CN101524318A - 含有两性共聚物的使毛发丰盈的定型剂 - Google Patents
含有两性共聚物的使毛发丰盈的定型剂 Download PDFInfo
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- CN101524318A CN101524318A CN200910117844A CN200910117844A CN101524318A CN 101524318 A CN101524318 A CN 101524318A CN 200910117844 A CN200910117844 A CN 200910117844A CN 200910117844 A CN200910117844 A CN 200910117844A CN 101524318 A CN101524318 A CN 101524318A
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Abstract
本发明公开一种含有两性共聚物的使毛发丰盈的定型剂。一种用于处理角蛋白结构,特别是人毛发的化妆用制剂,所述制剂包含:a)聚合物A,其由下列单体构成:乙烯吡咯烷酮、丙烯酸叔丁基酯、甲基丙烯酸、二甲氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵,其中甲基丙烯酸的比例小于二甲氨基丙基甲基丙烯酰胺的比例,并且用适合的酸中和所述聚合物,b)阳离子表面活性剂K和/或阳离子聚合物B,c)含有聚氧乙烯单元和/或聚氧丙烯单元的非离子表面活性剂N。
Description
技术领域
本发明涉及一种新型毛发定型剂。
背景技术
为了临时改变和稳定发型而使用已知作为定型剂的产品。其中包括喷发胶、泡沫定型剂、凝胶、发蜡等。
配方是多种多样的,成分必须是在乙醇、水性乙醇或水性介质中相容的。
这种用于固定毛发的制剂通常由成膜的天然或合成聚合物或者聚合物组合的溶液构成。在此涉及非离子、阴离子、阳离子或两性聚合物。所述制剂施加到毛发上之后留下无色透明的薄膜。对这种薄膜有一系列的要求:所述薄膜应该是透明的、有光泽、对湿度不敏感、坚固、保持时间长、柔韧、不粘附的,不影响毛发的自然感觉并且可以用市售的洗发剂轻易地再洗掉。毛发定型剂在定型类产品中具有特殊位置。不仅薄膜特性(固定性(Halt)、柔韧)处于重要地位,而且对毛发的护理功效(可梳理性、经护理的感觉)也很重要。毛发定型剂被大多数消费者用来在发型设定时增加毛发丰盈(Haarvolumen)。
此外,泡沫定型剂的泡沫特征(泡沫细致、奶油状(cremig)、稳定)还对产品性能有相当大影响。
定型剂通常包含具有不同功能的其它化妆用助剂,例如护理物质、防腐剂、杀菌剂、香料、乳化剂、推进剂、用于软化、润湿和/或保湿的物质、脂肪、油、蜡、脂肪醇、脂肪酸酯或其它化妆用或皮肤病用配方中常见的成分,例如醇、多元醇、聚合物、泡沫稳定剂、电解质、有机溶剂、聚硅氧烷或聚硅氧烷衍生物、UV过滤剂、抗氧化剂、提取物、蛋白质和/或蛋白质水解物或颜料。
主要使用无规共聚物作为毛发定型剂中固定用(haltgebend)的聚合物。通常将具有乙烯基或酰基官能的不同的非离子、阴离子或阳离子/阳离子原单体共聚化,所述单体例如乙烯基内酰胺(乙烯吡咯烷酮、乙烯基己内酰胺)、乙酸乙烯酯、(甲基)丙烯酸烷基酯((甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸叔丁酯、(甲基)丙烯酸环己酯等)、苯乙烯、(甲基)丙烯酰胺、烷基(甲基)丙烯酰胺、官能化的(甲基)丙烯酸烷基酯(例如(甲基)丙烯酸羟乙酯、(甲基)丙烯酸二甲氨基乙酯)、(甲基)丙烯酸二甲氨基丙酯、官能化的烷基(甲基)丙烯酰胺(二甲氨基丙基(甲基)丙烯酰胺)、(甲基)丙烯酸、马来酸、巴豆酸、丙烯酰胺甲基丙磺酸、包含氨基基团的单体,其氨基基团被烷基化(季铵化),例如(甲基)丙烯酰基乙基三烷基氯化铵、(甲基)丙烯酰基丙基三烷基氯化铵、(甲基)丙烯酰基氨基丙基三烷基氯化铵、(甲基)丙烯酰基乙基三烷基甲基硫酸铵、(甲基)丙烯酰基丙基三烷基甲基硫酸铵、(甲基)丙烯酰基氨基丙基三烷基甲基硫酸铵。这类用于毛发定型剂中的聚合物的实例是例如具有下列INCI名称的聚合物:丙烯酸(酯)类共聚物(BASF的Soft,National Starch的BalanceBalanceLubrizol的Avalure)、丙烯酸(酯)类/羟酯类丙烯酸酯类共聚物(Rohm&Haas的)、丙烯酸(酯)类/辛基丙烯酰胺类共聚物(National Starch的或Resyn XP)、丙烯酸(酯)类/烯丙基甲基丙烯酸(酯)类共聚物AMP盐(Lubrizol的)、PVM/MA共聚物的丁酯(ISP的)、PVM/MA共聚物的乙酯(ISP的或)、丙烯酰胺/丙烯酰基二甲基酒石酸钠/丙烯酸聚合物(Rohm&Haas的Acudyne)、异丁烯/乙基马来酰亚胺/羟乙基马来酰亚胺共聚物(ISP的Aquaflex)、辛基丙烯酰胺/丙烯酸(酯)类/甲基丙烯酸丁基氨基乙酯共聚物(National Starch的或)、丙烯酸(酯)类/叔丁基丙烯酰胺共聚物(BASF的)、PEG/PPG-25/25聚二甲基硅氧烷/丙烯酸(酯)类/丙烯酸叔丁酯类共聚物(BASF的Luviflex)、聚乙烯基己内酰胺(BASF的Luviskol)、PVM/MA共聚物(BASF的Luviform)、PVP(BASF的)、PVP/VA共聚物(BASF的)、VP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的)、聚苯乙烯磺酸钠(NationalStarch的)、VA/巴豆酸(酯)类/新癸酸乙烯基酯共聚物(BASF的LuvisetNational Starch的)、VA/巴豆酸(酯)类/丙酸乙烯基酯共聚物(BASF的Luviset)、VA/马来酸丁酯/丙烯酸异冰片酯共聚物(ISP的Advantage)、VA/巴豆酸(酯)类共聚物(BASF的Luviset CAClariant的)、VA/苯甲酸乙烯基丁酯/巴豆酸(酯)类共聚物(Chimex的Mexomere)、乙烯基己内酰胺/PVP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的)、VA/马来酸丁酯/丙烯酸异冰片酯共聚物(ISP的Advantage)、丙烯酸(酯)类/C1-2琥珀酸(酯)类/羟基丙烯酸(酯)类共聚物(ISP的Allianz)、VP/乙烯基己内酰胺/DMAPA丙烯酸(酯)类共聚物(ISP的Aquaflex)、乙烯基己内酰胺/VP/甲基丙烯酸二甲氨基乙酯共聚物(ISP的)、VP/DMAPA丙烯酸(酯)类共聚物(ISP的Styleze CC-10)、VP/丙烯酸(酯)类/甲基丙烯酸月桂酯共聚物(ISP的Styleze)、VP/甲基丙烯酰胺/N-乙烯基咪唑共聚物(BASF的Luviset)、所有聚丙烯酸酯类(Lubrizol的Fixate和Fixate Superhold、BASF的Luviset)等很多。
其它用于毛发定型剂中的聚合物类是例如聚氨酯,例如聚氨酯-1(BASF的Luviset)、聚氨酯-2(Lubrizol的Avalure)、聚氨酯-6(BASF的Luviset SI)、聚酯,例如聚酯-5(Eastman的AQ Polymere)、聚酰亚胺,例如聚酰亚胺-1(ISP的Aquaflex)等很多。
毛发定型剂中固定用的聚合物的主要缺点是护理特性不足:毛发不易梳理且感觉无光泽、粗糙和缺少护理。薄膜干燥之后相对硬、脆和不柔韧。对使用者不利的是,薄膜的触觉特性和在梳理时残余物的形成(薄膜屑)。它落在肩上或衣服上并且让使用者看上去不修边幅。
对毛发定型剂配方的手感和可梳理性的改进典型地通过所述聚合物与阳离子聚合物、阳离子表面活性剂或聚硅氧烷(例如环状聚二甲基硅氧烷(环聚甲基硅氧烷))、聚二甲基硅氧烷类的聚硅氧烷表面活性剂(聚醚改性的硅氧烷)的组合来实现。
适当的阳离子表面活性剂选自季铵化合物类,特别是苄基三烷基铵盐或烷基三甲基铵盐,例如鲸蜡基三甲基氯化铵或鲸蜡基三甲基溴化铵、烷基二甲基羟乙基氯化铵或烷基二甲基羟乙基溴化铵、二烷基二甲基氯化铵或二烷基二甲基溴化铵、烷基酰胺乙基三甲基硫酸铵醚酯(Alkylamidethyltrimethylammoniumethersulfate)、羟乙基鲸蜡基二甲基磷酸铵、烷基吡啶鎓盐,例如月桂基氯化吡啶鎓或鲸蜡基氯化吡啶鎓、咪唑啉衍生物和具有阳离子特征的化合物例如氧化胺,例如烷基二甲基氧化胺或烷基氨基乙基二甲基氧化胺。
适当的阳离子聚合物是被称为聚季铵盐的聚合物例如乙烯基咪唑、乙烯吡咯烷酮和/或乙烯基己内酰胺的季铵化共聚物(聚季铵盐-16、聚季铵盐-44和聚季铵盐-46)、季铵化的乙烯吡咯烷酮/甲基丙烯酸二甲氨基乙酯共聚物(聚季铵盐-11)、二甲基二烯丙基氯化铵的均聚物和共聚物(聚季铵盐-6、聚季铵盐-7或聚季铵盐-22)、季铵化的纤维素聚合物(聚季铵盐-4、聚季铵盐-10)、由阳离子纤维素和淀粉构成的共聚物(聚季铵盐-4/羟丙基淀粉共聚物)、季铵化的乙烯吡咯烷酮/甲基丙烯酸二甲氨基丙基酯/甲基丙烯酸月桂基二甲基氨基丙酯共聚物(聚季铵盐-55)、乙烯吡咯烷酮/乙烯基咪唑/甲基丙烯酰胺/季铵化的乙烯基咪唑(聚季铵盐-68)、季铵化的乙烯基己内酰胺/乙烯吡咯烷酮/二甲氨基丙基甲基丙烯酰胺/甲基丙烯酰氨基丙基月桂基二甲基氯化铵(聚季铵盐-69)或季铵化的瓜尔胶衍生物。
然而,这些阳离子聚合物或阳离子表面活性剂的使用大多数情况下导致丰盈特性的明显降低。
如果以泡沫形式施加,所述毛发定型剂还通过使用许多固定用的成膜剂造成不充分的、非化妆用的泡沫特征(泡沫不细致、软、不太象奶油状)。
为了改善泡沫特性通常加入使泡沫稳定的添加剂,例如非离子表面活性剂。
适当的非离子表面活性剂是醇;烷醇酰胺,例如椰油酰胺MEA/DEA/MIPA;氧化胺,例如氧化椰油酰氨基丙基胺;通过羧酸与氧化乙烯、甘油、脱水山梨醇或其它醇的酯化产生的酯;醚,例如乙氧基化/丙氧基化醇、乙氧基化/丙氧基化酯、乙氧基化/丙氧基化甘油酯、乙氧基化/丙氧基化胆固醇、乙氧基化/丙氧基化甘油三酯、乙氧基化/丙氧基化羊毛脂、乙氧基化/丙氧基化聚硅氧烷、丙氧基化POE醚和烷基聚葡糖苷例如月桂基葡糖苷、癸基葡糖苷和椰油基葡糖苷、蔗糖酯、蔗糖醚、聚甘油酯、甘油双酯、甘油单酯、甲基葡糖酯以及羟基酸的酯。
适当的推进剂是烃例如丁烷、异丁烷和丙烷、二甲醚或碳氟化合物例如1,2-二氟乙烷。其它推进剂是氮气、二氧化碳、一氧化二氮或压缩空气。
发明内容
令人惊奇地发现,用于处理角蛋白结构,特别是人毛发的化妆用制剂弥补了现有技术的缺陷,所述制剂包含:
a)聚合物A,其由下列单体构成:乙烯吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵,其中甲基丙烯酸的比例小于二甲氨基丙基甲基丙烯酰胺的比例,并且用适合的酸中和所述聚合物,
b)阳离子表面活性剂K和/或阳离子聚合物B,
c)含有聚氧乙烯单元和/或聚氧丙烯单元的非离子表面活性剂N。
上述制剂特别对丰盈特性有协同作用。
在此优选,所述制剂包含浓度为0.01至30重量%,特别优选0.05至20重量%,特别优选0.5至15重量%的聚合物A。在此优选,所述聚合物A是无规和线型共聚物。在此优选,利用磷酸将所述聚合物A中和至pH 6.0。在此优选,所述阳离子表面活性剂K和/或阳离子聚合物B的浓度为0.01至20重量%,优选0.05至3重量%,特别优选0.1至2重量%的西曲氯铵(Cognis的Dehyquart或Kci的CTAC6025)和/或0.05至3重量%,特别优选0.1至2重量%的羟乙基鲸蜡基二甲基磷酸铵(BASF的Luviquat Mono)和/或0.5至15重量%,特别优选1.0至10重量%聚季铵盐-68(BASF的Luviquat)或它们的混合物。在此优选,所述制剂包含浓度为0.01至5重量%的表面活性剂N。在此优选,作为表面活性剂N包含0至3重量%,特别优选0至2重量%的月桂醇聚醚-3(Cognis的Dehydol LS3Deo)和/或0至3重量%,特别优选0至2重量%十三烷醇聚醚-12(Lipo的Lipocol),其中一种或多种表面活性剂N的总浓度大于0。在此优选,所述制剂包含0至25重量%,特别优选1至25重量%的乙醇。在此优选,所述制剂包含0至25重量%,特别优选1至25重量%的推进剂。本发明还包括上述制剂的用途,作为用于施加在角蛋白物质,特别是人毛发上的毛发定型剂,优选作为包含推进剂的泡沫定型剂、泵式泡沫定型剂或者作为泵式喷发胶。
根据本发明的毛发定型剂还可以额外包含护理物质、防腐剂、杀菌剂、香料、乳化剂、推进剂、用于软化、润湿和/或保湿的物质、脂肪、油、蜡、脂肪醇、脂肪酸酯或其它化妆用或皮肤病用配方中常见的成分,例如醇、多元醇、聚合物、泡沫稳定剂、电解质、有机溶剂、聚硅氧烷或聚硅氧烷衍生物、UV过滤剂、抗氧化剂、提取物、蛋白质和/或蛋白质水解物或颜料。
根据本发明的毛发定型剂还可以额外包含至少一种其它阴离子、阳离子、非离子或两性成膜聚合物,浓度为0至10重量%。
具体实施方式
实施例
聚合物1:
由乙烯吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵构成的无规、线型共聚物,用磷酸将其中和至pH 6.0。
由下面的单体比例可得到聚合物1:
47重量%的丙烯酸叔丁酯,
25重量%的乙烯吡咯烷酮,
10重量%的二甲氨基丙基甲基丙烯酰胺,
15重量%的乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵,
3重量%的甲基丙烯酸。
检验不同毛发定型剂与聚合物1的3%溶液的毛发丰盈程度,比较得出下面的结果:
添加阳离子表面活性剂K和/或阳离子聚合物B导致丰盈增加2%。添加含有聚氧乙烯单元和/或聚氧丙烯单元的非离子表面活性剂N导致丰盈增加4%。添加阳离子表面活性剂K和/或阳离子聚合物B以及含有聚氧乙烯单元和/或聚氧丙烯单元的非离子表面活性剂N导致丰盈增加20%。
毛发定型剂的配方实施例:
1 | 2 | 3 | 4 | 5 | 6 | |
聚合物1 | 12 | 10 | 15 | 8 | 6 | 3 |
聚季铵盐-68 | 8 | 10 | 3 | - | - | - |
聚季铵盐-16 | - | 5 | - | - | ||
聚季铵盐-4 | - | - | 0,5 | - | 1 | - |
聚季铵盐-4/羟丙基淀粉共聚物 | - | - | - | - | - | 2 |
西曲氯铵 | 1,0 | 1,0 | - | 1,0 | - | 1,0 |
羟乙基鲸蜡基二甲基磷酸铵 | - | 0,5 | - | 0,5 | 1,0 | - |
聚二甲基硅氧烷共聚醇 | - | - | 0,3 | - | 0,2 | - |
泛醇 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 |
柠檬酸 | 0,2 | 0,2 | 0,3 | 0,3 | 0,2 | 0,3 |
苯甲酸钠 | 0,2 | 0,2 | 0,2 | - | - | 0,2 |
月桂醇聚醚-3 | 0,8 | 1,5 | 1,0 | - | 0,25 | 0,5 |
十三烷醇聚醚-12 | 0,8 | - | 1,0 | 1,5 | 0,25 | 0,5 |
PEG-40氢化蓖麻油 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 |
香料 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
丙烷/丁烷 | 10 | 10 | - | 10 | 10 | 10 |
乙醇 | - | - | - | 15 | 15 | - |
水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
7 | 8 | 9 | 10 | 11 | 12 | |
聚合物1 | 18 | 6 | 4 | 12 | 9 | 3 |
VP/VA共聚物 | - | 4 | 8 | - | - | - |
VP/甲基丙烯酰胺/乙烯基咪唑共聚物 | - | - | - | 5 | - | - |
聚酰亚胺-1 | - | - | - | - | 5 | 6 |
聚季铵盐-68 | - | 5 | 3 | - | 5 | - |
聚季铵盐-16 | - | - | - | - | 0,5 | 2 |
聚季铵盐-4 | - | - | 0,5 | - | - | 2 |
聚季铵盐-4/羟丙基淀粉共聚物 | - | - | - | 2 | - | 2 |
西曲氯铵 | 2,0 | 1,0 | - | 1,0 | - | 1,0 |
羟乙基鲸蜡基二甲基磷酸铵 | 1,0 | - | - | - | 1,0 | - |
聚二甲基硅氧烷共聚醇 | 0,3 | - | 0,3 | - | 0,2 | - |
泛醇 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 |
柠檬酸 | 0,2 | 0,2 | 0,3 | 0,3 | 0,2 | 0,3 |
苯甲酸钠 | 0,2 | 0,2 | 0,2 | - | - | 0,2 |
月桂醇聚醚-3 | 1,0 | 0,3 | 1,0 | - | 1,5 | 0,5 |
十三烷醇聚醚-12 | 1,0 | 0,3 | 1,0 | 1,5 | - | 0,5 |
PEG-40氢化蓖麻油 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 |
香料 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
丙烷/丁烷 | 10 | 10 | - | 10 | 10 | 10 |
乙醇 | - | - | - | 15 | 15 | - |
水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
13 | 14 | 15 | 16 | 17 | 18 | |
聚合物1 | 18 | 6 | 4 | 12 | 9 | 3 |
丙烯酸(酯)类/烯丙基甲基丙烯酸(酯)类共聚物AMP盐 | 2 | 8 | - | - | - | - |
丙烯酸(酯)类共聚物 | - | - | 10 | 2 | - | - |
丙烯酸(酯)类/羟基酯丙烯酸(酯)类共聚物 | - | - | - | - | 3 | 10 |
聚季铵盐-68 | 7 | 5 | 10 | - | 5 | - |
聚季铵盐-16 | 0,5 | - | - | - | - | - |
聚季铵盐-4 | - | - | 0,5 | - | 0,5 | - |
聚季铵盐-4/羟丙基淀粉共聚物 | - | - | - | - | - | - |
氨甲基丙醇 | - | - | 0,9 | 0,2 | 0,5 | 0,1 |
西曲氯铵 | 1,0 | - | - | - | 1,0 | 1,0 |
羟乙基鲸蜡基二甲基磷酸铵 | 0,5 | - | - | 1,0 | - | 0,5 |
聚二甲基硅氧烷共聚醇 | - | - | - | 0,3 | - | 0,2 |
泛醇 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 | 0,1 |
苯氧乙醇 | 0,5 | 0,5 | 0,5 | 0,5 | 0,5 | - |
对羟基苯甲酸酯 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 | - |
月桂醇聚醚-3 | 1,0 | 1,5 | 0,3 | - | 1,5 | 0,5 |
十三烷醇聚醚-12 | 1,0 | - | 0,3 | 1,5 | - | 0,5 |
PEG-40氢化蓖麻油 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 |
香料 | 适量 | 适量 | 适量 | 适量 | 适量 | 适量 |
丙烷/丁烷 | 10 | 10 | - | 10 | 10 | 10 |
乙醇 | - | - | - | 15 | 15 | - |
水 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 | 加至100 |
Claims (10)
1.一种用于处理角蛋白结构,特别是人毛发的化妆用制剂,所述制剂包含:
a)聚合物A,其由下列单体构成:乙烯吡咯烷酮、丙烯酸叔丁酯、甲基丙烯酸、二甲氨基丙基甲基丙烯酰胺和乙基硫酸甲基丙烯酰氧乙基二甲基乙基铵,其中甲基丙烯酸的比例小于二甲氨基丙基甲基丙烯酰胺的比例,并且用适合的酸中和所述聚合物,
b)阳离子表面活性剂K和/或阳离子聚合物B,
c)含有聚氧乙烯单元和/或聚氧丙烯单元的非离子表面活性剂N。
2.根据权利要求1的制剂,其特征在于,所述制剂包含浓度为0.01至30重量%,特别优选0.05至20重量%,特别优选0.5至15重量%的聚合物A。
3.根据前述权利要求中任一项的制剂,其特征在于,所述聚合物A是无规和线型共聚物。
4.根据前述权利要求中任一项的制剂,其特征在于,利用磷酸将所述聚合物A中和至pH 6.0。
6.根据前述权利要求中任一项的制剂,其特征在于,所述制剂包含浓度为0.01至5重量%的表面活性剂N。
8.根据前述权利要求中任一项的制剂,其特征在于,所述制剂包含0至25重量%,特别优选1至25重量%的乙醇。
9.根据前述权利要求中任一项的制剂,其特征在于,所述制剂包含0至25重量%,特别优选1至25重量%的推进剂。
10.根据前述权利要求中任一项的制剂的用途,作为用于施加在角蛋白物质,特别是人毛发上的毛发定型剂,优选作为包含推进剂的泡沫定型剂、泵式泡沫定型剂或者作为泵式喷发胶。
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DE200810013171 DE102008013171A1 (de) | 2008-03-07 | 2008-03-07 | Volumengebender Haarfestiger mit ampholytischem Copolymer |
DE102008013171.1 | 2008-03-07 |
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Cited By (3)
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CN102488629A (zh) * | 2011-12-21 | 2012-06-13 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
CN101721325B (zh) * | 2009-11-11 | 2013-05-08 | 广东名臣有限公司 | 两性护发定型组合物 |
CN103347992A (zh) * | 2010-12-01 | 2013-10-09 | Isp投资公司 | 持久定型的组合物及其用途 |
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DE102008040102A1 (de) * | 2008-07-03 | 2010-01-07 | Beiersdorf Ag | Volumengebender Haarfestiger |
EP2116225A1 (de) * | 2008-10-16 | 2009-11-11 | Beiersdorf AG | Ausspülhaarspülungen zur Steigerung des Frisurvolumens |
EP2403472B1 (en) * | 2009-03-05 | 2014-08-20 | Basf Se | Ampholytic ter-polymers for use in personal care compositions |
DE102011088148A1 (de) * | 2011-12-09 | 2013-06-13 | Henkel Ag & Co. Kgaa | Treibmittelhaltiges kosmetisches Mittel |
DE102011089627A1 (de) * | 2011-12-22 | 2013-06-27 | Henkel Ag & Co. Kgaa | Mittel für keratinhaltige Fasern, enthaltend mindestens eine Cellulose mit kationischer Struktureinheit und mindestens ein spezielles Copolymer |
WO2017019009A1 (en) | 2015-07-27 | 2017-02-02 | Kimberly-Clark Worldwide, Inc. | Residual disinfectant composition |
FR3045361B1 (fr) * | 2015-12-21 | 2018-02-02 | L'oreal | Composition comprenant un copolymere vinylformamide/vinylamine, un polymere fixant et une association particuliere d'agents tensioactifs |
FR3045371B1 (fr) * | 2015-12-21 | 2020-02-07 | L'oreal | Composition pulverisable sous forme de mousse comprenant un copolymere vinylformamide/vinylamine, un agent tensioactif particulier et un agent propulseur |
DE102016223588A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
DE102016223590A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymer enthaltende reinigungsmittelzusammensetzungen |
DE102016223586A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
WO2018095813A1 (en) | 2016-11-28 | 2018-05-31 | Clariant International Ltd | Cosmetic composition comprising a cationic copolymer |
DE102018216640A1 (de) * | 2018-09-27 | 2020-04-02 | Beiersdorf Ag | Pumpbare Zubereitung für die Haare |
DE102018216625A1 (de) * | 2018-09-27 | 2020-04-02 | Beiersdorf Ag | Kosmetische Zubereitung für die Haare freigesetzt in Aerosolform |
FR3090363B1 (fr) * | 2018-12-21 | 2021-11-19 | Oreal | Dispositif Aérosol Contenant une Composition Comprenant au moins un Polymère, au moins un Tensioactif et au moins un Agent Propulseur |
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FR2829383B1 (fr) * | 2001-09-11 | 2005-09-23 | Oreal | Compositions cosmetiques contenant un copolymere d'acide methacrylique, une silicone et un polymere cationique et leurs utilisations |
FR2840213B1 (fr) * | 2002-05-31 | 2005-08-05 | Oreal | Dispositif aerosol a deux compartiments comprenant une composition aqueuse de coiffage et procede de coiffage |
CN1887010A (zh) * | 2003-11-21 | 2006-12-27 | 意大利电信股份公司 | 服务质量监控架构、相关方法、网络及计算机程序产品 |
DE102004041294A1 (de) * | 2004-08-25 | 2006-03-09 | Beiersdorf Ag | Mittel zur fixierenden Behandlung keratinischer Fasern mit einer Kombination aus fixierenden Polymeren mit bestimmten Molmassen |
BRPI0504472A (pt) * | 2004-10-13 | 2006-06-27 | Oreal | uso de uma composição, composição cosmética, processos para o tratamento das matérias queratìnicas e kit |
DE102004054278A1 (de) * | 2004-11-10 | 2006-06-01 | Wella Ag | Klares, zweiphasiges, schaumbildendes Aerosol-Haarstylingprodukt |
ES2405615T3 (es) * | 2005-07-22 | 2013-05-31 | Basf Se | Uso de copolímeros anfolíticos aniónicos y catiónicos |
WO2008031892A1 (de) * | 2006-09-15 | 2008-03-20 | Basf Se | Ampholytisches copolymer auf basis quaternisierter stickstoffhaltiger monomere |
WO2009103735A1 (de) * | 2008-02-21 | 2009-08-27 | Basf Se | Zusammensetzung, enthaltend ein ampholytisches copolymer auf der basis quaternisierter stickstoffhaltiger monomere und mindestens ein hiervon verschiedenes polymer, und ihre verwendung |
-
2008
- 2008-03-07 DE DE200810013171 patent/DE102008013171A1/de not_active Withdrawn
-
2009
- 2009-02-04 EP EP09152047.8A patent/EP2098217A3/de not_active Withdrawn
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101721325B (zh) * | 2009-11-11 | 2013-05-08 | 广东名臣有限公司 | 两性护发定型组合物 |
CN103347992A (zh) * | 2010-12-01 | 2013-10-09 | Isp投资公司 | 持久定型的组合物及其用途 |
CN102488629A (zh) * | 2011-12-21 | 2012-06-13 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
CN102488629B (zh) * | 2011-12-21 | 2012-11-14 | 广州好迪集团有限公司 | 一种发用定型剂及发用定型品 |
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