CN101157478A - 一种多钒酸铵的制备方法 - Google Patents
一种多钒酸铵的制备方法 Download PDFInfo
- Publication number
- CN101157478A CN101157478A CNA2007102017543A CN200710201754A CN101157478A CN 101157478 A CN101157478 A CN 101157478A CN A2007102017543 A CNA2007102017543 A CN A2007102017543A CN 200710201754 A CN200710201754 A CN 200710201754A CN 101157478 A CN101157478 A CN 101157478A
- Authority
- CN
- China
- Prior art keywords
- vanadium
- solution
- calcium
- value
- vanadate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 44
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 40
- 238000001556 precipitation Methods 0.000 claims abstract description 20
- 238000002386 leaching Methods 0.000 claims abstract description 11
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000011575 calcium Substances 0.000 claims description 33
- WQEVDHBJGNOKKO-UHFFFAOYSA-K vanadic acid Chemical compound O[V](O)(O)=O WQEVDHBJGNOKKO-UHFFFAOYSA-K 0.000 claims description 32
- 229910052791 calcium Inorganic materials 0.000 claims description 29
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 26
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000009835 boiling Methods 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 230000001105 regulatory effect Effects 0.000 claims description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- 159000000007 calcium salts Chemical class 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 5
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 208000004434 Calcinosis Diseases 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000008267 milk Substances 0.000 claims description 2
- 210000004080 milk Anatomy 0.000 claims description 2
- 235000013336 milk Nutrition 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 12
- 239000011734 sodium Substances 0.000 abstract description 12
- 239000002351 wastewater Substances 0.000 abstract description 10
- 229910052708 sodium Inorganic materials 0.000 abstract description 7
- 229910021529 ammonia Inorganic materials 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052700 potassium Inorganic materials 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 abstract description 2
- 239000001099 ammonium carbonate Substances 0.000 abstract description 2
- DNWNZRZGKVWORZ-UHFFFAOYSA-N calcium oxido(dioxo)vanadium Chemical compound [Ca+2].[O-][V](=O)=O.[O-][V](=O)=O DNWNZRZGKVWORZ-UHFFFAOYSA-N 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- QUEDYRXQWSDKKG-UHFFFAOYSA-M [O-2].[O-2].[V+5].[OH-] Chemical compound [O-2].[O-2].[V+5].[OH-] QUEDYRXQWSDKKG-UHFFFAOYSA-M 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 229940043430 calcium compound Drugs 0.000 abstract 1
- 150000001674 calcium compounds Chemical class 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 19
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 238000005406 washing Methods 0.000 description 8
- 239000006228 supernatant Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 4
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 4
- 229910001935 vanadium oxide Inorganic materials 0.000 description 4
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229910001199 N alloy Inorganic materials 0.000 description 2
- SKKMWRVAJNPLFY-UHFFFAOYSA-N azanylidynevanadium Chemical compound [V]#N SKKMWRVAJNPLFY-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
- GFNGCDBZVSLSFT-UHFFFAOYSA-N titanium vanadium Chemical compound [Ti].[V] GFNGCDBZVSLSFT-UHFFFAOYSA-N 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Removal Of Specific Substances (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
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CNB2007102017543A CN100558643C (zh) | 2007-09-18 | 2007-09-18 | 一种多钒酸铵的制备方法 |
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CNB2007102017543A CN100558643C (zh) | 2007-09-18 | 2007-09-18 | 一种多钒酸铵的制备方法 |
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CN101157478A true CN101157478A (zh) | 2008-04-09 |
CN100558643C CN100558643C (zh) | 2009-11-11 |
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CNB2007102017543A Expired - Fee Related CN100558643C (zh) | 2007-09-18 | 2007-09-18 | 一种多钒酸铵的制备方法 |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010057410A1 (en) * | 2008-11-18 | 2010-05-27 | Panzhihua New Steel & Vanadium Co., Ltd. | Clean production method of vanadium oxide |
WO2010057411A1 (en) * | 2008-11-18 | 2010-05-27 | Panzhihua New Steel & Vanadium Co., Ltd. | Production method of vanadium oxide using ion-exchange to realize wastewater circulation |
CN102050491A (zh) * | 2010-11-29 | 2011-05-11 | 中信锦州金属股份有限公司 | 一种三氧化二钒的生产方法 |
CN102328954A (zh) * | 2011-08-04 | 2012-01-25 | 佛山市邦普循环科技有限公司 | 一种从电动汽车用磷酸钒锂动力电池中回收钒的方法 |
CN102476829A (zh) * | 2010-11-30 | 2012-05-30 | 攀钢集团钢铁钒钛股份有限公司 | 一种硫酸氧钒的制备方法 |
CN102534233A (zh) * | 2012-02-10 | 2012-07-04 | 四川省达州钢铁集团有限责任公司 | 低品位高钙含钒钢渣的提钒工艺 |
CN102758088A (zh) * | 2012-06-07 | 2012-10-31 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种制备高密度多钒酸铵的方法及湿法提钒工艺 |
CN102912130A (zh) * | 2012-11-13 | 2013-02-06 | 吉首大学 | 一种分离富集石煤浸出液中钒的方法 |
CN102994751A (zh) * | 2011-09-13 | 2013-03-27 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低含钙溶液中钙离子浓度的方法 |
CN104538660A (zh) * | 2014-12-25 | 2015-04-22 | 河北钢铁股份有限公司承德分公司 | 一种适用于全钒液流电池的高纯度钒氧化物制备方法 |
CN104843789A (zh) * | 2015-04-30 | 2015-08-19 | 河北钢铁股份有限公司承德分公司 | 一种提纯五氧化二钒的方法 |
CN106164304A (zh) * | 2014-03-11 | 2016-11-23 | 韩国地质资源研究院 | 从脱硝废弃催化剂的浸出液中回收钒和钨的方法 |
CN107937737A (zh) * | 2017-11-24 | 2018-04-20 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低高铬钒酸钙中铬含量的方法 |
CN107964601A (zh) * | 2017-11-24 | 2018-04-27 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低钒酸钙中铬含量的方法 |
CN111099656A (zh) * | 2020-01-14 | 2020-05-05 | 攀钢集团攀枝花钢铁研究院有限公司 | 钙化焙烧酸浸液铵氢协同制备高密度多钒酸铵的方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1269639A (en) * | 1968-07-12 | 1972-04-06 | Murex Ltd | Preparation of sodium ammonium polyvanadate and ammonium metavanadate |
IT1196514B (it) * | 1986-07-17 | 1988-11-16 | Ente Minerario Siciliano | Procedimento di recupero del vanadio da residui della combustione di frazioni del petrolio |
CN1059885A (zh) * | 1990-07-24 | 1992-04-01 | 湖南省煤炭科学研究所 | 一种从含钒石煤中提取五氧化二钒的新方法 |
CN1207409C (zh) * | 2003-05-08 | 2005-06-22 | 锦州铁合金(集团)有限责任公司 | 从废触媒中湿法提取钒和/或钼的工艺 |
-
2007
- 2007-09-18 CN CNB2007102017543A patent/CN100558643C/zh not_active Expired - Fee Related
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010057410A1 (en) * | 2008-11-18 | 2010-05-27 | Panzhihua New Steel & Vanadium Co., Ltd. | Clean production method of vanadium oxide |
WO2010057411A1 (en) * | 2008-11-18 | 2010-05-27 | Panzhihua New Steel & Vanadium Co., Ltd. | Production method of vanadium oxide using ion-exchange to realize wastewater circulation |
RU2454368C1 (ru) * | 2008-11-18 | 2012-06-27 | Панган Груп Стил Ванадиум & Титаниум Ко., Лтд. | Способ получения оксида ванадия с применением ионообмена для осуществления циркуляции сточной воды |
CN102050491A (zh) * | 2010-11-29 | 2011-05-11 | 中信锦州金属股份有限公司 | 一种三氧化二钒的生产方法 |
CN102050491B (zh) * | 2010-11-29 | 2012-04-18 | 中信锦州金属股份有限公司 | 一种三氧化二钒的生产方法 |
CN102476829A (zh) * | 2010-11-30 | 2012-05-30 | 攀钢集团钢铁钒钛股份有限公司 | 一种硫酸氧钒的制备方法 |
CN102476829B (zh) * | 2010-11-30 | 2013-06-12 | 攀钢集团钢铁钒钛股份有限公司 | 一种硫酸氧钒的制备方法 |
CN102328954A (zh) * | 2011-08-04 | 2012-01-25 | 佛山市邦普循环科技有限公司 | 一种从电动汽车用磷酸钒锂动力电池中回收钒的方法 |
CN102328954B (zh) * | 2011-08-04 | 2013-06-26 | 佛山市邦普循环科技有限公司 | 一种从电动汽车用磷酸钒锂动力电池中回收钒的方法 |
CN102994751A (zh) * | 2011-09-13 | 2013-03-27 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低含钙溶液中钙离子浓度的方法 |
CN102994751B (zh) * | 2011-09-13 | 2014-10-01 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低含钙溶液中钙离子浓度的方法 |
CN102534233A (zh) * | 2012-02-10 | 2012-07-04 | 四川省达州钢铁集团有限责任公司 | 低品位高钙含钒钢渣的提钒工艺 |
CN102758088A (zh) * | 2012-06-07 | 2012-10-31 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种制备高密度多钒酸铵的方法及湿法提钒工艺 |
CN102912130A (zh) * | 2012-11-13 | 2013-02-06 | 吉首大学 | 一种分离富集石煤浸出液中钒的方法 |
CN106164304A (zh) * | 2014-03-11 | 2016-11-23 | 韩国地质资源研究院 | 从脱硝废弃催化剂的浸出液中回收钒和钨的方法 |
CN104538660A (zh) * | 2014-12-25 | 2015-04-22 | 河北钢铁股份有限公司承德分公司 | 一种适用于全钒液流电池的高纯度钒氧化物制备方法 |
CN104843789A (zh) * | 2015-04-30 | 2015-08-19 | 河北钢铁股份有限公司承德分公司 | 一种提纯五氧化二钒的方法 |
CN107937737A (zh) * | 2017-11-24 | 2018-04-20 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低高铬钒酸钙中铬含量的方法 |
CN107964601A (zh) * | 2017-11-24 | 2018-04-27 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低钒酸钙中铬含量的方法 |
CN107964601B (zh) * | 2017-11-24 | 2019-06-14 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种降低钒酸钙中铬含量的方法 |
CN111099656A (zh) * | 2020-01-14 | 2020-05-05 | 攀钢集团攀枝花钢铁研究院有限公司 | 钙化焙烧酸浸液铵氢协同制备高密度多钒酸铵的方法 |
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Address after: 617000 No. 90 Taoyuan Road, Sichuan, Panzhihua Co-patentee after: Pangang Group Steel Vanadium & Titanium Co., Ltd. Patentee after: Panzhihua Iron & Steel Research Institute of PanGang Group Address before: 617000 No. 90 Taoyuan Road, Sichuan, Panzhihua Co-patentee before: Panzhihua New Steel & Vanadium Co., Ltd. Patentee before: Panzhihua Iron & Steel Research Institute of PanGang Group |
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