CN101885557B - 一种含酚废水的回收和处理方法 - Google Patents
一种含酚废水的回收和处理方法 Download PDFInfo
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- CN101885557B CN101885557B CN 201010207908 CN201010207908A CN101885557B CN 101885557 B CN101885557 B CN 101885557B CN 201010207908 CN201010207908 CN 201010207908 CN 201010207908 A CN201010207908 A CN 201010207908A CN 101885557 B CN101885557 B CN 101885557B
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- reaction
- waste water
- phenol
- wastewater
- formaldehyde
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- 239000002351 wastewater Substances 0.000 title claims abstract description 98
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 55
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000003054 catalyst Substances 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000006467 substitution reaction Methods 0.000 claims abstract description 7
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 45
- 239000000243 solution Substances 0.000 claims description 31
- 229920003987 resole Polymers 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 27
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 26
- 239000008098 formaldehyde solution Substances 0.000 claims description 17
- 238000007254 oxidation reaction Methods 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 14
- 239000011240 wet gel Substances 0.000 claims description 14
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 13
- 238000011084 recovery Methods 0.000 claims description 13
- 238000000926 separation method Methods 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 230000035484 reaction time Effects 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 230000002378 acidificating effect Effects 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- -1 Marinco H Substances 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 244000005700 microbiome Species 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 2
- 239000005011 phenolic resin Substances 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000009279 wet oxidation reaction Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 10
- 238000000605 extraction Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 238000001514 detection method Methods 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 4
- 229940090668 parachlorophenol Drugs 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- GAKLFAZBKQGUBO-UHFFFAOYSA-N 2-methyl-3-nitrophenol Chemical compound CC1=C(O)C=CC=C1[N+]([O-])=O GAKLFAZBKQGUBO-UHFFFAOYSA-N 0.000 description 1
- HORNXRXVQWOLPJ-UHFFFAOYSA-N 3-chlorophenol Chemical compound OC1=CC=CC(Cl)=C1 HORNXRXVQWOLPJ-UHFFFAOYSA-N 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- 208000012902 Nervous system disease Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Removal Of Specific Substances (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN 201010207908 CN101885557B (zh) | 2010-06-24 | 2010-06-24 | 一种含酚废水的回收和处理方法 |
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CN 201010207908 CN101885557B (zh) | 2010-06-24 | 2010-06-24 | 一种含酚废水的回收和处理方法 |
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CN101885557A CN101885557A (zh) | 2010-11-17 |
CN101885557B true CN101885557B (zh) | 2012-07-25 |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102146342B (zh) * | 2011-01-11 | 2012-01-04 | 山东潍坊润丰化工有限公司 | 一种嗜盐菌菌剂及其制备方法和固定有菌剂的生物处理***及其应用 |
CN104671384A (zh) * | 2014-12-31 | 2015-06-03 | 西北大学 | 兰炭废水或焦化废水的资源化处理方法 |
CN104787955B (zh) * | 2015-04-17 | 2016-10-12 | 青岛科技大学 | 一种含酚废水中有机物去除的方法 |
CN104761095B (zh) * | 2015-04-17 | 2017-03-08 | 青岛科技大学 | 一种含酚废水颜色脱除的方法 |
CN106430768B (zh) * | 2015-08-10 | 2019-07-19 | 彤程化学(中国)有限公司 | 一种酚醛树脂含酚含醛废水的处理方法 |
CN105236611B (zh) * | 2015-09-25 | 2018-02-02 | 浙江奇彩环境科技股份有限公司 | 一种苯类废水的处理方法 |
CN105198094B (zh) * | 2015-10-22 | 2017-06-20 | 黄河三角洲京博化工研究院有限公司 | 一种强化处理工业高含酚废水的方法 |
CN107721081A (zh) * | 2017-11-22 | 2018-02-23 | 江苏省环境科学研究院 | 一种氯酚类废水的无害化处理***及方法 |
CN108408957B (zh) * | 2018-02-13 | 2021-09-24 | 洛阳理工学院 | 一种沉淀-活性炭吸附联合处理酚类废水的方法 |
CN109306043B (zh) * | 2018-09-20 | 2021-01-12 | 吉林大学 | 一种生物质发电含酚焦油废水回收利用的方法 |
CN111115940A (zh) * | 2019-12-31 | 2020-05-08 | 江苏远畅环保科技有限公司 | 一种工业废水处理*** |
CN112047572A (zh) * | 2020-09-08 | 2020-12-08 | 江苏众志新禹环境科技有限公司 | 含酚废水的处理方法 |
CN113816563A (zh) * | 2021-09-30 | 2021-12-21 | 天津正达科技有限责任公司 | 一种煤化工含酚废水的处理方法 |
CN115784534B (zh) * | 2023-01-09 | 2023-07-21 | 湖北省宏源药业科技股份有限公司 | D-对羟基苯甘氨酸生产废水多级连续聚合处理方法及装置 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4370241A (en) * | 1977-01-27 | 1983-01-25 | Degussa Ag | Process for the detoxification of waste water containing phenol, phenol derivative or phenol and formaldehyde |
CN101215055A (zh) * | 2008-01-03 | 2008-07-09 | 山东圣泉化工股份有限公司 | 一种酚醛污水回收治理的方法 |
CN101264995A (zh) * | 2008-04-21 | 2008-09-17 | 赵四刚 | 酚醛树脂生产废水的循环利用工艺 |
-
2010
- 2010-06-24 CN CN 201010207908 patent/CN101885557B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4370241A (en) * | 1977-01-27 | 1983-01-25 | Degussa Ag | Process for the detoxification of waste water containing phenol, phenol derivative or phenol and formaldehyde |
CN101215055A (zh) * | 2008-01-03 | 2008-07-09 | 山东圣泉化工股份有限公司 | 一种酚醛污水回收治理的方法 |
CN101264995A (zh) * | 2008-04-21 | 2008-09-17 | 赵四刚 | 酚醛树脂生产废水的循环利用工艺 |
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Address after: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee after: Shandong Weifang Rainbow Chemical Co., Ltd. Address before: 250101 Shandong city of Ji'nan province high tech Zone (Lixia District Shunhua Road No. 750) hi tech innovation service center room A-303 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. Address after: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee after: Shandong Weifang Rainbow Chemical Co., Ltd. Address before: 250101 Shandong city of Ji'nan province high tech Zone (Lixia District Shunhua Road No. 750) hi tech innovation service center room A-303 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. |
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Address after: No. 03001, chlor alkali Road, Weifang Coastal Economic Development Zone, Shandong, Shandong Patentee after: Shandong Weifang Rainbow Chemical Co.,Ltd. Address before: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee before: Shandong Weifang Rainbow Chemical Co.,Ltd. |