CN100339449C - 处理镀有铝锌合金钢板的水性树脂组合物、其涂覆方法和镀有铝锌合金的钢板 - Google Patents
处理镀有铝锌合金钢板的水性树脂组合物、其涂覆方法和镀有铝锌合金的钢板 Download PDFInfo
- Publication number
- CN100339449C CN100339449C CNB2003101130663A CN200310113066A CN100339449C CN 100339449 C CN100339449 C CN 100339449C CN B2003101130663 A CNB2003101130663 A CN B2003101130663A CN 200310113066 A CN200310113066 A CN 200310113066A CN 100339449 C CN100339449 C CN 100339449C
- Authority
- CN
- China
- Prior art keywords
- steel plate
- zinc alloy
- water
- aluminum
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 121
- 239000010959 steel Substances 0.000 title claims abstract description 121
- 229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 104
- 238000000576 coating method Methods 0.000 title claims abstract description 81
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000011342 resin composition Substances 0.000 title claims description 63
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 title description 4
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000011248 coating agent Substances 0.000 claims abstract description 79
- 125000000129 anionic group Chemical group 0.000 claims abstract description 41
- 229920002635 polyurethane Polymers 0.000 claims abstract description 37
- 239000004814 polyurethane Substances 0.000 claims abstract description 37
- 150000003755 zirconium compounds Chemical class 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 19
- 239000007787 solid Substances 0.000 claims description 49
- 239000000463 material Substances 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- 238000001035 drying Methods 0.000 claims description 14
- 230000007704 transition Effects 0.000 claims description 8
- WRAGBEWQGHCDDU-UHFFFAOYSA-M C([O-])([O-])=O.[NH4+].[Zr+] Chemical compound C([O-])([O-])=O.[NH4+].[Zr+] WRAGBEWQGHCDDU-UHFFFAOYSA-M 0.000 claims description 6
- 239000000203 mixture Substances 0.000 abstract description 14
- 238000003860 storage Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 239000013035 waterborne resin Substances 0.000 abstract 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 230000003628 erosive effect Effects 0.000 description 48
- -1 isocyanic acid terephthaldehyde esters Chemical class 0.000 description 33
- 239000001993 wax Substances 0.000 description 25
- 238000012545 processing Methods 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 23
- 238000012360 testing method Methods 0.000 description 21
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 14
- 239000002585 base Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 11
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 7
- 150000001718 carbodiimides Chemical class 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 229910052757 nitrogen Chemical group 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 6
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 125000004069 aziridinyl group Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 229920001515 polyalkylene glycol Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000005246 galvanizing Methods 0.000 description 3
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 235000012976 tarts Nutrition 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- JLZVTZOKUJLPGY-UHFFFAOYSA-K [O-]C(CC(CC([O-])=O)(C([O-])=O)O)=O.N.[Zr+4] Chemical compound [O-]C(CC(CC([O-])=O)(C([O-])=O)O)=O.N.[Zr+4] JLZVTZOKUJLPGY-UHFFFAOYSA-K 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000008397 galvanized steel Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002605 large molecules Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical compound CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- DOYKFSOCSXVQAN-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CCO[Si](C)(OCC)CCCOC(=O)C(C)=C DOYKFSOCSXVQAN-UHFFFAOYSA-N 0.000 description 1
- AHYFYQKMYMKPKD-UHFFFAOYSA-N 3-ethoxysilylpropan-1-amine Chemical compound CCO[SiH2]CCCN AHYFYQKMYMKPKD-UHFFFAOYSA-N 0.000 description 1
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- SVIGLHWGKWJUIO-UHFFFAOYSA-N P.CC1NC1 Chemical compound P.CC1NC1 SVIGLHWGKWJUIO-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Chemical group 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- GAURFLBIDLSLQU-UHFFFAOYSA-N diethoxy(methyl)silicon Chemical compound CCO[Si](C)OCC GAURFLBIDLSLQU-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005968 oxazolinyl group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Description
用于处理镀有铝-锌合金的钢板的水性树脂组合物(固体物质) | 经干燥的薄膜的厚度(μm) | 干燥温度(℃) | |||||||||||||||
阴离子型的水分散性的聚氨酯 | 硅烷偶联剂 | 锆化合 | 交联剂 | 蜡 | 组合物的pH | ||||||||||||
种类 | Tg(℃) | 质量份 | 种类 | 质量份 | 种类 | pH | 质量份 | 种类 | 质量份 | 种类 | 平均颗粒直径(μm) | 质量份 | |||||
实施例 | 1 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 |
2 | a2 | 32 | 100 | b1 | 5 | c1 | 8.5 | 5 | - | - | - | - | - | 9.5 | 2.0 | 100 | |
3 | a1 | -10 | 100 | b1/b2=1/1 | 5 | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
4 | a3 | 48 | 100 | b3 | 5 | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
5 | a1 | -10 | 100 | b2 | 0.1 | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
6 | a1 | -10 | 100 | b2 | 10 | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
7 | a1 | -10 | 100 | b2 | 5 | c1 | 8.5 | 0.1 | - | - | - | - | - | 8.0 | 2.0 | 100 | |
8 | a1 | -10 | 100 | b2 | 5 | c1 | 8.5 | 10 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
9 | a1 | -10 | 100 | b1/b3=1/2 | 0.1 | c1 | 8.5 | 0.1 | d1 | 4 | - | - | - | 8.0 | 2.0 | 100 | |
10 | a1 | -10 | 100 | b2/b3=2/1 | 0.1 | c1 | 8.5 | 0.1 | d1 | 0.5 | - | - | - | 8.0 | 2.0 | 120 | |
11 | a1 | -10 | 100 | b3 | 0.1 | c1 | 8.5 | 0.1 | d2 | 20 | - | - | - | 8.0 | 2.0 | 150 | |
12 | a1 | -10 | 100 | b4 | 5 | c1 | 8.5 | 5 | d1 | 4 | e1 | 2.0 | 0.4 | 8.1 | 2.0 | 120 | |
13 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | d1 | 4 | e2 | 0.6 | 1.0 | 8.1 | 2.0 | 120 | |
14 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | d3 | 4 | e1 | 2.0 | 0.1 | 8.1 | 2.0 | 120 | |
15 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | d3 | 4 | e1 | 2.0 | 0.4 | 8.1 | 1.0 | 120 | |
16 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | d1 | 4 | e3 | 3.0 | 0.4 | 8.1 | 3.0 | 80 | |
比较例 | 1 | a4 | 101 | 100 | b1 | 5 | c1 | 8.5 | 5 | - | - | - | - | - | 8.6 | 2.0 | 100 |
2 | a1 | -10 | 100 | b2 | 5 | - | - | - | - | - | - | - | - | 8.0 | 2.0 | 100 | |
3 | a1 | -10 | 100 | - | - | c1 | 8.5 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
4 | a5 | -16 | 100 | b2 | 5 | c2 | 6.2 | 10 | - | - | - | - | - | 6.9 | 2.0 | 100 | |
5 | a1 | -10 | 100 | b1 | 5 | c3 | 10.0 | 5 | - | - | - | - | - | 8.1 | 2.0 | 100 | |
6 | a1 | -10 | 100 | b1 | 5 | c1 | 8.5 | 5 | A | 1.0 | - | - | - | 4.0 | 2.0 | 100 |
耐腐蚀性 | 防止变黑的性能 | 耐气候性能 | 可被加工处理的性能 | 在对涂膜的附着性能 | 储存稳定性 | |||
平坦的部分 | 经加工处理的部分 | |||||||
实施例 | 1 | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ |
2 | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | |
3 | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | |
4 | ◎ | ○ | ○ | ◎ | ○ | ◎ | ◎ | |
5 | ○ | ○ | ○ | ◎ | ○ | ○ | ◎ | |
6 | ○ | ○ | ○ | ◎ | ○ | ◎ | ○ | |
7 | ○ | ○ | ○ | ◎ | ○ | ◎ | ◎ | |
8 | ○ | ○ | ○ | ◎ | ○ | ◎ | ○ | |
9 | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | |
10 | ○ | ○ | ○ | ◎ | ○ | ◎ | ◎ | |
11 | ◎ | ◎ | ◎ | ◎ | ○ | ○ | ◎ | |
12 | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
13 | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
14 | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
15 | ◎ | ◎ | ○ | ○ | ○ | ◎ | ◎ | |
16 | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
比较例 | 1 | ○ | △ | △ | ◎ | ○ | △ | ◎ |
2 | ○ | △ | △ | ○ | ○ | ◎ | ◎ | |
3 | ○ | △ | △ | ○ | ○ | ○ | ◎ | |
4 | △ | × | × | ○ | ○ | ○ | × | |
5 | ○ | △ | △ | ○ | ○ | ○ | △ | |
6 | × | × | × | △ | △ | △ | × |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002377809A JP3865693B2 (ja) | 2002-12-26 | 2002-12-26 | アルミニウム−亜鉛合金メッキ鋼板処理用水性樹脂組成物、被覆方法及びアルミニウム−亜鉛合金メッキ鋼板 |
JP377809/2002 | 2002-12-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1511908A CN1511908A (zh) | 2004-07-14 |
CN100339449C true CN100339449C (zh) | 2007-09-26 |
Family
ID=32463592
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003101130663A Expired - Lifetime CN100339449C (zh) | 2002-12-26 | 2003-12-25 | 处理镀有铝锌合金钢板的水性树脂组合物、其涂覆方法和镀有铝锌合金的钢板 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1433827B1 (zh) |
JP (1) | JP3865693B2 (zh) |
KR (1) | KR20040057919A (zh) |
CN (1) | CN100339449C (zh) |
DE (1) | DE60303660T2 (zh) |
ES (1) | ES2258703T3 (zh) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005070985A1 (en) * | 2004-01-12 | 2005-08-04 | Ecolab Inc. | Polyurethane coating cure enhancement using zirconium carbonate |
US8128998B2 (en) | 2004-01-12 | 2012-03-06 | Ecolab Usa Inc. | Polyurethane coating cure enhancement using ultrafine zinc oxide |
US7655718B2 (en) | 2004-01-12 | 2010-02-02 | Ecolab Inc. | Polyurethane coating cure enhancement using zinc carbonate initiators |
US7527861B2 (en) | 2004-01-12 | 2009-05-05 | Ecolab, Inc. | Jobsite-renewable multilayer floor finish with enhanced hardening rate |
ES2565502T3 (es) | 2004-10-20 | 2016-04-05 | Valspar Sourcing, Inc. | Métodos de recubrimiento de una lata de comida o bebida |
JP2006219512A (ja) * | 2005-02-08 | 2006-08-24 | Daicel Chem Ind Ltd | 金属表面用水分散性樹脂処理剤及び表面処理金属板 |
JP3872493B1 (ja) | 2005-08-17 | 2007-01-24 | 日本パーカライジング株式会社 | 金属材料用水系表面処理剤及び表面被覆金属材料 |
CN101326308B (zh) * | 2005-12-15 | 2010-09-29 | 日本帕卡濑精株式会社 | 金属材料用表面处理剂、表面处理方法及表面处理的金属材料 |
JP4796410B2 (ja) * | 2006-03-08 | 2011-10-19 | 日鉄住金鋼板株式会社 | 表面被覆アルミニウム−亜鉛合金めっき鋼板 |
DE102007011553A1 (de) * | 2007-03-09 | 2008-09-11 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen mit einer wässerigen, Polymere enthaltenden Zusammensetzung, die wässerige Zusammensetzung und Verwendung der beschichteten Substrate |
CN101289741B (zh) * | 2007-04-18 | 2010-05-19 | 宝山钢铁股份有限公司 | 用于电镀锌钢板表面处理的无铬钝化液及其使用方法 |
JP5144660B2 (ja) * | 2007-06-29 | 2013-02-13 | 日本パーカライジング株式会社 | 亜鉛系めっき鋼板用水系表面処理液及び亜鉛系めっき鋼板 |
JP2009107311A (ja) * | 2007-11-01 | 2009-05-21 | Jfe Galvanizing & Coating Co Ltd | 潤滑樹脂が被覆された亜鉛−アルミニウム合金めっき鋼板 |
KR101529339B1 (ko) * | 2008-05-22 | 2015-06-16 | 디아이씨 가부시끼가이샤 | 수성 복합 수지 조성물, 그것을 포함하는 코팅제 및 그것을 사용한 적층체 |
RU2470092C2 (ru) | 2008-10-08 | 2012-12-20 | Ниппон Стил Корпорейшн | Металлический материал, имеющий очень хорошую коррозионную стойкость |
CN101629288B (zh) | 2009-08-21 | 2011-06-22 | 攀钢集团钢铁钒钛股份有限公司 | 热镀铝锌板用钝化处理剂及其制备方法 |
KR101290878B1 (ko) * | 2009-09-11 | 2013-07-29 | 니혼 파커라이징 가부시키가이샤 | 복층 표면 처리 강판에 사용하는 접착층 형성용 조성물 |
JP5349379B2 (ja) * | 2010-03-16 | 2013-11-20 | 日新製鋼株式会社 | 化成処理鋼鈑の製造方法 |
JP5563359B2 (ja) * | 2010-04-26 | 2014-07-30 | 関西ペイント株式会社 | 金属表面処理剤 |
CN102220577B (zh) * | 2011-06-29 | 2013-09-04 | 安徽工业大学 | 一种用于镀锌板彩涂预处理的有机无机复合水性表面处理液 |
JP6072569B2 (ja) * | 2012-02-28 | 2017-02-01 | 日鉄住金鋼板株式会社 | 表面被覆アルミニウム含有亜鉛系めっき鋼板 |
JP2012233264A (ja) * | 2012-07-30 | 2012-11-29 | Nisshin Steel Co Ltd | 化成処理鋼板の製造方法 |
CN102898775B (zh) * | 2012-08-28 | 2014-03-26 | 石家庄世易糠醛糠醇有限公司 | 烟囱防腐耐高温用的呋喃树脂材料的制备方法 |
JP6036177B2 (ja) * | 2012-10-31 | 2016-11-30 | 住友大阪セメント株式会社 | 親水性膜と親水性膜コーティング物品及び親水性膜形成用塗布液並びに親水性膜の製造方法 |
CN103254755B (zh) * | 2013-05-27 | 2016-01-27 | 宝山钢铁股份有限公司 | 具有优异耐候性、耐蚀性和耐碱性的热镀铝锌钢板及其制备方法和表面处理剂 |
CN105733430A (zh) * | 2014-12-11 | 2016-07-06 | 宝山钢铁股份有限公司 | 一种热镀铝锌钢板用表面处理剂、热镀铝锌钢板及其制造方法 |
KR101736557B1 (ko) * | 2014-12-26 | 2017-05-17 | 주식회사 포스코 | 내흑변성 및 내식성이 우수한 크롬프리 코팅 조성물 및 표면처리 강판 |
CN106318169A (zh) * | 2015-06-30 | 2017-01-11 | 宝山钢铁股份有限公司 | 一种具有优良弯折加工性的有机复合涂层镀锌钢板 |
CN105038464B (zh) * | 2015-09-10 | 2017-07-14 | 广州慧谷化学有限公司 | 具有优异冲制性的水性高耐腐蚀涂料及制备方法和应用 |
CN105295598A (zh) * | 2015-10-12 | 2016-02-03 | 奎克化学(中国)有限公司 | 不含铬、磷和氟化物的钝化和有机薄膜涂料 |
CN107488847B (zh) * | 2016-06-12 | 2019-10-25 | 宝山钢铁股份有限公司 | 一种表面处理剂、涂覆有该表面处理剂的搪瓷用钢和零件 |
WO2018178108A1 (en) * | 2017-03-30 | 2018-10-04 | Tata Steel Ijmuiden B.V. | Aqueous acidic composition for treating metal surfaces, treating method using this composition and use of treated metal surface |
CN112585187B (zh) * | 2018-08-15 | 2023-02-21 | 科思创知识产权两合公司 | 一种粘着剂及其应用 |
KR102307916B1 (ko) * | 2019-12-05 | 2021-09-30 | 주식회사 포스코 | 우수한 내식성 및 표면색상을 부여하는 삼원계 용융아연합금 도금강판용 표면처리 조성물, 이를 이용하여 표면처리된 삼원계 용융아연합금도금 강판 및 이의 제조방법 |
CN111270230A (zh) * | 2020-02-21 | 2020-06-12 | 攀钢集团攀枝花钢铁研究院有限公司 | 热镀铝锌板环保表面处理液及热镀铝锌钝化板的制备方法 |
CN113522706B (zh) * | 2020-04-16 | 2022-10-21 | 宝山钢铁股份有限公司 | 适于辐射固化型彩板生产工艺的表面处理彩涂基板 |
JP7316020B2 (ja) * | 2020-12-08 | 2023-07-27 | Jfeスチール株式会社 | 表面処理皮膜付き亜鉛系めっき鋼板の製造方法、及び表面処理皮膜付き亜鉛系めっき鋼板 |
CN114289281A (zh) * | 2021-12-02 | 2022-04-08 | 烨辉(中国)科技材料有限公司 | 制备抗黑变的铝锌镁产品的方法和用该方法制得的产品 |
CN115011226A (zh) * | 2022-01-17 | 2022-09-06 | 德锡化学(山东)有限公司 | 一种水溶性低流挂高耐蚀的镀锌及锌合金封闭剂 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001048264A1 (en) * | 1999-12-27 | 2001-07-05 | Henkel Corporation | Composition and process for treating metal surface and resulting article |
CN1308661A (zh) * | 1998-05-01 | 2001-08-15 | 保谷株式会社 | 涂料组合物及其制备方法,和耐划痕塑料透镜 |
-
2002
- 2002-12-26 JP JP2002377809A patent/JP3865693B2/ja not_active Expired - Fee Related
-
2003
- 2003-12-08 KR KR1020030088498A patent/KR20040057919A/ko not_active Application Discontinuation
- 2003-12-24 ES ES03293333T patent/ES2258703T3/es not_active Expired - Lifetime
- 2003-12-24 EP EP03293333A patent/EP1433827B1/en not_active Expired - Fee Related
- 2003-12-24 DE DE60303660T patent/DE60303660T2/de not_active Expired - Lifetime
- 2003-12-25 CN CNB2003101130663A patent/CN100339449C/zh not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1308661A (zh) * | 1998-05-01 | 2001-08-15 | 保谷株式会社 | 涂料组合物及其制备方法,和耐划痕塑料透镜 |
WO2001048264A1 (en) * | 1999-12-27 | 2001-07-05 | Henkel Corporation | Composition and process for treating metal surface and resulting article |
Also Published As
Publication number | Publication date |
---|---|
EP1433827A1 (en) | 2004-06-30 |
JP3865693B2 (ja) | 2007-01-10 |
JP2004204333A (ja) | 2004-07-22 |
CN1511908A (zh) | 2004-07-14 |
ES2258703T3 (es) | 2006-09-01 |
DE60303660D1 (de) | 2006-04-27 |
DE60303660T2 (de) | 2006-09-07 |
KR20040057919A (ko) | 2004-07-02 |
EP1433827B1 (en) | 2006-02-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100339449C (zh) | 处理镀有铝锌合金钢板的水性树脂组合物、其涂覆方法和镀有铝锌合金的钢板 | |
CN1263892C (zh) | 金属表面处理用组合物及经表面处理过的金属材料 | |
EP2034050B1 (en) | Coated steel sheet | |
EP0792908B2 (en) | Precoating of aluminium and stainless steel sheets | |
CN1047782C (zh) | 热固性覆盖组合物 | |
CN100345921C (zh) | 镜用边缘涂料及涂布了该边缘涂料的镜 | |
CN1676318A (zh) | 清漆涂装不锈钢钢板 | |
CN1614089A (zh) | 金属材料表面处理用组合物和处理方法 | |
CN1510164A (zh) | 用于涂覆的预处理方法 | |
CN1743085A (zh) | 表面处理金属板 | |
CN1172996C (zh) | 金属材料用水性表面处理剂及表面处理金属板 | |
CN1353744A (zh) | 使用呈混合物的脲基硅烷和多甲硅烷基官能化硅烷处理金属的方法 | |
CN1345359A (zh) | 能够形成用于成型加工的碱溶性润滑膜基材的涂料组合物及其用途 | |
JP5185911B2 (ja) | 樹脂塗装金属板 | |
CN1250393C (zh) | 表面处理的镀锌系钢板 | |
TWI255225B (en) | Resin-coated metal sheet and manufacturing method thereof | |
CN101153196A (zh) | 金属板一次防锈处理用水性组合物及一次防锈处理金属板 | |
CN1550266A (zh) | 在塑料基材上形成涂膜的方法 | |
JP2009061608A (ja) | ロール成形性に優れた樹脂塗装金属板 | |
JPH10237478A (ja) | 傷付き部耐食性に優れた水系金属表面処理組成物 | |
CN1303421A (zh) | 具有优异的耐腐蚀性和涂布性及低指纹印迹的有机复合涂层金属材料及其制造方法 | |
JP5436481B2 (ja) | 熱交換器及びその製造方法 | |
JPH05117558A (ja) | 有機系コーテイング組成物 | |
CN1597825A (zh) | 干式层压材料用胶粘剂及由该胶粘剂层压的复合塑料薄膜 | |
JP5436482B2 (ja) | 熱交換器及びその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: Osaka Japan Patentee after: NIPPON PAINT HOLDINGS CO.,LTD. Address before: Osaka Patentee before: NIPPON PAINT Co.,Ltd. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20160113 Address after: Tokyo, Japan Patentee after: NIPPON PAINT SURF CHEMICALS CO.,LTD. Address before: Osaka Japan Patentee before: NIPPON PAINT HOLDINGS CO.,LTD. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20180102 Address after: Shanghai City, Pudong New Area Zhuqiao gold smell Road No. 2 10 Patentee after: NIPPON (SHANGHAI) CHEMICAL CO.,LTD. Address before: Tokyo, Japan Patentee before: NIPPON PAINT SURF CHEMICALS CO.,LTD. |
|
TR01 | Transfer of patent right | ||
CX01 | Expiry of patent term |
Granted publication date: 20070926 |
|
CX01 | Expiry of patent term |