CN101298644A - High-performance electrophoresis aluminum alloy construction section bar and method for making same - Google Patents

High-performance electrophoresis aluminum alloy construction section bar and method for making same Download PDF

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CN101298644A
CN101298644A CNA200810044740XA CN200810044740A CN101298644A CN 101298644 A CN101298644 A CN 101298644A CN A200810044740X A CNA200810044740X A CN A200810044740XA CN 200810044740 A CN200810044740 A CN 200810044740A CN 101298644 A CN101298644 A CN 101298644A
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aluminum alloy
aluminium
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section bar
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CN101298644B (en
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廖健
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Chengdu Sunshine Aluminium Co.,Ltd.
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廖健
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Abstract

The invention discloses an electrophoretic aluminum alloy building proximate matter with high performance and a preparation method thereof, and belongs to the technical field of aluminum alloy application. The electrophoretic aluminum alloy building proximate matter consists of following ingredients by mass: 0.5 to 0.54 percent of Mg, 0.4 to 0.44 percent of Si, 0.04 to 0.08 percent of RE, 0.01 to 0.02 percent of Ti, 0.002 to 0.004 percent of B, 0 to 0.2 percent of Fe and remaining aluminum. The preparation method of the electrophoretic aluminum alloy building proximate matter consists of following steps: a misch metal ingot, an alloy of Al, Ti and B, and a pure aluminum ingot are smelted into a refining and modifying agent of RE, Al, Ti and B; the refining and modifying agent is added during an alloy smelting process and cast into an aluminum rod; the electrophoretic proximate matter with high performance is prepared by techniques of squeeze aging and oxidizing electrophoresis, etc. By utilizing rare earth to subdivide second-phase particles, electrophoretic paint films of the proximate matter that are obtained by improving surface processing performance have higher uniformity, adhesive attraction, wear resistance, corrosion resistance and large film thickness than common proximate matters, and can be widely used for aluminum alloy doors and windows of buildings and curtain walls.

Description

A kind of high-performance electrophoresis aluminum alloy construction section bar and preparation method thereof
Technical field:
The present invention relates to a kind of aluminum alloy building section and preparation method, a kind of specifically high-performance electrophoresis aluminum alloy section bar and preparation method thereof.
Background technology:
The application of rare earth in aluminium alloy extrusions is very extensive, and research is a lot.Patent publication No. is that CN1332259A discloses a kind of rare earth-aluminium alloy rod for producing extrusion shapes, is to make aluminium alloy 670~800 ℃ of meltings, adds mixed rare earth alloy content 0.05~0.35%.This rare earth aluminium alloy rod through extruding, can be made into the various section bars that are used for decoration and structural part, this section bar corrosion resistance and good, and welding property is better than common aluminum alloy section bar, and has further improved the physical strength of section bar, can be widely used in various structural parts.Patent publication No. is that CN1171453A has announced that a kind of rare earth replaces the homogenising treatment method of deformable Al-Si-Mg alloy, this invention adds Rare-Earth Ce in aluminium alloy, production technique is simplified, saved and carried out the production link that homogenizing is handled under the high temperature, thereby not only save energy, equipment and occupation of land, and the performance index of product have been improved.Patent publication No. is that CN1456697A discloses a kind of modified version 6063 aluminum alloy materials, and this material is mishmetal La and the Ce that adds 0.11~0.2% (weight) in former 6063 aluminium alloys.This application result shows, adds an amount of rare earth and can improve machinery, physics and processing performance in aluminium alloy, and the scatterer in that semi-conductor and air conditioning machinery and condenser/evaporator device use this material to make has good extrudability and electrical and thermal conductivity performance.At present the applied research in aluminium section bar mainly concentrates on aspect aluminium section mechanical performance, processing characteristics, electrical and thermal conductivity performance and the corrosion resistance nature to rare earth, to rare earth in the also not research of application aspect the building aluminium alloy extrusions electrophoretic painting.And in recent years, along with the fast development of Chinese national economy, construction market further keeps good growth momentum.The electrophoretic painting aluminum alloy building section possesses advantages such as high anti-corrosion, anti-marquis, decorate properties because of it, obtained sufficient development in the aluminium section bar industry.But electrophoretic aluminium section is with high content of technology, tight to the alloy matrix aluminum material requirements, in process of production usually because defective such as the thick second phase impurity that contains causes that electrodeposited paint film is inhomogeneous, thickness is not enough, sticking power is little in the aluminum matrix alloy, hardness, wear resistance and solidity to corrosion are not enough.The present invention's research is intended to improve the aluminium alloy extrusions matrix by adding trace rare-earth, prepares high performance building electrophoresis aluminum alloy section bar.
Summary of the invention:
For often solving in process of production because of problems such as the thick second phase impurity that contains in the aluminum matrix alloy cause that electrodeposited paint film is inhomogeneous, thickness is not enough, sticking power is little, hardness, wear resistance and solidity to corrosion are not enough, the invention provides a kind of high performance electrophoresis aluminum alloy construction section bar and preparation method thereof, this section bar electrodeposited paint film has higher homogeneity, sticking power, hardness, wear resistance, solidity to corrosion and thickness than common section bar.
The present invention is achieved in that
A kind of high-performance electrophoresis building aluminium alloy extrusions, its mass percent composition is 0.5~0.54%Mg, 0.4~0.44%Si, 0.04~0.08%RE, 0.01~0.02%Ti, 0.002~0.004%B, 0~0.2%Fe, surplus is an aluminium.Its middle-weight rare earths RE and Ti, B make block rare earth aluminium titanium boron refining deterioration agent by mishmetal ingot, AlTiB alloy, the melting of fine aluminium ingot and add in the aluminium alloy smelting casting cycle.The concrete mass percent composition of this refining deterioration agent is that 14~17%La, 2~5%Pr, 1~3%Ce, 1~3%Ti, 0.2~0.6%B surplus are aluminium, 900~1000 ℃ of smelting temperatures.
A kind of preparation method of high-performance electrophoresis building aluminium alloy extrusions is characterized in that comprising following steps:
A, mishmetal ingot, AlTiB alloy and fine aluminium ingot are carried out melting in the resistance-type crucible furnace, refining, the degasification slagging-off, stirring is cast into block refining deterioration agent, and its concrete mass percent composition is that 14~17%La, 2~5%Pr, 1~3%Ce, 1~3%Ti, 0.2~0.6%B surplus are aluminium.
B, make melting section bar aluminium alloy in the energy-conservation stove in the flat-top hot-cast, add alloying elements such as Mg, Si, add block refining deterioration agent before the casting, guarantee that alloy mass per-cent composition is 0.5~0.54%Mg, 0.4~0.44%Si, 0.04~0.08%RE, 0.01~0.02%Ti, 0.002~0.004%B, 0~0.2%Fe, surplus is an aluminium, 900~1000 ℃ of smelting temperatures.
C, liquation continuous casting become bar-shaped cast ingot, are hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃.
D, by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes high-performance electrophoresis aluminum alloy construction section bar.
Wherein the every quality of block refining deterioration agent among the step a is 0.2~0.3kg.
In common aluminium alloy extrusions, exist a large amount of lath-shaped β-AlFeSi compounds, as shown in Figure 1.These compounds do not wait from several microns to tens of microns, and its electropotential is different with aluminium, has a strong impact on the homogeneity and the continuity of oxidation and electrophoretic painting, reduce sticking power, wear resistance and the solidity to corrosion of rete.Rare-earth elements La, Pr, elements such as Ce, in its atom electronic shell, there is one deck not have the 4f internal layer of the full electronics of row,, makes the RE element have unique characteristic just because of the existence of this unsaturated electronic shell, in chemical reaction, show typical metalline, its attribute is only second to basic metal and alkaline-earth metal, has very high chemically reactive, very easily loses 2~3 electronics in the reaction.After alloy adds rare earth element, element reactions such as the Si in rare earth and the alloy, Fe generate tiny compound, and as shown in Figure 2, analyzing these compounds through EDS energy praseodymium is the AlFeSiRE compound, see accompanying drawing 3, eliminated the thick β-AlFeSi compound of lath-shaped simultaneously.These tiny rare earth compounds are enriched in the crystal boundary surface and form net distribution, hinder grain growth on the crystal boundary, the alloy structure refinement.Eliminated the thick compound of alloy surface enrichment simultaneously, the alloy surface luminance brightness improves, and material is smooth smooth, accepts polarizability and improves, and helps the generation of oxide film and paint film.
Description of drawings
Thick β-AlFeSi compound in the common section bar of Fig. 1,
Fig. 2 adds the tiny rare earth compound that forms behind the rare earth,
The tiny rare earth compound EDS of Fig. 3 energy spectrum analysis figure.
Embodiment
The present invention is described further below in conjunction with accompanying drawing.
At first mishmetal ingot, AlTiB alloy and fine aluminium ingot are carried out melting in the resistance-type crucible furnace, refining then, the degasification slagging-off, stir and be cast into the block refining deterioration agent of 0.25kg, its concrete mass percent composition is 14~17%La, 2~5%Pr, 1~3%Ce, 1~3%Ti, 0.2~0.6%B, and surplus is an aluminium.Make melting section bar aluminium alloy in the energy-conservation stove in the flat-top hot-cast then, add alloying elements such as Mg, Si, add block refining deterioration agent before the casting, guarantee that alloy mass per-cent composition is that 0.5~0.54%Mg, 0.4~0.44%Si, 0.04~0.08%RE, 0.01~0.02%Ti, 0.002~0.004%B, Fe≤0.2% surplus are aluminium, 900~1000 ℃ of smelting temperatures.The liquation continuous casting becomes bar-shaped cast ingot, is hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃, behind the air 200 ℃ of timeliness 2 hours.Then by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes high-performance electrophoresis aluminum alloy construction section bar.Thickness adopts the ED3000 eddy current to survey the film instrument and measures, sticking power adopts the automatic scratching instrument of WS-2000 coating adhesion to measure, wear resistance adopts the micromicrofarad experiment measuring, hardness adopts the pencil experiment measuring, solidity to corrosion adopts the hydrochloric acid mist method to measure, microscopic appearance adopts Olympus metallography microscope sem observation, and the EDS energy spectrum analysis is adopted in the second phase composition analysis.
By accompanying drawing 1 as seen, in common aluminium alloy extrusions, exist a large amount of lath-shaped β-AlFeSi compounds.These compounds do not wait from several microns to tens of microns, and its electropotential is different with aluminium, has a strong impact on the homogeneity and the continuity of oxidation and electrophoretic painting, reduce sticking power, wear resistance and the solidity to corrosion of rete.Rare-earth elements La, Pr, elements such as Ce, in its atom electronic shell, there is one deck not have the 4f internal layer of the full electronics of row,, makes the RE element have unique characteristic just because of the existence of this unsaturated electronic shell, in chemical reaction, show typical metalline, its attribute is only second to basic metal and alkaline-earth metal, has very high chemically reactive, very easily loses 2~3 electronics in the reaction.After alloy adds rare earth element, shown in accompanying drawing 2,3, element reactions such as the Si in rare earth and the alloy, Fe generate tiny compound, and analyzing these compounds through EDS energy praseodymium is the AlFeSiRE compound, has eliminated the thick β-AlFeSi compound of lath-shaped simultaneously.These tiny rare earth compounds are enriched in the crystal boundary surface and form net distribution, hinder grain growth on the crystal boundary, the alloy structure refinement.Eliminated the thick compound of alloy surface enrichment simultaneously, the alloy surface luminance brightness improves, and material is smooth smooth, accepts polarizability and improves, and helps the generation of oxide film and paint film.
Specific embodiment is described as follows:
Embodiment 1: add rare earth element 0.04% by adding block rare earth aluminium titanium boron refining deterioration agent in the alloy melting process, continuous casting becomes bar-shaped cast ingot, is hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃.Then by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes electrophoresis aluminum alloy construction section bar.The component of alloy and mass percent are: 0.50%Mg-0.43%Si-0.04%RE-0.016%Ti-0.0029%B-0.20%Fe.
Embodiment 2: add rare earth element 0.06% by adding block rare earth aluminium titanium boron refining deterioration agent in the alloy melting process, continuous casting becomes bar-shaped cast ingot, is hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃.Then by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes electrophoresis aluminum alloy construction section bar.The component of alloy and mass percent are: 0.53%Mg-0.41%Si-0.06%RE-0.012%Ti-0.0027%B-0.17%Fe.
Embodiment 3: add rare earth element 0.08% by adding block rare earth aluminium titanium boron refining deterioration agent in the alloy melting process, continuous casting becomes bar-shaped cast ingot, be hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃, behind the air 200 ℃ of timeliness 2 hours.Then by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes electrophoresis aluminum alloy construction section bar.The component of alloy and mass percent are: 0.51%Mg-0.43%Si-0.08%RE-0.019%Ti-0.0035%B-0.13%Fe.
Comparative Examples: alloy becomes bar-shaped cast ingot by the melting continuous casting, is hot extruded into aluminium alloy extrusions through 560 ℃ of homogenizing 6 hours at 430~450 ℃, behind the air 200 ℃ of timeliness 2 hours.Then by anodic oxidation (H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min), electrophoretic painting operations such as (time 1~3min toast 180 ± 5 ℃, constant temperature 30min for voltage 100~180V, electric current 200~800A) makes electrophoresis aluminum alloy construction section bar.The component of alloy and mass percent are: 0.54%Mg-0.40%Si-0.014%Ti-0.0031%B-0.15%Fe.
The electrophoresis aluminum alloy section bar performance of adding rare earth aluminium titanium boron refining deterioration agent is apparently higher than Comparative Examples, and is as shown in table 1.
Table 1 embodiment and Comparative Examples section bar electrodeposited paint film performance comparison table
Section bar Maximum film thickness (μ m) Minimum thickness (μ m) Average film thickness (μ m) Solidity to corrosion (level) Wear resistance (g) Hardness (H) Sticking power (N)
Embodiment 1 25 26 26 10 3700 5 28.32
Embodiment 2 27 27 27 10 3800 5 30.15
Embodiment 3 24 24 24 10 3500 4 27.57
Comparative Examples 20 23 21 9.8 3100 3 20.77

Claims (6)

1, a kind of high-performance electrophoresis aluminum alloy construction section bar, it is characterized in that: the mass percent composition is 0.5~0.54%Mg, 0.4~0.44%Si, 0.04~0.08%RE, 0.01~0.02%Ti, 0.002~0.004%B, 0~0.2%Fe, and surplus is an aluminium.
2, a kind of preparation method of high-performance electrophoresis building aluminium alloy extrusions is characterized in that: comprise following steps:
A, mishmetal ingot, AlTiB alloy and fine aluminium ingot are carried out melting in the resistance-type crucible furnace, refining, the degasification slagging-off, stirring is cast into block refining deterioration agent;
B, make melting section bar aluminium alloy in the energy-conservation stove in the flat-top hot-cast, add alloying elements such as Mg, Si, Fe, add block refining deterioration agent before the casting, guarantee that alloy mass per-cent composition is 0.5~0.54%Mg, 0.4~0.44%Si, 0.04~0.08%RE, 0.01~0.02%Ti, 0.002~0.004%B, 0~0.2%Fe, surplus is an aluminium, 900~1000 ℃ of smelting temperatures;
C, liquation continuous casting become bar-shaped cast ingot, through 560 ℃ of homogenizing 6 hours, are hot extruded into aluminium alloy extrusions by 430~450 ℃ again;
D, by anodic oxidation, the electrophoretic painting operation makes high-performance electrophoresis aluminum alloy construction section bar.
3, the preparation method of a kind of high-performance electrophoresis building aluminium alloy extrusions according to claim 2, it is characterized in that: the mass percent composition of described block refining deterioration agent is 14~17%La, 2~5%Pr, 1~3%Ce, 1~3%Ti, 0.2~0.6%B, and surplus is an aluminium.
4, the preparation method of a kind of high-performance electrophoresis building aluminium alloy extrusions according to claim 3, it is characterized in that: every quality of described block refining deterioration agent is 0.2~0.3kg.
5, the preparation method of a kind of high-performance electrophoresis building aluminium alloy extrusions according to claim 2, it is characterized in that: described anodic oxidation condition is H 2SO 4130~200g/L, Al 3+≤ 30g/L, temperature: 18~25 ℃, current density: 100~250A/m 2, oxidation voltage: 12~18V, oxidization time≤10min.
6, the preparation method of a kind of high-performance electrophoresis building aluminium alloy extrusions according to claim 2, it is characterized in that: described electrophoretic painting condition is: voltage 100~180V, electric current 200~800A, time 1~3min toasts 180 ± 5 ℃, constant temperature 30min.
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