CN100363137C - Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material - Google Patents

Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material Download PDF

Info

Publication number
CN100363137C
CN100363137C CNB2005101313555A CN200510131355A CN100363137C CN 100363137 C CN100363137 C CN 100363137C CN B2005101313555 A CNB2005101313555 A CN B2005101313555A CN 200510131355 A CN200510131355 A CN 200510131355A CN 100363137 C CN100363137 C CN 100363137C
Authority
CN
China
Prior art keywords
welding
vibration
aluminium base
composite material
discontinuous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2005101313555A
Other languages
Chinese (zh)
Other versions
CN1792531A (en
Inventor
闫久春
许志武
许惠斌
赵维巍
张洋
李大成
于汉臣
杨士勤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Harbin Institute of Technology
Original Assignee
Harbin Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Institute of Technology filed Critical Harbin Institute of Technology
Priority to CNB2005101313555A priority Critical patent/CN100363137C/en
Publication of CN1792531A publication Critical patent/CN1792531A/en
Application granted granted Critical
Publication of CN100363137C publication Critical patent/CN100363137C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Pressure Welding/Diffusion-Bonding (AREA)
  • Arc Welding In General (AREA)
  • Laser Beam Processing (AREA)

Abstract

The present invention provides a welding method for filling composite welding materials and vibration liquid phase of discontinuous enhanced aluminium base composite materials. The present invention is characterized in that firstly 400# abrasive paper is used for grinding the surface to be welded of discontinuous enhanced aluminium base composite materials, and the surface to be welded of discontinuous enhanced aluminium base composite materials is carried out ultrasonic cleaning in acetone; when the cleaned discontinuous enhanced aluminium base composite materials are aired, the discontinuous enhanced aluminium base composite materials are clamped on a clamping apparatus in a butt joint form, and composite welding materials are placed between the two surfaces to be welded of discontinuous enhanced aluminium base composite materials; the composite welding materials sufficiently melt by heat, and thermocouple control is used for keeping welding temperature, starting a vibrating device and exerting pre-pressure; when vibration reaches presetting time, the vibration is stopped, simultaneously, pressure is enhanced, and constant value is remained; when the process is finished, joints of the discontinuous enhanced aluminium base composite materials are cooled. The present invention has uniformly distributed enhanced phase energy, welded seams with composite structures and joints with good performances can weld aluminium base composite materials under non-vacuum conditions and provides large flexibility for actual production.

Description

Fill composite solder non-continuous reinforced aluminium-based composite material Vibration Liquid Phase welding method
(1) technical field
What the present invention relates to is a kind of welding method, specifically a kind of welding method of aluminum matrix composite.
(2) background technology
Non-continuous reinforced aluminium-based composite material is by the parent metal aluminium alloy of plasticity, good toughness and nonmetal short fiber, whisker or the particle of some high strength, high-modulus, high-melting-point, low-density and low thermal coefficient of expansion, as Al commonly used 2O 3Short fiber, SiC, AlBO whisker and Al 2O 3, SiC, TiC particle etc., be composited through special preparation technology.The special composite construction of this kind material makes its more former alloy matrix aluminum have excellent comprehensive performance more just, as specific strength, specific stiffness height, wearability is good, thermal coefficient of expansion is little etc., thereby in Aero-Space, national defence field, as guided missile, tank, panzer etc., and be with a wide range of applications in the civilian industry, as automobile engine piston, connecting rod brake and bicycle part etc.Material just has bigger practical use after being processed to member.And solder technology is one of very important secondary processing method in this process.For the welding joint of member, its performance depends on the heterogeneous microstructure of weld seam to a great extent.Therefore, for being consistent of the joint performance that makes member and mother metal as far as possible, guaranteeing that appearance of weld is good, pore-free, be mingled with etc. on the basis of defective, should make the institutional framework of weld seam approximate consistent with the maintenance of mother metal, promptly weld seam also should have wild phase equally distributed composite construction in matrix alloy.In the existing various welding methods of aluminum matrix composite, as melting (TIG weldering, Laser Welding etc.), Solid-State Welding (friction welding (FW), diffusion welding (DW), transient liquid phase weldering etc.) and other certain methods (electric resistance welding, soldering), domestic and international many Welder authors try hard to by various measures to reach this purpose.Yet the whole bag of tricks still exists certain difficulty in realizing this purpose process.The main feature of the whole bag of tricks is:
1, melting welding
During molten solder (TIG, MIG weldering, laser, electron beam welding etc.) welding of aluminum based composites, used packing material when used welding wire often is welding aluminum alloy is as ER4043, ER4047 etc.These welding wires and welding procedure are very successful when welding aluminum alloy, when still applying it to the welding of aluminum matrix composite, but are faced with the following urgency problem to be solved:
On the one hand, consider that from physical compatibility the fusing point of aluminum matrix composite matrix and wild phase differs bigger, existence is melted wild phase in a large number and is made its viscosity become big in the molten bath, and mobile variation is filled metal and is difficult to mix with molten pool metal.This will cause generation of defects such as pore, lack of penetration and incomplete fusion; In addition, in the weld pool solidifies process, molten wild phase particle is concentrated partially at solidification front and is gathered, and has destroyed original characteristic distributions and makes mis-behave; The more important thing is, aspect chemical compatibility, the wild phase particle in the not only direct scaling loss molten bath of the high temperature that molten solder produces, and make the following interfacial reaction of easy generation between matrix and the wild phase:
3SiC(s)+4Al(l)=Al 4C 3(s)+3Si(s)
Or 3Mg (l)+4Al 2O 3(s)=3MgAl 2O 3(s)+2Al (l)
Also cause the wild phase loss.Reaction product Al 4C 3Perhaps MgAl 2O 3All be the fragility phase, seriously reduced weld properties and cracking resistance.Especially, Al 4C 3Under aqueous environment, can emit CH with the water reaction 4Gas causes the joint low stress damage.Thereby, in final joint made by flame welding, promptly exist no wild phase zone, exist again to strengthen the poly-zone of skew, the difference of seam organization and mother metal is very big, and joint performance is very undesirable.Solve above two problems, want the filling metal of selective wetting, good fluidity on the one hand, and take technological measure, reduce the fusing of composite,, adopt the low TIG weldering of heat input etc. as strengthening groove; For avoiding and the reaction between parent metal and the wild phase when suppressing to weld, can in matrix, add suitable alloying component simultaneously and be suppressed on the other hand by reducing the heat input in molten bath.It is found that interpolation Si is especially effective in matrix.Yet this might damage matrix strength, causes the loss of strength of composite.Some scholars also utilize high energy laser beam, and the cooling and the temperature field that are equipped with the nitrogen sieve are regulated, and induce and improve the interfacial reaction of aluminum matrix composite wild phase and matrix to a certain extent, thereby improve strength of joint, but problem is not solved.In addition, molten solder technology only limits to the aluminum matrix composite of wild phase volume fraction lower (<20%), for the composite of high-volume fractional more (as electronic encapsulation device with composite wild phase volume fraction greater than 30%) be powerless.
2, friction welding (FW)
Need not packing material during the friction welding aluminum matrix composite, also can avoid the loss of wild phase, strength of welded joint is higher.But the welding process center tap produces bigger plastic deformation, the local softening phenomenon occurs, and this position intensity reduces, and joint need pass through solid solution+Ageing Treatment.In addition, friction welding (FW) has higher requirement to the shape of connected piece, is generally the bar-shaped part of simple shape, makes this kind welding method range of application be subjected to certain restriction.
3, diffusion welding (DW)
Diffusion welding (DW) is the more promising method of a kind of welding of aluminum based composites, but same difficulty when with the diffusion welding (DW) aluminum matrix composite time, having run into the diffusion welding (DW) aluminium alloy.
(1) there is the oxide-film of one deck densification on the aluminum matrix composite surface, and it seriously hinders two diffusion combinations that connect between the surface.With generating immediately again after machinery or the soak cleaning, even under high vacuum condition, this layer oxide-film also is difficult to decompose, and influences the atom diffusion.Just need bring up to the connection temperature near the fusing point of aluminium or on linkage interface, impose severe pressure for destroying oxide-film on the combination interface.This inevitably can make connector produce excessive plastic deformation.
(2) under the situation that does not adopt the intermediate layer, there is the direct contact phenomena of wild phase one wild phase on the aluminum matrix composite contact-making surface, be difficult to realize that the diffusion between the wild phase connects under the diffusion welding (DW) condition.The transmission capacity of load has not only been reduced at this position, and also provides opportunity for the germinating and the expansion of crackle, becomes the not high main hidden danger of strength of joint.
(3) adopt intermediate course, can reduce or eliminate little connection of wild phase/wild phase in the joint join domain as Cu, Al-Si-Mg, Ag paper tinsel etc., joint performance is improved.But no wild phase zone still appears in joint easily, and joint quality is stable inadequately.
In addition, this method is longer welding interval, apparatus expensive, and cost is very high, and the welding surroundings of vacuum makes weldment size, shape also be subjected to bigger restriction, and its extensive use is restricted.
4, transient liquid phase weldering (Transient Liquid Phase bonding, TLP)
The transient liquid phase weldering is by forming low melting eutectics at a lower temperature between the test specimen welding surface, eliminated the way of contact of wild phase/wild phase in the weld seam, apply the oxide-film that less pressure just can destroy the mother metal surface, and make wild phase enter into liquid intermediate layer by dissolving part mother metal, obtain having the joint microstructure of composite construction by isothermal solidification, strength of joint is higher.
Also there is certain deficiency in transient liquid phase weldering when having more advantage: (1) owing to be static isothermal solidification, in the liquid phase eutectic area process of setting wild phase passed by solid liquid interface and cause poly-ly partially become the subject matter that this kind material TLP welds.Domestic and international many scholars find to select thin middle paper tinsel layer, dissolve and come wild phase effectively to address this problem from mother metal with what reduce that the liquid phase intermediate layer comprised.Generally all about several micron, but this has relatively high expectations to surface roughness to be welded the selected intermediate layer thickness of this method, particularly for the member of big bonding area, implement the comparison difficulty, thereby engineering significance is undesirable.In addition, the particle size that composite comprises also can reduce the poly-partially degree of particle when big, but from composite property, the preparation composite is generally all pursued micron, sub-micron or even nano level particle and has generally also all been surpassed 550 ℃ as wild phase (2) transient liquid phase welding temperature, under this temperature, mother metal has in various degree softening, and this is a challenge to matrices of composite material.(3) the transient liquid phase weldering is carried out under vacuum environment mostly, and shape and size that this has limited member to be welded reduce this kind adaptation of methods.
5, soldering
Lead base composite soldering solder commonly used also is a solder commonly used in the aluminium alloy brazing, as BAlSi-1, BAlSi-4 and Zn-Al solder etc.During this method welding of aluminum based composites, subject matter is the restriction that strength of joint is subjected to original solder intensity, and tensile strength is lower.For the aluminum matrix composite welding, adopt method for welding also to have following several problem:
(1) oxide-film on aluminum matrix composite surface has a strong impact on welding quality.Because Al 2O 3The film fusing point is very high, in welding process, be difficult to the fusing, have a strong impact on solder on mother metal wetting with sprawl, become one of major obstacle of aluminum matrix composite soldering.
(2) welding procedure is controlled improper meeting and is caused matrix fusing, and it is poly-that the diffusion region strengthens skew; Residual no wild phase layer can't keep original particular tissues of mother metal and property in the brazing seam structure.This butt joint occasion that can require that has specific characteristics is not suitable for, and keeps good antidamping characteristic and dimensional stability etc. as the need joint.
(3) alloy matrix aluminum and wild phase fusing point differ greatly, at brazing temperature lower substrate partial melting, do not melt and strengthen body, cause solder viscous, mobile variation, solder on mother metal wetting with sprawl because the existence of solid-state wild phase is subjected to serious obstruction, add some alloying element, improve brazing temperature and can improve to a certain extent, and the too high burning corrode that easily causes mother metal of temperature is brought very big difficulty to brazing process.
6, electric resistance welding
Resistance welded generally need not packing material, because its heat time heating time is short, can suppress the interfacial reaction between wild phase and matrix, and connector area is difficult for producing crackle and pore under pressure.But having run into challenge for the aluminum matrix composite that discontinuous fiber strengthens, mainly is to exist serious enhancing skew poly-in the nugget.In addition, the existence of wild phase makes the distribution of electric current line and the complex distributionization of electrode pressure in the aluminum matrix composite, has brought difficulty for the selection of welding parameter and the control of welding quality.And the enhancing body of composite and matrix resistance differs greatly, composite produced superfuse, splash, fiber bonds, broken and generation is empty, strength of joint is subjected to very big influence.
(3) summary of the invention
The object of the present invention is to provide a kind of enhancing to be on good terms and evenly distribute, have the weld seam of composite construction, joint performance is good, can realize the welding of aluminum matrix composite under non-vacuum condition, the filling composite solder non-continuous reinforced aluminium-based composite material Vibration Liquid Phase welding method of greater flexibility is provided for actual production.
The object of the present invention is achieved like this:
Welding method of the present invention is: earlier with 400# sand papering non-continuous reinforced aluminium-based composite material, and in acetone, carry out ultrasonic wave and clean, after non-continuous reinforced aluminium-based composite material after to be cleaned dries, it is installed on the jig with the banjo fixing butt jointing form, and composite solder is placed between the two non-continuous reinforced aluminium-based composite material to be welded surfaces, heating is fully melted composite solder, the heating-up temperature scope is 380~620 ℃, and control by thermocouple, keep welding temperature, Vibration on Start-up device and apply precompression, one of following dual mode is adopted in vibration: with frequency is 50~4000Hz, amplitude is the low-frequency vibration of 0~1.5mm, time of vibration is 0.1~5 minute, vibrating after-applied pressure limit is 0.25~10Mpa; Or frequency is that 15~60KHz, amplitude are that supersonic frequency vibration, the time of vibration of 5~50 μ m is that 0.1~30s, the after-applied pressure limit of vibration are 0.25~10MPa, treat that vibration arrives after the Preset Time, stop vibration, while intensified pressure to 0.25~10Mpa, and maintenance steady state value, insulation is no more than 10 minutes, after the end non-continuous reinforced aluminium-based composite material joint is cooled off.
Method of the present invention can also comprise:
1, the wild phase of described non-continuous reinforced aluminium-based composite material is that the volume ratio that accounts for total amount is the Al of 2-25% 2O 3Or SiC short fiber, or the SiC of 5-40%, Mg 2B 2O 5Or Al 18B 4O 33Whisker, or the particle mean size of 5-70% is SiC, the Al of 0.01-50 μ m 2O 3, TiC, TiB 2, AlN, TiN or ZrO 2Particle, or the 1:1 mixture of the whisker of 4-40% and particle; The matrix of non-continuous reinforced aluminium-based composite material is a kind of in industrial pure Al or Al-Cu system, Al-Mn system, Al-Si system, Al-Si-Cu system, Al-Si-Mg system, Al-Mg system, Al-Mg-Si system, the Al-Zn-Mg line aluminium alloy.
2, used composite solder is that volume ratio is the Al of 2-15% 2O 3Or SiC short fiber, or the SiC of 5-20%, Mg 2B 2O 5Or Al 18B 4O 33Whisker, or the particle mean size of 5-30% is SiC, the Al of 0.01~50 μ m 2O 3, TiC, TiB 2, AlN, TiN or ZrO 2Particle, or or 1: 1 mixture of the whisker of 4-20% and particle in a kind of Zn parent metal or aluminium base scolder for wild phase and surplus be composited.
3, described Zn parent metal is the Zn-Al-Cu that impurity is formed by Cu:3.22wt%, Mg:0.82wt%, Mn:0.91wt%, Fe:0.01wt%, Si:0.81wt%, Zn:89.3wt%, Ni:0.05wt%, Al:4.2wt%, surplus, PTZn95Al, PTZn90Al, PTZn70Al, Zn72.5Al, a kind of among Zn60Cd or the Zn58SnCu; Described aluminium base scolder is a kind of among HLAlSi10, HLAlSi12, HLAlSiCu10, Al12SiSrLa, HL403, HL401, B62, Al60GeSi, HlAlSiMg7.5-1.5, HLAlSiMg10-1.5 or the HLAlSiMg12-1.5.
4, the shape of described composite solder is a kind of in bar-shaped, sheet and the graininess, and its filling mode is to be positioned between two welding surfaces when being coated on welding surface or welding in advance.
5, described welding point form is butt joint, overlap joint, tube sheet joint or T junction form.
6, described heating is a kind of in flame heat, high-frequency induction heating or the resistance radiation heating.
7, oscillatory type can be low-frequency mechanical vibrations or high frequency ultrasound vibration, and vibration is applied to the top or the below test specimen of non-continuous reinforced aluminium-based composite material to be welded.
8, the type of cooling after the welding is air cooling, water-cooled or cooling naturally.
Aluminum matrix composite special organization structure makes its weldability also become special, and matrix and the greatest differences of wild phase physics, chemical property make it be connected technology to be difficult to control.Based on the analysis of front, though transient liquid phase weldering and soldering obviously are better than melting.But can't satisfy the needs of the extensive development of aluminum matrix composite owing to their limitation.On the contrary, the productivity ratio height, the melting that technology is comparatively easy is difficult to obtain the result of satisfaction owing to its metallurgical problems.For this reason, further develop welding material and welding procedure and remain an arduousness and important task.
In the aluminum matrix composite welding process, if wild phase can be from mother metal to the weld seam transition, just easier realization seam organization is consistent with the mother metal tissue.But, adopt the conventional scolder of filling, realize that this transition is very difficult, promptly allow to realize transition, its control procedure is also quite difficult, welds as transient liquid phase.In the preferred solder matrix, mix wild phase, promptly adopt the composite solder of band wild phase just may realize this purpose.For the aluminum matrix composite of high-volume fractional, adopt the composite solder that contains wild phase more to seem very necessary especially for the uniformity that guarantees seam organization and mother metal.Therefore, the exploitation good fluidity, wetability is good, can suppress disadvantageous metallurgical reaction, and the compound special-purpose packing material of strengthen welds is an important field of research comprising special scolder.
Develop new technologies such as transition liquid phase diffusion weld and eutectic diffusion brazing at process aspect from reduction welding temperature, raising joint bond strength; especially; if can assist special process to realize that the diffusion of aluminum matrix composite liquid phase connects under argon shield or the atmospheric environment; improve the distribution of wild phase in the weld seam simultaneously, will step a more significant step for the practicability of this kind material.
Advantage that this method is main and the performance indications that reach are:
(1) this method can realize the welding of aluminum matrix composite under atmospheric environment or under the inert gas shielding environment, and face of weld need not special cleaning, need not to use brazing flux, and the welding flexibility is stronger, and engineering significance is comparatively desirable.
(2) welding temperature can be controlled in below harmful chemical reaction temperature of wild phase and matrix, prevents that the interfacial reaction of the two from causing joint performance to reduce.
(3) vibration that applies can make liquid solder pass through to impact, rub, and the realization physical process is thoroughly removed oxide-film, and wetability is enhanced, and has solved the problem that is difficult to remove such as oxide-film in soldering, the diffusion welding (DW).
Weld seam does not have the problem of wild phase when (4) adopting the composite solder of band wild phase to solve to adopt conventional no wild phase scolder, and the welding line structure that requirement is determined according to serviceability can easier be realized from the composite solder of selecting coupling, external energy-the oscillator field that applies simultaneously effectively in homogenising when welding liquid phase layer wild phase distribute, it is poly-to avoid strengthening skew, and improve wild phase and weld seam matrix alloy microcosmic combination interface, improve joint performance greatly.
(5) composite solder self of band wild phase has higher intensity, and welding process need not to shorten the setting time of the weld seam of knowing clearly as for a long time isothermal homogenising and process of setting in the methods such as diffusion welding (DW), transient liquid phase weldering, refinement seam organization.
(6) the property of welded joint index of non-continuous reinforced aluminium-based composite material:
Joint tensile strength: 〉=80%
Joint thermal coefficient of expansion: suitable with mother metal
Joint percentage elongation: 〉=1%.
(4) description of drawings
Accompanying drawing is discontinuous reinforced aluminum matrix composites composite solder Vibration Liquid Phase welding process schematic diagram.
(5) specific embodiment
For example the present invention is done in more detail below and describes:
Earlier with 400# sand papering non-continuous reinforced aluminium-based composite material, and in acetone, carry out ultrasonic wave and clean, after non-continuous reinforced aluminium-based composite material 1 after to be cleaned dries, it is installed on the jig 2 with the banjo fixing butt jointing form, and composite solder 3 is placed between the two non-continuous reinforced aluminium-based composite material to be welded surfaces, by heater 4, heating is fully melted composite solder, the heating-up temperature scope is 380~620 ℃, and by thermocouple 5 controls, keep welding temperature, Vibration on Start-up device and apply precompression, one of following dual mode is adopted in vibration: with frequency is 50~4000Hz, amplitude is the low-frequency vibration of 0~1.5mm, time of vibration is 0.1~5 minute, vibrating after-applied pressure limit is 0.25~10Mpa; Or frequency is that 15~60KHz, amplitude are that supersonic frequency vibration, the time of vibration of 5~50 μ m is that 0.1~30s, the after-applied pressure limit of vibration are 0.25~10MPa, treat that vibration arrives after the Preset Time, stop vibration, while intensified pressure to 0.25~10Mpa, and maintenance steady state value, insulation is no more than 10 minutes, after the end non-continuous reinforced aluminium-based composite material joint is cooled off.
The wild phase of the non-continuous reinforced aluminium-based composite material that is welded can be Al 2O 3, SiC short fiber (volume fraction is 2~25%); SiC, Mg 2B 2O 5(antifungin), Al 18B 4O 33(aluminium borate) whisker (volume fraction is 5~40%); SiC, Al 2O 3, TiC, TiB 2, AlN, TiN, ZrO 2A kind of in the particle (particle mean size 0.01~50 μ m, volume fraction 5~70%).Its matrix can be an industrial pure Al and aluminium alloy system, is a kind of in the alloy as Al-Cu system, Al-Mn system, Al-Si system, Al-Si-Cu system, Al-Si-Mg system, Al-Mg system, Al-Mg-Si system, Al-Zn-Mg.
Used composite solder can be Al 2O 3, SiC short fiber (volume fraction is 2~15%); SiC, Mg 2B 2O 5(antifungin), Al 18B 4O 33(aluminium borate) whisker (volume fraction is 5~20%); SiC, Al 2O 3, TiC, TiB 2, AlN, TiN, ZrO 2A kind of wild phase and Zn parent metal Zn-Al-Cu (Cu:3.22% in the particle (particle mean size 0.01~50 μ m, volume fraction 5~30%), Mg:0.82%, Mn:0.91%, Fe:0.01%, Si:0.81%, Zn:89.3%, Ni:0.05%, Al:4.2%, surplus is an impurity), PTZn95Al, PTZn90Al, PTZn70Al, Zn72.5Al, Zn60Cd, Zn58SnCu or aluminium base scolder HLAlSi10, HLAlSi12, HLAlSiCu10, Al12SiSrLa, HL403, HL401, B62, Al60GeSi, HlAlSiMg7.5-1.5, a kind of being composited among HLAlSiMg10-1.5 or the HLAlSiMg12-1.5.Composite solder can be bar-shaped, sheet and graininess.Its filling mode can be to be positioned between two welding surfaces when being coated on welding surface or welding in advance.
Described welding point form can be the form of butt joint, overlap joint, tube sheet joint, T junction.
Used mode of heating can be flame heat, high-frequency induction heating, resistance heated, and the welding temperature scope is 380~620 ℃, and temperature retention time is for being no more than 10 minutes, and the precompression scope is 0~0.5MPa.
Used vibration mode can be low-frequency vibration (frequency 50~4000Hz, amplitude is 0~1.5mm, time of vibration is 0~5 minute, vibrating after-applied pressure limit and be 0.25~10MPa) also can be supersonic frequency vibration (frequency 15~60KHz, amplitude is 5~50 μ m, the ultrasonic vibration time is 0.1~30s, and vibrating after-applied pressure limit is 0.25~10MPa).Vibration can apply from top test specimen or below test specimen.
After the welding, the type of cooling of test specimen can be air cooling, water-cooled or cooling naturally.

Claims (2)

1. fill composite solder non-continuous reinforced aluminium-based composite material Vibration Liquid Phase welding method for one kind, it is characterized in that: the wild phase of the non-continuous reinforced aluminium-based composite material of selection is that the volume ratio that accounts for total amount is the Al of 2-25% 2O 3Or SiC short fiber, or the SiC of 5-40%, Mg 2B 2O 5Or Al 18B 4O 33Whisker, or the particle mean size of 5-70% is SiC, the Al of 0.01-50 μ m 2O 3, TiC, TiB 2, AlN, TiN or ZrO 2Particle, or in 1: 1 mixture of the whisker of 4-40% and particle, the matrix of non-continuous reinforced aluminium-based composite material is a kind of in industrial pure Al or Al-Cu system, Al-Mn system, Al-Si system, Al-Si-Cu system, Al-Si-Mg system, Al-Mg system, Al-Mg-Si system, the Al-Zn-Mg line aluminium alloy; Earlier with 400# sand papering non-continuous reinforced aluminium-based composite material welding surface, and in acetone, carry out ultrasonic wave and clean, after non-continuous reinforced aluminium-based composite material after to be cleaned dries, it is installed on the jig with the banjo fixing butt jointing form, and composite solder is placed between the two non-continuous reinforced aluminium-based composite material to be welded surfaces, used composite solder is that volume ratio is the Al of 2-15% 2O 3Or SiC short fiber, or the SiC of 5-20%, Mg 2B 2O 5Or Al 18B 4O 33Whisker, or the particle mean size of 5-30% is SiC, the Al of 0.01~50 μ m 2O 3, TiC, TiB 2, AlN, TiN or ZrO 2Particle, or or 1: 1 mixture of the whisker of 4-20% and particle in a kind of Zn parent metal or aluminium base scolder for wild phase and surplus be composited, heating is fully melted composite solder, the heating-up temperature scope is 380~620 ℃, and control by thermocouple, keep welding temperature, temperature retention time is for being no more than 10 minutes, Vibration on Start-up device and apply precompression, one of following dual mode is adopted in vibration: with frequency is 50~4000Hz, amplitude is the low-frequency vibration of 0~1.5mm, time of vibration is 0.1~5 minute, vibrating after-applied pressure limit is 0.25~10Mpa; Or frequency is that 15~60KHz, amplitude are that supersonic frequency vibration, the time of vibration of 5~50 μ m is that 0.1~30s, the after-applied pressure limit of vibration are 0.25~10MPa, and maintenance steady state value, insulation is no more than 10 minutes, after the end non-continuous reinforced aluminium-based composite material joint is cooled off.
2. filling composite solder non-continuous reinforced aluminium-based composite material Vibration Liquid Phase welding method according to claim 1, it is characterized in that: described Zn parent metal is the Zn-Al-Cu that impurity is formed by Cu:3.22wt%, Mg:0.82wt%, Mn:0.91wt%, Fe:0.01wt%, Si:0.81wt%, Zn:89.3wt%, Ni:0.05wt%, Al:4.2wt%, surplus, PTZn95Al, PTZn90Al, PTZn70Al, Zn72.5Al, a kind of among Zn60Cd or the Zn58SnCu; Described aluminium base scolder is a kind of among HLAlSi10, HLAlSi12, HLAlSiCu10, Al12SiSrLa, HL403, HL401, B62, Al60GeSi, HlAlSiMg7.5-1.5, HLAlSiMg10-1.5 or the HLAlSiMg12-1.5.
CNB2005101313555A 2005-12-30 2005-12-30 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material Expired - Fee Related CN100363137C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005101313555A CN100363137C (en) 2005-12-30 2005-12-30 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005101313555A CN100363137C (en) 2005-12-30 2005-12-30 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material

Publications (2)

Publication Number Publication Date
CN1792531A CN1792531A (en) 2006-06-28
CN100363137C true CN100363137C (en) 2008-01-23

Family

ID=36804288

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005101313555A Expired - Fee Related CN100363137C (en) 2005-12-30 2005-12-30 Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material

Country Status (1)

Country Link
CN (1) CN100363137C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101623786B (en) * 2008-07-10 2012-07-11 株式会社日立制作所 Soldering method and soldering apparatus
EP4108370A1 (en) * 2021-06-22 2022-12-28 Hilti Aktiengesellschaft Joining method and hammer drilling tool

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102151930B (en) * 2011-03-18 2013-04-10 哈尔滨工业大学深圳研究生院 Dissimilar metal material brazing method
CN102266994B (en) * 2011-07-20 2013-04-24 重庆理工大学 Heterogeneous semi-solid brazing method for aluminum alloy and magnesium alloy under assistance of external vibration energy
CN102501006B (en) * 2011-10-26 2013-07-31 西安交通大学 Method for manufacturing shape memory alloy-aluminum metal matrix composite material through ultrasonic welding
JP5915198B2 (en) * 2012-01-19 2016-05-11 日本軽金属株式会社 Surface brazing method of aluminum alloy member and copper alloy member
CN102581414A (en) * 2012-03-16 2012-07-18 李明雨 Method for brazing copper aluminum tubes without aid of brazing flux
CN102658411B (en) * 2012-05-24 2013-12-25 哈尔滨工业大学 Ultrasonic brazing method for high-volume-fraction silicon carbide particle enhanced aluminum-base composite and low-expansion alloy
CN103203510B (en) * 2013-03-18 2015-06-17 河南科技大学 Brazing experimental device and method assisted by supersonic vibration and electric fields
CN103924115B (en) * 2014-03-26 2016-02-24 南昌大学 A kind of nano aluminum nitride strengthens the preparation method of magnesium base composite material
KR20180043282A (en) * 2015-07-24 2018-04-27 노스이스턴 유니버시티 Low Temperature Welding Using Nano Rods and Process Alloys with Spacings
CN105269105A (en) * 2015-12-03 2016-01-27 天津理工大学 High-silicon aluminum alloy welding method for forming particle-reinforced weld joints through thermo-acoustic coupling
CN105598571A (en) * 2016-01-21 2016-05-25 常熟理工学院 Method for connecting TiB2/ZL115 aluminum matrix composites through TiB2 particles
CN105618885B (en) * 2016-03-25 2019-01-18 浙江邦驰汽车零部件有限公司 A method of reinforced phase is formed by regulation and strengthens composite weld structural material
CN106270872A (en) * 2016-08-31 2017-01-04 郑州机械研究所 A kind of vacuum induction composite brazing method
CN108115308B (en) * 2018-01-03 2020-06-19 重庆大学 Al (aluminum)18B4O33Whisker reinforced silver-copper composite solder and preparation method thereof
CN108754358B (en) * 2018-05-29 2020-03-17 江苏理工学院 Low-temperature-resistant aluminum alloy composite material and preparation method thereof
CN109623072B (en) * 2018-11-26 2020-12-25 国宏中晶集团有限公司 Special tool and method for ultrasonic brazing of sapphire
CN109365986B (en) * 2018-12-14 2020-10-27 东莞市新玛博创超声波科技有限公司 Welding method of 40% silicon carbide particle reinforced aluminum matrix composite material with pure Zn as intermediate reaction material layer
CN109483040A (en) * 2018-12-14 2019-03-19 东莞市新玛博创超声波科技有限公司 A kind of welding method of 55% enhancing aluminum-base composite material by silicon carbide particles of pure Zn as intermediate reaction material layer
CN109365985B (en) * 2018-12-14 2020-10-27 东莞市新玛博创超声波科技有限公司 Ultrasonic auxiliary welding method of silicon carbide particle reinforced aluminum matrix composite material with pure Zn as intermediate reaction material layer
CN111112874A (en) * 2019-12-31 2020-05-08 上海交通大学 ZrB-containing material2Aluminum alloy welding wire with AlN mixed particles and preparation method thereof
CN112338346B (en) * 2020-10-29 2022-11-04 河海大学常州校区 Method for connecting sapphire by adopting transient liquid phase diffusion welding
CN114672699A (en) * 2022-03-22 2022-06-28 山东金马汽车装备科技有限公司 High-strength high-plasticity aluminum-based composite material and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1644291A (en) * 2005-01-19 2005-07-27 哈尔滨工业大学 Aluminium base composite material ultrasonic wave fine welding method
CN1224492C (en) * 2003-02-27 2005-10-26 哈尔滨工业大学 High efficiency aluminium base composite material liquid phase vibrating welding method
CN1686659A (en) * 2005-04-29 2005-10-26 哈尔滨工业大学 Aluminium base composite material ultra sonic electrical resistance welding method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1224492C (en) * 2003-02-27 2005-10-26 哈尔滨工业大学 High efficiency aluminium base composite material liquid phase vibrating welding method
CN1644291A (en) * 2005-01-19 2005-07-27 哈尔滨工业大学 Aluminium base composite material ultrasonic wave fine welding method
CN1686659A (en) * 2005-04-29 2005-10-26 哈尔滨工业大学 Aluminium base composite material ultra sonic electrical resistance welding method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SiC颗粒增强铝基复合材料的焊接. 任德亮等.焊接技术,第3期. 1999 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101623786B (en) * 2008-07-10 2012-07-11 株式会社日立制作所 Soldering method and soldering apparatus
EP4108370A1 (en) * 2021-06-22 2022-12-28 Hilti Aktiengesellschaft Joining method and hammer drilling tool

Also Published As

Publication number Publication date
CN1792531A (en) 2006-06-28

Similar Documents

Publication Publication Date Title
CN100363137C (en) Filling composite welding flux vibrating liquid phase welding method for non-continuous strengthening aluminium base composite material
Li et al. Effect of groove shape on laser welding-brazing Al to steel
CN1326658C (en) Aluminium base composite material ultrasonic wave fine welding method
CN100493795C (en) Process of obtaining composite brazed seam with ultrasonic brazed aluminium-base composite material
CN100408243C (en) Aluminum alloy and its composite material non-vacuum semi-solid state vibration-rheological connection method
Sierra et al. Steel to aluminium braze welding by laser process with Al–12Si filler wire
Li et al. Special brazing and soldering
CN1686659A (en) Aluminium base composite material ultra sonic electrical resistance welding method
Wang et al. Rapid ultrasound-induced transient-liquid-phase bonding of Al-50Si alloys with Zn interlayer in air for electrical packaging application
CN101434014B (en) Flux suitable for arc welding-brazing of dissimilar metals between aluminium alloy and stainless steel
CN102266994B (en) Heterogeneous semi-solid brazing method for aluminum alloy and magnesium alloy under assistance of external vibration energy
CN111872598A (en) Aluminum alloy welding wire
CN101745709A (en) Assistant coating TIG fusing-brazing method suitable for aluminum/steel dissimilar alloy butting
CN107931840B (en) Laser-induced monotectic and homogeneous reaction welding method for titanium-nickel heterojunction
CN106001967A (en) Butt welding method for double-layer metal composite boards
CN101890561A (en) Method for improving aluminum alloy MIG welding seam penetration
CN107971650A (en) A kind of automobile-used steel-aluminium bonded lap joints welding method and system
Li et al. Recent development of ultrasonic brazing
Jia et al. Mechanism of ultrasonic-assisted transient liquid phase bonding of 6061 Al alloy with cladded Zn-Al alloy in air
Kaushik et al. Al-steel dissimilar joining: Challenges and opportunities
CN105618885B (en) A method of reinforced phase is formed by regulation and strengthens composite weld structural material
US20090020589A1 (en) Ultrasonic brazing of aluminum alloy and aluminum matrix composite
CN1224492C (en) High efficiency aluminium base composite material liquid phase vibrating welding method
CN105269105A (en) High-silicon aluminum alloy welding method for forming particle-reinforced weld joints through thermo-acoustic coupling
CN104646850A (en) Al-Cu-Mg-Ti quaternary active solder for high-volume-fraction cast aluminum-based composite material, and preparation method for Al-Cu-Mg-Ti quaternary active solder

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee