CN103865376A - UV spraying frosted paint - Google Patents
UV spraying frosted paint Download PDFInfo
- Publication number
- CN103865376A CN103865376A CN201410088943.4A CN201410088943A CN103865376A CN 103865376 A CN103865376 A CN 103865376A CN 201410088943 A CN201410088943 A CN 201410088943A CN 103865376 A CN103865376 A CN 103865376A
- Authority
- CN
- China
- Prior art keywords
- paint
- spraying
- frosted paint
- frosted
- spraying frosted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a UV spraying frosted paint, comprising the following components in parts by weight: 5-20 parts of polyurethane acrylic resin, 40-60 parts of reactive diluents, 1-7 parts of frosted powder, 1-5 parts of anti-settling thickener, 1-5 parts of photoinitiator, 5-20 parts of solvent and the like. The UV spraying frosted paint disclosed by the invention is the UV frosted paint which is quick to dry, high in hardness and high in solid content. The UV spraying frosted paint disclosed by the invention is baked at 60 DEG C for 3-5 minutes and then light-cured after being constructed, and the UV frosted paint is high in drying speed. Thus, the problems that the traditional coating is long in construction time, poor in hardness, not ideal in frosted effect and the like are solved.
Description
Technical field
The present invention relates to a kind of paint, relate in particular to a kind of UV frosted paint.
Background technology
Frosted paint is exactly the gloss that there is no common paint after spraying, touch up and there is frosted texture, for furniture provides diversified painting effect, but while using frosted paint, for paint filler can be dispersed in paint, often need to use a large amount of solvents, auxiliary agent.Preparation and use to frosted paint have brought great inconvenience and potential harm.Due to the special composition of frosted paint, frosted paint also needs the film formation time of growing, and has extended the required duration.
The feature of emerging photocuring technology is mainly environmental protection and quick; photocuring refers to monomer, oligomer or the polymer matrix planning process under photoinduction; specifically photocuring technology is-an energy-conservation and clean and environment-friendly technology; its save energy---energy consumption is only 1/10th of traditional mercury lamp; and do not contain solvent, ecotope is had to provide protection; can be to airborne release poison gas and carbonic acid gas, therefore be described as " green technology ".Photocuring technology (UV) is the UV-irradiation by certain wavelength, makes liquid epoxy acrylic resin high speed of polymerization form solid-state a kind of light complete processing, and photocuring reaction is light-initiated polymerization, crosslinking reaction in essence.Photo-cured coating is the earliest example of photocuring technology in industrial extensive successful Application, also be the product of current photocuring industrial field volume of production and marketing maximum, scale is much larger than light-curable ink and curable adhesive, and epoxy acrylic is main photo-cured coating.
Existing photo-cured coating, refers to that coating products is under the irradiation of UV-light (wavelength is 320-390nm), makes to activate after light trigger absorption UV energy, cause molecular breakdown to form free radical or positively charged ion, thereby the chemical reaction of unsaturated double-bond material in initiation coating, film-forming, its advantage comprises: environmental protection, height contains admittedly, hardness is good, and efficiency is high, and painting cost is low, color and luster is stable, and paint film is full; The curing speed of UV paint is fast, by uviolizing, within the extremely short time, reaches surface drying.When film is during by wet film exsiccation film, its shrinking percentage is larger, and internal stress is relatively also large, makes to be coated with interlayer adherence poor.The hardness of UV paint is generally better than the paint of other kinds, and film is harder, more crisp, more not wear-resisting conventionally, and film also easily ftractures.In the time that the hardness of film exceedes requirement, expand with heat and contract with cold or the variation of bulking universe contracting with work coated article surface, for want of elasticity and can not being out of shape with the micro-deformation on floor of the variation of surperficial paint film, thus there is crackle.Therefore, in the time covering with paint, lacquer, colour wash, etc., to strictly control the quality of coating, could ensure like this total quality of timber.
In prior art, patent CN102501421A discloses a kind of frosted hardened film for in-mold decoration, it contains support and transparent hard layer, wherein said transparent hard layer comprises: the components such as the polyurethane acroleic acid prepolymer of 35～50 parts, produced the effect of frosted, but and unexposed can be used in UV paint; But CN103342952A discloses a kind of urethane resin frosted coating, it contains the components such as urethane resin 50-65, the painting of gained is sprayed on glass, obtains having the glass of better frosted finish effect, this coating is mainly used in the spraying of glass, and range of application is less.
Summary of the invention
The length consuming time that the object of the invention is to solve traditional frosted finish effect, frosted finish effect is undesirable, and the problem such as wear no resistance.
The present invention specifically provides a kind of UV spraying frosted paint, according to parts by weight, comprising:
Described UV spraying frosted paint can also comprise:
Solvent 5-20 part; And/or
Auxiliary agent 0.2-1.5 part.
In the preferred embodiment of above-mentioned a kind of UV spraying frosted paint, according to parts by weight, more preferably comprise:
Wherein, in described preferred embodiment, described UV spraying frosted paint can also comprise:
Solvent 8-18 part; And/or
Auxiliary agent 0.5-1.5 part.
In the preferred embodiment of above-mentioned a kind of UV spraying frosted paint,, according to parts by weight, can also comprise::
Wherein, in described preferred embodiment, described UV spraying frosted paint can also comprise:
Solvent 5-20 part; And/or
Auxiliary agent 0.5-1 part.
One of content of the present invention comparatively in preferred embodiment, the molecular weight of described polyurethane acrylic resin is preferably 50-5000, more preferably 80-3000, more preferably 100-1500.
Reactive thinner of the present invention can be to be selected from TPGDA(tri (propylene glycol) diacrylate), HEMA(hydroxyethyl methylacrylate), HDDA(hexanediyl ester), E03-TMPTA(ethoxylated trimethylolpropane triacrylate), TMPTA(trimethylolpropene acid esters), LA(lauryl acrylate) etc., wherein TPGDA(tri (propylene glycol) diacrylate more preferably), HEMA(hydroxyethyl methylacrylate), HDDA(hexanediyl ester), E03-TMPTA(ethoxylated trimethylolpropane triacrylate), TMPTA(trimethylolpropene acid esters) in one or more mixture, most preferably be E03-TMPTA(ethoxylated trimethylolpropane triacrylate).
Anti-settling thickening material of the present invention can be the mixture that is selected from one or more in cured etc. of organobentonite, aerosil, modified hydrogenated Viscotrol C, polymeric amide.Wherein, described more preferably aerosil of anti-settling thickening material.
Frosting powder of the present invention is selected from one or more in the particle powder that size is 5-300 μ m.Wherein, described particle powder most preferably is silicon-dioxide, and the size of frosting powder is 5-200 μ m more preferably.
Described light trigger, according to above-mentioned part by weight, is 1-5 part, and more preferably 2-5 part, is further preferably 3-5 part.
Solvent of the present invention can be one or more the mixture being selected from dibasic alcohol ethers, ethyl acetate, butylacetate, dialkyl capped polyether, man-made fiber finish or propylene glycol ether-ether, more preferably esters solvent, as ethyl acetate, the mixture of one or both in butylacetate etc.
Other auxiliary agent of the present invention comprises light trigger, wherein light trigger is selected from 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, light trigger-1105, phenyl two-2, the mixture of one or more in 4,6-Three methyl Benzene methyl acyl-phosphorus oxide, benzophenone (BP).
Auxiliary agent of the present invention can be selected from one or more in dispersion agent, flow agent, matting agent or defoamer.
Above-mentioned dispersion agent can be one or more the mixture in carboxylate salt, polymeric carboxylic salt, polymer salt unsaturated carboxylic acid, the poly-polyphosphazene polymer amide salt containing hydroxyl unsaturated carboxylic acid etc. of modified polyurethane, modification acrylate, unsaturated polyester acid amides.
Above-mentioned flow agent can be one or more the mixture in silicone oil, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane etc.
Above-mentioned matting agent can be one or more the mixture in polyester matting resin RB608, polyester matting resin RB3329, white carbon black etc., wherein, most preferably is white carbon black.
Above-mentioned defoamer can be one or more the mixture in natural fats and oils (as soya-bean oil, Semen Maydis oil), polyethers defoamer, higher alcohols, polydimethylsiloxane, polyether-modified silicon etc.
A kind of UV spraying frosted paint of the present invention, is that a kind of rate of drying is fast, and hardness is high, the UV frosted finish effect paint that solid content is high.
UV provided by the invention spraying frosted paint, can carry out photocuring after toasting 3-5min after construction at 60 DEG C, and rate of drying is fast, and the solution traditional coating engineering time is long, difference of hardness, the shortcoming such as frosted finish effect is undesirable.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but not as limiting to the invention.
embodiment 1
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises dispersion agent, flow agent, and it is respectively modified polyurethane and silicone oil.
Make required UV spraying frosted paint.
embodiment 2
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises flow agent, matting agent, and it is respectively silicone oil and white carbon black.
Make required UV spraying frosted paint.
embodiment 3
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises dispersion agent, matting agent, and it is respectively carboxylate salt and the white carbon black of unsaturated polyester acid amides.
Make required UV spraying frosted paint.
embodiment 4
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent also comprises flow agent, matting agent, and it is respectively silicone oil and white carbon black.
Make required UV spraying frosted paint.
embodiment 5
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises flow agent, defoamer, and it is respectively silicone oil and polydimethylsiloxane.
Make required UV spraying frosted paint.
embodiment 6
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises dispersion agent, flow agent, matting agent, and it is respectively modified polyurethane, silicone oil, white carbon black.
Make required UV spraying frosted paint.
embodiment 7
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises flow agent, matting agent, and it is respectively silicone oil and white carbon black.
Make required UV spraying frosted paint.
embodiment 8
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises dispersion agent, flow agent, matting agent, defoamer, and it is respectively modification acrylate, silicone oil, white carbon black and polydimethylsiloxane.
Make required UV spraying frosted paint.
embodiment 9
Prepare a kind of UV spraying frosted paint, wherein, its component comprises:
Above-mentioned auxiliary agent comprises dispersion agent, flow agent, matting agent, defoamer, and it is respectively modification acrylate, silicone oil, white carbon black and polydimethylsiloxane.
Make required UV spraying frosted paint.
embodiment 10
Experimental technique: " carry out by the associated viscera in UV-light (UV) cured woodware paint with reference to HG-T3655-1999 for the mensuration of dry solidification speed.
Hardness is carried out with reference to the associated viscera in GB/T6739-1996 " hardness of film pencil assay method ".
Experimental result: as shown in table 1.
Table 1 is the UV spraying frosted paint of embodiment of the present invention gained and the performance synopsis of PU, NC paint
| Project | Dry solidification speed | Hardness |
| PU | >24h | HB-H |
| NC | >12h | B |
| Embodiment 1 | 3-5s | 2H |
| Embodiment 2 | 3-5s | 2H |
| Embodiment 3 | 3-5s | 2H |
| Embodiment 4 | 3-4s | 2H |
| Embodiment 5 | 3-5s | 2H |
| Embodiment 6 | 3-6s | 2H-H |
| Embodiment 7 | 6-8s | H |
| Embodiment 8 | 7-8s | H |
| Embodiment 9 | 7-8s | H |
Interpretation:
As can be seen from Table 1, in embodiment of the present invention 1-9, the UV of gained spraying frosted paint dry solidification speed and hardness are all better than PU paint and NC paint.Especially with regard to dry solidification speed, in the embodiment of the present invention, be 3-5s.The dry solidification time of PU paint and NC paint exceedes respectively 24h, 12h.Therefore,, for PU paint and NC paint, the frosted paint described in the embodiment of the present invention has shorter dry solidification time and hardness.
Between embodiment 1-6, the dry solidification speed of paint film and hardness all change not quite, embodiment 7-9, and dry solidification speed and hardness are slightly smaller than dry solidification speed and the hardness of embodiment 1-6.
To sum up, a kind of UV spraying frosted paint of the present invention, is that a kind of rate of drying is fast, and hardness is high, the UV frosted finish effect paint that solid content is high.
Above specific embodiments of the invention be have been described in detail, but it is as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that this practicality is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the amendment done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.
Claims (10)
1. a UV spraying frosted paint, is characterized in that, according to parts by weight, comprising:
2. UV spraying frosted paint according to claim 1, is characterized in that, described polyurethane acrylic resin molecular weight is 100-2000.
3. UV spraying frosted paint according to claim 1, is characterized in that, described reactive thinner is one or more mixtures in TPGDA, HEMA, HDDA, E03-TMPTA and TMPTA.
4. UV spraying frosted paint according to claim 1, is characterized in that, the size of described frosting powder is 5-300 μ m.
5. UV according to claim 1 spraying frosted paint, is characterized in that, described anti-settling thickening material is selected from the mixture of one or more in cured etc. of organobentonite, aerosil, modified hydrogenated Viscotrol C, polymeric amide.
6. UV spraying frosted paint according to claim 1, is characterized in that, according to above-mentioned parts by weight, also comprises:
Light trigger 1-5 part.
7. UV spraying frosted paint according to claim 6, it is characterized in that, described light trigger is selected from 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, light trigger-1105, phenyl two-2, the mixture of one or more in 4,6-Three methyl Benzene methyl acyl-phosphorus oxide, benzophenone.
8. according to the UV spraying frosted paint described in any one in claim 1-7, it is characterized in that, according to parts by weight, also comprise:
Solvent 5-20 part; And/or
Auxiliary agent 0.2-1.5 part.
9. UV according to claim 8 spraying frosted paint, is characterized in that, described solvent is one or more the mixture in dibasic alcohol ethers, ethyl acetate, butylacetate, dialkyl capped polyether, man-made fiber finish or propylene glycol ether-ether.
10. UV spraying frosted paint according to claim 8, is characterized in that, described auxiliary agent is also selected from one or more in dispersion agent, flow agent, matting agent or defoamer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410088943.4A CN103865376A (en) | 2014-03-11 | 2014-03-11 | UV spraying frosted paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410088943.4A CN103865376A (en) | 2014-03-11 | 2014-03-11 | UV spraying frosted paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103865376A true CN103865376A (en) | 2014-06-18 |
Family
ID=50904414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410088943.4A Pending CN103865376A (en) | 2014-03-11 | 2014-03-11 | UV spraying frosted paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103865376A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176351A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based frosted new material and preparing method thereof |
| CN105949982A (en) * | 2016-06-30 | 2016-09-21 | 成都华聚杨武家具有限公司 | Antibacterial insect-expelling furniture coating |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN109021795A (en) * | 2018-08-20 | 2018-12-18 | 深圳市漆友实业有限公司 | Kirsite automobile toy water high light high temperature baking vanish |
| CN109181447A (en) * | 2018-08-15 | 2019-01-11 | 东莞市佩琦涂料有限公司 | A kind of optical curing of UV coating and preparation method thereof |
| CN110358424A (en) * | 2019-06-11 | 2019-10-22 | 浙江伟星实业发展股份有限公司 | A kind of spray painting major ingredient and sand glaze paint for button |
| CN112059931A (en) * | 2020-09-02 | 2020-12-11 | 东莞金太阳研磨股份有限公司 | Polishing grinding tool and preparation method thereof |
| CN114875710A (en) * | 2022-03-24 | 2022-08-09 | 上海睿途新材料科技有限公司 | Frosted coating and preparation method and application thereof |
| CN115073791A (en) * | 2022-06-24 | 2022-09-20 | 金石包装（嘉兴）有限公司 | Gravure printing coating film based on frosted gloss oil and preparation method thereof |
| CN115173662A (en) * | 2022-07-19 | 2022-10-11 | 东莞市吉铼升电机股份有限公司 | Vibration horn motor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701129A (en) * | 2009-11-24 | 2010-05-05 | 武汉嘉特利佰联创科技有限公司 | High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating |
| CN103131318A (en) * | 2011-11-21 | 2013-06-05 | 孙月静 | UV paint for building sheet material |
| CN103305097A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | UV (Ultra Violet)-flexible sanding primer on laminate flooring |
| CN103409058A (en) * | 2013-08-07 | 2013-11-27 | 长春市三化实业有限责任公司 | Non-yellowing ultraviolet light curing abrasion resistant paint and preparation method thereof |
-
2014
- 2014-03-11 CN CN201410088943.4A patent/CN103865376A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701129A (en) * | 2009-11-24 | 2010-05-05 | 武汉嘉特利佰联创科技有限公司 | High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating |
| CN103131318A (en) * | 2011-11-21 | 2013-06-05 | 孙月静 | UV paint for building sheet material |
| CN103305097A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | UV (Ultra Violet)-flexible sanding primer on laminate flooring |
| CN103409058A (en) * | 2013-08-07 | 2013-11-27 | 长春市三化实业有限责任公司 | Non-yellowing ultraviolet light curing abrasion resistant paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 沈浩: "《涂料行业职业技能鉴定培训教材-制漆配色调制工》", 31 July 2006 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176351A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based frosted new material and preparing method thereof |
| CN105949982A (en) * | 2016-06-30 | 2016-09-21 | 成都华聚杨武家具有限公司 | Antibacterial insect-expelling furniture coating |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN109181447A (en) * | 2018-08-15 | 2019-01-11 | 东莞市佩琦涂料有限公司 | A kind of optical curing of UV coating and preparation method thereof |
| CN109021795A (en) * | 2018-08-20 | 2018-12-18 | 深圳市漆友实业有限公司 | Kirsite automobile toy water high light high temperature baking vanish |
| CN110358424A (en) * | 2019-06-11 | 2019-10-22 | 浙江伟星实业发展股份有限公司 | A kind of spray painting major ingredient and sand glaze paint for button |
| CN112059931A (en) * | 2020-09-02 | 2020-12-11 | 东莞金太阳研磨股份有限公司 | Polishing grinding tool and preparation method thereof |
| CN114875710A (en) * | 2022-03-24 | 2022-08-09 | 上海睿途新材料科技有限公司 | Frosted coating and preparation method and application thereof |
| CN115073791A (en) * | 2022-06-24 | 2022-09-20 | 金石包装（嘉兴）有限公司 | Gravure printing coating film based on frosted gloss oil and preparation method thereof |
| CN115073791B (en) * | 2022-06-24 | 2024-03-05 | 金石包装（嘉兴）有限公司 | Gravure printing coating film based on sanding oil and preparation method thereof |
| CN115173662A (en) * | 2022-07-19 | 2022-10-11 | 东莞市吉铼升电机股份有限公司 | Vibration horn motor |
| CN115173662B (en) * | 2022-07-19 | 2023-08-11 | 东莞市吉铼升电机股份有限公司 | Vibrating horn motor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103865376A (en) | UV spraying frosted paint | |
| CN101407651B (en) | UV curing color decorative coating | |
| CN103540240B (en) | UV-composite laser coating composition | |
| CN104387945A (en) | Odorless staining-resistant anti-yellowing UV coated matt finish paint coating, and preparation method and construction technology thereof | |
| CN100588691C (en) | Coating for UV cured plastic and use | |
| CN101423675A (en) | Ultraviolet curing coating for preventing static on plastic surface and method for preparing the same | |
| CN106497391A (en) | Ultraviolet light polymerization Weather-proof self-cleaning coating composition | |
| CN104987828B (en) | Coloured UV coating with curing plastic and preparation method thereof | |
| CN104559698B (en) | A kind of color inhibition UV transparent primings for electrostatic spraying | |
| CN103589324B (en) | The anti-scratch matte varnish of a kind of UV | |
| CN104830209A (en) | Organic volatile solvent-free environmentally friendly anti-cracking transparent UV spray priming paint | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN101283062A (en) | High-solid UV-curable coating composition | |
| CN104263208A (en) | UV (Ultraviolet) laminated topcoat gloss coating with performances of smell removal, stain resistance and yellowing resistance as well as preparation method and construction process thereof | |
| CN102220084A (en) | Photocureable coating and curing method thereof | |
| CN109486318A (en) | Solvent-free UV resin and its application | |
| CN102977748A (en) | UV furniture spray-coating gloss topcoat without volatile organic solvent | |
| CN104152007A (en) | Solvent-free UV vacuum spraying priming paint and preparation method thereof | |
| CN106675275A (en) | Waterborne UV-curable matt paint | |
| CN103059717A (en) | High-leveling-property ultraviolet curable coating composition for shower coating | |
| CN103396732B (en) | A kind of PVC elasticity minute surface scratch resistance agent and apply its technique preparing the anti-scratch PVC film of elasticity minute surface | |
| CN101748657A (en) | Ultraviolet cured gloss oil for paper | |
| CN104371536B (en) | Hardened coating composite and preparation method thereof, and PETG (polyethylene terephthalate glycol) composite membrane and preparation method thereof | |
| CN105440894B (en) | For Metal surface anti-corrosion light solidifying paint composition | |
| CN101629030B (en) | Coating with high weatherability and self repairability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140618 |
|
| RJ01 | Rejection of invention patent application after publication |