |
CN104162625A (zh) * | 2014-08-14 | 2014-11-26 | 济南圣泉集团股份有限公司 | 一种铸造用粘结剂及其制备方法 |
CN105295353A (zh) * | 2015-11-19 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | 一种铸件用粘结剂及其制备方法 |
CN106040966A (zh) * | 2015-06-18 | 2016-10-26 | 济南圣泉集团股份有限公司 | 冷芯盒粘结剂及铸造成型体 |
CN108463532A (zh) * | 2016-09-09 | 2018-08-28 | Nok株式会社 | 硫化胶粘剂 |
CN111014570A (zh) * | 2019-12-31 | 2020-04-17 | 苏州兴业材料科技股份有限公司 | 一种酚尿烷冷芯盒粘结剂及制备方法 |
CN114101575A (zh) * | 2021-12-02 | 2022-03-01 | 承德北雁新材料科技有限公司 | 一种铸造用型芯有机粘结剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1583931A (zh) * | 2004-06-02 | 2005-02-23 | 姚立猛 | 酚醛型聚氨酯粘结剂以及铸造用热芯盒法制芯造型的方法 |
CN101147953A (zh) * | 2007-11-12 | 2008-03-26 | 济南圣泉集团股份有限公司 | 一种高性能低烟阻燃胺法冷芯盒粘结剂 |
US20090023862A1 (en) * | 2007-07-17 | 2009-01-22 | Ppg Industries Ohio, Inc. | Solventborne thermosetting compositions containing copolymers of isobutylene type monomers |
CN101524737A (zh) * | 2009-04-10 | 2009-09-09 | 苏州市兴业铸造材料有限公司 | 有色铸造用酚尿烷冷芯盒粘结剂及制备方法 |
-
2010
- 2010-05-11 CN CN2010101760206A patent/CN102069141B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1583931A (zh) * | 2004-06-02 | 2005-02-23 | 姚立猛 | 酚醛型聚氨酯粘结剂以及铸造用热芯盒法制芯造型的方法 |
US20090023862A1 (en) * | 2007-07-17 | 2009-01-22 | Ppg Industries Ohio, Inc. | Solventborne thermosetting compositions containing copolymers of isobutylene type monomers |
CN101147953A (zh) * | 2007-11-12 | 2008-03-26 | 济南圣泉集团股份有限公司 | 一种高性能低烟阻燃胺法冷芯盒粘结剂 |
CN101524737A (zh) * | 2009-04-10 | 2009-09-09 | 苏州市兴业铸造材料有限公司 | 有色铸造用酚尿烷冷芯盒粘结剂及制备方法 |
Non-Patent Citations (1)
Title |
---|
《应用化学》 20040131 胡飞等 硼酸盐固化酚醛树脂 78-80 1-9 第21卷, 第1期 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102717025B (zh) * | 2012-06-29 | 2016-03-30 | 济南圣泉集团股份有限公司 | 冷芯盒法环氧树脂单组份粘结剂、铸造混合物、铸造成型体 |
CN102717025A (zh) * | 2012-06-29 | 2012-10-10 | 济南圣泉集团股份有限公司 | 冷芯盒法环氧树脂单组份粘结剂、铸造混合物、铸造成型体 |
CN103302234A (zh) * | 2013-06-13 | 2013-09-18 | 济南圣泉集团股份有限公司 | 一种易脱模的胺法冷芯盒粘结剂 |
CN103317083A (zh) * | 2013-06-13 | 2013-09-25 | 济南圣泉集团股份有限公司 | 一种提高胺法冷芯盒砂芯脱模性的方法 |
CN103317083B (zh) * | 2013-06-13 | 2015-09-09 | 济南圣泉集团股份有限公司 | 一种提高胺法冷芯盒砂芯脱模性的方法 |
CN104162625A (zh) * | 2014-08-14 | 2014-11-26 | 济南圣泉集团股份有限公司 | 一种铸造用粘结剂及其制备方法 |
CN106040966A (zh) * | 2015-06-18 | 2016-10-26 | 济南圣泉集团股份有限公司 | 冷芯盒粘结剂及铸造成型体 |
CN106040966B (zh) * | 2015-06-18 | 2019-02-05 | 济南圣泉集团股份有限公司 | 冷芯盒粘结剂及铸造成型体 |
CN105295353A (zh) * | 2015-11-19 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | 一种铸件用粘结剂及其制备方法 |
CN105295353B (zh) * | 2015-11-19 | 2018-06-12 | 陆河南方机械铸造有限公司 | 一种铸件用粘结剂及其制备方法 |
CN108463532A (zh) * | 2016-09-09 | 2018-08-28 | Nok株式会社 | 硫化胶粘剂 |
CN108463532B (zh) * | 2016-09-09 | 2019-09-03 | Nok株式会社 | 硫化胶粘剂 |
CN111014570A (zh) * | 2019-12-31 | 2020-04-17 | 苏州兴业材料科技股份有限公司 | 一种酚尿烷冷芯盒粘结剂及制备方法 |
CN114101575A (zh) * | 2021-12-02 | 2022-03-01 | 承德北雁新材料科技有限公司 | 一种铸造用型芯有机粘结剂及其制备方法 |
CN114101575B (zh) * | 2021-12-02 | 2023-12-01 | 承德北雁新材料科技有限公司 | 一种铸造用型芯有机粘结剂及其制备方法 |
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