CN101323704B - Resin slicer for granite sand wall paint, preparation and use thereof - Google Patents

Resin slicer for granite sand wall paint, preparation and use thereof Download PDF

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Publication number
CN101323704B
CN101323704B CN2008100631874A CN200810063187A CN101323704B CN 101323704 B CN101323704 B CN 101323704B CN 2008100631874 A CN2008100631874 A CN 2008100631874A CN 200810063187 A CN200810063187 A CN 200810063187A CN 101323704 B CN101323704 B CN 101323704B
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granite
coating
wall
resin slicer
granite sand
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CN101323704A (en
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朱林红
姚勤生
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Abstract

The invention relates to a wall decoration coating, in particular to a resin slice used in granite sand-wall coating and a preparation method thereof and the granite sand-wall coating using the slice. The resin slice used in the granite sand-wall coating is prepared through the following steps: (1) a stuffing, a pigment, water, an antifoaming agent, hydroxyethyl cellulose, an antifreeze and a dispersing wetting agent are stirred in high speed and fully blended; (2) acrylic acid silicone emulsion, a PH value regulating agent and a film forming agent are added for blending the coating, the film is formed, dried and shattered. The invention also discloses a granite sand-wall coating with a sense of reality utilizing the resin slice of the invention. The invention has the following effects: (1) a lively decorative effect of natural granite or marble can be acquired by single gun spraying with a building spray gun; (2) the granite sand-wall coating layer has the a certain flexibility, therefore, the requirements of the heat preservation of the wall body on the decorative finish coating can be met and the crack of the wall body can be avoided; (3) the decorative coating of the invention has low cost per square meter, can reduce the load of the wall body and ensure the heat preservation effect of the heat preservation layer of the wall body.

Description

Be used for resin slicer of granite sand wall paint and its production and application
Technical field
The present invention relates to a kind of wall fitting coating, relate in particular to a kind of resin slicer that is used for granite sand wall paint and preparation method thereof and with the granite sand wall paint of this section.
Background technology
General true mineral varnish or the stone similar paint of claiming of texture sand wall paint.The buildings of decorating through lithotome is magnificent, noble quality, and quality is higher.But because lithotome costs an arm and a leg, construction is inconvenient, so develop a kind of building coating-Zhen mineral varnish coating of artificial stone in the market, this coating directly sprays, and its decorative effect has the texture and the color of lithotome.The buildings that uses true mineral varnish to decorate not only has the luxurious outward appearance and the flintiness of stone material, and has elegance, noble quality, artistic effect such as stereoscopic sensation is strong.True mineral varnish has good weathering resistance, colour-fast and contamination resistance, and be a kind of material that substitutes the lithotome facing work-ing life more than 10 years.But it is not true to nature when adopting true mineral varnish to imitate grouan or marble fully as the effect of using monochromatic single rifle to construct out; As use the big construction of simulated effect but square feed consumption rate of constructing out of monochromatic multiple gun complicated and form and aspect that construct out are not quite identical.
(application number is Chinese invention patent: 91108820.2) disclose a kind of wall decoration material, especially be suitable for outdoor wall and decorate.It is to be that 1: 5 glue and sand grains mixes with weight ratio; in the weight of glue, contain ACRYLIC EMULSION 48%, polyvinyl acetate emulsion 48%, ethylene glycol 1.495%, Sodium hexametaphosphate 99 1%, phosphorus benzene bis-acid potassium dibutylester 5 ‰, rosined soap 0.05 ‰ and Sodium Benzoate 1%.The kind of sand grains has glass sand, quartzy aggregate chips, marble chips, granite chipping, color little sand and pottery grain.This coating is thinner, so in light weight, it is less to solidify the rear surface hole, smears easily, can join shades of colour, and cost is low, and water tolerance is heat-resisting good with frost resistance in addition.
(application number is Chinese invention patent: 03132294.8) disclose a kind of true mineral varnish of artificial granite type body of wall and manufacture method, make by coating, mineral powder, Natvosol, mixing diluents, its component ratio is: coating sheet 20-30%, mineral powder 30-40%, olefin(e) acid fat or emulsion 20-30% in Natvosol such as the silicon, thinner 10-20%; Its optimum proportion ratio is: coating sheet 30%, mineral powder 30%, olefin(e) acid fat or emulsion 20% in Natvosol such as the silicon, thinner 20%.Its manufacture craft is: coating is sprayed in the surface of materials such as glass, makes sheet material, again order add mineral powder, Natvosol, mixing diluents stir the companion evenly after, pack and be finished product.
Summary of the invention
At present designing unit and real estate developer liking and deficiency that current material is decorated to the decorative effect of grouan.An object of the present invention is to provide a kind of resin slicer that is used for granite sand wall paint, another one purpose of the present invention provides the preparation method of above-mentioned resin slicer, three purposes of the present invention provide the granite sand wall paint with above-mentioned resin slicer, this granite sand wall paint list rifle can construct out grouan fully true to nature decorative effect and do not increase body of wall and bear a heavy burden.
In order to realize first above-mentioned purpose, the present invention has adopted following technical scheme:
The resin slicer that is used for granite sand wall paint, its resin slicer comprise that by weight percentage the component film-making of following prescription obtains:
Vinylformic acid organic silicon emulsion 15%~40%; Filler 35%~70%;
Defoamer 0.05%~0.4%; Natvosol 0.05%~0.4%;
PH value conditioning agent 0.05%~0.4%; Dispersion moisture agent 0.2%~1.0%;
Frostproofer 0.5%~3%; Film coalescence aid 0.25%~4%;
Weather-proof pigment 0.1%~12%; Surplus is a water;
Each component total amount of resin slicer is 100%.
As preferably, above-mentioned resin slicer comprises that by weight percentage the component film-making of following prescription obtains:
Vinylformic acid organic silicon emulsion 23.6%~36.1%; Filler 47.1%~66.3%;
Defoamer 0.1%~0.24%; Natvosol 0.1%~0.24%;
PH value conditioning agent 0.1%~0.24%; Dispersion moisture agent 0.47%~0.72%;
Frostproofer 1.5%~1.8%; Film coalescence aid 0.75%~2.1%;
Pigment 0.1%~12%; Surplus is a water;
Each component total amount of resin slicer is 100%.
As preferably, above-mentioned resin slicer also comprises thickening material 0.1%~0.24%.
As preferably, above-mentioned filler is selected one or both in kaolin or the coarse whiting for use.
As preferably, above-mentioned pigment adopts weather-proof color, especially iron oxide pigment or titanium dioxide.
In order to realize second above-mentioned purpose, the present invention is used for the preparation method of the resin slicer of granite sand wall paint, comprises the steps: 1. with filler, pigment, water, defoamer, Natvosol, frostproofer and dispersion moisture agent high-speed stirring mixing; 2. add vinylformic acid organic silicon emulsion, pH value conditioning agent and film coalescence aid paint, the system film, oven dry is pulverized.
In order to realize the 3rd above-mentioned purpose, texture granite sand wall paint of the present invention comprises following component by weight percentage:
Vinylformic acid organic silicon emulsion 15.0%~35.0%; Resin slicer 5.0%~15.0%;
Natural silica Sand 45.0%~75.0%; Film coalescence aid 0.5%~3%;
PH conditioning agent 0.05~0.4%; Surplus is a water;
Above-mentioned resin slicer is selected the resin slicer that is used for granite sand wall paint in the above-mentioned technical scheme for use.
As preferably, this wall lacquer comprises following component by weight percentage:
Vinylformic acid organic silicon emulsion 20.5%~26.8%; Resin slicer 7.0%~11.0%;
Natural silica Sand 56.4%~64.5%; Film coalescence aid 1%~1.5%;
PH conditioning agent 0.1~0.2%; Surplus is a water.
As preferably, this wall lacquer also comprises anticorrosion and bactericidal agent 0.02~0.2% and thickening material 0.05~0.2%.
As preferably, the effective diameter of above-mentioned resin slicer is 5~10mm.
The present invention adopts vinylformic acid organic silicon emulsion, filler, weather-proof pigment and functional agent etc. to produce versicolor resin slicer (effective diameter 5-10mm scope) to satisfy color requirement in the natural granite, be refined into the texture granite sand wall paint with vinylformic acid organic silicon emulsion, natural silica Sand, different colours resin slicer, functional agent again.Because its system adds the resin slicer of different colours, the present invention has following effect: 1. make texture be subjected to granite sand wall paint by building spray gun list rifle construct out natural granite very true to nature or marmorean decorative effect; 2. make texture granite sand wall lacquering have certain elasticity, thereby can satisfy the requirement of wall thermal insulating, and can avoid body of wall crackle to occur veneer coating; 3. compare with actual dry hanging granite or marble, its square cost is low, it is negative as to guarantee the heat insulation effect of wall insulating layer simultaneously to reduce body of wall.
Embodiment
Embodiment 1
The preparation of the resin slicer of different colours:
Resin slicer prescription: deionized water 100kg; Defoamer: 1~2kg; Natvosol: 1~2kg; PH value conditioning agent: 2kg; Dispersion moisture agent: 5~6kg; Frostproofer: 15kg; Titanium dioxide: 50~75kg; Iron oxide pigment: 3-5kg; Filler: 500~550kg; Film coalescence aid: 8-18kg; Vinylformic acid organic silicon emulsion: 250~300kg; Thickening material: 1~2kg.
Above-mentioned vinylformic acid organic silicon emulsion: outward appearance: the oyster white translucent liquid, minimum film-forming temperature: 16-20 ℃, second-order transition temperature: 27 ℃, particle diameter (micron) is about 0.1, and free monomer≤0.5 is ionic: anionic; Producer is clear day chemical industry company limited of Japan.
Above-mentioned film coalescence aid: producer is a U.S. Eastman Chemical.
Above-mentioned PH conditioning agent: producer is the LG-DOW chemical industry.
The present invention is used for the preparation method of the resin slicer of granite sand wall paint, comprises the steps: 1. with filler, titanium dioxide, iron oxide pigment, deionized water, defoamer, Natvosol, frostproofer and dispersion moisture agent high-speed stirring mixing; 2. add vinylformic acid organic silicon emulsion, thickening material, pH value conditioning agent and film coalescence aid paint, make film and enter thermostatic chamber and carry out drying and forming-film, (effective diameter 5~10mm) is so just made resin slicer to pulverize different irregular fragments again.
Embodiment 2
Texture granite sand wall paint formula:
Vinylformic acid organic silicon emulsion: 200~250kg; Different colours resin slicer: 70~100kg; Natural silica Sand: 550~600kg; Deionized water: 50~60kg; Film coalescence aid: 10~15kg; PH conditioning agent: 1~2kg; Defoamer: 0.5~1kg; Frostproofer: 4~1kg; Anticorrosion and bactericidal agent: 0.5~1kg; Thickening material: an amount of.
Above-mentioned natural silica Sand: silt content<0.2%, angle type coefficient<1.35, particle diameter specification: 30~50 orders, 40~70 orders, manufacturer: Shijiazhuang, Chinese Hebei Jin Yuan mining industry company limited.
The even stirring of component low speed of above-mentioned prescription can be obtained described texture granite sand wall paint.
The texture granite sand wall paint that These parameters is obtained detects detected result such as table 1:
Table 1
Figure G2008100631874D00051

Claims (7)

1. texture granite sand wall paint is characterized in that this wall lacquer comprises following component by weight percentage:
Vinylformic acid organic silicon emulsion 15.0%~35.0%; Resin slicer 5.0%~15.0%;
Natural silica Sand 45.0%~75.0%; Film coalescence aid 0.5%~3%;
PH conditioning agent 0.05~0.4%; Surplus is a water;
Above-mentioned resin slicer comprises that by weight percentage the component film-making of following prescription obtains:
Vinylformic acid organic silicon emulsion 15%~40%; Filler 35%~70%;
Defoamer 0.05%~0.4%; Natvosol 0.05%~0.4%;
PH value conditioning agent 0.05%~0.4%; Dispersion moisture agent 0.2%~1.0%;
Frostproofer 0.5%~3%; Film coalescence aid 0.25%~4%;
Weather-proof pigment 0.1%~12%; Surplus is a water;
Each component total amount of resin slicer is 100%.
2. texture granite sand wall paint according to claim 1 is characterized in that resin slicer comprises that by weight percentage the component film-making of following prescription obtains:
Vinylformic acid organic silicon emulsion 23.6%~36.1%; Filler 47.1%~66.3%;
Defoamer 0.1%~0.24%; Natvosol 0.1%~0.24%;
PH value conditioning agent 0.1%~0.24%; Dispersion moisture agent 0.47%~0.72%;
Frostproofer 1.5%~1.8%; Film coalescence aid 0.75%~2.1%;
Pigment 0.1%~12%; Surplus is a water;
Each component total amount of resin slicer is 100%.
3. the texture granite sand wall paint that is used for according to claim 1 and 2, it is characterized in that: resin slicer also comprises thickening material 0.1%~0.24%.
4. the texture granite sand wall paint that is used for according to claim 1 and 2, it is characterized in that: filler is selected one or both in kaolin or the coarse whiting for use.
5. texture granite sand wall paint according to claim 1 is characterized in that this wall lacquer comprises following component by weight percentage:
Vinylformic acid organic silicon emulsion 20.5%~26.8%; Resin slicer 7.0%~11.0%;
Natural silica Sand 56.4%~64.5%; Film coalescence aid 1%~1.5%;
PH conditioning agent 0.1~0.2%; Surplus is a water.
6. texture granite sand wall paint according to claim 1 is characterized in that: this wall lacquer also comprises anticorrosion and bactericidal agent 0.02~0.2% and thickening material 0.05~0.2%.
7. texture granite sand wall paint according to claim 1 is characterized in that: the effective diameter of resin slicer is 5~10mm.
CN2008100631874A 2008-07-22 2008-07-22 Resin slicer for granite sand wall paint, preparation and use thereof Expired - Fee Related CN101323704B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002296A (en) * 2010-12-10 2011-04-06 现代精密化工(郑州)有限公司 Ceramic encaustic brick lacquer
CN102731056A (en) * 2012-07-16 2012-10-17 广州立邦涂料有限公司 Basic coating used as sand gel coating, and preparation method of basic coating
CN102827522A (en) * 2012-09-03 2012-12-19 黑龙江省林城涂料有限公司 Natural stone paint and preparation method thereof
CN103232778A (en) * 2013-04-22 2013-08-07 广西启利新材料科技股份有限公司 Anti-crack building paint and preparation method thereof
CN104231820B (en) * 2013-06-09 2016-12-28 上海展辰涂料有限公司 A kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344771A (en) * 2001-09-25 2002-04-17 张良 Polyacrylate paint and its production process
CN1473885A (en) * 2002-08-07 2004-02-11 张贵洲 Nano composite road and bridge emulsion paint
CN1580138A (en) * 2003-08-07 2005-02-16 王光胜 Granite-imitating wall true-stone paint and its manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1344771A (en) * 2001-09-25 2002-04-17 张良 Polyacrylate paint and its production process
CN1473885A (en) * 2002-08-07 2004-02-11 张贵洲 Nano composite road and bridge emulsion paint
CN1580138A (en) * 2003-08-07 2005-02-16 王光胜 Granite-imitating wall true-stone paint and its manufacturing method

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