CA2784199A1 - Tubular reactor for thermal treatment of biomass - Google Patents

Tubular reactor for thermal treatment of biomass Download PDF

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Publication number
CA2784199A1
CA2784199A1 CA2784199A CA2784199A CA2784199A1 CA 2784199 A1 CA2784199 A1 CA 2784199A1 CA 2784199 A CA2784199 A CA 2784199A CA 2784199 A CA2784199 A CA 2784199A CA 2784199 A1 CA2784199 A1 CA 2784199A1
Authority
CA
Canada
Prior art keywords
reactor
tubular reactor
chamber
drum
tubular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2784199A
Other languages
French (fr)
Other versions
CA2784199C (en
Inventor
Klaus Trattner
Heinrich Pauli
Wolfgang Plienegger
Wolfgang Janisch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Global Intelligent Fuel AB
Original Assignee
Andritz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Andritz AG filed Critical Andritz AG
Publication of CA2784199A1 publication Critical patent/CA2784199A1/en
Application granted granted Critical
Publication of CA2784199C publication Critical patent/CA2784199C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/08Rotary-drum furnaces, i.e. horizontal or slightly inclined externally heated
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/02Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles
    • F26B11/04Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis
    • F26B11/0404Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis with internal subdivision of the drum, e.g. for subdividing or recycling the material to be dried
    • F26B11/0409Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis with internal subdivision of the drum, e.g. for subdividing or recycling the material to be dried the subdivision consisting of a plurality of substantially radially oriented internal walls, e.g. forming multiple sector-shaped chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/02Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles
    • F26B11/04Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis
    • F26B11/0445Machines or apparatus for drying solid materials or objects with movement which is non-progressive in moving drums or other mainly-closed receptacles rotating about a horizontal or slightly-inclined axis having conductive heating arrangements, e.g. heated drum wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B23/00Heating arrangements
    • F26B23/10Heating arrangements using tubes or passages containing heated fluids, e.g. acting as radiative elements; Closed-loop systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/18Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact
    • F26B3/22Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact the heat source and the materials or objects to be dried being in relative motion, e.g. of vibration
    • F26B3/24Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact the heat source and the materials or objects to be dried being in relative motion, e.g. of vibration the movement being rotation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/14Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge
    • F27B7/16Rotary-drum furnaces, i.e. horizontal or slightly inclined with means for agitating or moving the charge the means being fixed relatively to the drum, e.g. composite means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B2200/00Drying processes and machines for solid materials characterised by the specific requirements of the drying good
    • F26B2200/02Biomass, e.g. waste vegetative matter, straw
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B25/00Details of general application not covered by group F26B21/00 or F26B23/00
    • F26B25/06Chambers, containers, or receptacles
    • F26B25/14Chambers, containers, receptacles of simple construction
    • F26B25/16Chambers, containers, receptacles of simple construction mainly closed, e.g. drum
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Abstract

The invention relates to a tubular reactor with a rotating reactor chamber (9) for thermal treatment of biomass. It is characterized by the reactor chamber (9) being subdivided into zones by means of ring-shaped plates (10). These zones cause the particles to be retained in a particular area and thoroughly mixed there, i.e. the particles being treated are homogenized and the retention time also becomes more homogenous.

Description

Tubular Reactor For Thermal Treatment Of Biomass The invention relates to a tubular reactor with a rotating reactor chamber for thermal treatment of biomass.

Reactors of this kind are also known as heated drum reactors. In addition to controlling and checking the process temperature in thermal treatment of biomass, e.g. torrefaction, it is also necessary to control the retention time in the tubular reactor in order to ensure uniform treatment. The retention time distribution should be as narrow as possible in order to obtain a product that is as uniform as possible. In the tubular reactors known, however, the spectrum of retention times, depending on length and speed, is very broad.

The aim of the invention is, therefore, to provide a drum or tubular reactor that delivers a product that is as uniform as possible.

According to the invention, this is achieved by the reactor chamber being subdivided into zones by means of ring-shaped plates. These zones cause the particles to be retained in a particular area and thoroughly mixed there, i.e.
the particles being treated are homogenized. Material (particles) cannot pass into the next chamber or be discharged at the end of the reactor until their height reaches the inner circumference of the ring-shaped plate.

An advantageous further embodiment of the invention is characterized by a conveying tool being secured to at least one plate, where the conveying tool can be mechanically adjustable. As a result, the material is conveyed evenly into the next chamber according to the reactor speed, thus the distribution of retention times for all particles in the chamber becomes more homogenous.

If conveying tools for different directions of rotation are provided on at least one plate, these tools either convey material or convey no material, depending on the direction of rotation. In this way, the reactor can be emptied more quickly by changing the direction of rotation. This also prevents caking and/or overheating of the particles when the reactor is shut down.

A favourable further embodiment of the invention is characterized by a conveying spiral being provided on the shell of the reactor's inner drum. With a conveying spiral of this kind, preferably with a low height, it is possible to empty the reactor completely. If rotated in the opposite direction to the operating direction of rotation of the reactor, this spiral also contributes additional mixing within a zone.

A favourable embodiment of the invention is characterized by heating tubes being arranged in longitudinal (axial) direction in the reactor chamber, where the heating tubes can be arranged in several circular rows, preferably two circular rows, on the reactor's inner drum shell. A heating medium, e.g. flue gas, is fed through these tubes, ensuring on the one hand that the particles are heated evenly and, on the other hand, that they are also well homogenized.

If the rotating reactor chamber is enclosed in an outer reactor drum and an annular gap is provided between the rotating reactor chamber and the outer reactor drum, where the outer reactor drum can rotate together with the reactor chamber, the particles can be heated even better with a large transfer surface area.

In the following, the invention is exemplified on the basis of the drawings, where Fig. 1 shows a 3D view of a tubular reactor according to the invention, Fig. 2 shows a schematic view of a tubular reactor according to the invention, and Fig. 3 shows a section through the line marked III-III in Fig. 2.

Figure 1 shows a tubular reactor according to the invention. It is designed as an indirectly heated drum reactor 1. The biomass to be treated, e.g. wood chips, is fed through an inlet flange 2 to a heated feed screw 3, which conveys it into the rotating reactor chamber (not shown here). The heating medium - in this case flue gas - is introduced into the reactor chamber and into the gap
2 between the reactor chamber and the reactor's outer drum 6 through the connection 4 at a temperature of approximately 360 - 450 C. Rotary valves are used before and after the reactor 1 and the cooling screw conveyor, respectively, as seal against the atmosphere.

The cooled heating medium - in this case flue gas - then leaves the drum reactor 1 through the connection 7 at an approximate temperature of 280 -300 C. The gas generated by thermal treatment is discharged at the connecting piece 8. If the reactor is used for torrefaction, the torrefaction gas is discharged here.

Figure 2 now shows the tubular reactor design according to the invention in a schematic diagram that is used to help describe its mode of operation. The reactor chamber 9 of the drum reactor 1 is divided into several zones by ring-shaped zone plates 10 in order to keep mixing in axial direction to a minimum.
In the reactor chamber 9, heat is applied to the input material by means of the inner reactor drum 11 and the heating tubes 12, both of which are heated by flue gas. The process temperature here is approximately 280 - 300 C. The individual zone plates 10 are fitted with at least one conveying tool 13 on each zone plate 10. The conveying tools 13 transport more or less material over the zone plates 10 towards the reactor outlet 15 depending on the reactor speed and design. The speed here ranges between approximately 8 and 20 rpm.

The conveying tools 13 are specially shaped either to convey material or not convey material, depending on the direction of rotation. In addition, conveying tools 13', preferably several, are provided, which only convey material when rotating in the opposite direction to the operating direction of rotation of the reactor. These can be used to accelerate emptying of the reactor by changing the direction of rotation, thus there can be no caking and also no overheating of the material. This also prevents any outbreak of fire.

In addition to the conveying tools 13, 13', a conveying spiral 14 of low height is mounted, making it possible to empty the reactor completely when rotating in one direction. If it is rotated in the opposite direction, the spiral provides additional mixing within a zone. A certain filling level according to the conveying
3 capacity of the conveying tools 13 is the result. The retention time of the material in the tubular reactor is approximately 20 to 40 minutes.

At the reactor outlet 15, there is a conical tube section 16 attached through which material is conveyed towards the cooling screw 17 independently of the speed.

In the cooling screw 17, very finely atomized water is sprayed onto the hot product through a nozzle system 18 comprising several nozzles. The water volume is controlled by switching single nozzles on and off. A temperature measurement at the screw shell is used as command variable. The water vapour forming is removed through the connection 8 together with the torrefaction gas or through an additional connection 19.

Figure 3 shows a sectional view along the line marked III-III in Fig. 2 looking towards the reactor inlet. The zone plate 10 and the heating tubes 12 are visible, arranged in this example in two rows, but they can also be arranged in one or several rows. Between the reactor's inner drum shell 11 and outer reactor drum 6 there is a ring-shaped chamber 20 through which flue gas, for example, is directed. As a result, the reactor's inner drum shell 11 heats up, thus enlarging the heat transfer surface area. The conveying tool 13 that conveys the material in the direction of the reactor outlet 15 when rotating in the operating direction of rotation 21 of the reactor is also visible. It would be possible, however, to include several such conveying tools. For rapid emptying, the direction of rotation is reversed and the conveying tools 13' (this figure shows three) convey the material out of the respective zone rapidly and completely. Several conveying tools may also be provided here, however the number of conveying tools 13' for emptying must always be (much) larger than the number of conveying tools 13 to control the retention time in normal operation.
4

Claims (9)

Claims
1. Tubular reactor with a rotating reactor chamber (9) for thermal treatment of biomass, characterized by the reactor chamber (9) being subdivided into zones by means of ring-shaped plates (10)
2. Tubular reactor according to Claim 1, characterized by a conveying tool (13, 13') being secured to at least one plate (10).
3. Tubular reactor according to Claim 2, characterized by the conveying tool (13, 13') being mechanically adjustable.
4. Tubular reactor according to one of Claims 2 or 3, characterized by conveying tools (13, 13') for different directions of rotation being provided on at least one plate (10).
5. Tubular reactor according to one of Claims 1 to 4, characterized by a conveying spiral (14) being provided on the shell (11) of the reactor's inner drum.
6. Tubular reactor according to one of Claims 1 to 5, characterized by heating tubes (12) being arranged in longitudinal (axial) direction in the reactor chamber (9).
7. Tubular reactor according to Claim 6, characterized by the heating tubes (12) being arranged in several circular rows, preferably two circular rows, on the reactor's inner drum shell (11).
8. Tubular reactor according to one of Claims 1 to 7, characterized by the rotating reactor chamber (9) being enclosed in an outer reactor drum (6) and an annular gap (20) being provided between the rotating reactor chamber (9) and the outer reactor drum (6).
9. Tubular reactor according to Claim 8, characterized by the outer reactor drum (6) rotating together with the reactor chamber (9).
CA2784199A 2011-08-05 2012-07-31 Tubular reactor for thermal treatment of biomass Active CA2784199C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ATA1133/2011 2011-08-05
ATA1133/2011A AT511780B1 (en) 2011-08-05 2011-08-05 PIPE REACTOR FOR THE THERMAL TREATMENT OF BIOMASS

Publications (2)

Publication Number Publication Date
CA2784199A1 true CA2784199A1 (en) 2013-02-05
CA2784199C CA2784199C (en) 2019-11-26

Family

ID=46601674

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2784199A Active CA2784199C (en) 2011-08-05 2012-07-31 Tubular reactor for thermal treatment of biomass

Country Status (10)

Country Link
US (1) US9664445B2 (en)
EP (1) EP2554932B1 (en)
AT (1) AT511780B1 (en)
BR (1) BR102012019673B1 (en)
CA (1) CA2784199C (en)
DK (1) DK2554932T3 (en)
ES (1) ES2549054T3 (en)
PT (1) PT2554932E (en)
RU (1) RU2606762C2 (en)
SI (1) SI2554932T1 (en)

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CN104329917A (en) * 2013-07-22 2015-02-04 太仓市环新生物质燃料有限公司 Wood chip drying machine
WO2015042041A1 (en) * 2013-09-18 2015-03-26 Georgia-Pacific LLC Method for producing organic acids and organic acid degradation compounds from biomass
CN104925470A (en) * 2014-03-18 2015-09-23 沈阳铝镁设计研究院有限公司 Novel structure and use method of spiral feeder
CN105564919B (en) * 2016-01-29 2017-11-07 张海娟 Auger elevator without abrasion
CN108955148A (en) * 2018-07-18 2018-12-07 安徽省兴源草业有限公司 A kind of heating, drying device for stalk
CN109108434B (en) * 2018-10-11 2024-04-16 广西建工集团第一安装工程有限公司 Improved raw sugar dryer roller assembling process and dryer roller
EP3980515A2 (en) 2019-06-07 2022-04-13 Torrgreen B.V. Torrefaction reactor and process
CN110822853B (en) * 2019-11-22 2021-08-03 上海通尊自动化设备有限公司 Automatic processing system of water based paint raw materials
CN111964392B (en) * 2020-08-08 2021-11-30 江苏同正机械制造有限公司 Fly ash drum type dryer adopting natural gas for heating
CN113074540B (en) * 2020-09-18 2023-09-12 南京利卡维智能科技有限公司 Multi-section ceramic furnace tube rapid assembling structure and material progressive method
CN112728891A (en) * 2020-12-30 2021-04-30 安徽省文胜生物工程股份有限公司 Drying device for ecological fertilizer capable of improving amino acid content of tea leaves and using method
CN115654875B (en) * 2022-12-12 2023-04-14 山东天力能源股份有限公司 Self-returning circular pipe split type steam rotary dryer, method and system

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Also Published As

Publication number Publication date
US9664445B2 (en) 2017-05-30
EP2554932A1 (en) 2013-02-06
ES2549054T3 (en) 2015-10-22
RU2606762C2 (en) 2017-01-10
AT511780B1 (en) 2013-11-15
AT511780A1 (en) 2013-02-15
PT2554932E (en) 2015-10-23
DK2554932T3 (en) 2015-10-12
BR102012019673A8 (en) 2017-09-12
RU2012133096A (en) 2014-02-10
BR102012019673B1 (en) 2018-12-26
CA2784199C (en) 2019-11-26
US20130078589A1 (en) 2013-03-28
EP2554932B1 (en) 2015-07-08
SI2554932T1 (en) 2015-11-30
BR102012019673A2 (en) 2013-08-06

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