CN101418146A - 一种紫外光-热双固化聚苯胺防腐涂料及其制备方法 - Google Patents
一种紫外光-热双固化聚苯胺防腐涂料及其制备方法 Download PDFInfo
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- CN101418146A CN101418146A CNA2008100515765A CN200810051576A CN101418146A CN 101418146 A CN101418146 A CN 101418146A CN A2008100515765 A CNA2008100515765 A CN A2008100515765A CN 200810051576 A CN200810051576 A CN 200810051576A CN 101418146 A CN101418146 A CN 101418146A
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- Prior art keywords
- polyaniline
- coating
- curing
- ultraviolet
- polyurethane
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- 229920000767 polyaniline Polymers 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 230000009977 dual effect Effects 0.000 title claims description 21
- 239000003973 paint Substances 0.000 title abstract description 33
- 238000001723 curing Methods 0.000 claims abstract description 50
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- 239000004814 polyurethane Substances 0.000 claims abstract description 27
- 229920002635 polyurethane Polymers 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000706 filtrate Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 25
- 239000004576 sand Substances 0.000 claims description 20
- 229920005862 polyol Polymers 0.000 claims description 12
- 150000003077 polyols Chemical class 0.000 claims description 12
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 10
- 238000003801 milling Methods 0.000 claims description 10
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical group C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 6
- -1 phenolic aldehyde Chemical class 0.000 claims description 6
- 239000013638 trimer Substances 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 5
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 4
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical group C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000468 ketone group Chemical group 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- 125000003944 tolyl group Chemical group 0.000 claims description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 235000004443 Ricinus communis Nutrition 0.000 claims description 2
- 240000000528 Ricinus communis Species 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical group CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 229940106691 bisphenol a Drugs 0.000 claims description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 239000010773 plant oil Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 13
- 239000002184 metal Substances 0.000 abstract description 13
- 238000005260 corrosion Methods 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 238000004132 cross linking Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 3
- 229910052725 zinc Inorganic materials 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000001029 thermal curing Methods 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- 239000011888 foil Substances 0.000 description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 238000005498 polishing Methods 0.000 description 9
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 9
- 238000009998 heat setting Methods 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002468 redox effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Description
项目 | 对比例1 | 对比例2 | 对比例3 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 |
涂膜厚度(μm) | 45 | 45 | 85 | 85 | 90 | 100 | 95 | 90 |
固化时间(s) | 30 | 30 | 20 | 20 | 20 | 20 | 20 | 20 |
冲击强度(cm)(GB1732/93) | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 |
硬度(H)(GB6739/86) | 3 | 3 | 5 | 5 | 5 | 5 | 4 | 4 |
柔韧性(mm)(GB1731/93) | 2 | 2 | 2 | 2 | 2 | 2 | 1 | 1 |
盐雾(h)(GB1771/91)漆膜不起泡、不锈蚀 | 200 | 700 | 500 | 1500 | 1750 | 2000 | 1700 | 1600 |
10%盐水浸泡(h),漆膜不起泡、不锈蚀 | 50 | 200 | 150 | 400 | 450 | 500 | 450 | 400 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2008100515765A CN101418146B (zh) | 2008-12-11 | 2008-12-11 | 一种紫外光-热双固化聚苯胺防腐涂料及其制备方法 |
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CN2008100515765A CN101418146B (zh) | 2008-12-11 | 2008-12-11 | 一种紫外光-热双固化聚苯胺防腐涂料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101418146A true CN101418146A (zh) | 2009-04-29 |
CN101418146B CN101418146B (zh) | 2012-01-18 |
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CN2008100515765A Active CN101418146B (zh) | 2008-12-11 | 2008-12-11 | 一种紫外光-热双固化聚苯胺防腐涂料及其制备方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102002304A (zh) * | 2010-12-20 | 2011-04-06 | 中国科学院长春应用化学研究所 | 涂料组合物及其制备和使用方法 |
CN102604456A (zh) * | 2012-02-27 | 2012-07-25 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料的制备方法 |
CN102618100A (zh) * | 2012-02-27 | 2012-08-01 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料 |
CN103589317A (zh) * | 2013-10-24 | 2014-02-19 | 安徽柏拉图涂层织物有限公司 | 一种防盗的卡车侧帘用涂料 |
CN106336699A (zh) * | 2016-07-28 | 2017-01-18 | 江苏昌悦重工科技有限公司 | 一种污水处理集装箱 |
CN116285450A (zh) * | 2022-11-23 | 2023-06-23 | 常州纳欧新材料科技有限公司 | 一种紫外光固化导电卷材涂料及其制备方法 |
-
2008
- 2008-12-11 CN CN2008100515765A patent/CN101418146B/zh active Active
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102002304A (zh) * | 2010-12-20 | 2011-04-06 | 中国科学院长春应用化学研究所 | 涂料组合物及其制备和使用方法 |
CN102604456A (zh) * | 2012-02-27 | 2012-07-25 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料的制备方法 |
CN102618100A (zh) * | 2012-02-27 | 2012-08-01 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料 |
CN102604456B (zh) * | 2012-02-27 | 2013-12-18 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料的制备方法 |
CN102618100B (zh) * | 2012-02-27 | 2014-03-12 | 孝感学院 | 一种光固化纳米聚苯胺-环氧丙烯酸树脂互穿网络防静电涂料 |
CN103589317A (zh) * | 2013-10-24 | 2014-02-19 | 安徽柏拉图涂层织物有限公司 | 一种防盗的卡车侧帘用涂料 |
CN103589317B (zh) * | 2013-10-24 | 2016-04-06 | 安徽柏拉图涂层织物有限公司 | 一种防盗的卡车侧帘用涂料 |
CN106336699A (zh) * | 2016-07-28 | 2017-01-18 | 江苏昌悦重工科技有限公司 | 一种污水处理集装箱 |
CN116285450A (zh) * | 2022-11-23 | 2023-06-23 | 常州纳欧新材料科技有限公司 | 一种紫外光固化导电卷材涂料及其制备方法 |
CN116285450B (zh) * | 2022-11-23 | 2024-05-07 | 常州纳欧新材料科技有限公司 | 一种紫外光固化导电卷材涂料及其制备方法 |
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CN101418146B (zh) | 2012-01-18 |
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