CN102234490A - Manufacturing method of composite adhesive tape with high adhesion and high wear resistance - Google Patents
Manufacturing method of composite adhesive tape with high adhesion and high wear resistance Download PDFInfo
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- CN102234490A CN102234490A CN2010101630819A CN201010163081A CN102234490A CN 102234490 A CN102234490 A CN 102234490A CN 2010101630819 A CN2010101630819 A CN 2010101630819A CN 201010163081 A CN201010163081 A CN 201010163081A CN 102234490 A CN102234490 A CN 102234490A
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- adhesive plaster
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Abstract
The invention provides a manufacturing method of a composite adhesive tape with high adhesion and high wear resistance. The manufacturing method comprises the following steps: firstly immersing a base cloth in a hardening dilute solution, then heating the base cloth for drying, applying a binder on one surface of the base cloth, and finally affixing a composite adhesive film containing polyvinyl chloride (PVC) and polyurethane (TPU) to the surface of the base cloth through the binder. In the manufacturing process, the base cloth is immersed in the hardening dilute solution, thus enhancing the adhesive strength of the base cloth; and simultaneously the characteristics of the composite adhesive film are utilized to effectively reduce the overall chlorine content, thus reducing the possibility of harm to human health.
Description
Technical field
The present invention relates to a kind of manufacture method of adhesive plaster, particularly a kind of high then with the manufacture method of the compound adhesive plaster of high abrasion.
Background technology
Polyvinyl chloride { PVC, (Poly (vinyl chloride)) } be most important and use the most general a kind of among the man-made polymer, mainly be because it has very big variability, in the process of making polyvinyl chloride product, can cooperate different purposes and needs, add various plasticizers and additive and change its physics or chemical property.
After the maximum of polyvinyl chloride was characterized as and adds aqueous plasticizer, glass transition temperature (Tg) point will begin to descend, and because of plasticization can make semi-rigid to soft material with extensive spring rate, this is the reason of soft PVC tool practicality.And the polyvinyl chloride work range is very wide, is used by arrange in pairs or groups all kinds of modification agents of different polymerization degree, can obtain the product of complete different rerum naturas, and institute thinks widely used polymer.
Yet, the melt temperature of polyvinyl chloride is not high, the temperature of its moulding be controlled at usually Celsius 150 to 180 the degree between, therefore the temperature tolerance of polyvinyl chloride is poor, in addition, the chemical composition of polyvinyl chloride is carbon, hydrogen, chlorine, after polyvinyl chloride produces thermolysis, can produce carcinogenic hydrogenchloride, and then influence HUMAN HEALTH.
Therefore, the present invention is directed to above-mentioned puzzlement, propose a kind of high then with the manufacture method of the compound adhesive plaster of high abrasion, to solve the problem that prior art was produced.
Summary of the invention
Main purpose of the present invention, be to provide a kind of high then with the manufacture method of the compound adhesive plaster of high abrasion, it is in manufacturing processed, base fabric is dipped in the sclerosis diluting soln, to strengthen the then intensity of cloth, more fit mutually simultaneously,, and reduce the chance that injures HUMAN HEALTH with the whole cl content of effective reduction with the compound cutan of polyvinyl chloride and polyurethane(s).
For reaching above-mentioned purpose, the invention provides a kind of high then with the manufacture method of the compound adhesive plaster of high abrasion, at first in a sclerosis diluting soln, embathe a base fabric, then heat this base fabric with oven dry, form the surface of a binder in base fabric again, a compound cutan that will have polyvinyl chloride (PVC) and polyurethane(s) (TPU) at last concurrently sees through the surface that above-mentioned binder fits in base fabric.
Wherein, in the step of this base fabric of oven dry, be with 180 ± 20 degree heating Celsius 10～20 seconds.
Wherein, forming this binder after the step of this base fabric is finished, is with 180 ± 20 degree Celsius this base fabric to be heated 10～20 seconds, again this compound cutan is seen through this binder and fits in this base fabric.
Wherein, seeing through this binder at this compound cutan and fit in the step of this base fabric, is to be under the environment of 180 ± 20 degree Celsius in temperature, utilizes embossed wheel that this compound cutan is exerted pressure, and fits on this base fabric so that this compound cutan is seen through this binder.
Wherein, the manufacture method of this compound cutan comprises the following step: carry out mixing with 90～180 degree Celsius a compound sizing material that comprises this polyvinyl chloride and this polyurethane(s); And this compound sizing material that comprises this polyvinyl chloride and this polyurethane(s) sent in the film generation device, form this compound cutan through being calendered to a fixed thickness.
Wherein, to comprise the weighting agent of 10 weight parts (PHR), the plasticizer of 80 weight parts, the plastic powder of 50 weight parts, the polyurethane(s) grain of 50 weight parts, the barium-zinc (Ba-Zn) of 2 weight parts be liquid tranquilizer, 1 weight part epoxy soybean oil to this moiety that comprises the compound sizing material of this polyvinyl chloride and this polyurethane(s).
Wherein, the moiety of this binder comprises the solid of 100 weight parts and the bridging agent of 5 weight parts.
Wherein, this solid is polyurathamc (PU), and this bridging agent is isocyanate group (Isocyanate).
Wherein, the moiety of this sclerosis diluting soln comprises isocyanate (Hylene) stiffening agent of the isocyanic ester base system of 1 weight part, and the toluene of 80 weight parts.
Wherein, the material of this base fabric is polyester (polyester).
In sum, the present invention is dipped in base fabric in the sclerosis diluting soln, to strengthen the then intensity of cloth, more utilizes the voltinism of the compound cutan of polyvinyl chloride and polyurethane(s) simultaneously, have the polyvinyl chloride of high cl content with replacement, and reduce the chance of injury HUMAN HEALTH simultaneously.
Description of drawings
Fig. 1 is the manufacture method schema of compound adhesive plaster of the present invention;
Fig. 2 is a compound adhesive plaster structure sectional view of the present invention;
Fig. 3 is the manufacture method schema of compound cutan of the present invention.
Description of reference numerals: 10-base fabric; The 12-compound cutan.
Embodiment
Below in conjunction with drawings and Examples, be described in more detail with other technical characterictic and advantage the present invention is above-mentioned, it should be understood that these embodiment only are used for the purpose of illustration, never limit protection scope of the present invention.
Below see also Fig. 1, at first shown in step S10, embathe the base fabric that a material is polyester (polyester) in a sclerosis diluting soln, to reduce the viscosity of base fabric, making the solution weight of having on the base fabric is 150 ± 20 gram/square centimeter (g/cm
2), the moiety of the diluting soln that wherein hardens comprises isocyanate (Hylene) stiffening agent that the isocyanate group (Isocyanate) of 1 weight part (PHR) is, and the toluene of 80 weight parts.Shown in step S12, be then to base fabric heating 10～20 seconds, to dry it with 180 ± 20 degree Celsius.Come again shown in step S14, use and stick with paste wheel paper one binder on 30～120 purposes in a surface of base fabric, wherein the moiety of binder comprises the solid of 100 weight parts and the bridging agent of 5 weight parts, and solid is polyurathamc (PU), and bridging agent is an isocyanate group.
After binder has papered, shown in step S16, be to base fabric heating 10～20 seconds, to dry it with 180 ± 20 degree Celsius.Shown in step S18, be under the environment of 180 ± 20 degree Celsius at last, utilize embossed wheel to exert pressure with a compound cutan of polyurethane(s) (TPU), so that this glued membrane is seen through the surface that above-mentioned binder fits in base fabric to having polyvinyl chloride (PVC) concurrently in temperature.The structure sectional view of the compound adhesive plaster of finishing as shown in Figure 2, base fabric 10 is fitted with compound cutan 12, wherein the thickness of base fabric is 0.1 centimetre, the thickness of compound cutan is 0.5 centimetre.
Polyvinyl chloride itself be use among the man-made polymer the most general a kind of, in addition, the rerum natura of polyurethane(s) is between plastic material and elastomeric material, therefore when the blending of polyvinyl chloride adding polyurethane(s), not only can effectively reduce whole cl content, also, can replace the function of plasticizer owing to have elasticity.Moreover the polyester base fabric has compatible effect based on base fabric after being soaked and solid after the sclerosis diluting soln embathes, and can strengthen polyvinyl chloride and the mutual then intensity of polyurethane(s) in the compound cutan.
Deliver to the lab analysis check with making good composite gum cloth, the then intensity that obtains adhesive plaster is more than 50 newton/centimetres (N/cm), and the wear-resisting effect of its glue face is that hence one can see that below 0.5 gram/1000 changeed, and this compound adhesive plaster has the height that is better than general adhesive plaster and follows and the high abrasion characteristic.
Below introduce the manufacturing process of above-mentioned compound cutan, as shown in Figure 3, at first shown in step S20, the one compound sizing material blending dispersion that comprises polyvinyl chloride and polyurethane(s) is placed kneading device, and carry out mixingly with 90～180 degree, wherein to comprise the weighting agent of 10 weight parts, the plasticizer of 80 weight parts, the plastic powder of 50 weight parts, the polyurethane(s) grain of 50 weight parts, the barium-zinc (Ba-Zn) of 2 weight parts be liquid tranquilizer, 1 weight part epoxy soybean oil to the moiety of compound sizing material.Wherein weighting agent is lime carbonate CaCO
3, plasticizer is a dioctyl phthalate (DOP), plastic powder is a polyvinylchloride.Then shown in step S22, compound sizing material is drawn from kneading device, and deliver to the film generation device, form compound cutan through continuous calendering to a fixed thickness, this thickness is 0.5 centimetre.
In sum, the present invention is dipped in base fabric in the sclerosis diluting soln, to strengthen the then intensity of cloth, more utilizes the voltinism of the compound cutan of polyvinyl chloride and polyurethane(s) simultaneously, have the polyvinyl chloride of high cl content with replacement, and reduce the chance of injury HUMAN HEALTH simultaneously.
The above only is preferred embodiment of the present invention, only is illustrative for the purpose of the present invention, and nonrestrictive.Those skilled in the art is understood, and can carry out many changes to it in the spirit and scope that claim of the present invention limited, revise, even equivalence, but all will fall within the scope of protection of the present invention.
Claims (10)
- One kind high then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that comprising the following step:In a sclerosis diluting soln, embathe a base fabric;Dry this base fabric;Form the surface of a binder in this base fabric; AndA compound cutan that has polyvinyl chloride and polyurethane(s) concurrently is seen through the surface that this binder fits in this base fabric.
- 2. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that in the step of this base fabric of oven dry, be with 180 ± 20 degree heating Celsius 10～20 seconds.
- 3. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that forming this binder after the step of this base fabric is finished, be this base fabric to be heated 10～20 seconds, again this compound cutan seen through this binder and fit in this base fabric with 180 ± 20 degree Celsius.
- 4. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that seeing through this binder at this compound cutan fits in the step of this base fabric, be temperature be Celsius 180 ± 20 the degree environment under, utilize embossed wheel that this compound cutan is exerted pressure, fit on this base fabric so that this compound cutan is seen through this binder.
- 5. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that the manufacture method of this compound cutan comprises the following step:Carry out mixing with 90～180 degree Celsius a compound sizing material that comprises this polyvinyl chloride and this polyurethane(s); AndThis compound sizing material that comprises this polyvinyl chloride and this polyurethane(s) is sent in the film generation device, formed this compound cutan through being calendered to a fixed thickness.
- 6. height as claimed in claim 5 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that barium-zinc that this moiety that comprises the compound sizing material of this polyvinyl chloride and this polyurethane(s) comprises the polyurethane(s) grain of the plastic powder of the plasticizer of the weighting agent of 10 weight parts, 80 weight parts, 50 weight parts, 50 weight parts, 2 weight parts is liquid tranquilizer, 1 weight part epoxy soybean oil.
- 7. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that the moiety of this binder comprises the solid of 100 weight parts and the bridging agent of 5 weight parts.
- 8. height as claimed in claim 7 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that this solid is a polyurathamc, this bridging agent is an isocyanate group.
- 9. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, it is characterized in that the moiety of this sclerosis diluting soln comprises the isocyanate stiffening agent of the isocyanic ester base system of 1 weight part, reach the toluene of 80 weight parts.
- 10. height as claimed in claim 1 then with the manufacture method of the compound adhesive plaster of high abrasion, the material that it is characterized in that this base fabric is a polyester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101630819A CN102234490A (en) | 2010-04-30 | 2010-04-30 | Manufacturing method of composite adhesive tape with high adhesion and high wear resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101630819A CN102234490A (en) | 2010-04-30 | 2010-04-30 | Manufacturing method of composite adhesive tape with high adhesion and high wear resistance |
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| CN102234490A true CN102234490A (en) | 2011-11-09 |
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| CN2010101630819A Pending CN102234490A (en) | 2010-04-30 | 2010-04-30 | Manufacturing method of composite adhesive tape with high adhesion and high wear resistance |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102729559A (en) * | 2012-06-25 | 2012-10-17 | 无锡翔隆高分子面料有限公司 | Preparation method of TPU and PVC blended improved composite fabrics |
| CN103131345A (en) * | 2011-12-05 | 2013-06-05 | 何信定 | Gummed cloth and manufacturing method of gummed cloth |
| CN103254613A (en) * | 2013-03-08 | 2013-08-21 | 许清水 | RVAC synthetic adhesive plaster |
| CN103571368A (en) * | 2012-07-18 | 2014-02-12 | 厚生股份有限公司 | Composite adhesive tape structure with high adhesive strength and manufacturing method thereof |
| CN103666308A (en) * | 2012-09-05 | 2014-03-26 | 厚生股份有限公司 | Flame-retardant compound adhesive tape and manufacturing method thereof |
| CN103862783A (en) * | 2012-12-13 | 2014-06-18 | 厚生股份有限公司 | Making method of ultrathin elastic adhesive tape |
| CN103981699A (en) * | 2013-02-08 | 2014-08-13 | 厚生股份有限公司 | Method for manufacturing polymer cloth |
| CN110791212A (en) * | 2019-10-28 | 2020-02-14 | 江苏大海塑料股份有限公司 | High-elasticity low-cost adhesive tape for football |
Citations (4)
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|---|---|---|---|---|
| EP0164594A2 (en) * | 1984-05-14 | 1985-12-18 | Kuraray Co., Ltd. | Heat-laminatable composite film and laminated material using the same |
| JP2000191993A (en) * | 1998-12-25 | 2000-07-11 | Minnesota Mining & Mfg Co <3M> | Adhesive sheet, protection film for adhesive film, structural body for floor surface protection and production of adhesive sheet |
| CN101210389A (en) * | 2006-12-30 | 2008-07-02 | 厚生股份有限公司 | Method for processing low-smoke flame-retardant rubber cloth |
| CN101423642A (en) * | 2007-10-29 | 2009-05-06 | 厚生股份有限公司 | Non-toxic polyvinyl chloride rolling product and production formula thereof |
-
2010
- 2010-04-30 CN CN2010101630819A patent/CN102234490A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0164594A2 (en) * | 1984-05-14 | 1985-12-18 | Kuraray Co., Ltd. | Heat-laminatable composite film and laminated material using the same |
| JP2000191993A (en) * | 1998-12-25 | 2000-07-11 | Minnesota Mining & Mfg Co <3M> | Adhesive sheet, protection film for adhesive film, structural body for floor surface protection and production of adhesive sheet |
| CN101210389A (en) * | 2006-12-30 | 2008-07-02 | 厚生股份有限公司 | Method for processing low-smoke flame-retardant rubber cloth |
| CN101423642A (en) * | 2007-10-29 | 2009-05-06 | 厚生股份有限公司 | Non-toxic polyvinyl chloride rolling product and production formula thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131345A (en) * | 2011-12-05 | 2013-06-05 | 何信定 | Gummed cloth and manufacturing method of gummed cloth |
| CN102729559A (en) * | 2012-06-25 | 2012-10-17 | 无锡翔隆高分子面料有限公司 | Preparation method of TPU and PVC blended improved composite fabrics |
| CN102729559B (en) * | 2012-06-25 | 2015-09-30 | 无锡翔隆高分子面料有限公司 | The preparation method of the blended improvement composite material of a kind of TPU and PVC |
| CN103571368A (en) * | 2012-07-18 | 2014-02-12 | 厚生股份有限公司 | Composite adhesive tape structure with high adhesive strength and manufacturing method thereof |
| CN103666308A (en) * | 2012-09-05 | 2014-03-26 | 厚生股份有限公司 | Flame-retardant compound adhesive tape and manufacturing method thereof |
| CN103862783A (en) * | 2012-12-13 | 2014-06-18 | 厚生股份有限公司 | Making method of ultrathin elastic adhesive tape |
| CN103981699A (en) * | 2013-02-08 | 2014-08-13 | 厚生股份有限公司 | Method for manufacturing polymer cloth |
| CN103254613A (en) * | 2013-03-08 | 2013-08-21 | 许清水 | RVAC synthetic adhesive plaster |
| CN110791212A (en) * | 2019-10-28 | 2020-02-14 | 江苏大海塑料股份有限公司 | High-elasticity low-cost adhesive tape for football |
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Application publication date: 20111109 |