CN107419614A - One kind is used for anlistatig wallpaper for decoration - Google Patents

One kind is used for anlistatig wallpaper for decoration Download PDF

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Publication number
CN107419614A
CN107419614A CN201610345077.1A CN201610345077A CN107419614A CN 107419614 A CN107419614 A CN 107419614A CN 201610345077 A CN201610345077 A CN 201610345077A CN 107419614 A CN107419614 A CN 107419614A
Authority
CN
China
Prior art keywords
wallpaper
antistatic additive
antistatic
coating material
decoration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610345077.1A
Other languages
Chinese (zh)
Inventor
徐小芹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610345077.1A priority Critical patent/CN107419614A/en
Publication of CN107419614A publication Critical patent/CN107419614A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D21H19/68—Coatings characterised by a special visual effect, e.g. patterned, textured uneven, broken, discontinuous
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention be in order to manufacture it is a kind of there is high-antistatic performance and be easy to the wallpaper for decoration for making electrostatic leakage, put aside with the electrostatic solved in the electric panel room having higher requirements and interference.Method is coating material of the even spread with antistatic additive and to be allowed to heating plasticizing on paper substrate and turn into a kind of anlistatig wallpaper, and antistatic additive coating material is by polyvinyl chloride（PVC）, dioctyl phthalate（DOP）, butyl benzyl（BBP）Calcium carbonate（CaCO ↓ ［ 3 ］）, azodicarbonamide（AC）, titanium dioxide（TiO ↓ ［ 2 ］）, zinc oxide（ZnO）, CZ-2 liquid calcium zinc complex stabilizers（Ca/Zn）, amide-type antistatic additive（HOA）Composition.

Description

One kind is used for anlistatig wallpaper for decoration
Technical field
The present invention relates to the anlistatig wallpaper for decoration of energy for interior.
Background technology
At present, in computer floor, automated workshop, semiconductor integrated component product workshop, electronic circuit Maintenance Room, precision Streamline, automatic dispatching room, electric panel room, the interior such as storehouse of electronic component, in addition to requiring wallpaper and there is decoration function, Also needing to this kind of wallpaper has antistatic property.Because in interiors such as computer floors, the interference of electrostatic will cause misprogramming, Component failure, severe patient will produce malfunction even device damage.Moreover, easily cause electrostatic to be put aside in using practice, The defects of being not easy to disappear and adsorbing dust, it is unfavorable for the antistatic use for requiring the higher interior space such as computer floor.This hair Bright purpose is to manufacture a kind of wallpaper for decoration for having high-antistatic performance and being easy to make electrostatic leakage.
The content of the invention
The antistatic wallpaper primary raw material of the present invention is to use polyvinyl chloride（PVC）Resin, and PVC is excellent insulation in itself Material, because its resistive performance is very high, easily electrostatic is caused to be put aside, will when the electrostatic field of formation exceedes certain limit Static discharge phenomenon is produced, easily causes the accidents such as computer program disorder.In order to reach sewing for electrostatic, by amide-type （HOA）Antistatic additive, which is added in the plastic paste that polyvinyl chloride resin is prepared with other materials, makes it equably be coated on substrate surface.It is anti- Electrostatic agent has certain intermiscibility with PVC, can be adsorbed on PVC strands, and this antistatic additive is hydrophily base Group, has certain hygroscopicity, adds wallpaper surface-active, forms a monomolecular conducting film, electrostatic energy is passed through conduction Film is sewed, and plays antistatic property.In addition, there is certain immiscible property between such a antistatic additive and PVC, therefore, when leading When electrolemma goes to pot, the antistatic additive in PVC coatings can ooze out in time, form the new conducting film with antistatic effect, So such a antistatic wallpaper also has certain rub resistance, washing fastness.
Because polyvinyl chloride resin heat endurance is poor, when making temperature reaches 160~220 DEG C, PVC can be decomposed, therefore, also It must be added to avirulent CZ-2 liquid calcium zinc complex stabilizers（That is the compound such as calcium zinc and phosphite ester, abbreviation Ca/Zn）, come Improve PVC stability.In addition, also to add plasticizer liquid（O-2 potassium acid dioctyl ester, abbreviation DOP）, and butyl benzyl（ It is BBP）, calcium carbonate（CaCO3）, azo dipotassium amide（Also it is AC）, titanium dioxide（TiO2）, zinc oxide（ZnO）Deng raw material.
The preparation of antistatic coating material is in following ratio：
Title code name proportioning acts on
Polyvinylchloride 61-32% adhesives
Dioctyl phthalate DOP 24-33% plasticizer
Butyl benzyl BBP 3-7% plasticizer
Calcium carbonate CaCO36-17% inserts
Azo dipotassium amide AC 0.5-2% foaming agents
Titanium dioxide TiO23-5% colouring agents
Zinc oxide ZnO 0.3-1.0% colorings, inspire infusion
The 0.5-2% stabilizers of CZ-2 liquid calcium zinc complex stabilizer Ca/Zn calcium contents 0.8 ± 0.1%
Zn content 5.8 ± 2%
Amide-type antistatic additive HOA 2-6% antistatic additive.
The coating material being configured to according to the above ratio is spread evenly across on paper substrate, is carried out baking oven plasticizing, can be turned into antistatic Wallpaper.It is embossed after plasticizing on wallpaper, decorative effect can be obtained by producing certain pattern.
The antistatic wallpaper made of such a method, its sheet resistance are 3.85 × 107Ω.Used by 3 years, its table Surface resistance is 1.5 × 10 through repetition measurement7Ω。
Embodiment：In following ratio
Code name ratio
PVC 43.29%
DOP 28.14%
BBP 4.33%
CaCO3 12.99%
AC 0.87%
TiO2 4.33%
ZnO 0.43%
Ca/Zn 1.29%
HOA 4.33%
The slurry being made into, is spread evenly across paper substrate（It is required that：Wood fibre accounts for 75% in paper substrate, and cotton fibre accounts for 25%, weight 100g/m2, thickness 0.15mm）On, coating layer thickness rests in 0.35, is plastified through 200 DEG C of baking ovens, and after being sent into cotton gin embossing, The antistatic wallpaper with certain decorative effect can be obtained.After tested, such a wallpaper sheet resistance value is 7 × 106~2 × 107 Ω。

Claims (2)

1. one kind is used for anlistatig wallpaper for decoration, it is characterised in that the anlistatig wallpaper for decoration is a kind of antistatic Agent coating material is spread evenly across on paper substrate, antistatic additive coating material by polyvinyl chloride (PVC), dioctyl phthalate (DOP), Butyl benzyl (BBP), calcium carbonate (CaCO3), azodicarbonamide (AC), titanium dioxide (TiO2), zinc oxide (ZnO), CZ-2 liquid calciums Zinc composite stabilizer (Ca/Zn), amide-type antistatic additive (HOA) composition.
2. the antistatic additive coating material of antistatic wallpaper according to claim 1, it is characterised in that this is a kind of slurry, Its composition and proportioning be：Title code name weight is than polyvinylchloride 61-32% dioctyl phthalates DOP 24-33% butyl benzyl BBP 3-7% calcium carbonate CaCO36-17% azo dipotassium amide AC 0.5-2% titanium dioxides TiO23- 5% zinc oxide ZnO 0.3-1.0%CZ-2 liquid calcium zinc complex stabilizer Ca/Zn 0.5-2% amide-type antistatic additive HOA 2-6%。
CN201610345077.1A 2016-05-24 2016-05-24 One kind is used for anlistatig wallpaper for decoration Pending CN107419614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610345077.1A CN107419614A (en) 2016-05-24 2016-05-24 One kind is used for anlistatig wallpaper for decoration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610345077.1A CN107419614A (en) 2016-05-24 2016-05-24 One kind is used for anlistatig wallpaper for decoration

Publications (1)

Publication Number Publication Date
CN107419614A true CN107419614A (en) 2017-12-01

Family

ID=60422244

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610345077.1A Pending CN107419614A (en) 2016-05-24 2016-05-24 One kind is used for anlistatig wallpaper for decoration

Country Status (1)

Country Link
CN (1) CN107419614A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109296152A (en) * 2018-09-12 2019-02-01 浙江路联装饰材料有限公司 A kind of antistatic wall paper and its production technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109296152A (en) * 2018-09-12 2019-02-01 浙江路联装饰材料有限公司 A kind of antistatic wall paper and its production technology
CN109296152B (en) * 2018-09-12 2020-10-27 浙江路联装饰材料有限公司 Anti-static wall cloth and production process thereof

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Application publication date: 20171201