CN101407651A - UV curing color decorative coating - Google Patents
UV curing color decorative coating Download PDFInfo
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- CN101407651A CN101407651A CNA2008100798321A CN200810079832A CN101407651A CN 101407651 A CN101407651 A CN 101407651A CN A2008100798321 A CNA2008100798321 A CN A2008100798321A CN 200810079832 A CN200810079832 A CN 200810079832A CN 101407651 A CN101407651 A CN 101407651A
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Abstract
The invention relates to an ultraviolet curing color decorative coating, the components of the coating and the parts by weight thereof are as follows: 5 to 25 parts of epoxy acrylate prepolymer, 5 to 30 parts of polyurethane acrylate prepolymer, 2 to 10 parts of polyester acrylate prepolymer, 15 to 70 parts of acrylate monomer, 1 to 10 parts of photoinitiator, 1 to 35 parts of pigment, 0.5 to 10 parts of dispersant and 0.1 to 2 parts of auxiliary agent, the acrylate monomer is a mixture of the monomer with bifunctionality and the monomer with high functionality, wherein, the mixture ratio of the monomer with high bifunctionality to the monomer with bifunctionality is 1: 0.3 to 8. Compared with an ultraviolet curing transparent varnish, the ultraviolet curing color decorative coating has stronger decorative effect and almost the same curing speed, paint film hardness, adhesion, paint film gloss, and the like; and compared with a traditional solvent based colored paint, the ultraviolet curing color decorative coating does not contain volatile organic solvent, thereby avoiding the pollution and greatly improving the production efficiency. The ultraviolet curing color decorative coating is applicable to the decoration of plastics, wood materials, metals and other base materials.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of UV curing color decorative coating.
Background technology
The ultraviolet light polymerization product have save the energy, be beneficial to environmental protection, economy and characteristics such as efficient, so be widely used in every field.At present, UV-curing technology is used widely in fields such as coating, printing ink, electronic chemical product, tackiness agent and medical devices.
Be used for the colored paint that various substrate surfaces are decorated at present, mostly be solvent-borne type.Solvent-type paint can satisfy substrate surface decorative effect demand substantially, but has shortcomings such as paint film is plentiful inadequately, glossiness is low, hardness is low, weathering resistance is poor, decorative effect is undesirable, and production efficiency is low.In addition, solvent-type paint generally uses a large amount of volatile organic solvent (VOC), causes environmental pollution easily.Though UV-curing technology production efficiency height, do not contain volatile organic solvent (VOC), because the restriction of UV-curing technology itself, existing ultraviolet-curing paint can not satisfy the requirement of colourful decorative effect based on transparent varnish.
As everyone knows, ultraviolet-curing paint is to carry out the polymerization crosslinking solidified by the UV-light energy, and the curing performance of light penetration and coating has necessary relation.The high covering power pigment that in the ultraviolet light polymerization system, adds, though can satisfy the decorative effect of substrate surface, but because the adding of pigment, cause light to be strengthened in surface reflection, refraction and the scattering of pigment, make that light is difficult to see through, can't arrive the deep layer of coating, promptly can not satisfy the requirement of deep layer solidified, cause film curing not thorough, sticking power is low, hardness and weathering resistance are poor.Simultaneously,, add the pigment in the ultraviolet light polymerization system, reassemble easily after the dispersion, be unfavorable for using and preserving of coating owing to the viscosity and the viscosity of the coating that satisfies modes such as showering, roller coat are all lower.Publication number is that the Chinese patent of CN1176985 discloses special-purpose ultraviolet cured colored paint of a kind of wooden pencil and preparation method thereof, but pigment and filler all are transparent and translucent, deep layer problem of solidification under the also unresolved pigment high covering power situation, and hardness, scratch-proofness and the weathering resistance of paint film do not proposed clear and definite solution.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the defective of above-mentioned prior art, provide a kind of have good decorative effect and hardness of paint film, can deep layer solidified UV curing color decorative coating.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is:
A kind of UV curing color decorative coating, the component of described coating and parts by weight thereof are:
Epoxy acrylate class prepolymer 5～25,
Urethane acrylate class prepolymer 5～30,
Polyester acrylate class prepolymer 2～10,
Acrylic ester monomer 15～70,
Light trigger 1～10,
Pigment 1～35,
Dispersion agent 0.5～10,
Auxiliary agent 0.1～2,
Described acrylic ester monomer is difunctionality monomer and the monomeric mixture of high functionality, and wherein the monomeric proportioning of high functionality monomer and difunctionality is 1: 0.3～8.
Described epoxy acrylate class prepolymer is selected from a kind of of bisphenol A epoxy acrylate and modified bisphenol A epoxy acrylate or its mixture.
Described urethane acrylate class prepolymer is selected from a kind of or its mixture of high functionality aliphatic urethane acrylate class prepolymer and difunctionality aliphatic urethane acrylate class prepolymer.
Described high functionality acrylic ester monomer is one or more in three-functionality-degree, four functionality, five functionality or the six functionality acrylic ester monomers, is selected from Viscoat 295 (TMPTA), pentaerythritol triacrylate (PETA), tetramethylol methane tetraacrylate (PETTA), double pentaerythritol C5 methacrylate (DPEPA), double pentaerythritol methacrylate (DPHA), the third oxidation Viscoat 295 (PO-TMPTA) or oxyethyl group Viscoat 295 (EO-TMPTA).
Described difunctionality acrylic ester monomer is selected from 1,6 hexanediol diacrylate (HDDA), two contract propylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), neopentylglycol diacrylate (NPGDA) or ethoxyquin neopentylglycol diacrylate (PO-NPGDA).
Described light trigger is selected from 1-hydroxy-cyclohexyl methyl phenyl ketone (Irgacure184), α, alpha-alpha-dimethyl-Alpha-hydroxy methyl phenyl ketone (Darocur1173), 2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907), 2-phenyl-2-dimethylin-1-(4-morpholinyl phenyl)-butanone-1 (Irgacure369), 2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide (lucirinTPO), two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide ((Irgacure819) or two (2,6-dimethoxy benzoyl)-(4 ', 4 '-dimethyl octyl group-2) in the phosphine oxide one or more.
Described pigment is selected from one or more in titanium white, carbon black, pigment yellow 83, pigment yellow 17 4, pigment red 3, Pigment red 5, Pigment red 170, pigment Blue 15, the pigment Green 7.
Described dispersion agent is selected from the polymer wetting dispersing agent or contains the dispersion agent of acidic-group.
Described auxiliary agent is selected from modified polyorganosiloxane compound or fluorine-carbon modified acrylate.
The quick initiated polymerization of UV-light that ultraviolet light polymerization product utilization mercury lamp sends, have save the energy, be beneficial to environmental protection, economy and characteristics such as efficient.UV curing color decorative coating provided by the invention, be to be the main body component with epoxy acrylate class prepolymer, urethane acrylate class prepolymer, polyester acrylate class prepolymer and acrylic ester monomer, light trigger is under UV-irradiation, produce living radical through cracking or hydrogen transference, living radical is attacked unsaturated double-bond wherein, makes crosslinked generation solid superpolymer thereby make two keys become singly-bound.Superpolymer and pigment wherein, auxiliary agent etc. are membranaceous attached on the base material, form paint film.
Epoxy acrylate class prepolymer, it is the important component part in the ultraviolet-curing paint, it is to use esters of acrylic acid prepolymer the most widely, it has characteristics such as curing speed is fast, hardness is high, glossiness is high, pigment wettability is good, chemical resistance is strong, but has that snappiness is poor, paint film is crisp, wears no resistance, shortcomings such as not anti-stroke, weathering resistance difference; The epoxy acrylic esters resin that the present invention selects for use is a kind of or its mixture of bisphenol A epoxy acrylate and modified bisphenol A type epoxy acrylate, it is fast that bisphenol A epoxy acrylate has curing speed, the shrinking percentage height, product has high rigidity after solidifying, characteristics such as high abrasion, the bisphenol A epoxy acrylate WSR-U125 of preferred Wuxi resin processing plant, the bisphenol A epoxy acrylate 621A-80 of the 20% tripropylene glycol diacrylate dilution of Changxing, Taiwan chemical company, the modified bisphenol A epoxy acrylate 623-100 of Changxing, Taiwan chemical company, the modified bisphenol A epoxy acrylate 6231A-80 of Changxing, Taiwan chemical company 20% tripropylene glycol diacrylate dilution.
The Polyurethane acrylic resin has low smell, low volatilization, low irritant and good film-forming properties, and solidifying product has the wear resistance and the excellent high-temperature stability of high-tensile, brilliance.Adding the urethane acrylate purpose among the present invention is to be used with epoxy acrylate, utilize urethane acrylate snappiness and weathering resistance preferably, and along with the increase of functionality shows good wear resistance and scratch-proofness, so that paint film has high rigidity, high gloss, high abrasion, high anti-stroke, good snappiness and weathering resistance.The urethane acrylate class prepolymer that the present invention selects for use is a kind of or its mixture that is selected from high functionality aliphatic urethane acrylate class prepolymer and difunctionality aliphatic urethane acrylate class prepolymer, aliphatic polyurethane six acrylate 6145-100,6161-100 as Changxing, Taiwan chemical company, 15%1, the aliphatic urethane diacrylate 611B-85 of 6-hexanediyl ester (HDDA) dilution, the polyester polyol of 20% ethoxyquin Viscoat 295 dilution, aliphatic urethane diacrylate 6141H-80; The aliphatic urethane acrylate CN9013 of U.S. Sartomer company (9 functionality), U.S. Sartomer company 15%1, the aliphatic urethane acrylate CN966B85 (2 functionality) of 6-hexanediyl ester (HDDA) dilution, aliphatic urethane acrylate CN962 (2 functionality).
In order to improve the fullness ratio of product, added polyester acrylate class prepolymer in the formula for a product provided by the invention with higher refraction coefficient, the present invention is selected to be the polyester acrylate of high functionality, as the polyester acrylate performed polymer CN2203 (4 functionality) of U.S. Sartomer company, polyester acrylate oligomer CN2295 (6 functionality) etc.
Acrylic ester monomer is divided into difunctionality monomer and high functionality monomer, the acrylic ester monomer of difunctionality is the low viscosity thinner, have remarkable solvability and viscosity adjustment, but solidify rapidly on its top layer, the easy like this paint film deep layer that causes is solidified not exclusively, cause paint film adhesion low, resistance to marring is poor.The high functionality acrylic ester monomer can improve the degree of crosslinking of paint film, improve hardness, wear resistance, scratch-proofness, weathering resistance and the gloss of paint film, but its exist viscosity big, to the shortcoming of the viscosity adjustment difference of system, can not reach the requirement of application when using separately to viscosity.
In order to solve the deep layer problem of solidification of coating, and guarantee the hardness of paint film simultaneously, acrylic ester monomer is difunctionality monomer and the monomeric mixture of high functionality in the formula system of UV curing color decorative coating provided by the invention, and wherein the monomeric proportioning of difunctionality monomer and high functionality is 1: 0.3～8.
High functionality acrylic ester monomer of the present invention is one or more in three-functionality-degree, four functionality, five functionality or the six functionality acrylic ester monomers, is selected from Viscoat 295 (TMPTA), pentaerythritol triacrylate (PETA), tetramethylol methane tetraacrylate (PETTA), double pentaerythritol C5 methacrylate (DPEPA), double pentaerythritol methacrylate (DPHA), the third oxidation Viscoat 295 (PO-TMPTA) or oxyethyl group Viscoat 295 (EO-TMPTA); Described difunctionality acrylic ester monomer is selected from 1,6 hexanediol diacrylate (HDDA), two contract propylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), neopentylglycol diacrylate (NPGDA) or the third oxidation neopentylglycol diacrylate (PO-NPGDA).
In order to increase the decorative effect of this coating, used high covering power pigment in the product provided by the invention, simultaneously in order to improve the weathering resistance of paint film, the pigment that the present invention selects for use is that fast light rank is more than or equal to 6, water resistance is more than or equal to 5 pigment, being fit to pigment of the present invention has titanium white (rutile-type), carbon black, pigment yellow 83, pigment yellow 17 4, pigment red 3, Pigment red 5, Pigment red 170, pigment Blue 15, pigment Green 7, and the pigment that the present invention adopts is wherein one or more.(numeral of pigment back is international pigment call number)
The present invention uses by the selection of initiator, has solved the deep layer solidified problem of the band look coating in the presence of high covering power pigment.
Being fit to light trigger of the present invention can be 1-hydroxy-cyclohexyl methyl phenyl ketone (Irgacure184), α, alpha-alpha-dimethyl-Alpha-hydroxy methyl phenyl ketone (Darocur1173), 2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907), 2-phenyl-2-dimethylin-1-(4-morpholinyl phenyl)-butanone-1 (Irgacure369), 2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide (lucirinTPO), two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide ((Irgacure819), two (2,6-dimethoxy benzoyl)-(4 ', 4 '-dimethyl octyl group-2) phosphine oxide one or more combination wherein.
In order further to improve the weathering resistance and the wear resistance of paint film, can add pigment extender in the coating with excellent abrasive resistance.Described pigment extender can be lime carbonate, talcum powder, silicon-dioxide or their combination.For example: Jiangxi one ring mineral products company limited 6000 purpose superfine heavy calcium carbonates, the super ingeniously chemical industry in Shanghai company limited 6000 order superfine heavy calcium carbonates, Shandong Pingdu flying pigeon talcum company talcum powder, German Wa Ke company fumed silica: WACKER
H20, H18, H2000; Degussa (DEGUSSA) aerosil A-200.
In order to improve the wettability of pigment, reduce " reunion " between pigment, increase coating stability and preservation period in use, added dispersion agent in the coating provided by the invention.For purposes of the invention, various pigment wetting agent are many can be as dispersion agent of the present invention, but preferably uses the polymer wetting dispersing agent or contain the dispersion agent of acidic-group.As the wetting dispersing auxiliary Disperbyk170 of BYK company polymer, Disperbyk171, Disperbyk183; Dispersion agent Disperbyk110, the Disperbyk111 of acidic-group, the Dispers685 of TEGO company, Dispers710 are contained in BYK company.
Levelling property and smooth property in order to improve coating have added dispersion agent in the coating provided by the invention.Being fit to dispersion agent agent of the present invention can be modified polyorganosiloxane compound, fluorine-carbon modified acrylate or its mixture, Glide432 as Di Gao company, the BYK333 of Bi Ke chemistry, its main component of BYK307 is polyether-modified polydimethylsiloxane, the EFKA3777 of EFKA company, EFKA3772, its main component is fluorine-carbon modified polyacrylic ester.
Coating of the present invention can prepare by following method:
(1), grinds, disperses with part prepolymer and pigment, dispersant;
(2) prepolymer with remainder mixes stirring and dissolving with acrylic ester monomer, initiator;
(3) material with above-mentioned steps (1) and (2) mixes with auxiliary agent, stirs, and obtains UV curing color decorative coating.
UV curing color decorative coating provided by the invention can be coated with on the base materials such as being contained in plastics, woodenware, metal by known manner such as roller coat, spraying, showerings, forms the polychromy paint film.
Compare with traditional solvent based colored paint, UV curing color decorative coating provided by the invention does not contain volatile solvent, has avoided environmental pollution, and has improved production efficiency; Compare with ultraviolet light polymerization varnish, have better decorative effect and paint film weatherability, improved hardness, wear resistance, scratch resistance, weathering resistance, gloss, the fullness ratio of paint film, solved the deep layer problem of solidification under the high covering power.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1. ultraviolet light polymerization decorative paints-red
Bisphenol A epoxy acrylate (WSR-U125) 6,
Aliphatic polyurethane six acrylate (6145-100) 5,
The aliphatic urethane diacrylate (611B-85) 25 of dilution,
Polyester acrylate performed polymer (CN2203) 10,
Double pentaerythritol methacrylate (DPHA) 5,
Viscoat 295 (TMPTA) 25,
Two propylene glycol diacrylates (DPGDA) 10 that contract,
Two (2,6-dimethoxy benzoyl)-(4 ', 4 '-dimethyl octyl group-2) phosphine oxide 1,
Pigment red 52,
Lime carbonate 4,
Silicon-dioxide (H18) 0.5,
Polymer wetting dispersing agent (Disperbyk183) 0.5,
Polyether-modified polydimethylsiloxane (BYK333) 0.1,
Preparation:
(1) preparation:, require fineness less than 15 μ m with grinding with three-roller or other grinding plant after 2/3 prepolymer and all coloring pigment, extender pigment, the dispersant and disperseing.
(2) will remain 1/3 prepolymer, acrylic ester monomer, solid photoinitiator mixing, and be warming up to 50 ± 5 ℃, and be stirred to dissolving fully, and cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) with the mixing of materials of above-mentioned steps (1) and (2), high-speed stirring obtains UV curing color decorative coating to mixing.
Embodiment 2. ultraviolet light polymerization decorative paint-indigo plants
Bisphenol A epoxy acrylate (WSR-U125) 15,
Modified bisphenol A epoxy acrylate (623-100) 10,
Aliphatic urethane acrylate (CN962) 5,
Polyester acrylate (QA-98) 2,
Pentaerythritol triacrylate (PETA) 7,
Tripropylene glycol diacrylate (TPGDA) 20,
Neopentylglycol diacrylate (NPGDA) 10,
The third oxidation neopentylglycol diacrylate (PO-NPGDA) 10,
1,6 hexanediol diacrylate (HDDA) 16,
2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907) 2,
α, alpha-alpha-dimethyl-Alpha-hydroxy methyl phenyl ketone (Darocur1173) 2,
Pigment Blue 15: 3 15,
Lime carbonate 5,
Silicon-dioxide (H15) 0.5,
Polymer wetting dispersing agent (Disperbyk170) 5,
Polyether-modified polydimethylsiloxane (BYK333) 0.1,
Polyether-modified polydimethylsiloxane (TGO432) 0.5,
Preparation:
(1) with grinding with three-roller or other grinding plant after prepolymer WSRU-125 and tinting pigment, extender pigment, the dispersant and disperseing, require fineness less than 15 μ m.
(2) prepolymer 632-100, CN962 and QA-98, acrylic ester monomer, solid photoinitiator are mixed, be warming up to 50 ± 5 ℃, be stirred to dissolving fully, cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) with the mixing of materials of above-mentioned steps (1) and (2), high-speed stirring obtains UV curing color decorative coating to mixing.
Embodiment 3.Ultraviolet light polymerization decorative paint-Huang
The modified bisphenol A epoxy acrylate (6231A-80) 10 of dilution,
Aliphatic urethane acrylate (CN9013) 5,
Aliphatic urethane acrylate (CN966B85) 10,
Polyester acrylate (CN2203) 6,
Tetramethylol methane tetraacrylate (PETTA) 5,
Double pentaerythritol C5 methacrylate (DPEPA) 5,
Tripropylene glycol diacrylate (TPGDA) 15,
Two propylene glycol diacrylates (DPGDA) 5 that contract,
2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907) 3,
1-hydroxy-cyclohexyl methyl phenyl ketone (Irgacure184) 2,
2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide (LucirinTPO) 3,
Pigment Yellow 73 15:3 13,
Silicon-dioxide (H2000) 0.3,
Polymer wetting dispersing agent (Disperbyk171) 5,
Polyether-modified polydimethylsiloxane (BYK307) 0.5,
Polyether-modified polydimethylsiloxane (TEGO432) 0.5,
Fluorine-carbon modified polyacrylic ester (EFKA3772) 1,
Preparation:
(1) with grinding with three-roller or other grinding plant after prepolymer 6231A-80, CN9013 and tinting pigment, extender pigment, the dispersant and disperseing, require fineness less than 15 μ m.
(2) prepolymer CN966B85 and CN2203, acrylic ester monomer, solid photoinitiator are mixed, heat up 50 ± 5 ℃, be stirred to dissolving fully, cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) above-mentioned steps (1) and (2) component are mixed, high-speed stirring obtains UV curing color decorative coating to mixing.
Embodiment 4. ultraviolet light polymerization decorative paint-Bai
The bisphenol A epoxy acrylate (621A-80) 25 of dilution,
Aliphatic polyurethane six acrylate (6161-100) 5,
Aliphatic urethane acrylate (CN962) 5,
Polyester acrylate (QA-98) 5,
Polyester acrylate oligomer (CN2295) 5,
Double pentaerythritol C5 methacrylate (DPEPA) 5,
Tripropylene glycol diacrylate (TPGDA) 15,
1,6 hexanediol diacrylate (HDDA) 20,
2-phenyl-2-dimethylin-1-(4-morpholinyl phenyl)-butanone-1 (Irgacure369) 5,
Titanium white 25,
Talcum powder 8,
Silicon-dioxide (A-200) 0.5,
The dispersion agent (Disperbyk111) 10 that contains acidic-group,
Fluorine-carbon modified polyacrylic ester (EFKA3772) 1,
Preparation:
(1) with grinding with three-roller or other grinding plant after pre-2/3 prepolymer 621A-80 and tinting pigment, extender pigment, the dispersant and disperseing, require fineness less than 15 μ m.
(2) prepolymer 621A-80, acrylic ester monomer, the solid photoinitiator of prepolymer 6161-100, CN962, QA-98, CN2295 and residue 1/3 are mixed, be warming up to 50 ± 5 ℃, be stirred to dissolving fully, cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) above-mentioned steps (1) and (2) component are mixed, high-speed stirring obtains UV curing color decorative coating to mixing.
Embodiment 5. ultraviolet light polymerization decorative paints-green
Bisphenol A epoxy acrylate (WSR-U125) 10,
Modified bisphenol A epoxy acrylate (623-100) 5,
Aliphatic urethane acrylate (CN9013) 10,
Aliphatic urethane acrylate (CN962) 10,
Polyester acrylate performed polymer (CN2203) 7,
The third oxidation Viscoat 295 (PO-TMPTA) 10,
Double pentaerythritol methacrylate (DPHA) 10,
Tetramethylol methane tetraacrylate (PETTA) 10,
Tripropylene glycol diacrylate (TPGDA) 15,
Two propylene glycol diacrylates (DPGDA) 10 that contract,
1,6 hexanediol diacrylate (HDDA) 15,
2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907) 3,
2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide (LucirinTPO) 3,
Pigment green 15,
Lime carbonate 5,
Talcum powder 5,
The dispersion agent (Dispers685) 8 that contains acidic-group,
Polyether-modified polydimethylsiloxane (BYK307) 0.5,
Fluorine-carbon modified polyacrylic ester (EFKA3772) 1.5,
Preparation:
(1) with grinding with three-roller or other grinding plant after 3/4 prepolymer and tinting pigment, extender pigment, the dispersant and disperseing, require fineness less than 15 μ m.
(2) will remain 1/4 prepolymer, acrylic ester monomer, solid photoinitiator mixing, and be warming up to 50 ± 5 ℃, and be stirred to dissolving fully, and cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) (3) with the mixing of materials of above-mentioned steps (1) and (2), high-speed stirring obtains UV curing color decorative coating to mixing.
Embodiment 6. ultraviolet light polymerization decorative paint-Hei
Bisphenol A epoxy acrylate (WSR-U125) 25,
Aliphatic urethane acrylate (CN9013) 10,
Aliphatic urethane diacrylate (6141H-80) 5,
Polyester acrylate oligomer (CN2295) 8,
Oxyethyl group Viscoat 295 (EO-TMPTA) 5,
Tripropylene glycol diacrylate (TPGDA) 10,
2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1 (Irgacure907) 3,
2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide (LucirinTPO) 3,
Two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide (Irgacure819) 1,
Carbon black 1,
The dispersion agent (Disperbyk110) 0.5 that contains acidic-group,
Polyether-modified polydimethylsiloxane (BYK333) 0.5,
Preparation:
(1) with grinding with three-roller or other grinding plant after 2/3 prepolymer WSRU-125 and tinting pigment, extender pigment, the dispersant and disperseing, require fineness less than 5 μ m.
(2) prepolymer WSRU-125, acrylic ester monomer, the solid photoinitiator of prepolymer CN962, QA-98,6141H-80 and residue 1/3 are mixed, be warming up to 50 ± 5 ℃, be stirred to dissolving fully, cool to then below 40 ℃, adding liquid initiator and auxiliary agent are stirred to and mix and filter.
(3) (3) with the mixing of materials of above-mentioned steps (1) and (2), high-speed stirring obtains UV curing color decorative coating to mixing.
Comparative example
Ultraviolet light polymerization decorative paint-Bai
Bisphenol A epoxy acrylate (WSR-U125) 40,
Tripropylene glycol diacrylate (TPGDA) 25,
Two propylene glycol diacrylates (DPGDA) 25 that contract,
α, alpha-alpha-dimethyl-Alpha-hydroxy methyl phenyl ketone (Darocur1173) 10,
Titanium white 20,
Lime carbonate 10,
Polymer wetting dispersing agent (Disperbyk171) 0.5,
Polyether-modified polydimethylsiloxane (BYK333) 0.5,
Fluorine-carbon modified polyacrylic ester (EFKA3772) 0.5,
Implementation result
With each embodiment gained coating roller coat, showering or be sprayed at the PVC plastic basis material, survey its correlated performance, concrete outcome sees the following form.
Every performance in the table takes following method to measure:
Hardness: measure by GB6739-86 paint film determination of pencil hardness method.
Gloss: by the GB9754-88 paint and varnish not the mensuration of 20 °, 60 °, 85 ° specular glosss of the colored paint paint film of containing metal pigment measure.
Sticking power: draw the lattice experiment by GB9286-88 paint and varnish paint film and measure.
Weathering resistance: expose (filterable xenon arc radiation) by artificial weathering of GB1865-97 paint and varnish and man-made radiation and measure.
Claims (9)
1. a UV curing color decorative coating is characterized in that, the component of described coating and parts by weight thereof are:
Epoxy acrylate class prepolymer 5～25,
Urethane acrylate class prepolymer 5～30,
Polyester acrylate class prepolymer 2～10,
Acrylic ester monomer 15～70,
Light trigger 1～10,
Pigment 1～35,
Dispersion agent 0.5～10,
Auxiliary agent 0.1～2,
Described acrylic ester monomer is difunctionality monomer and the monomeric mixture of high functionality, and wherein the monomeric proportioning of high functionality monomer and difunctionality is 1: 0.3～8.
2. according to the described UV curing color decorative coating of claim 1, it is characterized in that described epoxy acrylate class prepolymer is selected from a kind of of bisphenol A epoxy acrylate and modified bisphenol A epoxy acrylate or its mixture.
3. according to the described UV curing color decorative coating of claim 2, it is characterized in that described urethane acrylate class prepolymer is selected from a kind of or its mixture of high functionality aliphatic urethane acrylate class prepolymer and difunctionality aliphatic urethane acrylate class prepolymer.
4. according to the described UV curing color decorative coating of claim 3, it is characterized in that described high functionality acrylic ester monomer is one or more in three-functionality-degree, four functionality, five functionality or the six functionality acrylic ester monomers.
5. according to the described UV curing color decorative coating of claim 4, it is characterized in that described high functionality acrylic monomer is selected from Viscoat 295, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, double pentaerythritol C5 methacrylate, double pentaerythritol methacrylate, the third oxidation Viscoat 295 or oxyethyl group Viscoat 295.
6. according to the described UV curing color decorative coating of claim 5, it is characterized in that, described difunctionality acrylic ester monomer is selected from 1,6 hexanediol diacrylate, two contract propylene glycol diacrylate, tripropylene glycol diacrylate, neopentylglycol diacrylate or the third oxidation neopentylglycol diacrylate.
7. according to the described UV curing color decorative coating of claim 6, it is characterized in that, described light trigger is selected from 1-hydroxy-cyclohexyl methyl phenyl ketone, α, alpha-alpha-dimethyl-Alpha-hydroxy methyl phenyl ketone, 2-methyl isophthalic acid-(4-first sulfydryl)-2-morpholine acetone-1,2-phenyl-2-dimethylin-1-(4-morpholinyl phenyl)-butanone-1,2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide, two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide or two (2,6-dimethoxy benzoyl)-(4
/, 4
/-dimethyl octyl group-2) phosphine oxide.
8. according to the described UV curing color decorative coating of claim 7, it is characterized in that described dispersion agent is selected from the polymer wetting dispersing agent or contains the dispersion agent of acidic-group.
9. described according to Claim 8 UV curing color decorative coating is characterized in that described auxiliary agent is selected from modified polyorganosiloxane compound or fluorine-carbon modified acrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100798321A CN101407651B (en) | 2008-11-27 | 2008-11-27 | UV curing color decorative coating |
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| CN101845263A (en) * | 2010-05-14 | 2010-09-29 | 上海长悦涂料有限公司 | UV (Ultraviolet) curing coatings with high weatherability |
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| CN103554540B (en) * | 2013-10-27 | 2015-11-18 | 合肥乐凯科技产业有限公司 | A kind of hardening film for in-mold decorating |
| CN104629612A (en) * | 2013-11-14 | 2015-05-20 | 江南大学 | Preparation method of high-refractive anti-fog film coating |
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