CN101781486A - 紫外光固化阻燃涂料及其制备方法 - Google Patents
紫外光固化阻燃涂料及其制备方法 Download PDFInfo
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- CN101781486A CN101781486A CN 201010121966 CN201010121966A CN101781486A CN 101781486 A CN101781486 A CN 101781486A CN 201010121966 CN201010121966 CN 201010121966 CN 201010121966 A CN201010121966 A CN 201010121966A CN 101781486 A CN101781486 A CN 101781486A
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- Prior art keywords
- acrylate
- retardant coating
- monomer
- ultraviolet cured
- agent
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- 238000000576 coating method Methods 0.000 title claims abstract description 27
- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- 239000003063 flame retardant Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 21
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 7
- 238000005303 weighing Methods 0.000 claims abstract description 6
- -1 acrylic ester Chemical class 0.000 claims description 40
- 239000002253 acid Substances 0.000 claims description 36
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 28
- 239000012752 auxiliary agent Substances 0.000 claims description 22
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 18
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000005299 abrasion Methods 0.000 claims description 8
- 125000001246 bromo group Chemical group Br* 0.000 claims description 8
- 239000006224 matting agent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910021538 borax Inorganic materials 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- 150000002924 oxiranes Chemical group 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinyl group Chemical group C1(O)=CC(O)=CC=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 150000003512 tertiary amines Chemical class 0.000 claims description 6
- 239000004254 Ammonium phosphate Substances 0.000 claims description 5
- 238000003848 UV Light-Curing Methods 0.000 claims description 5
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 5
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 5
- 230000003115 biocidal effect Effects 0.000 claims description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 4
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- OWXJKYNZGFSVRC-NSCUHMNNSA-N (e)-1-chloroprop-1-ene Chemical compound C\C=C\Cl OWXJKYNZGFSVRC-NSCUHMNNSA-N 0.000 claims description 3
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 claims description 3
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001924 cycloalkanes Chemical class 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 8
- 239000004814 polyurethane Substances 0.000 abstract description 5
- 229920002635 polyurethane Polymers 0.000 abstract description 5
- WDHYRUBXLGOLKR-UHFFFAOYSA-N phosphoric acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OP(O)(O)=O WDHYRUBXLGOLKR-UHFFFAOYSA-N 0.000 abstract description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 2
- 239000012796 inorganic flame retardant Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000012757 flame retardant agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 8
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000004593 Epoxy Chemical class 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- IQQVCMQJDJSRFU-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO IQQVCMQJDJSRFU-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- 241000282693 Cercopithecidae Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000003340 retarding agent Substances 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
名称 | 类别 | 用量 |
卤代环氧丙烯酸酯EA | 低聚物 | 25~35% |
脂肪族聚氨酯丙烯酸酯PUA | 低聚物 | 10~20% |
磷酸酯丙烯酸酯PA | 低聚物 | 5~10% |
卤代丙烯酸酯 | 单体 | 10~15% |
TMPTA | 单体 | 10~28% |
光引发剂1173 | 光引发剂 | 5~6% |
无机阻燃剂 | 添加剂 | 10~20% |
分散剂 | 添加剂 | 0.5~1% |
哑光粉 | 消光剂 | 3~6% |
耐磨粉 | 耐磨材料 | 5-10% |
消泡剂 | 消泡 | 0.6-2.2% |
流平剂 | 流平 | 0.4-1.8% |
检测项目 | 检测结果 | 检测方法 | 备注 |
涂膜外观 | 平整光滑 | GB1721-79 | |
固化速度 | ≥20 | 2灯一次 | 能量≥300mj/cm2 |
附着力(级数) | 1-2 | GB9286-88 | 划格法 |
涂膜硬度H | ≥2 | GB6739-1999 | 铅笔法 |
耐燃时间min | 20 | GB12441-2005 |
检测项目 | 检测结果 | 检测方法 | 备注 |
火焰传播直径比 | <20 | GB12441-2005 | |
碳化体积cm3 | <25 | GB12441-2005 | |
质量损失g | <5 | GB12441-2005 | |
耐盐水浸泡 | 无变化 | GB/T1733-93 | 168小时 |
耐丁酮擦拭 | 大于100次 | GB/T1743-93 | |
柔韧性mm | 1 | GB/T1731-93 | 干膜30um |
耐热性 | 无脱膜开裂 | GB/T1735-85 |
Claims (8)
Priority Applications (1)
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CN2010101219662A CN101781486B (zh) | 2010-03-11 | 2010-03-11 | 紫外光固化阻燃涂料及其制备方法 |
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CN2010101219662A CN101781486B (zh) | 2010-03-11 | 2010-03-11 | 紫外光固化阻燃涂料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101781486A true CN101781486A (zh) | 2010-07-21 |
CN101781486B CN101781486B (zh) | 2012-03-21 |
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Cited By (27)
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CN102167950A (zh) * | 2011-03-18 | 2011-08-31 | 赣州市赐彩油墨涂料实业有限公司 | 一种真空电镀涂料及其制备与施工方法 |
CN103012634A (zh) * | 2012-12-10 | 2013-04-03 | 苏州市明大高分子科技材料有限公司 | 一种紫外光固化的磷酸酯改性丙烯酸酯低聚物及其制备方法 |
CN103450795A (zh) * | 2013-09-17 | 2013-12-18 | 成都优品涂料有限公司 | 一种紫外线光固化防火阻燃木器涂料及其制备方法 |
CN103525235A (zh) * | 2013-09-24 | 2014-01-22 | 淮南师范学院 | 水性除锈防锈纳米涂料及其制备方法 |
CN103602202A (zh) * | 2013-10-22 | 2014-02-26 | 芜湖市鸿坤汽车零部件有限公司 | 一种紫外光固化漆及其制备方法 |
CN103774448A (zh) * | 2013-05-03 | 2014-05-07 | 江南大学 | 一种光固化法纺织品阻燃整理方法 |
CN103805051A (zh) * | 2014-02-13 | 2014-05-21 | 芜湖市宝艺游乐科技设备有限公司 | 一种耐盐水uv光固化涂料及其制备方法 |
CN104277519A (zh) * | 2014-10-28 | 2015-01-14 | 成都纳硕科技有限公司 | 一种塑料电路板用紫外光固化抗污阻燃涂料 |
CN104312423A (zh) * | 2014-11-07 | 2015-01-28 | 广东希贵光固化材料有限公司 | 一种uv固化阻燃涂料 |
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CN105131673A (zh) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | 一种紫外光固化阻燃底漆涂料及其制备方法 |
CN105153773A (zh) * | 2015-09-14 | 2015-12-16 | 上海应用技术学院 | 一种水性阻燃涂料及其制备方法 |
CN105153772A (zh) * | 2015-09-14 | 2015-12-16 | 上海应用技术学院 | 一种抗粘污水性阻燃涂料及其制备方法 |
CN105295671A (zh) * | 2015-11-27 | 2016-02-03 | 苏州市明大高分子科技材料有限公司 | 一种紫外光固化的负离子涂料及其制备方法 |
CN105647259A (zh) * | 2016-04-14 | 2016-06-08 | 湖州睿高新材料有限公司 | 环境友好的阻燃涂料及其制备方法 |
CN105778752A (zh) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | 一种光固化阻燃性水性涂料的制备方法 |
CN105778751A (zh) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | 紫外光固化阻燃性水性涂料 |
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CN113004782A (zh) * | 2021-03-06 | 2021-06-22 | 高州市名洋化工有限公司 | 一种光固化涂料及其制备方法和应用 |
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CN113234382A (zh) * | 2021-03-26 | 2021-08-10 | 鹤山市创享科技有限公司 | 一种抗菌阻燃的紫外光固化哑光面漆 |
CN113755071A (zh) * | 2021-09-09 | 2021-12-07 | 江南大学 | 一种光固化阻燃地板涂料及其制备方法 |
CN114686096A (zh) * | 2022-03-30 | 2022-07-01 | 深圳德诚达光电材料有限公司 | 一种透明阻燃型uv涂料及其制备方法 |
CN116463016A (zh) * | 2023-04-17 | 2023-07-21 | 南通煜源科技有限公司 | 一种耐热型uv阻燃涂料 |
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