CN101787100A - 一种水乳型荧光颜料的合成工艺 - Google Patents
一种水乳型荧光颜料的合成工艺 Download PDFInfo
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- CN101787100A CN101787100A CN 201010113614 CN201010113614A CN101787100A CN 101787100 A CN101787100 A CN 101787100A CN 201010113614 CN201010113614 CN 201010113614 CN 201010113614 A CN201010113614 A CN 201010113614A CN 101787100 A CN101787100 A CN 101787100A
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- 239000000839 emulsion Substances 0.000 title claims abstract description 77
- 239000000049 pigment Substances 0.000 title claims abstract description 63
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 42
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 67
- 238000004945 emulsification Methods 0.000 claims abstract description 28
- 239000004816 latex Substances 0.000 claims description 33
- 229920000126 latex Polymers 0.000 claims description 33
- 239000003999 initiator Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 18
- 230000003750 conditioning effect Effects 0.000 claims description 17
- 239000003995 emulsifying agent Substances 0.000 claims description 16
- 239000007850 fluorescent dye Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 238000012805 post-processing Methods 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 230000001804 emulsifying effect Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 20
- 239000000047 product Substances 0.000 description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- -1 polyoxyethylene Polymers 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000004075 alteration Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 241000024287 Areas Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
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- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
原料 | 重量 | 原料 | 重量 |
丁二烯 | 62 | 乳化剂 | 9.2 |
苯乙烯 | 38 | 调节剂 | 0.3 |
丙烯酸 | 7.2 | 引发剂 | 0.2 |
去离子水 | 120 | 荧光染料 | 5.1 |
原料 | 重量 | 原料 | 重量 |
甲基丙烯酸甲酯 | 55 | 乳化剂 | 8.7 |
甲基丙烯酸丁酯 | 45 | 调节剂 | 0.3 |
丙烯酸 | 7.9 | 引发剂 | 0.2 |
去离子水 | 140 | 荧光染料 | 6.3 |
原料 | 重量 | 原料 | 重量 |
甲基丙烯酸甲酯 | 67 | 乳化剂 | 9.4 |
丙烯腈 | 33 | 调节剂 | 0.3 |
原料 | 重量 | 原料 | 重量 |
丙烯酸 | 8.6 | 引发剂 | 0.2 |
去离子水 | 130 | 荧光染料 | 7.1 |
原料 | 重量 | 原料 | 重量 |
甲基丙烯酸甲酯 | 42 | 乳化剂 | 7.6 |
甲基丙烯酰胺 | 58 | 调节剂 | 0.3 |
丙烯酸 | 7.8 | 引发剂 | 0.2 |
去离子水 | 100 | 荧光染料 | 5.9 |
原料 | 重量 | 原料 | 重量 |
丁二烯 | 44 | 乳化剂 | 9.2 |
苯乙烯 | 56 | 引发剂 | 0.2 |
丙烯酸 | 7.2 | 调节剂 | 3 |
去离子水 | 120 | 荧光染料 | 5.1 |
固含量 | pH | 粘度 | 色差(ΔE) | |
对比实例 | 45.9% | 7.4 | 217S | 3.57 |
固含量 | pH | 粘度 | 色差(ΔE) | |
实施例1 | 46.7% | 7.8 | 41S | 0.71 |
实施例2 | 43.9% | 8.1 | 38S | 0.45 |
实施例3 | 45.2% | 7.5 | 47S | 0.56 |
实施例4 | 51.6% | 8.4 | 65S | 0.28 |
Claims (10)
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CN101787100A true CN101787100A (zh) | 2010-07-28 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709298A (zh) * | 2013-12-16 | 2014-04-09 | 丽王化工(南通)有限公司 | 一种无甲醛荧光涂料乳液及其制备方法 |
CN105951525A (zh) * | 2016-05-04 | 2016-09-21 | 太仓市源创包装材料厂 | 一种具有夜光效果的包装纸 |
CN105951513A (zh) * | 2016-05-04 | 2016-09-21 | 太仓市源创包装材料厂 | 一种具有夜光效果的包装纸的制备方法 |
CN107083104A (zh) * | 2017-06-01 | 2017-08-22 | 黄山加佳荧光材料有限公司 | 一种水性荧光墨水用水乳型荧光颜料的制备方法 |
Citations (6)
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CN1544533A (zh) * | 2003-11-17 | 2004-11-10 | 广州擎天新材料研究开发有限公司 | 一种聚合物型白色有机颜料的制备方法 |
JP2006213863A (ja) * | 2005-02-04 | 2006-08-17 | Dainichiseika Color & Chem Mfg Co Ltd | 蛍光性着色組成物、着色方法および着色物品 |
CN101161697A (zh) * | 2007-09-30 | 2008-04-16 | 攀钢集团攀枝花钢铁研究院 | 一种接枝纳米二氧化钛功能粒子的制备方法 |
EP1991597A1 (en) * | 2006-12-19 | 2008-11-19 | Dow Global Technologies Inc. | Composition comprising polyurethane dispersion having high solids content |
CN101486845A (zh) * | 2008-01-14 | 2009-07-22 | 深圳市海川实业股份有限公司 | 一种纳米色料水性分散体的制备方法 |
CN101538339A (zh) * | 2009-04-23 | 2009-09-23 | 杭州精彩化工有限公司 | 一种荧光颜料乳液的制备方法 |
-
2010
- 2010-02-10 CN CN2010101136142A patent/CN101787100B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1544533A (zh) * | 2003-11-17 | 2004-11-10 | 广州擎天新材料研究开发有限公司 | 一种聚合物型白色有机颜料的制备方法 |
JP2006213863A (ja) * | 2005-02-04 | 2006-08-17 | Dainichiseika Color & Chem Mfg Co Ltd | 蛍光性着色組成物、着色方法および着色物品 |
EP1991597A1 (en) * | 2006-12-19 | 2008-11-19 | Dow Global Technologies Inc. | Composition comprising polyurethane dispersion having high solids content |
CN101161697A (zh) * | 2007-09-30 | 2008-04-16 | 攀钢集团攀枝花钢铁研究院 | 一种接枝纳米二氧化钛功能粒子的制备方法 |
CN101486845A (zh) * | 2008-01-14 | 2009-07-22 | 深圳市海川实业股份有限公司 | 一种纳米色料水性分散体的制备方法 |
CN101538339A (zh) * | 2009-04-23 | 2009-09-23 | 杭州精彩化工有限公司 | 一种荧光颜料乳液的制备方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709298A (zh) * | 2013-12-16 | 2014-04-09 | 丽王化工(南通)有限公司 | 一种无甲醛荧光涂料乳液及其制备方法 |
CN103709298B (zh) * | 2013-12-16 | 2016-07-06 | 丽王化工(南通)有限公司 | 一种无甲醛荧光涂料乳液及其制备方法 |
CN105951525A (zh) * | 2016-05-04 | 2016-09-21 | 太仓市源创包装材料厂 | 一种具有夜光效果的包装纸 |
CN105951513A (zh) * | 2016-05-04 | 2016-09-21 | 太仓市源创包装材料厂 | 一种具有夜光效果的包装纸的制备方法 |
CN107083104A (zh) * | 2017-06-01 | 2017-08-22 | 黄山加佳荧光材料有限公司 | 一种水性荧光墨水用水乳型荧光颜料的制备方法 |
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