CN102061633A - Method for dyeing protein fiber and fabric thereof with natural dye extracted from grape seeds - Google Patents
Method for dyeing protein fiber and fabric thereof with natural dye extracted from grape seeds Download PDFInfo
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- CN102061633A CN102061633A CN2010105820418A CN201010582041A CN102061633A CN 102061633 A CN102061633 A CN 102061633A CN 2010105820418 A CN2010105820418 A CN 2010105820418A CN 201010582041 A CN201010582041 A CN 201010582041A CN 102061633 A CN102061633 A CN 102061633A
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Abstract
The invention relates to a method for dyeing with a dye extracted from a grape beverage and grape seeds as waste resources in wine industry processing, which is characterized in that a grape seed pigment solution is adopted to dye protein fiber fabrics such as wools, silks and the like with a directly dyeing method or an aluminium ion and iron ion pre-mordant dyeing method. A dyeing technology has the following parameters: the bath ratio of (25-50):1, a dye bath pH value of 3-5, the grape seed dosage of 1-6 percent (o.w.f), dyeing temperature of 30 DEG C, temperature rise rate of 1-3 DEG C/min, temperature rising to 80-100 DEG C and insulation time of 60-120min. The aluminium ion and iron ion pre-mordant dyeing method is characterized by comprising the following steps of, firstly, carrying out pre-mordant dyeing on the protein fiber fabrics by adopting aluminium ions and iron ions, and putting the protein fiber fabrics such as the wools, the silks and the like into a grape seed pigment dye bath to dye. Fabrics in different colors can be obtained by adopting different mordants. The invention can efficiently utilize grape seed waste resources and expand the application field of completely nontoxic grape seed pigments.
Description
Technical field
The present invention relates to a kind of colouring method of vegetable colour, especially relate to the method for protein fibre such as a kind of natural dye dyeing wool that in grape pip, extracts, silk and fabric thereof, belong to the natural dye dying field.
Background technology
Derive from the natural colouring matter of animal and plant.Particularly the natural colouring matter that extracts from the edibility plant is safe, the color and luster nature, and majority has nourishing healthy and painted double action concurrently, thereby enjoys people's favor.China has very abundant grape resource.There are a large amount of discarded residue of grape seeds in many grape beverages and the brewing industry processing.With the 60%-95% ethanol water is solvent, adopts that lixiviate, filtration, decompression concentrate, can extract from grape pip behind the spray drying supervisor and obtain puniceus powder pigment, can make full use of waste resource.The grape pip pigment is generally used for the painted of beverage, cake, jam, cosmetics etc.
China uses vegetable colour to have a long history, and just can skillfully adopt sophora bud dyestuff to dye manufacture-yellow look textiles the Song dynasty working people the latest according to textual criticism.Before nearly 150 years, synthetic dyestuffs are succeeded in developing, and the vegetable colour consumption reduces.Closely during the last ten years, reinforcement along with the development of synthetic dyestuffs and people's environmental protection, health perception, the synthetic dyestuffs that people find some kinds gradually are harmful, that have even carcinogenic to human itself and environment, and the obvious deficiency of the petroleum resources that are used to make most of synthetic dyestuffs.Therefore, biodegradable, renewable, vegetable colour that have a health-care effect again is subjected to people's extensive attention again, extracts vegetable colour and be applied to the focus that textile dyeing becomes current weaving, dyeing and finishing field from plant kingdom.
Summary of the invention
The objective of the invention is to overcome the deficiency of existing synthetic dyestuffs, the more environmental protection of a kind of protein fibre kind fabric, health are provided, effectively utilize the colouring method of waste resource, to enlarge the Application Areas of grape pip pigment.
According to technical scheme provided by the invention, the colouring method of described grape pip natural dye dsred protein fiber-like is characterized in that adopting the colouring method of direct dyeing method and aluminium ion, the pre-mordant dyeing of iron ion.Coloured differently method gained fabric color difference.
The present invention adopts aluminium ion, iron ion as follows to the method that the protein fibre kind fabric carries out pre-mordant dyeing:
Adopt normal temperature type dyeing sample machine, water-bath etc., the protein fibre kind fabric is carried out pre-mordant dyeing.Mordant adopts environment-friendly type mordants such as aluminium ion, iron ion.The pre-mordant dyeing technology of aluminium ion mordant: mordant KAl (SO
4)
2.12H
2O, mordant consumption 1%-6% (o.w.f), bath raio (25-50): 1,30 ℃ is dyed, and heating rate 1-2 ℃/min, is warming up to 60-80 ℃, insulation 40-60min.The pre-mordant dyeing technology of iron ion mordant: mordant FeSO
47H
2O, mordant consumption 0.5-3%, bath raio (25-50): 1,30 ℃ is risen and to dye, and heating rate 1-2 ℃/min, is warming up to 40-60 ℃ and be incubated 30-60min.
Colouring method of the present invention is as follows:
Dye bath pH value is an important dyeing parameter.The grape pip pigment is stable in acid medium, and the pH value is more little, and the absworption peak of pigment aqueous solution in the 440-600nm scope is big more, illustrates that acid condition has hyperchromicity to the grape pip pigment; When pH＞7, pigment aqueous solution does not almost have absworption peak in the 440-600nm scope, illustrates that this pigment is unstable under alkali condition.It is acid that grape pip pigment aqueous solution itself shows, electronegative in the aqueous solution.The isoelectric point of protein fibre such as wool, silk is 3.5-5.2, below isoelectric point, and the fiber band positive charge.Therefore, the grape pip pigment is suitable for the dsred protein fibrid, and dyeing pH value is 3-5, by the electrostatic attraction effect between dyestuff-fiber, dyes on the fiber on the dyestuff.
Will be through in the protein fibre kind fabric or protein fibre kind fabric input grape pip dye solution that soak into, wash; bath raio (25-50): 1, dye bath pH value 3-5, grape pip dye dosage 1-6% (o.w.f) (dye dosage calculates fiber consumption with the powder grape pip dye dosage that extracts); 30 ℃ are dyed; heating rate 1-3 ℃/min; be warming up to 80 ℃-100 ℃, insulation 60-120min through pre-mordant dyeing.Sample after the dyeing adopts the neutral soap lotion of 0.5g/L to wash 10-30min under 30-50 ℃ of condition, adopts clear water to clean then.
Can obtain different color and lusters after direct dyeing or the protein fibre kind fabric dyeing through the pre-mordant dyeing of different mordant dyeing agent.
The specific embodiment
The invention will be further described below in conjunction with specific embodiment.
Specific embodiment 1: direct dyeing method
To drop into through the protein fibre kind fabric that soaks into, washs in the grape pip dye solution, bath raio 30: 1, dye bath pH value 3, grape pip dye dosage 2% (o.w.f), 30 ℃ are dyed, and 2 ℃/min of heating rate is warming up to 100 ℃, insulation 80min.Sample after the dyeing adopts the neutral soap lotion of 0.5g/L to wash 10min under 30 ℃ of conditions, adopts clear water to clean then.
Specific embodiment 2: the pre-mordant dying method of aluminium ion
Adopt normal temperature type dyeing sample machine, water-bath etc., at first the protein fibre kind fabric is carried out pre-mordant dyeing.Mordant adopts aluminium ion mordant KAl (SO
4)
2.12H
2O, mordant consumption 3% (o.w.f), bath raio 25: 1,30 ℃ are dyed, and 2 ℃/min of heating rate is warming up to 60 ℃, insulation 60min.Then, will drop into through the protein fibre kind fabric of pre-mordant dyeing in the grape pip dye solution, bath raio 30: 1, dye bath pH value 4, grape pip dye dosage 4% (o.w.f), 30 ℃ are dyed, and 1 ℃/min of heating rate is warming up to 90 ℃, insulation 70min.Sample after the dyeing adopts the neutral soap lotion of 0.5g/L to wash 30min under 50 ℃ of conditions, adopts clear water to clean then.
Specific embodiment 3: the pre-mordant dying method of iron ion
Adopt normal temperature type dyeing sample machine, water-bath etc., the protein fibre kind fabric is carried out pre-mordant dyeing.Mordant adopts iron ion FeSO
47H
2O, mordant consumption 1%, bath raio 30: 1,30 ℃ are risen and to dye, and 2 ℃/min of heating rate is warming up to 40 ℃ and be incubated 40min.To drop into through the protein fibre kind fabric of pre-mordant dyeing in the grape pip dye solution, bath raio 40: 1, dye bath pH value 4, grape pip dye dosage 4% (o.w.f), 30 ℃ are dyed, and 2 ℃/min of heating rate is warming up to 100 ℃, insulation 120min.Sample after the dyeing adopts the neutral soap lotion of 0.5g/L to wash 30min under 50 ℃ of conditions, adopts clear water to clean then.
Claims (3)
1. the dyeing method of the extraction waste resource grape pip in grape beverage and brewing industry processing is characterized in that adopting the grape pip pigment solution to adopt the method for direct dyeing method or aluminium ion, the pre-mordant dyeing of iron ion to dye to protein fibre kind fabrics such as wool, silks.
2. colouring method according to claim 1, it is characterized in that the dyeing parameter is as follows: bath raio (25-50): 1, dye bath pH value 3-5, grape pip dye dosage 1-6% (o.w.f), 30 ℃ are dyed heating rate 1-3 ℃/min, be warming up to 80 ℃-100 ℃, insulation 60-120min.
3. the colouring method of aluminium ion according to claim 1, the pre-mordant dyeing of iron ion, its feature may further comprise the steps: (1) at first adopts aluminium ion, iron ion that the protein fibre kind fabric is carried out pre-mordant dyeing; (2) will dye in the dye bath of protein fibre kind fabrics such as the wool after the pre-mordant dyeing, silk input grape pip pigment.Different mordant dyeing agent gained fabric color difference.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010105820418A CN102061633A (en) | 2010-12-10 | 2010-12-10 | Method for dyeing protein fiber and fabric thereof with natural dye extracted from grape seeds |
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| CN2010105820418A CN102061633A (en) | 2010-12-10 | 2010-12-10 | Method for dyeing protein fiber and fabric thereof with natural dye extracted from grape seeds |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102628227A (en) * | 2012-03-29 | 2012-08-08 | 江南大学 | Grape-seed-based ecological preparation method for ultravioresistant woolen and silk textiles |
| WO2012159920A1 (en) * | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair care composition |
| CN104233872A (en) * | 2013-06-17 | 2014-12-24 | 无锡市东新织造有限公司 | Dyeing process for real-silk fabrics pre-mordanted by iron salt by using lawsonia pigment |
| CN104499309A (en) * | 2014-12-15 | 2015-04-08 | 常熟市启弘纺织实业有限公司 | Environment-friendly printing and dyeing method of fabric |
| CN105544238A (en) * | 2015-12-18 | 2016-05-04 | 河南工程学院 | Printing color paste containing grape pigment and printing process by using the same |
| CN105780534A (en) * | 2016-03-18 | 2016-07-20 | 河南工程学院 | Process of utilizing Fructus chebulae pigment to dye silk fabric |
| CN106320001A (en) * | 2016-08-19 | 2017-01-11 | 河南工程学院 | Method for dyeing wool by myrobalan pigment |
| CN109575640A (en) * | 2018-12-20 | 2019-04-05 | 罗莱生活科技股份有限公司 | A kind of grape pip dye microcapsule and its preparation method and application |
| CN114150514A (en) * | 2021-12-31 | 2022-03-08 | 江南大学 | Preparation method of multifunctional chinlon fabric |
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| KR100512384B1 (en) * | 2000-08-18 | 2005-09-05 | 정필훈 | Natural dye material extracted from outer surface of grapes(GE) |
| CN101476248A (en) * | 2009-01-20 | 2009-07-08 | 西安际华三五一一家纺有限公司 | Method for using natural grape seed dyeing extract in textile dyeing |
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Patent Citations (2)
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|---|---|---|---|---|
| KR100512384B1 (en) * | 2000-08-18 | 2005-09-05 | 정필훈 | Natural dye material extracted from outer surface of grapes(GE) |
| CN101476248A (en) * | 2009-01-20 | 2009-07-08 | 西安际华三五一一家纺有限公司 | Method for using natural grape seed dyeing extract in textile dyeing |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012159920A1 (en) * | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair care composition |
| CN102628227A (en) * | 2012-03-29 | 2012-08-08 | 江南大学 | Grape-seed-based ecological preparation method for ultravioresistant woolen and silk textiles |
| CN104233872A (en) * | 2013-06-17 | 2014-12-24 | 无锡市东新织造有限公司 | Dyeing process for real-silk fabrics pre-mordanted by iron salt by using lawsonia pigment |
| CN104499309A (en) * | 2014-12-15 | 2015-04-08 | 常熟市启弘纺织实业有限公司 | Environment-friendly printing and dyeing method of fabric |
| CN105544238A (en) * | 2015-12-18 | 2016-05-04 | 河南工程学院 | Printing color paste containing grape pigment and printing process by using the same |
| CN105544238B (en) * | 2015-12-18 | 2018-01-30 | 河南工程学院 | Print paste and its printing technology containing grape pigment |
| CN105780534A (en) * | 2016-03-18 | 2016-07-20 | 河南工程学院 | Process of utilizing Fructus chebulae pigment to dye silk fabric |
| CN105780534B (en) * | 2016-03-18 | 2018-06-05 | 河南工程学院 | The technique dyed using myrobalan's pigment to silk fabric |
| CN106320001A (en) * | 2016-08-19 | 2017-01-11 | 河南工程学院 | Method for dyeing wool by myrobalan pigment |
| CN109575640A (en) * | 2018-12-20 | 2019-04-05 | 罗莱生活科技股份有限公司 | A kind of grape pip dye microcapsule and its preparation method and application |
| CN109575640B (en) * | 2018-12-20 | 2020-07-14 | 罗莱生活科技股份有限公司 | Grape seed dye microcapsule and preparation method and application thereof |
| CN114150514A (en) * | 2021-12-31 | 2022-03-08 | 江南大学 | Preparation method of multifunctional chinlon fabric |
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Application publication date: 20110518 |