CN101898439A - Manufacturing method for polrvinyl chloride anti-static rubber - Google Patents
Manufacturing method for polrvinyl chloride anti-static rubber Download PDFInfo
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- CN101898439A CN101898439A CN2009101423411A CN200910142341A CN101898439A CN 101898439 A CN101898439 A CN 101898439A CN 2009101423411 A CN2009101423411 A CN 2009101423411A CN 200910142341 A CN200910142341 A CN 200910142341A CN 101898439 A CN101898439 A CN 101898439A
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- polrvinyl chloride
- static rubber
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- rubber
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Abstract
The invention provides a manufacturing method for a polrvinyl chloride anti-static rubber. The method comprises the steps of coating a layer of paste on a base cloth of a fabric or a non-fabric, wherein the paste comprises a solvent paste, heating and drying the base cloth coated with the paste, batching into a paste cloth, making the polrvinyl chloride rubber material, processing into a rubber cloth, sticking the rubber cloth with the paste cloth and rolling into a polrvinyl chloride rolled rubber through a rubber roller.
Description
Technical field
The present invention relates to a kind of manufacturing technology of antistatic rubber, particularly a kind of manufacture method of polrvinyl chloride anti-static rubber.
Background technology
At present, under the quick growth of electronics industry and pharmaceuticals industry, stimulated the demand of anti-static material, as the manufacturing of electronic product, transport, pack, storage etc. all needs to carry out Electrostatic protection.Moreover the floor of using in Electronics Factory or the pharmaceutical factory's dust free room, work top, operation tool, anti-dust respirator, gloves, dust-free clothes etc., and transport as the raw material storage of packaging for foodstuff and chemical plant in other industry etc., if the help of anti-static material is arranged, not only can increase the convenience of operation, more the loss that can avoid great disaster to cause.
Polyvinyl chloride (PVC) is most important and use the most general a kind of among the man-made polymer, mainly be because it has very big variability, in the process of making polyvinyl chloride product, can cooperate different purposes and needs, add various plasticizers and additive and change its physics or chemical property.
Polyvinyl chloride (PVC) is an insulator, has very high resistance coefficient, and resistance coefficient is about 10
12～10
13Ohm/sq, it is in the nature good electrical insulators, so its goods produce static because of friction easily.But because employed product processing machine in the prior art, be all the machine that is easy to generate friction as blender (Mixers), calender (Calendars), to the non-property led Process Technology of Polymer the time, just as electrostatic generator, excessive accumulation be can produce in sizing material, machine table surface, and the back segment processability of this macromolecular material and operating personnel's safety influenced.So in order to solve the problem of static, can use in several modes usually: antistatic additive adds, gives other conductive material such as conductive carbon black, air ionization and improves relative humidity.
Therefore, the present invention promptly proposes a kind of manufacture method of polrvinyl chloride anti-static rubber, effectively to overcome above-mentioned variety of issue.
Summary of the invention
Main purpose of the present invention is to provide a kind of manufacture method of polrvinyl chloride anti-static rubber, its mainly be in the polyvinyl chloride sizing material, adding at the type antistatic additive, make the polrvinyl chloride anti-static rubber of producing have good antistatic effect.
Another object of the present invention is to provide a kind of manufacture method of polrvinyl chloride anti-static rubber, the glue face of the polrvinyl chloride anti-static rubber that it manufactures does not have the pollution of conductive carbon black.
In order to achieve the above object, the invention provides a kind of manufacture method of polrvinyl chloride anti-static rubber, it comprises the following steps: a) coating one deck thickener on a base fabric, is wound into one behind the heating, drying and sticks with paste cloth; B) polyvinyl chloride sizing material processing back is formed an adhesive plaster; C) again adhesive plaster is fitted with sticking with paste cloth, form polyvinyl chloride calendering rubber.
Among the described step a, described base fabric is fabric or non-woven.Described thickener comprises solvent paste (paste solution ofthe polyurethane base), and paste amount is 30～70g/m2 on it; Described thickener was also dried with 120～180 ℃ temperature heating in 10～30 seconds.
Wherein, described thickener uses a pasting machine to coat on the described base fabric.Described pasting machine one on to stick with paste wheel be 30～120 orders.
Among the described step b, the composition of described polyvinyl chloride sizing material comprises: the antistatic additive of the plasticizer of the molding powder of 100 weight portions, 60 weight portions, the filler of 16 weight portions, 17 weight portions, the stabilizing agent and the look grain of 2 weight portions.
Wherein, described plasticizer comprises first plasticizer, 40 weight portions and second plasticizer, 20 weight portions.Described antistatic additive comprises aqueous antistatic additive 15 weight portions and wax shape antistatic additive 2 weight portions; Described antistatic additive is inherent type antistatic additive (Internal antistatic agent).Described look grain comprises redness, green, blueness and yellow look grain.Described stabilizing agent is barium zinc system (Ba Zn) powder attitude stabilizing agent.
Described step b further comprises: the polyvinyl chloride sizing material is stirred in a mixer; Carry out mixing gel by 10,000 horsepowers of machines; And send in the adhesive tape machine body and to form described adhesive plaster.
The rotating speed of wherein said mixer is 1700～2300 commentaries on classics, and temperature is 80～120 ℃, and mixing time is 4～6 minutes.The temperature of described ten thousand horsepowers of machines is 130～170 ℃, and mixing gel process is 3～6 minutes.Can be incubated material controlling after the mixing gel of described polyvinyl chloride sizing material, the temperature of insulation is 120～160 ℃, and temperature retention time is 2～4 minutes.
The polrvinyl chloride anti-static rubber that uses manufacture method of the present invention to obtain, its antistatic effect reaches the reliability height for a long time, has superior lasting antistatic behaviour, resistance coefficient obviously can be reduced to, and do not have the problem such as durability, hear resistance, temperature dependency of general antistatic additive, the polrvinyl chloride anti-static rubber of using manufacture method made of the present invention can reach desirable antistatic effect.
Description of drawings
Fig. 1 is the calcspar of the manufacturing process of polrvinyl chloride anti-static rubber of the present invention;
Fig. 2 is the flow chart of the manufacture method of polrvinyl chloride anti-static rubber of the present invention.
Description of reference numerals: 10-pasting machine; The 12-adhesive tape machine; The 122-homogenizer; Ten thousand horsepowers of machines of 124-; Thick, the thin wheel of 126-; 128-adhesive tape machine body.
The specific embodiment
Below in conjunction with accompanying drawing, be described in more detail with other technical characterictic and advantage the present invention is above-mentioned.
The invention provides a kind of manufacture method of polrvinyl chloride anti-static rubber, it mainly is to prevent plastic tape static demand at industry, cloth kind with fabric or non-woven adds conductive carbon black, and the special formula rate of the high molecular inherent type antistatic additive of adding interacts in polyvinyl chloride (PVC) sizing material, cooperate each equipment of manufacturing process production line, and then produce a kind of polrvinyl chloride anti-static rubber.
Figure 1 shows that employed equipment in the manufacturing process of the present invention, comprise pasting machine 10 and adhesive tape machine (Calendars) 12, and comprise homogenizer 122, ten thousand horsepowers of machines 124 in the adhesive tape machine 12, slightly, carefully take turns 126 and adhesive tape machine body 128.
Fig. 2 please also refer to Fig. 1 for the flow chart of the manufacture method of each equipment in the application drawing 1 of the present invention.Among the step S10, utilize pasting machine 10 on a base fabric, to be coated with one deck thickener, the upward paste wheel of this pasting machine 10 is 30～120 orders, base fabric is fabric (for example nylon (Nylon)) or non-woven (for example polyethylene (PE) film), thickener is comprising that solvent sticks with paste the paste of (for example polyurethanes (PU) is stuck with paste), and last paste amount is 30～70g/m2; And, stick with paste cloth with being wound into one behind the processing temperature heating, drying of this base fabric that is coated with thickener with process time of 10～30 seconds and 120～180 ℃ as described in the step S12.
Then for making the step of a polyvinyl chloride sizing material.At first in step S14, the molding powder (for example PVC powder) of 100 weight portions, the plasticizer of 60 weight portions, the filler (for example calcium carbonate) of 16 weight portions, the antistatic additive of 17 weight portions, the stabilizing agent and an amount of look grain raw materials such as (for example 0.1365 weight portions) of 2 weight portions are stirred in homogenizer 122, the rotating speed of homogenizer 122 is 1700～2300 commentaries on classics, temperature is 80～120 ℃, and mixing time is 4～6 minutes; The polyvinyl chloride sizing material that stirs among the step S16 mixing gel in ten thousand horsepowers of machines 124, the temperature of ten thousand horsepowers of machines 124 is 130～170 ℃, mixing gel process is 3～6 minutes, change over to immediately and slightly, carefully take turns the step of carrying out step S18 insulation material controlling in 126 and be beneficial to following process, temperature is controlled at 120～160 ℃, about 2～4 minutes of temperature retention time; The polyvinyl chloride sizing material of gel then as described in the step S20, is sent in the adhesive tape machine body 128 via conveyer belt, and control width and thickness form an adhesive plaster; Among the final step S22 adhesive plaster of adhesive tape machine 12 dischargings is fitted with sticking with paste cloth, form polyvinyl chloride calendering rubber.
In the raw material of polyvinyl chloride sizing material, plasticizer comprises first plasticizer (for example dioctyl phthalate DOP) of 40 weight portions and second plasticizer (for example dioctyl adipate DOA) of 20 weight portions; Antistatic additive comprises the aqueous antistatic additive (for example organic salt antistatic additive-quarternary ammonium salt) of 15 weight portions and the wax shape antistatic additive of 2 weight portions (for example amine antistatic additive-second chloro tertiary amine (Ethoxy tertiary amine)), and antistatic additive is inherent type antistatic additive (Internal antistatic agent); The look grain comprises redness, green, blueness and yellow look grain; Stabilizing agent is barium zinc system (Ba Zn) powder attitude stabilizing agent.
As described below for an embodiment.Can select suitable cloth as base fabric according to finished product purposes characteristic,, add conductive carbon black in this cloth kind and prepare to interact, and be thickener with the solution paste with antistatic additive as nylon (Nylon), make base fabric nylon can with the polyvinyl chloride sizing material one of adhering mutually.On base fabric, be coated with thickener in the cutter mode of mounting, batch via heating, drying and form paste cloth, fit for adhesive tape machine and use.
Then after the raw material mixing gel with the polyvinyl chloride sizing material, behind adhesive tape machine measurement thickness and control width formation adhesive plaster, the paste cloth of discharging and pasting machine is fitted, and constitutes the polyvinyl-chloride anti-static rolled products.The resistance coefficient of this polyvinyl-chloride anti-static rolled products is 10
7Ohm/sq, and the glue face there is no the conductive carbon black pollution.
In sum, the manufacture method of polrvinyl chloride anti-static rubber provided by the present invention is at type antistatic additive (Internal antistatic agent) in having added in the raw material of polyvinyl chloride sizing material, and then slowly be spread in frosting (approximately through 24～72 hours), so effect reaches the reliability height for a long time, have superior lasting antistatic behaviour, resistance coefficient can be reduced to 10
7Ohm/sq, and do not have the problem such as durability, hear resistance, temperature dependency of general antistatic additive, the polrvinyl chloride anti-static rubber of using manufacture method made of the present invention can reach desirable antistatic effect.
The above only is preferred embodiment of the present invention, only is illustrative for the purpose of the present invention, and nonrestrictive.Those skilled in the art is understood, and can carry out many changes to it in the spirit and scope that claim of the present invention limited, revise, even equivalence, but all will fall within the scope of protection of the present invention.
Claims (18)
1. the manufacture method of a polrvinyl chloride anti-static rubber, its step comprises:
(a) coating one deck thickener on a base fabric is wound into one and sticks with paste cloth behind the heating, drying;
(b) polyvinyl chloride sizing material processing back is formed an adhesive plaster; Then
(c) described adhesive plaster and described paste cloth are fitted, form polyvinyl chloride calendering rubber.
2. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that described base fabric is fabric or non-woven.
3. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that described thickener comprises the solvent paste.
4. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that the last paste amount of described thickener is 30～70g/m
2
5. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that described thickener is with 120～180 ℃ temperature heating 10～30 seconds and oven dry.
6. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that thickener described in the described step a uses a pasting machine to coat on the described base fabric.
7. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 6, it is characterized in that described pasting machine one on to stick with paste wheel be 30～120 orders.
8. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that the composition of described polyvinyl chloride sizing material comprises:
The molding powder of 100 weight portions;
The plasticizer of 60 weight portions;
The filler of 16 weight portions;
The antistatic additive of 17 weight portions;
The stabilizing agent of 2 weight portions; And
The look grain.
9. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 8 is characterized in that described plasticizer comprises first plasticizer, 40 weight portions and second plasticizer, 20 weight portions.
10. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 8 is characterized in that described antistatic additive comprises aqueous antistatic additive 15 weight portions and wax shape antistatic additive 2 weight portions.
11. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 8 is characterized in that described antistatic additive is inherent type antistatic additive.
12. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 8 is characterized in that described look grain comprises redness, green, blueness and yellow look grain.
13. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 8 is characterized in that described stabilizing agent is a powder attitude stabilizing agent for barium zinc.
14. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that further comprising among the described step b:
The polyvinyl chloride sizing material is stirred in a mixer;
Carry out mixing gel by 10,000 horsepowers of machines; And
Send into and form described adhesive plaster in the adhesive tape machine body.
15. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 14, the rotating speed that it is characterized in that described mixer are 1700～2300 commentaries on classics, temperature is 80～120 ℃, and mixing time is 4～6 minutes.
16. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 14, the temperature that it is characterized in that described ten thousand horsepowers of machines is 130～170 ℃, and mixing gel process is 3～6 minutes.
17. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 14 is characterized in that the laggard row insulation of the mixing gel of described polyvinyl chloride sizing material material controlling, the temperature of insulation is 120～160 ℃, and temperature retention time is 2～4 minutes.
18. the manufacture method of polrvinyl chloride anti-static rubber as claimed in claim 1 is characterized in that adding conductive carbon black in the described base fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101423411A CN101898439A (en) | 2009-05-27 | 2009-05-27 | Manufacturing method for polrvinyl chloride anti-static rubber |
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| CN2009101423411A CN101898439A (en) | 2009-05-27 | 2009-05-27 | Manufacturing method for polrvinyl chloride anti-static rubber |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045120A (en) * | 2011-10-12 | 2013-04-17 | 厚生股份有限公司 | Manufacturing method for anti-static rubber and structure thereof |
| CN103666308A (en) * | 2012-09-05 | 2014-03-26 | 厚生股份有限公司 | Flame-retardant compound adhesive tape and manufacturing method thereof |
| CN105415836A (en) * | 2014-09-22 | 2016-03-23 | 厚生股份有限公司 | Method for manufacturing PVC/EVA composite material antistatic articles |
| CN105437688A (en) * | 2014-09-18 | 2016-03-30 | 厚生股份有限公司 | Manufacture method for TPU-PVC composite material |
| CN105623146A (en) * | 2016-01-29 | 2016-06-01 | 芜湖利通新材料有限公司 | PVC (polyvinyl chloride) rubber formula |
| CN110154492A (en) * | 2018-11-26 | 2019-08-23 | 四川金路高新材料有限公司 | A kind of production technology of anti-fold hot-water bottle leather |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5557432A (en) * | 1978-10-24 | 1980-04-28 | Toyo Rubber Chem Ind Co Ltd | Manufacture of combined vinyl chloride and base cloth sheet |
| CN1209829A (en) * | 1996-11-22 | 1999-03-03 | 大瑟路化学工业株式会社 | Heat-fusible composition and multi-layer mouldings comprising layers made therefrom |
| CN101096244A (en) * | 2007-07-29 | 2008-01-02 | 宋长江 | Thermoplastic elastomer surface unitary-core flame-resistant conveying belt and manufacturing method thereof |
| CN101397382A (en) * | 2007-09-29 | 2009-04-01 | 苏州工业园区凯维新材料有限公司 | Anti-yellowing polyvinyl chloride |
| CN101423642A (en) * | 2007-10-29 | 2009-05-06 | 厚生股份有限公司 | Non-toxic polyvinyl chloride rolling product and production formula thereof |
-
2009
- 2009-05-27 CN CN2009101423411A patent/CN101898439A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5557432A (en) * | 1978-10-24 | 1980-04-28 | Toyo Rubber Chem Ind Co Ltd | Manufacture of combined vinyl chloride and base cloth sheet |
| CN1209829A (en) * | 1996-11-22 | 1999-03-03 | 大瑟路化学工业株式会社 | Heat-fusible composition and multi-layer mouldings comprising layers made therefrom |
| CN101096244A (en) * | 2007-07-29 | 2008-01-02 | 宋长江 | Thermoplastic elastomer surface unitary-core flame-resistant conveying belt and manufacturing method thereof |
| CN101397382A (en) * | 2007-09-29 | 2009-04-01 | 苏州工业园区凯维新材料有限公司 | Anti-yellowing polyvinyl chloride |
| CN101423642A (en) * | 2007-10-29 | 2009-05-06 | 厚生股份有限公司 | Non-toxic polyvinyl chloride rolling product and production formula thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045120A (en) * | 2011-10-12 | 2013-04-17 | 厚生股份有限公司 | Manufacturing method for anti-static rubber and structure thereof |
| CN103666308A (en) * | 2012-09-05 | 2014-03-26 | 厚生股份有限公司 | Flame-retardant compound adhesive tape and manufacturing method thereof |
| CN105437688A (en) * | 2014-09-18 | 2016-03-30 | 厚生股份有限公司 | Manufacture method for TPU-PVC composite material |
| CN105415836A (en) * | 2014-09-22 | 2016-03-23 | 厚生股份有限公司 | Method for manufacturing PVC/EVA composite material antistatic articles |
| CN105623146A (en) * | 2016-01-29 | 2016-06-01 | 芜湖利通新材料有限公司 | PVC (polyvinyl chloride) rubber formula |
| CN110154492A (en) * | 2018-11-26 | 2019-08-23 | 四川金路高新材料有限公司 | A kind of production technology of anti-fold hot-water bottle leather |
| CN110154492B (en) * | 2018-11-26 | 2021-07-09 | 四川金路高新材料有限公司 | Production process of anti-wrinkle hot-water bag leather |
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Application publication date: 20101201 |