CN101245053A - 叔碳酸缩水甘油酯的制备方法 - Google Patents
叔碳酸缩水甘油酯的制备方法 Download PDFInfo
- Publication number
- CN101245053A CN101245053A CNA2007100568293A CN200710056829A CN101245053A CN 101245053 A CN101245053 A CN 101245053A CN A2007100568293 A CNA2007100568293 A CN A2007100568293A CN 200710056829 A CN200710056829 A CN 200710056829A CN 101245053 A CN101245053 A CN 101245053A
- Authority
- CN
- China
- Prior art keywords
- acid
- reaction
- glycidyl ester
- hour
- carbonic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- OZCWUNHGNVXCCO-UHFFFAOYSA-N oxiran-2-ylmethyl hydrogen carbonate Chemical group OC(=O)OCC1CO1 OZCWUNHGNVXCCO-UHFFFAOYSA-N 0.000 title claims description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 47
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 239000000047 product Substances 0.000 claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- 238000005886 esterification reaction Methods 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004593 Epoxy Substances 0.000 claims abstract description 6
- 239000000706 filtrate Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 238000010907 mechanical stirring Methods 0.000 claims abstract description 4
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 22
- 150000002763 monocarboxylic acids Chemical group 0.000 claims description 13
- 230000032050 esterification Effects 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 4
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims description 2
- -1 neodecanoic acid glycidyl ester Chemical class 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 4
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 210000003739 neck Anatomy 0.000 abstract 1
- 238000005292 vacuum distillation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 12
- 230000035484 reaction time Effects 0.000 description 9
- 238000000576 coating method Methods 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000006735 epoxidation reaction Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 125000005908 glyceryl ester group Chemical group 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000002195 soluble material Substances 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229940072282 cardura Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- RUZYUOTYCVRMRZ-UHFFFAOYSA-N doxazosin Chemical compound C1OC2=CC=CC=C2OC1C(=O)N(CC1)CCN1C1=NC(N)=C(C=C(C(OC)=C2)OC)C2=N1 RUZYUOTYCVRMRZ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000004665 fatty acids Chemical group 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Landscapes
- Epoxy Compounds (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100568293A CN101245053B (zh) | 2007-02-15 | 2007-02-15 | 叔碳酸缩水甘油酯的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007100568293A CN101245053B (zh) | 2007-02-15 | 2007-02-15 | 叔碳酸缩水甘油酯的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101245053A true CN101245053A (zh) | 2008-08-20 |
CN101245053B CN101245053B (zh) | 2011-04-13 |
Family
ID=39945763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007100568293A Ceased CN101245053B (zh) | 2007-02-15 | 2007-02-15 | 叔碳酸缩水甘油酯的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101245053B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2261220A1 (en) | 2009-06-11 | 2010-12-15 | Hexion Specialty Chemicals Research Belgium S.A. | Process for preparing glycidyl esters of branched monocarboxylic acids |
WO2012037861A1 (zh) * | 2010-09-26 | 2012-03-29 | 西南化工研究设计院 | 一种叔碳酸缩水甘油酯的制备方法 |
CN103183652A (zh) * | 2011-12-28 | 2013-07-03 | 天津市四友精细化学品有限公司 | 叔碳酸缩水甘油酯的制备方法 |
CN110560159A (zh) * | 2019-08-13 | 2019-12-13 | 清华大学 | 一种用于叔碳酸缩水甘油酯制备的催化剂及其制备方法 |
CN115701284A (zh) * | 2020-03-20 | 2023-02-07 | 英格维蒂南卡罗来纳有限责任公司 | 妥尔油衍生的缩水甘油酯及其制备方法 |
CN118341173A (zh) * | 2024-06-17 | 2024-07-16 | 江苏奥凯环境技术有限公司 | 一种具有焊接剂材料的过滤袋及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW455584B (en) * | 1998-09-23 | 2001-09-21 | Shell Int Research | Process for the preparation of glycidylesters of branched carboxylic acids |
-
2007
- 2007-02-15 CN CN2007100568293A patent/CN101245053B/zh not_active Ceased
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI405758B (zh) * | 2009-06-11 | 2013-08-21 | Hexion Specialty Chemicals Res | 支鏈化單羧酸之縮水甘油酯的製備方法 |
WO2010142396A1 (en) | 2009-06-11 | 2010-12-16 | Momentive Specialty Chemicals Research Belgium S.A. | Process for preparing glycidyl esters of branched monocarboxylic acids |
CN102803242B (zh) * | 2009-06-11 | 2015-09-23 | 瀚森公司 | 用于制备支化单羧酸的缩水甘油酯的方法 |
EP2261220A1 (en) | 2009-06-11 | 2010-12-15 | Hexion Specialty Chemicals Research Belgium S.A. | Process for preparing glycidyl esters of branched monocarboxylic acids |
CN102803242A (zh) * | 2009-06-11 | 2012-11-28 | 迈图专业化学股份有限公司 | 用于制备支化单羧酸的缩水甘油酯的方法 |
US8802872B2 (en) | 2009-06-11 | 2014-08-12 | Momentive Specialty Chemicals Inc. | Process for preparing glycidyl esters of branched monocarboxylic acids |
CN102408396B (zh) * | 2010-09-26 | 2014-09-10 | 西南化工研究设计院 | 一种叔碳酸缩水甘油酯的制备方法 |
CN102408396A (zh) * | 2010-09-26 | 2012-04-11 | 西南化工研究设计院 | 一种叔碳酸缩水甘油酯的制备方法 |
WO2012037861A1 (zh) * | 2010-09-26 | 2012-03-29 | 西南化工研究设计院 | 一种叔碳酸缩水甘油酯的制备方法 |
WO2013097724A1 (zh) * | 2011-12-28 | 2013-07-04 | 天津市四友精细化学品有限公司 | 叔碳酸缩水甘油酯的制备方法 |
CN103183652A (zh) * | 2011-12-28 | 2013-07-03 | 天津市四友精细化学品有限公司 | 叔碳酸缩水甘油酯的制备方法 |
CN103183652B (zh) * | 2011-12-28 | 2016-04-06 | 河北四友卓越科技有限公司 | 叔碳酸缩水甘油酯的制备方法 |
CN110560159A (zh) * | 2019-08-13 | 2019-12-13 | 清华大学 | 一种用于叔碳酸缩水甘油酯制备的催化剂及其制备方法 |
CN115701284A (zh) * | 2020-03-20 | 2023-02-07 | 英格维蒂南卡罗来纳有限责任公司 | 妥尔油衍生的缩水甘油酯及其制备方法 |
CN118341173A (zh) * | 2024-06-17 | 2024-07-16 | 江苏奥凯环境技术有限公司 | 一种具有焊接剂材料的过滤袋及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101245053B (zh) | 2011-04-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101245053B (zh) | 叔碳酸缩水甘油酯的制备方法 | |
CN102803242B (zh) | 用于制备支化单羧酸的缩水甘油酯的方法 | |
CN102408396B (zh) | 一种叔碳酸缩水甘油酯的制备方法 | |
CN107552074A (zh) | 一种用于生产2,2,4‑三甲基‑1,3‑戊二醇双异丁酸酯的固体酸催化剂的制备方法 | |
CN108774209A (zh) | 一种采用管式反应器制备硫辛酸乙酯的方法 | |
CN111393272A (zh) | 一种3’-甲基苯丙酮的合成方法 | |
CN102336723A (zh) | 一种左旋氯哌斯汀芬地柞酸的制备方法 | |
CN106478381A (zh) | 一种由环氧乙烷催化制备双醚芴的方法 | |
CN107722053A (zh) | 一种亚磷酸二甲酯的精馏方法 | |
CN102850299B (zh) | 一种(甲基)丙烯酸缩水甘油酯的制备方法 | |
CN103102369B (zh) | 一种乙基膦酸二乙酯的生产方法 | |
CN110467632A (zh) | 一种γ-甲基丙烯酰氧基丙基甲基二甲氧基硅烷的制备方法 | |
CN104592283A (zh) | 硅烷偶联剂Si-69的合成工艺 | |
CN102659578A (zh) | 微波辐照合成乳酸酯的方法 | |
CN116655484B (zh) | 一种l-4-氯-2-氨基丁酸酯类盐酸盐的制备方法 | |
CN106800571B (zh) | 一种环状含硫硅烷低聚物及制备方法 | |
CN109810733A (zh) | 甲醇燃料及其制备方法 | |
CN102320957B (zh) | 一种制备4-(2,4,5-三氟苯基)-3-氧代丁酸的方法 | |
CN109053459A (zh) | 一种四正丙基溴化铵的制备方法 | |
CN103183611B (zh) | 一种乙二醇单烷基醚乙酸酯的制备方法 | |
CN108047038A (zh) | 一种乙酸2-羟基-3-氯-丙酯化合物的制备方法 | |
CN111943873A (zh) | 一种催化反应精馏合成高酯交换率间苯二甲酸双羟乙酯-5-磺酸钠的半连续工艺和装置 | |
CN103524729A (zh) | 一种砂浆混凝土外加剂的生产方法 | |
CN108484484A (zh) | 2-氧-3-哌啶甲酸乙酯的制备方法 | |
CN103183609B (zh) | 一种制备乙二醇单乙酸酯和乙二醇二乙酸酯的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C35 | Partial or whole invalidation of patent or utility model | ||
IW01 | Full invalidation of patent right |
Decision date of declaring invalidation: 20120621 Decision number of declaring invalidation: 18799 Granted publication date: 20110413 |
|
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20080820 Assignee: Hebei Siyou Excellence Technology Co.,Ltd. Assignor: TIANJIN SHIELD SPECIALTY CHEMICALS Co.,Ltd. Contract record no.: 2015130000046 Denomination of invention: Preparation method for tert-carbonic acid glycidyl ester Granted publication date: 20110413 License type: Exclusive License Record date: 20150421 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
CI01 | Publication of corrected invention patent application |
Correction item: invalidation announcement of patent right Correct: Cancel all invalid notice False: All invalid announcement Number: 13 Volume: 29 |
|
ERR | Gazette correction |