CN101103829B - 用乳制备的产品的增稠体系 - Google Patents

用乳制备的产品的增稠体系 Download PDF

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CN101103829B
CN101103829B CN200710084108.3A CN200710084108A CN101103829B CN 101103829 B CN101103829 B CN 101103829B CN 200710084108 A CN200710084108 A CN 200710084108A CN 101103829 B CN101103829 B CN 101103829B
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drying composite
thickening
hydrocolloid
beverage products
breast
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CN101103829A (zh
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K·P·斯佩尔曼
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Intercontinental Great Brands LLC
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Kraft Foods Global Brands LLC
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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    • A23F5/24Extraction of coffee; Coffee extracts; Making instant coffee
    • A23F5/36Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee
    • A23F5/42Further treatment of dried coffee extract; Preparations produced thereby, e.g. instant coffee using inorganic additives
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    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
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    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
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    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/325Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds containing inorganic compounds
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    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
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    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
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Abstract

一种用来制备含乳饮料产品的干燥混合物增稠体系,其包括缓冲剂、水解胶体和含焦磷酸四钠的螯合剂。当将该干燥混合物增稠体系加入到乳中时,粘度在约20秒至约90秒之间建立以提供一种增稠的饮料产品,而不形成水解胶体的不溶聚集体。不需要加热。另外,将干燥混合物增稠体系掺入到乳中所需的唯一剪切是手工搅拌。

Description

用乳制备的产品的增稠体系
发明背景
本发明涉及用乳制备的饮料产品的干燥混合物增稠体系、饮料产品和制备这种饮料产品的方法。该干燥混合物增稠体系包括缓冲剂、水解胶体(hydrocolloid)和含焦磷酸四钠的螯合剂。当使用低剪切与乳组合时,该干燥混合物在不加热和不形成不溶聚集体的情况下提供增稠的饮料产品。
用乳制得的商业粉状饮料非常稀。当在不提供剪切和/或加热的情况下将水解胶体加入到乳中时,它们与乳中的钙离子结合并形成不溶聚集体(例如,“白点(fish eyes)”)或不溶层。结果,没有预期的增稠。这种增稠的失败在无糖和低糖产品中尤为确切,这些产品没有足够的颗粒作为间隔剂(spacingagent)并且没有将水解胶体充分分散。当前,不使用剪切或加热就不能在乳(特别是冷乳)中建立粘度。即饮(ready-to-drink)产品会使用高剪切来将用作增稠剂的水解胶体分散和活化。另外,即饮产品会使用果胶,其需要加热步骤。
美国专利No.5,221,549公开了使用多磷酸盐例如多磷酸四钠(TSPP)和酸式多磷酸钠来减少在超过265°F的温度下加热处理即食布丁制剂产生的蛋白聚集的量。该体系形成一个完整基体并且也使用淀粉。
美国专利No.6,759,073公开了组合物,其用作稳定剂和增稠剂体系。该组合物包括果胶化合物、藻酸盐化合物和例如羧甲基纤维素的纤维素化合物。焦磷酸铁可以作为增强剂(enhancer)材料加入。
美国专利No.6,703,056公开了饮料组合物,它包括(a)第一组分,其是***半乳聚糖,和(b)包括一种或多种选自锌、铁、镁、钙、硒、碘和氟的矿物质的第二组分。铁可以是焦磷酸铁的形式。
美国专利No.6,616,955和美国专利申请公开2002/0122847公开了饮料组合物,它包括(a)包括选自碳酸钙、其加溶的种类及其混合物的形式的钙源;和(b)每份组合物中至少约20毫克的镁源。该饮料可以含有焦磷酸铁形式的铁。
美国专利申请公开2003/0026872A1公开了适于用作食物和/或饮料的基本上干燥的组合物。该基本上干燥的组合物优选是饮料组合物,其中组合物用液体稀释之后食用。该组合物可以含有焦磷酸铁形式的铁。
美国专利No.5,447,732公开了含矿物质吸收促进剂的组合物。该组合物含有矿物质和作为矿物质吸收促进剂的聚-γ-谷氨酸产品并且可以以各种形式用于食物中,包括饮料、凝胶、固体或粉末形式。矿物质可以是焦磷酸铁形式的铁。
美国专利No.5,356,654公开了藻酸盐和/或果胶酸盐凝胶,它是通过低温下形成水溶性或水分散性的藻酸盐和/或果胶酸盐、钙离子螯合剂和微溶性钙离子源的含水混合物并加热该混合物以使其胶凝化制得的。该螯合剂优选是焦磷酸钠或焦磷酸钾,但至少部分螯合剂可以由具有钙离子螯合活性的肉替代。
美国专利No.5,348,756公开了经配制以获得至少4.15的相对高pH和相对低的明胶负荷重量同时仍然保留所需酸味的水果味粉状明胶甜食混合物。
美国专利No.4,919,958公开了牛奶果酱饼形布丁用无蛋组合物。该无蛋组合物包括乳、增甜剂、米粉、角叉藻聚糖、焦磷酸四钾、果胶、刺槐豆胶和至少一种选自干酪乳清蛋白分离物和黄原胶的材料。布丁制备中需要烹调步骤。
美国专利No.4,859,484公开了将用0.7至2.0份水水合并使之接近胶凝化的淀粉与水解胶体树胶(也可以预水合)组合以形成混合物。该混合方法包括在将淀粉胶凝化的同时将水解胶体树胶和淀粉紧密混合;在压力但足够低的剪切下加热该均一掺合物,以防止淀粉降解;并将其通过模具挤压从而使其膨胀并产生表面积大的产品以便于干燥。TSPP列于其它盐中作为提高淀粉/树胶溶液的pH的途径。
美国专利No.4,276,320公开了一种具有控制的熔解温度的水甜食凝胶的制备方法和组合物,该凝胶由κ角叉藻聚糖、螯合剂的钠盐和量足够螯合存在的所有多价阳离子的可电离的钾组成。
美国专利No.4,136,209公开了一种果胶制剂的制备方法。将具有金属盐的30至140g金属结合能力的水果果胶用磷酸盐溶解以制得pH为4.4至4.8的溶液。将可溶金属盐加入该溶液中。果胶从溶液中沉淀出。
美国专利No.4,081,567公开了一种饮料,它是用乳或乳替代物重构含预胶凝化淀粉、可食用酸和水解胶体树胶的干燥混合物组合物制得的。水解胶体树胶优选是瓜耳胶和黄原胶的混合物。使用改性和/或预胶凝化的淀粉允许通过酸“迅速再水合和迅速凝固从而防止乳蛋白凝结和凝块”。该产品的pH为3至5。
美国专利No.3,934,049公开了一种改进的胶凝剂组合物,其包括碱金属焦磷酸盐、碱土金属正磷酸盐、碱金属碳酸盐和增稠剂的组合,该组合可用于制备冷凝固的乳布丁。该改进的胶凝剂组合优选包括焦磷酸四钠或酸式焦磷酸钠、磷酸一钙、碳酸钠和预胶凝化淀粉。将该改进胶凝剂加入到乳、或含水再溶解的脱脂乳粉或再溶解的酪蛋白中以形成布丁。
美国专利No.3,914,456公开了一种干燥混合物布丁组合物,它包括蜡质种玉米(waxy maize corn)和木薯预胶凝化淀粉和碱性焦磷酸盐、磷酸一钙和作为凝固盐的钾盐。该产品用制备用的搅打器剧烈搅打制成。
仍然需要一种可使用低剪切,在不进行加热并且不形成不溶聚集体下就可以与乳组合以形成增稠饮料产品的干燥混合物组合物。
发明概述
本发明涉及一种用乳制备的饮料产品用的干燥混合物增稠体系。该干燥混合物组合物包括缓冲剂、水解胶体和含焦磷酸四钠的螯合剂。当使用低剪切加入乳时,例如手工搅拌,该干燥混合物组合物在不用加热的情况下建立粘度以形成增稠的饮料产品。另外,所得增稠的饮料产品不含水解胶体的任何不溶聚集体。该增稠的饮料不形成凝胶,甚至在冷冻下。
发明详述
下面参照具体的干燥混合物增稠体系配方和增稠饮料产品和加工工艺描述本发明。然而,经验丰富的食物科学家将清楚使得对这些方面的改进成为可能的原理也可用于其它产品和方法。
A.干燥混合物增稠体系
根据本发明,用乳制得的饮料产品用的干燥混合物增稠体系包括缓冲剂、水解胶体和用于水解胶体的含焦磷酸四钠的螯合剂。该干燥混合物增稠体系为粉状。
本发明的干燥混合物增稠体系包括水解胶体。在实施方案中,水解胶体可以是水解胶体树胶,其包括但不限于,瓜耳胶、刺槐豆胶、黄原胶、角叉藻聚糖或其组合。水解胶体也可以是纤维素树胶,例如羧甲基纤维素。在优选实施方案中,水解胶体包括角叉藻聚糖,例如λ-角叉藻聚糖。λ-角叉藻聚糖也可以含ι-角叉藻聚糖。可以用于干燥混合物增稠体系的角叉藻聚糖的例子有商购自FMC的LactarinTM。每约200mL至约240mL份的含乳饮料产品中该干燥混合物增稠体系可以含约0.2g至约0.6g量的水解胶体。
本发明的干燥混合物增稠体系包括保持增稠的饮料产品pH在约6至约7.5范围内的缓冲剂。在实施方案中,缓冲剂可以包括柠檬酸三钾或柠檬酸三钠。优选不加酸至干燥混合物组合物中。增稠的饮料产品在pH为约6或更小时开始有稀农家干酪状浓度。每约200mL至约240mL份的含乳饮料产品中该干燥混合物增稠体系可以含有约0.25g至约1.0g的量的缓冲剂。
根据本发明,干燥混合物增稠体系也包括含焦磷酸四钠的螯合剂。螯合剂防止水解胶体在与乳混合时形成不溶聚集体或不溶层。每约200mL至约240mL份的含乳饮料中该干燥混合物增稠体系可以含有约0.15g至约0.2g的量的螯合剂。
干燥混合物增稠体系可以任选含有一种或多种添加剂。该一种或多种添加剂可以包括,但不限于,例如小麦或燕麦粉的谷类;可可;咖啡,例如可溶咖啡;食用香料;减少水分的流动剂,例如氧化镁;间隔剂,例如硅石;着色剂;淀粉;麦芽糖糊精,米粉(rice fines);米脆粒(rice crisp particulates);合成的增甜剂,例如阿斯巴甜或乙酰舒泛;天然增甜剂例如糖;维生素,例如维生素B2、B3、B6、C、A或E;矿物质,例如铁或镁;酶;益生元;纤维;益生菌;药物,或其任何组合。
B.饮料产品的制备
当将干燥混合物增稠体系加入到乳,例如室温或更低温度下的乳中时,水解胶体建立粘度来提供增稠的饮料产品。在实施方案中,粘度在约20秒至约90秒内增至约50cP至约70cP(如在室温下测量的)。由于乳蛋白-TSPP相互作用会有附加的粘度建立,从而增稠的饮料产品的粘度在约30分钟内增至约100cP至约300cP(如在室温下测量的)。不需要淀粉就建立粘度。因而,在实施方案中,干燥混合物组合物可以不含淀粉。在实施方案中,干燥混合物组合物可以不含果胶。
形成增稠的饮料产品所需的唯一剪切是例如匙搅拌的手工搅拌,其足以将干燥混合物组合物掺入到乳中。不需要使用搅打器或混合器。由于有螯合剂存在,所以没有形成水解胶体的不溶聚集体或不溶层。另外,不需要加热。增稠的饮料产品将不形成完整凝胶,而是保持为饮料,即使在冷冻之后,例如在约48小时之后。
在实施方案中,干燥混合物增稠体系可以以高水平加入到乳中,例如约3.0g/L至约6.0g/L,例如约4.5g/L。在实施方案中,干燥混合物增稠体系可以加入到乳粉中,其能再加入到水中以制得增稠的饮料产品。
根据干燥混合物组合物中所用的水解胶体和螯合剂的量,能够控制增稠的饮料产品的质地和粘度以制得不同类型的乳制品,例如可饮用型酸牛奶和牛奶冰淇淋。
通过以下实施例来进一步描述本发明,其中所有份、百分数和比率都按重量计算,所有压力都是大气压,且所有温度都以°F计,除非有相反指示:
实施例
实施例1
将上述干燥成分组合以形成干燥混合物。将该干燥混合物分别加入到200mL乳和240mL乳中,并用匙搅拌。得自树胶的初始粘度在约20至90秒内增加。在5分钟之后因乳蛋白-TSPP相互作用,有一些额外的粘度增加,但产品仍然是液体,甚至在冰箱中48小时后。饮料产品具有可饮用酸牛奶产品的浓度。
实施例2
将上述干燥成分组合以形成干燥混合物。将该干燥混合物分别加入到200mL水和240mL水中,并用匙搅拌直至完全溶解。
实施例3
将上述干燥成分组合以形成干燥混合物。将该干燥混合物分别加入到200mL乳和240mL乳中,并用匙搅拌直至完全溶解。
实施例4
将上述干燥成分组合以形成干燥混合物。将该干燥混合物分别加入到200mL乳和240mL乳中,并用匙搅拌直至完全溶解。
实施例5
如实施例1中相同地进行制备,但在干燥成分中加入柠檬酸。当将乳加到该干燥混合物中时,pH低于6,因此导致稀农家干酪状浓度。
前面的公开内容仅举例说明了本发明而不希望对其进行限制。由于本领域技术人员可以对并入本发明精神和实质的公开的实施方案进行修改,因此本发明应解释为包括在所附权利要求书及其等同方案的范围内的所有内容。

Claims (16)

1.一种用来制备含乳的增稠的饮料产品的干燥混合物,其包括缓冲剂、水解胶体和含焦磷酸四钠的螯合剂,其中所述干燥混合物为粉状并且不含淀粉,每200 mL至240 mL的增稠的饮料产品中水解胶体的量为0.2 g至0.6 g,每200 mL至240 mL的增稠的饮料产品中螯合剂的量为0.15 g至0.2 g,且所述增稠的饮料的粘度是50 cP至90 cP。
2.根据权利要求1的干燥混合物,其中所述缓冲剂维持增稠的饮料产品的pH在6至7.5。
3.根据权利要求1的干燥混合物,其中所述缓冲剂选自柠檬酸三钾和柠檬酸三钠。
4.根据权利要求1的干燥混合物,其中每200 mL至240 mL的增稠的饮料产品中缓冲剂的量为0.25 g至1.0 g。
5.根据权利要求1的干燥混合物,其中所述水解胶体包括水解胶体树胶或纤维素树胶。
6.根据权利要求5的干燥混合物,其中所述水解胶体树胶选自瓜耳胶、刺槐豆胶、黄原胶和角叉藻聚糖。
7.根据权利要求1的干燥混合物,其中所述水解胶体包括角叉藻聚糖。
8.根据权利要求7的干燥混合物,其中所述角叉藻聚糖包括λ-角叉藻聚糖。
9.根据权利要求1的干燥混合物,进一步包括谷类。
10.根据权利要求1的干燥混合物,进一步包括可可或可溶咖啡。
11.根据权利要求1的干燥混合物,进一步包括一种或多种选自增甜剂、维生素、矿物质、酶、益生元、纤维和益生菌的添加剂。
12.一种制备增稠的饮料产品的方法,其包括将权利要求1的干燥混合物与乳混合以形成增稠的饮料产品。
13.根据权利要求12的方法,其中所述增稠的饮料产品的pH是6至7.5。
14.根据权利要求12的方法,其中在没有加热的情况下进行混合并且乳处于室温或更低温度下。
15.根据权利要求12的方法,其中所述混合是通过手工搅拌进行的。
16.根据权利要求12的方法,其中所述增稠的饮料包括牛奶冰淇淋或可饮用酸牛奶。
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