CN101712832B - Water-soluble colorful insulation coating and preparation method thereof - Google Patents
Water-soluble colorful insulation coating and preparation method thereof Download PDFInfo
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- CN101712832B CN101712832B CN2009102485881A CN200910248588A CN101712832B CN 101712832 B CN101712832 B CN 101712832B CN 2009102485881 A CN2009102485881 A CN 2009102485881A CN 200910248588 A CN200910248588 A CN 200910248588A CN 101712832 B CN101712832 B CN 101712832B
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Abstract
The invention relates to a water-soluble colorful insulation coating and a preparation method thereof. The coating adopts the following components as raw materials by weight percent: 25-45% of acrylic acid emulsion, 5-15% of colorful hollow ceramic microspheres, 5-20% of light calcium carbonate, 10-25% of titanium dioxide powder, 0.5-1.5% of dispersant, 0.5-1.2% of thickener, 0.5-0.8% of deforming agent and 20-40% of water. The preparation method comprises the following steps: mixing acrylic acid emulsion, water, titanium dioxide powder and light calcium carbonate, stirring and dispersing, grinding with a grinder to mix evenly, wetting colorful hollow ceramic microspheres with dispersant, gradually adding colorful hollow ceramic microspheres in emulsion, then adding deforming agent and thickener to mix evenly and obtain the finished product. The color of the paint of the invention is from the colorful hollow ceramic microspheres, the paint does not contain volatile organic solvent such as benzene and formaldehyde, has thermal insulation and insulating performance, energy-saving performance and decorative performance, is beneficial for environmental protection, has outstanding thermal insulation performance and color retention performance, and has obvious environmental and social benefits.
Description
Technical field
The invention belongs to organic high molecular compound is main coating composition technical field, the particularly water-based paint compositions of propenoate.Also relate to the application of glass microballon in coating simultaneously, the application that particularly is incubated, decorates.
Background technology
21 century is huge to the needs of the energy, and the understanding of people to energy-saving significance has been deepened in the energy shortage in the global range, and the coating that architectural use has a heat-insulation and heat-preservation function can reduce the consumption of the electric power and the energy.The seventies in 20th century; Abroad proposing and beginning one's study a kind of is master's infrared external reflection radiation paint with near infrared in the reflected sunlight; Compare with traditional cool-down method; It does not need consumed energy just can effectively reduce the object surfaces temperature, stops the transmission of heat to interior of articles from the source, and then reaches the purpose of energy-conservation cooling.
From the angle of thermal conduction study, the temperature variation of interior of building depends on the capacity of heat transmission of material to a great extent, adopts the technological effects that can play cooling and insulating effectively of obstruct such as hollow microstructure.The molecular structure of material and chemical ingredients thereof are very big to the influence of thermal conductivity, and the molecular structure of material is different, and thermal conductivity is also different.The pottery hollow beads has light weight, low heat conduction, the height of anti-shearing resistance the and good chemical stability, and its hollow structure makes it have the refraction coefficient height, and the performance that light reflectance is high can be used as filler and is used for coating.
Coating has the function of decoration equally, and colo(u)r coating commonly used all is in the coating basic recipe, to have added special pigment, often need add multiple pigment in order to obtain a certain color, and color blending technique is complicated.Mostly pigment is inorganics, relatively poor with the consistency of coating matrix, has increased each component dispersive difficulty in the coating preparation, has increased the complicacy of technology.
Mostly the thermal insulation layer of external wall is to adopt the thermal insulating coating of isolation-type at present, though its starting material are easy to get, main drawback is thicker to reducing convection current and radiative transfer weak effect and thermal insulation layer, and water-intake rate is high, not anti-vibration, and work-ing life is short.Use the reflected radiation type thermal insulation coatings of hollow ceramic microspheres preparation, belong to new high-tech product, not only high insulating effect, and good weatherability, long service life, environmental friendliness meets the developing direction of current heat insulating coatings.
The information that the listing of this technological report and like product is not arranged so far.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble colorful insulation coating and preparation method thereof, this coating has heat-insulation and heat-preservation and multicolour decorating feature concurrently, can conveniently prepare various required colors, is applicable to surfaces such as building, pipeline, tank body.
Realize coating of the present invention, its raw materials used each component and mass percent are following:
Starting material each component mass percent %
ACRYLIC EMULSION 25～45
Water 20～40
Colorful hollow ceramic microspheres 5～15
Light calcium carbonate 5～20
White titanium pigment 10～25
Dispersion agent 0.5～1.5
Thickening material 0.5～1.2
Skimmer 0.5～0.8
Described acrylate copolymer emulsion is pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex or fluorine-containing emulsion, and the solid content of emulsion is 30%～50%.
Described dispersion agent, thickening material and skimmer are coatings additive(s), and addition is 1.5%～3% of a coating total mass umber.Wherein dispersion agent can be used a kind of among the SN5040, SN5027 of Henkel KGaA company; Thickening material can be used a kind of among the TT-935, TT-615 of U.S. Rhom and Hass; Skimmer can be used a kind of among BYK-052 or the BYK-057 of German Bi Ke company.
Described colorful hollow ceramic microspheres is to be processed through high-tech by titanium-borosilicate, is that a kind of face is filled out integrated non-metallic material, staple TiO
2, SiO
2And Al
2O
3, median size is 20～30 microns, wall thickness 1-2 micron, and outward appearance is white or various colours, spherical rate is greater than 95%, hollow, hard shell arranged.This series products can be used the product of Chongqing sieve's Ah development in science and technology ltd or Chengdu Saicai Technology Development Co., Ltd.
Described colorful hollow ceramic microspheres is to be processed through high-tech by titanium-borosilicate, is that a kind of face is filled out integrated non-metallic material, staple TiO
2, SiO
2And Al
2O
3, median size is 20～30 microns, wall thickness 1-2 micron, and outward appearance is white or various colours, spherical rate is greater than 95%, hollow, hard shell arranged.This series products can be used the product of Chongqing sieve's Ah development in science and technology ltd or Chengdu Saicai Technology Development Co., Ltd.
Advantages such as colorful ceramic hollow microballon color stuffing has light weight, little, the low heat conduction of density, specific refractory power is high, insulating property are good.Colorful ceramic hollow microballon color stuffing has bright-coloured, stable color, multiple colour systems such as its color adularescent, redness, yellow, blueness.Use the color stuffing of colorful ceramic hollow microballon, need not to add other pigment as coating.
A kind of water-soluble colorful insulation coating provided by the invention and preparation method thereof: in proportion an amount of ACRYLIC EMULSION, water, white titanium pigment, light calcium carbonate are mixed,, mix through the skin grinder barreling through the impeller dispersed with stirring; Get an amount of colorful hollow ceramic microspheres, with dispersion agent wetting after, divide to join for 3 times in the above-mentioned firm synthetic emulsion; After each the adding; Stir with low-speed mixer and to make its dispersion in 10 minutes, add skimmer again, thickening material mixes, promptly make to have heat-insulation and heat-preservation and ornamental water-borne coatings concurrently.
Beneficial effect of the present invention: in the time of will being coated with the outer wall of the box that the plasterboard that is contained in a 50cm (length) * 50cm (wide) * 70cm (height) constitutes by the coating (white) that above-mentioned raw materials and method are prepared; When outside temperature is 35～45 ℃; Temperature in the box is 21～30 ℃, and heat insulation and preservation effect is obvious.Use the heat insulation effect of the coating of yellow hollow ceramic microspheres preparation: when outside temperature was 35～45 ℃, the temperature in the box was 20～33 ℃.Use the heat insulation effect of the coating of red hollow ceramic microspheres preparation: when outside temperature was 35～45 ℃, the temperature in the box was 28～34 ℃.Use the heat insulation effect of the coating of blue hollow ceramic microspheres preparation: when outside temperature was 35～45 ℃, the temperature in the box was 27～35 ℃.The present invention has heat insulation heat preservation energy-saving concurrently and ornamental water-borne coatings does not contain volatile organic solvents such as benzene, formaldehyde, helps environmental protection, and has outstanding heat-insulating property and tint retention ability, has tangible environment, social benefit.
Below with embodiment the present invention is further described.
Embodiment
Embodiment 1
A kind of each component and content that has heat-insulation and heat-preservation and ornamental water-soluble colorful coating concurrently is following:
Starting material each component mass percent %
Benzene emulsion 30
Water 26
Hollow ceramic microspheres (white) 7
Light calcium carbonate 20
White titanium pigment 15
Dispersion agent: the SN5040 0.9 of Henkel KGaA company
Thickening material: the TT-935 0.6 of U.S. Rhom and Hass
Skimmer: the BYK-052 0.5 of German Bi Ke company
Preparing method: by above-mentioned prescription benzene emulsion, water, white titanium pigment, light calcium carbonate are mixed,, mix through the skin grinder barreling through the impeller dispersed with stirring; Get the white hollow ceramic fine bead that Chongqing sieve's Ah development in science and technology ltd produces; With dispersion agent SN5040 wetting after; Divide to join in the above-mentioned firm synthetic emulsion for 3 times, after each the adding, make its dispersion with the low-speed mixer stirring; Add again after skimmer BYK-052, thickening material TT-935 mix, promptly make and have heat-insulating and energy-saving and ornamental water-borne coatings concurrently.
When the whitewash that embodiment 1 is obtained was coated with the outer wall of the box that the plasterboard that is contained in a 50cm (length) * 50cm (wide) * 70cm (height) constitutes, when outside temperature was 35～45 ℃, the temperature in the box was 21～30 ℃, and heat insulation and preservation effect is obvious.
Embodiment 2
A kind of each component and content that has heat-insulation and heat-preservation and ornamental water-borne coatings concurrently is following:
Starting material each component mass percent %
Benzene emulsion 26
Water 24
Hollow ceramic microspheres (yellow) 14
Light calcium carbonate 10
White titanium pigment 23
Dispersion agent: the SN5040 1.2 of Henkel KGaA company
Thickening material: the TT-935 1.0 of U.S. Rhom and Hass
Skimmer: the BYK-057 0.8 of German Bi Ke company
Preparing method such as embodiment 1 are said, obtain yellow paint.
The yellow paint method described in the embodiment 1 of pressing is detected the coating heat insulation and preservation effect, and when outside temperature was 35～45 ℃, the temperature in the box was 20～33 ℃.
Embodiment 3
A kind of each component and content that has heat-insulation and heat-preservation and ornamental water-borne coatings concurrently is following:
Starting material each component mass percent %
Benzene emulsion 43
Water 31
Hollow ceramic microspheres (redness) 5.5
Light calcium carbonate 7
White titanium pigment 11
Dispersion agent: the SN5027 1.0 of Henkel KGaA company
Thickening material: the TT-615 0.8 of U.S. Rhom and Hass
Skimmer: the BYK-052 0.7 of German Bi Ke company
Preparing method such as embodiment 1 are said, obtain encrimson.
The encrimson method described in the embodiment 1 of pressing is detected the coating heat insulation and preservation effect, and when outside temperature was 35～45 ℃, the temperature in the box was 28～34 ℃.
Embodiment 4
A kind of each component and content that has heat-insulation and heat-preservation and ornamental water-borne coatings concurrently is following:
Starting material each component mass percent %
Organosilicon crylic acid latex 31
Water 35
Hollow ceramic microspheres (blueness) 7.5
Light calcium carbonate 14
White titanium pigment 10
Dispersion agent: the SN5027 0.9 of Henkel KGaA company
Thickening material: the TT-935 0.8 of U.S. Rhom and Hass
Skimmer: the BYK-057 0.8 of German Bi Ke company
Preparing method such as embodiment 1 are said, obtain blue paste.
The blue paste method described in the embodiment 1 of pressing is detected the coating heat insulation and preservation effect, and when outside temperature was 35～45 ℃, the temperature in the box was 27～35 ℃.
Claims (2)
1. water-soluble colorful insulation coating, it is characterized in that its color derives from contains the colorful hollow ceramic fine bead; By following component and quality percentage composition:
ACRYLIC EMULSION 25～45
Water 20～40
Colorful hollow ceramic microspheres 5～15
Light calcium carbonate 5～20
White titanium pigment 10～25
Dispersion agent 0.5～1.5
Thickening material 0.5～1.2
Skimmer 0.5～0.8
Wherein: described ACRYLIC EMULSION is pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex or fluorine-containing emulsion, and the solid content of emulsion is 30%～50%; Described colorful hollow ceramic microspheres is to be processed by titanium-borosilicate, is that a kind of face is filled out integrated non-metallic material, staple TiO
2, SiO
2And A1
2O
3, median size is 20～30 microns, wall thickness 1-2 micron, and outward appearance is white or various colors, spherical rate is greater than 95%, hollow, hard shell arranged.
2. the preparation method of water-soluble colorful insulation coating according to claim 1 is characterized in that raw materials used kind and quality per distribution ratio are:
ACRYLIC EMULSION 25～45
Water 20～40
Colorful hollow ceramic microspheres 5～15
Light calcium carbonate 5～20
White titanium pigment 10～25
Dispersion agent 0.5～1.5
Thickening material 0.5～1.2
Skimmer 0.5～0.8
Making each method is: in proportion an amount of ACRYLIC EMULSION, water, white titanium pigment, light calcium carbonate are mixed, through the impeller dispersed with stirring, mix through the skin grinder barreling; Get colorful hollow ceramic microspheres, with dispersion agent wetting after, divide to join for 3 times in the emulsion that above-mentioned skin grinder barreling mixes, after each the adding,, add skimmer again, thickening material mixes and forms with stirring at low speed 10 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102485881A CN101712832B (en) | 2009-12-18 | 2009-12-18 | Water-soluble colorful insulation coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102485881A CN101712832B (en) | 2009-12-18 | 2009-12-18 | Water-soluble colorful insulation coating and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN101712832A CN101712832A (en) | 2010-05-26 |
| CN101712832B true CN101712832B (en) | 2012-08-22 |
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| CN2009102485881A Expired - Fee Related CN101712832B (en) | 2009-12-18 | 2009-12-18 | Water-soluble colorful insulation coating and preparation method thereof |
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| CN101712832A (en) | 2010-05-26 |
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