CN101699933B - Production method of bright-copper-face high-heat-conductivity ceramic circuit board - Google Patents
Production method of bright-copper-face high-heat-conductivity ceramic circuit board Download PDFInfo
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- CN101699933B CN101699933B CN2009101935903A CN200910193590A CN101699933B CN 101699933 B CN101699933 B CN 101699933B CN 2009101935903 A CN2009101935903 A CN 2009101935903A CN 200910193590 A CN200910193590 A CN 200910193590A CN 101699933 B CN101699933 B CN 101699933B
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Abstract
The invention method discloses a production method of a bright-copper-face high-heat-conductivity ceramic circuit board, which comprises the following steps: (a) pretreating a base board; (b) transferring a pattern; (c) printing solder-resisting ink; (d) screen-printing the text; (e) chemically depositing nickel and gold; (f) and forming by cutting. The invention aims to overcome the defects in the prior art and provide a production method of the bright-copper-face high-heat-conductivity ceramic circuit board. The invention has the advantages of simple technique, and favorable effects of heat conduction and dissipation of the product.
Description
Technical field
The present invention relates to a kind of production method of bright-copper-face high-heat-conductivity ceramic circuit board.
Background technology
Along with the continuous development of science and technology, the improving constantly of people's material and spiritual civilization, people are tending towards energy-conservation and environmental protection to the development day of electronic product.Generally adopt incandescent lamp or fluorescent lamp such as traditional illumination, wherein the energy consumption of incandescent lamp is big, a little less than the light efficiency; Mercurous in the fluorescent lamp, not environmental protection, and its energy consumption is all bigger, and light efficiency is more weak.Invented emitting led in order to address this problem people, the 20% generation light but existing emitting led per in actual applications 100% the energy is only had an appointment, and there is 80% the energy to become heat energy loss, therefore heat is the consumption of energy maximum, but simultaneously if do not remove unnecessary heat energy then LED just reduce useful life.The heat radiation of LED is mainly dispelled the heat by its base plate for packaging, but along with base plate for packaging is more and more littler, the heat that LED produces can not distribute effectively, and general at present FR4 material or the employing resin of adopting adds ceramic powder as substrate, but the heat-conducting effect of this substrate is not ideal; Adopt metal substrates such as aluminium base as substrate in addition, this substrate is to cover the material of one deck resinae as dielectric layer on these metal substrates, the heat that LED produces must pass to metal substrate through dielectric layer earlier again, because the heat conductivility of dielectric layer is poor, thereby influenced whole heat sinking function, adding that metal substrates such as aluminium base are heated is easy to generate distortion, and its dimensional stability is poor, so be not suitable for the base plate for packaging as heat transmission; Use the substrate of not resiniferous ceramic material as circuit board, its heat conduction and good heat dissipation effect, but because its processing technology more complicated has limited its application.For this reason, how solving ceramic material is a great difficult problem as the production technology of the substrate of circuit board.
Summary of the invention
The objective of the invention is in order to overcome weak point of the prior art, provide that a kind of technology is simple, the production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board of product heat conduction and good heat dissipation effect.
In order to achieve the above object, the present invention adopts following scheme:
A kind of production method of bright-copper-face high-heat-conductivity ceramic circuit board, it may further comprise the steps:
The pre-treatment of a, substrate
To carrying out surface clean, electroplate layer of copper covering on the copper layer of ceramic copper-clad base plate two sides then through the ceramic copper-clad base plate of checking;
B, figure transfer
Covering one deck light-sensitive medium on the copper layer of aforesaid substrate, the film of placing the band predetermined pattern on light-sensitive medium exposes, and develops then, and etching is removed defective products with the automated optical Equipment Inspection after moving back film;
C, solder-mask printing printing ink
The local solder-mask printing printing ink that does not need soldering of electronic components at circuit board;
D, character silk printing
According to designing requirement in circuit board character silk printing in the localities accordingly;
E, chemical sinking nickel, gold
The method of utilizing chemical sinking nickel, gold is plated one deck gold then at the place of exposed copper plating one deck nickel;
F, excision forming
Utilize laser cutting device that circuit board is cut into predetermined specification,, qualified be product of the present invention through detection of electrons.
The production method of aforesaid a kind of bright-copper-face high-heat-conductivity ceramic circuit board is characterized in that the surface clean described in the step a is that chemical method is cleaned.
The production method of aforesaid a kind of bright-copper-face high-heat-conductivity ceramic circuit board is characterized in that it is to adopt sodium peroxydisulfate or ammonium persulfate that ceramic copper-clad plate is carried out microetch that described chemical method is cleaned.
The production method of aforesaid a kind of bright-copper-face high-heat-conductivity ceramic circuit board is characterized in that will carrying out 3 etchings among the step b, and etching is for the first time undertaken by 1.5m/min, and 2.0m/min is pressed in etching for the second time, and etching is for the third time undertaken by 5.5m/min.
The production method of aforesaid a kind of bright-copper-face high-heat-conductivity ceramic circuit board is characterized in that also comprising the blue glue process of silk-screen before step f excision forming: print the blue glue of a circle around predetermined some fluorescent glue zone, oven dry then.
In sum, beneficial effect of the present invention:
One, the present invention adopts the method for chemistry that ceramic copper-clad base plate is carried out surface clean, and does not adopt the habitual mechanical polish-brush method of ordinary epoxy resin plate that it is cleaned, and effectively prevents the fracture damage of ceramic copper-clad base plate, has guaranteed the rate of finished products of product;
Two, on the ceramic copper-clad base plate after the cleaning, electroplate layer of copper among the present invention, make its smooth surface, more glossy than the calendering copper of original ceramic substrate, and also surface compact is good; Help following process;
Three, the heat conduction of ceramic substrate of the present invention and good heat dissipation effect, processing technology is simple.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1
The production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board of the present invention, it may further comprise the steps:
The pre-treatment of a, substrate
Mainly comprise: supplied materials inspection → oil removing → pickling → electro-coppering → cleaning → operations such as oven dry;
Concrete way is: the ceramic copper-clad base plate through passed examination is carried out surface clean, specific practice is with sodium peroxydisulfate the copper layer that covers of ceramic copper-clad base plate to be carried out microetch, greasy dirt and the surperficial oxide on the copper layer covered in removal, this cleans circuit board substrate with respect to the method that adopts physics, more effective damage that prevents ceramic copper-clad base plate, because physical method generally is before this substrate to be compressed, adopt roller brush high speed rotating in its surface again, by the friction of roller brush to substrate surface, the oxide on the greasy dirt surface on it is cleaned up, but this method is had no idea to be applied on the ceramic copper-clad base plate, because the ceramic layer of ceramic copper-clad base plate is more crisp, be easy to fracture.
Adopt weakly acidic solution to carry out pickling the ceramic copper-clad base plate that cleaned, electroplate one deck thickening copper on the copper layer covering of ceramic copper-clad base plate two sides then, this its lustrous surface of copper layer is more glossy than the calendering copper of original ceramic copper-clad base plate, and surface compact is good; Help post-production; Enter next process through cleaning, drying after the electro-coppering;
B, figure transfer
Mainly comprise: press mold → exposure → development → etching → striping → oven dry → operations such as check;
Specific practice is: at the printing one deck photosensitive-ink or the subsides light-sensitive surface on the copper layer of covering of above-mentioned ceramic copper-clad base plate, treat after photosensitive-ink or the light-sensitive surface drying, painting the circuitous pattern film with the light of having made is placed on the ceramic copper-clad base plate upper and lower surface, carry out circuit pattern exposure, ceramic copper-clad base plate after the exposure is developed, demonstrate through the solid circuitous pattern of exposure light, ceramic copper-clad base plate after adopting etching machine to above-mentioned exposure carries out etching, wherein to carry out three etchings, etching is for the first time undertaken by 1.5m/min, 2.0m/min is pressed in etching for the second time, etching is for the third time undertaken by 5.5m/min, moves back film oven dry back and removes defective products with the automated optical Equipment Inspection; Cleaning, drying enters next step operation then;
C, solder-mask printing printing ink
Mainly comprise: pre-treatment → printing-ink → prebake → exposure → operations such as development → hot curing;
Specific practice is: carry out cleaning, drying at above-mentioned ceramic copper-clad base plate, do not needing the local solder-mask printing printing ink of soldering of electronic components; In drying baker, expose after the low temperature prebake and develop, carrying out hot curing then; When solder-mask printing printing ink can effectively prevent soldering of electronic components, scolding tin was bonded at non-welding zone, simultaneously solder-mask printing printing ink can be also the erosion of not making moist of some conductting layers on can the protective circuit plate increase the aesthetic measure of product simultaneously; Cleaning, drying enters next step operation then;
D, character silk printing
Mainly comprise: operations such as character silk printing → hot curing;
Specific practice is: according to designing requirement in aforesaid substrate character silk printing hot curing then in the localities accordingly; So that production and processing is again at corresponding local soldering of electronic components; For the assembling production of circuit board brings convenience; Cleaning, drying enters next step operation then;
E, chemical sinking nickel, gold
Mainly comprise: oil removing → pickling → microetch → preimpregnation → heavy nickel → turmeric → operations such as oven dry;
Specific practice is: aforesaid substrate is carried out oil removing clean, pickling then, in sodium peroxydisulfate solution, carry out microetch, clean the back and in nickel plating bath, carry out preimpregnation, utilize the method for chemical sinking nickel, gold to be 100-200 μ then at deposition one layer thickness that covers on the copper layer that needs soldering of electronic components " chemical nickel, electroplating a layer thickness then is 3 μ " gold; Cleaning, drying enters next step operation then;
F, excision forming
Mainly comprise: laser cutting → cleaning → check → operations such as packing;
Specific practice is: utilize the above laser cutting device of 8W that the substrate cut through chemical sinking nickel, gold is become predetermined specification, after detection of electrons, qualified be product of the present invention with the clear water cleaning and drying, packing gets final product then.
Embodiment 2
The production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board of the present invention, it may further comprise the steps:
The pre-treatment of a, substrate
Mainly comprise: supplied materials inspection → oil removing → pickling → electro-coppering → cleaning → operations such as oven dry;
Concrete way is: the ceramic copper-clad base plate through passed examination is carried out surface clean, specific practice is with sodium peroxydisulfate the copper layer that covers of ceramic copper-clad base plate to be carried out microetch, greasy dirt and the surperficial oxide on the copper layer covered in removal, this cleans circuit board substrate with respect to the method that adopts physics, more effective damage that prevents ceramic copper-clad base plate, because physical method generally is before this substrate to be compressed, adopt roller brush high speed rotating in its surface again, by the friction of roller brush to substrate surface, the oxide on the greasy dirt surface on it is cleaned up, but this method is had no idea to be applied on the ceramic copper-clad base plate, because the ceramic layer of ceramic copper-clad base plate is more crisp, be easy to fracture.
Adopt weakly acidic solution to carry out pickling the ceramic copper-clad base plate that cleaned, electroplate one deck thickening copper on the copper layer covering of ceramic copper-clad base plate two sides then, this its lustrous surface of copper layer is more glossy than the calendering copper of original ceramic copper-clad base plate, and surface compact is good; Help post-production; Enter next process through cleaning, drying after the electro-coppering;
B, figure transfer
Mainly comprise: press mold → exposure → development → etching → striping → oven dry → operations such as check;
Specific practice is: at the printing one deck photosensitive-ink or the subsides light-sensitive surface on the copper layer of covering of above-mentioned ceramic copper-clad base plate, treat after photosensitive-ink or the light-sensitive surface drying, painting the circuitous pattern film with the light of having made is placed on the ceramic copper-clad base plate upper and lower surface, carry out circuit pattern exposure, ceramic copper-clad base plate after the exposure is developed, demonstrate through the solid circuitous pattern of exposure light, ceramic copper-clad base plate after adopting etching machine to above-mentioned exposure carries out etching, wherein to carry out three etchings, etching is for the first time undertaken by 1.5m/min, 2.0m/min is pressed in etching for the second time, etching is for the third time undertaken by 5.5m/min, moves back film oven dry back and removes defective products with the automated optical Equipment Inspection; Cleaning, drying enters next step operation then;
C, solder-mask printing printing ink
Mainly comprise: pre-treatment → printing-ink → prebake → exposure → operations such as development → hot curing;
Specific practice is: carry out cleaning, drying at above-mentioned ceramic copper-clad base plate, do not needing the local solder-mask printing printing ink of soldering of electronic components; In drying baker, expose after the low temperature prebake and develop, carrying out hot curing then; When solder-mask printing printing ink can effectively prevent soldering of electronic components, scolding tin was bonded at non-welding zone, simultaneously solder-mask printing printing ink can be also the erosion of not making moist of some conductting layers on can the protective circuit plate increase the aesthetic measure of product simultaneously; Cleaning, drying enters next step operation then;
D, character silk printing
Mainly comprise: operations such as character silk printing → hot curing;
Specific practice is: according to designing requirement in aforesaid substrate character silk printing hot curing then in the localities accordingly; So that production and processing is again at corresponding local soldering of electronic components; For the assembling production of circuit board brings convenience; Cleaning, drying enters next step operation then;
E, chemical sinking nickel, gold
Mainly comprise: oil removing → pickling → microetch → preimpregnation → heavy nickel → turmeric → operations such as oven dry;
Specific practice is: aforesaid substrate is carried out oil removing clean, pickling then, in sodium peroxydisulfate solution, carry out microetch, clean the back and in nickel plating bath, carry out preimpregnation, utilize the method for chemical sinking nickel, gold to be 100-200 μ then at deposition one layer thickness that covers on the copper layer that needs soldering of electronic components " chemical nickel, electroplating a layer thickness then is 3 μ " gold; Cleaning, drying enters next step operation then;
F, the blue glue of silk-screen
Concrete way is to print the blue glue of a circle around predetermined some fluorescent glue zone, oven dry then, in the zone that blue glue surrounds, put fluorescent glue more as required in the process of processing,, prevent that effectively fluorescent glue from flowing to beyond the presumptive area because its surface ratio is more coarse after the blue adhesive curing;
G, excision forming
Mainly comprise: laser cutting → cleaning → check → operations such as packing;
Specific practice is: utilize the above laser cutting device of 8W that the substrate cut through chemical sinking nickel, gold is become predetermined specification, after detection of electrons, qualified be product of the present invention with the clear water cleaning and drying, packing gets final product then.
Claims (4)
1. the production method of a bright-copper-face high-heat-conductivity ceramic circuit board, it may further comprise the steps:
The pre-treatment of a, substrate
To carrying out surface clean, electroplate layer of copper covering on the copper layer of ceramic copper-clad base plate two sides then through the ceramic copper-clad base plate of checking; Wherein said surface clean is that chemical method is cleaned;
B, figure transfer
Covering one deck light-sensitive medium on the copper layer of aforesaid substrate, the film of placing the band predetermined pattern on light-sensitive medium exposes, and develops then, and etching is removed defective products with the automated optical Equipment Inspection after moving back film;
C, solder-mask printing printing ink
The local solder-mask printing printing ink that does not need soldering of electronic components at circuit board;
D, character silk printing
According to designing requirement in circuit board character silk printing in the localities accordingly;
E, chemical sinking nickel, gold
The method of utilizing chemical sinking nickel, gold is plated one deck gold then at the place of exposed copper plating one deck nickel;
F, excision forming
Utilize laser cutting device that circuit board is cut into predetermined specification, through detection of electrons, qualified getting final product.
2. the production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board according to claim 1 is characterized in that it is to adopt sodium peroxydisulfate or ammonium persulfate that ceramic copper-clad plate is carried out microetch that described chemical method is cleaned.
3. the production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board according to claim 1, it is characterized in that to carry out 3 etchings among the step b, etching is for the first time undertaken by 1.5m/min, and 2.0m/min is pressed in etching for the second time, and etching is for the third time undertaken by 5.5m/min.
4. the production method of a kind of bright-copper-face high-heat-conductivity ceramic circuit board according to claim 1, it is characterized in that before step f excision forming and step e after, comprise the blue glue process of silk-screen: around predetermined some fluorescent glue zone, print the blue glue of a circle, oven dry then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101935903A CN101699933B (en) | 2009-11-02 | 2009-11-02 | Production method of bright-copper-face high-heat-conductivity ceramic circuit board |
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| CN2009101935903A CN101699933B (en) | 2009-11-02 | 2009-11-02 | Production method of bright-copper-face high-heat-conductivity ceramic circuit board |
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| CN101699933A CN101699933A (en) | 2010-04-28 |
| CN101699933B true CN101699933B (en) | 2011-11-30 |
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| CN2009101935903A Expired - Fee Related CN101699933B (en) | 2009-11-02 | 2009-11-02 | Production method of bright-copper-face high-heat-conductivity ceramic circuit board |
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| CN102781170B (en) * | 2012-07-24 | 2016-02-24 | 中山市达进电子有限公司 | A kind of preparation method of mirror-surface aluminum base board |
| CN102781169A (en) * | 2012-07-24 | 2012-11-14 | 广东达进电子科技有限公司 | Method for producing silver-plated ceramic circuit boards |
| CN113543490B (en) * | 2021-07-08 | 2023-01-10 | 江西晶弘新材料科技有限责任公司 | Method for increasing adhesion of printing ink on ceramic substrate |
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| JP2002299793A (en) * | 2001-03-30 | 2002-10-11 | Sumitomo Heavy Ind Ltd | Method of laser-machining ceramics green sheet, and method of manufacturing ceramics multilayered device |
| EP1265467A2 (en) * | 2001-06-07 | 2002-12-11 | Ngk Insulators, Ltd. | Multilayer board having precise perforations and circuit substrate having precise through-holes |
| CN101087493A (en) * | 2006-06-06 | 2007-12-12 | 龙全国际有限公司 | Manufacturing method of circuit board encapsulated by accumulation circuit |
| CN101232774A (en) * | 2007-01-24 | 2008-07-30 | 南京汉德森科技股份有限公司 | High heat conductivity ceramic base printed circuit board and method for making the same |
| CN101448364A (en) * | 2007-11-26 | 2009-06-03 | 同欣电子工业股份有限公司 | Method for producing small-pore-diameter copper-plated through hole on ceramic substrate |
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2009
- 2009-11-02 CN CN2009101935903A patent/CN101699933B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5595668A (en) * | 1995-04-05 | 1997-01-21 | Electro-Films Incorporated | Laser slag removal |
| JP2002299793A (en) * | 2001-03-30 | 2002-10-11 | Sumitomo Heavy Ind Ltd | Method of laser-machining ceramics green sheet, and method of manufacturing ceramics multilayered device |
| EP1265467A2 (en) * | 2001-06-07 | 2002-12-11 | Ngk Insulators, Ltd. | Multilayer board having precise perforations and circuit substrate having precise through-holes |
| CN101087493A (en) * | 2006-06-06 | 2007-12-12 | 龙全国际有限公司 | Manufacturing method of circuit board encapsulated by accumulation circuit |
| CN101232774A (en) * | 2007-01-24 | 2008-07-30 | 南京汉德森科技股份有限公司 | High heat conductivity ceramic base printed circuit board and method for making the same |
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