CA2461872C - Enhanced formulations for neutralization of chemical, biological and industrial toxants - Google Patents

Enhanced formulations for neutralization of chemical, biological and industrial toxants Download PDF

Info

Publication number: CA2461872C
Authority: CA; Canada
Prior art keywords: formulation; water; reactive compound; combination; bleaching activator
Prior art date: 2001-10-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA2461872A

Other languages

English (en)

French (fr)

Other versions

CA2461872A1 (en

Inventor

Mark D. Tucker

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Technology and Engineering Solutions of Sandia LLC

Original Assignee

Sandia Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-10-01

Filing date

2002-09-20

Publication date

2013-11-26

2002-09-20 Application filed by Sandia Corp filed Critical Sandia Corp

2003-04-10 Publication of CA2461872A1 publication Critical patent/CA2461872A1/en

2013-11-26 Application granted granted Critical

2013-11-26 Publication of CA2461872C publication Critical patent/CA2461872C/en

2022-09-20 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 201
238000009472 formulation Methods 0.000 title claims abstract description 175
238000006386 neutralization reaction Methods 0.000 title claims description 20
239000000126 substance Substances 0.000 title abstract description 26
239000012190 activator Substances 0.000 claims abstract description 102
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
229910001868 water Inorganic materials 0.000 claims abstract description 81
238000004061 bleaching Methods 0.000 claims abstract description 79
150000001875 compounds Chemical class 0.000 claims abstract description 77
239000002904 solvent Substances 0.000 claims abstract description 25
230000003381 solubilizing effect Effects 0.000 claims abstract description 15
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 91
UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 claims description 64
229940116423 propylene glycol diacetate Drugs 0.000 claims description 64
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 48
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 42
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 39
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims description 32
239000007787 solid Substances 0.000 claims description 31
239000003093 cationic surfactant Substances 0.000 claims description 29
239000004615 ingredient Substances 0.000 claims description 26
239000011736 potassium bicarbonate Substances 0.000 claims description 26
235000015497 potassium bicarbonate Nutrition 0.000 claims description 26
229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 26
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 26
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 24
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 24
229940045872 sodium percarbonate Drugs 0.000 claims description 24
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 22
229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 20
JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 20
125000002091 cationic group Chemical group 0.000 claims description 19
150000005323 carbonate salts Chemical class 0.000 claims description 16
241000282372 Panthera onca Species 0.000 claims description 14
239000003752 hydrotrope Substances 0.000 claims description 13
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 12
150000002191 fatty alcohols Chemical class 0.000 claims description 12
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 12
KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 11
FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 claims description 11
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 11
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 11
JUGOREOARAHOCO-UHFFFAOYSA-M acetylcholine chloride Chemical compound [Cl-].CC(=O)OCC[N+](C)(C)C JUGOREOARAHOCO-UHFFFAOYSA-M 0.000 claims description 11
229960004266 acetylcholine chloride Drugs 0.000 claims description 11
XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims description 11
229910000027 potassium carbonate Inorganic materials 0.000 claims description 11
235000011181 potassium carbonates Nutrition 0.000 claims description 11
LHZYNHLHHRQGOX-UHFFFAOYSA-N dihydroperoxy carbonate Chemical compound OOOC(=O)OOO LHZYNHLHHRQGOX-UHFFFAOYSA-N 0.000 claims description 10
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
239000001099 ammonium carbonate Substances 0.000 claims description 8
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 8
229960001922 sodium perborate Drugs 0.000 claims description 8
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 8
WODGXFMUOLGZSY-UHFFFAOYSA-J tetrasodium phosphonatooxy phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OOP([O-])([O-])=O WODGXFMUOLGZSY-UHFFFAOYSA-J 0.000 claims description 8
KJFGIEUERFWKMN-UHFFFAOYSA-M tetrasodium trioxido(oxidooxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]O[Si]([O-])([O-])[O-] KJFGIEUERFWKMN-UHFFFAOYSA-M 0.000 claims description 8
229920003169 water-soluble polymer Polymers 0.000 claims description 8
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
239000004353 Polyethylene glycol 8000 Substances 0.000 claims description 6
229960000686 benzalkonium chloride Drugs 0.000 claims description 6
CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 6
229940085678 polyethylene glycol 8000 Drugs 0.000 claims description 6
235000019446 polyethylene glycol 8000 Nutrition 0.000 claims description 6
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 5
239000004094 surface-active agent Substances 0.000 claims description 5
229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 4
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 4
235000012538 ammonium bicarbonate Nutrition 0.000 claims description 4
235000012501 ammonium carbonate Nutrition 0.000 claims description 4
HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
ADCUEPOHPCPMCE-UHFFFAOYSA-N 4-cyanobenzoic acid Chemical compound OC(=O)C1=CC=C(C#N)C=C1 ADCUEPOHPCPMCE-UHFFFAOYSA-N 0.000 claims description 3
229920002594 Polyethylene Glycol 8000 Polymers 0.000 claims description 3
235000013773 glyceryl triacetate Nutrition 0.000 claims description 3
LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
229960002622 triacetin Drugs 0.000 claims description 3
AZUXKVXMJOIAOF-UHFFFAOYSA-N 1-(2-hydroxypropoxy)propan-2-ol Chemical compound CC(O)COCC(C)O AZUXKVXMJOIAOF-UHFFFAOYSA-N 0.000 claims description 2
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 2
229920002907 Guar gum Polymers 0.000 claims description 2
239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 2
229960001950 benzethonium chloride Drugs 0.000 claims description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 2
229960001927 cetylpyridinium chloride Drugs 0.000 claims description 2
150000001805 chlorine compounds Chemical class 0.000 claims description 2
239000000665 guar gum Substances 0.000 claims description 2
229960002154 guar gum Drugs 0.000 claims description 2
235000010417 guar gum Nutrition 0.000 claims description 2
229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 2
229920002401 polyacrylamide Polymers 0.000 claims description 2
229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
150000005217 methyl ethers Chemical class 0.000 claims 1
238000010944 pre-mature reactiony Methods 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 abstract description 44
-1 CW and BW compounds Chemical class 0.000 abstract description 30
231100000331 toxic Toxicity 0.000 abstract description 10
230000002588 toxic effect Effects 0.000 abstract description 10
230000002411 adverse Effects 0.000 abstract description 6
239000003317 industrial substance Substances 0.000 abstract description 6
230000008821 health effect Effects 0.000 abstract description 5
231100000252 nontoxic Toxicity 0.000 abstract description 5
230000003000 nontoxic effect Effects 0.000 abstract description 5
230000009972 noncorrosive effect Effects 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract description 2
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 50
239000006260 foam Substances 0.000 description 47
238000012360 testing method Methods 0.000 description 43
QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 39
239000000243 solution Substances 0.000 description 37
239000013043 chemical agent Substances 0.000 description 34
210000004215 spore Anatomy 0.000 description 31
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 30
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 30
241000219198 Brassica Species 0.000 description 27
235000003351 Brassica cretica Nutrition 0.000 description 27
235000003343 Brassica rupestris Nutrition 0.000 description 27
238000005202 decontamination Methods 0.000 description 27
230000003588 decontaminative effect Effects 0.000 description 27
235000010460 mustard Nutrition 0.000 description 27
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 26
241000193738 Bacillus anthracis Species 0.000 description 25
239000007800 oxidant agent Substances 0.000 description 24
230000001590 oxidative effect Effects 0.000 description 24
238000006243 chemical reaction Methods 0.000 description 22
238000000034 method Methods 0.000 description 22
150000002978 peroxides Chemical class 0.000 description 21
239000002002 slurry Substances 0.000 description 20
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230000007797 corrosion Effects 0.000 description 17
238000005260 corrosion Methods 0.000 description 17
229920000642 polymer Polymers 0.000 description 16
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
239000003112 inhibitor Substances 0.000 description 15
239000007788 liquid Substances 0.000 description 15
235000017557 sodium bicarbonate Nutrition 0.000 description 15
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244000063299 Bacillus subtilis Species 0.000 description 12
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RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 10
239000003599 detergent Substances 0.000 description 10
239000008258 liquid foam Substances 0.000 description 10
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239000003124 biologic agent Substances 0.000 description 8
239000013020 final formulation Substances 0.000 description 8
230000009467 reduction Effects 0.000 description 8
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239000006227 byproduct Substances 0.000 description 7
230000006378 damage Effects 0.000 description 7
239000011929 di(propylene glycol) methyl ether Substances 0.000 description 7
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241000607479 Yersinia pestis Species 0.000 description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 6
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238000001514 detection method Methods 0.000 description 6
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 5
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230000000694 effects Effects 0.000 description 5
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SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
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230000000994 depressogenic effect Effects 0.000 description 4
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235000019443 glyceryl diacetate Nutrition 0.000 description 4
LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
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239000000047 product Substances 0.000 description 4
241000894007 species Species 0.000 description 4
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AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 3
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 3
DYAHQFWOVKZOOW-UHFFFAOYSA-N Sarin Chemical compound CC(C)OP(C)(F)=O DYAHQFWOVKZOOW-UHFFFAOYSA-N 0.000 description 3
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 3
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 3
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150000001298 alcohols Chemical class 0.000 description 3
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KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 3
JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 3
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239000003906 humectant Substances 0.000 description 3
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YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 3
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238000012986 modification Methods 0.000 description 3
229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
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231100000419 toxicity Toxicity 0.000 description 3
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UZJXHJFKUSBWEL-UHFFFAOYSA-N 2,3,3-trimethylbutylphosphonic acid Chemical compound CC(C)(C)C(C)CP(O)(O)=O UZJXHJFKUSBWEL-UHFFFAOYSA-N 0.000 description 2
241000894006 Bacteria Species 0.000 description 2
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XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
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GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
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210000004666 bacterial spore Anatomy 0.000 description 2
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238000011109 contamination Methods 0.000 description 2
239000002537 cosmetic Substances 0.000 description 2
239000006184 cosolvent Substances 0.000 description 2
238000010586 diagram Methods 0.000 description 2
UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 2
239000013505 freshwater Substances 0.000 description 2
229940051250 hexylene glycol Drugs 0.000 description 2
208000015181 infectious disease Diseases 0.000 description 2
HNHVTXYLRVGMHD-UHFFFAOYSA-N n-butyl isocyanate Chemical compound CCCCN=C=O HNHVTXYLRVGMHD-UHFFFAOYSA-N 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
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JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 2
HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
QDXIHHOPZFCEAP-UHFFFAOYSA-N 2-chloroethylsulfanylbenzene Chemical compound ClCCSC1=CC=CC=C1 QDXIHHOPZFCEAP-UHFFFAOYSA-N 0.000 description 1
LTALJGSZILUUQA-UHFFFAOYSA-N 2-nonanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O LTALJGSZILUUQA-UHFFFAOYSA-N 0.000 description 1
108010053481 Antifreeze Proteins Proteins 0.000 description 1
108030001720 Bontoxilysin Proteins 0.000 description 1
241000283690 Bos taurus Species 0.000 description 1
0 C=*C1CCCC1 Chemical compound C=*C1CCCC1 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
BWLUMTFWVZZZND-UHFFFAOYSA-N Dibenzylamine Chemical compound C=1C=CC=CC=1CNCC1=CC=CC=C1 BWLUMTFWVZZZND-UHFFFAOYSA-N 0.000 description 1
239000012028 Fenton's reagent Substances 0.000 description 1
SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
OVRNDRQMDRJTHS-UHFFFAOYSA-N N-acelyl-D-glucosamine Natural products CC(=O)NC1C(O)OC(CO)C(O)C1O OVRNDRQMDRJTHS-UHFFFAOYSA-N 0.000 description 1
OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 1
MBLBDJOUHNCFQT-LXGUWJNJSA-N N-acetylglucosamine Natural products CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
206010035148 Plague Diseases 0.000 description 1
MLHOXUWWKVQEJB-UHFFFAOYSA-N Propyleneglycol diacetate Chemical group CC(=O)OC(C)COC(C)=O MLHOXUWWKVQEJB-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
241000700605 Viruses Species 0.000 description 1
BHIIGRBMZRSDRI-UHFFFAOYSA-N [chloro(phenoxy)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(=O)(Cl)OC1=CC=CC=C1 BHIIGRBMZRSDRI-UHFFFAOYSA-N 0.000 description 1
PJVJTCIRVMBVIA-JTQLQIEISA-N [dimethylamino(ethoxy)phosphoryl]formonitrile Chemical compound CCO[P@@](=O)(C#N)N(C)C PJVJTCIRVMBVIA-JTQLQIEISA-N 0.000 description 1
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
230000009471 action Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
229920006318 anionic polymer Polymers 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
VDEUYMSGMPQMIK-UHFFFAOYSA-N benzhydroxamic acid Chemical compound ONC(=O)C1=CC=CC=C1 VDEUYMSGMPQMIK-UHFFFAOYSA-N 0.000 description 1
230000031018 biological processes and functions Effects 0.000 description 1
229940053031 botulinum toxin Drugs 0.000 description 1
230000003139 buffering effect Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
210000004027 cell Anatomy 0.000 description 1
230000010261 cell growth Effects 0.000 description 1
231100000481 chemical toxicant Toxicity 0.000 description 1
230000001684 chronic effect Effects 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
238000012258 culturing Methods 0.000 description 1
235000013365 dairy product Nutrition 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007123 defense Effects 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000001784 detoxification Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
ZFAKTZXUUNBLEB-UHFFFAOYSA-N dicyclohexylazanium;nitrite Chemical compound [O-]N=O.C1CCCCC1[NH2+]C1CCCCC1 ZFAKTZXUUNBLEB-UHFFFAOYSA-N 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000003974 emollient agent Substances 0.000 description 1
150000002169 ethanolamines Chemical class 0.000 description 1
HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000003889 eye drop Substances 0.000 description 1
239000004872 foam stabilizing agent Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
MGZTXXNFBIUONY-UHFFFAOYSA-N hydrogen peroxide;iron(2+);sulfuric acid Chemical compound [Fe+2].OO.OS(O)(=O)=O MGZTXXNFBIUONY-UHFFFAOYSA-N 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
229920000831 ionic polymer Polymers 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
244000005700 microbiome Species 0.000 description 1
230000000116 mitigating effect Effects 0.000 description 1
229950006780 n-acetylglucosamine Drugs 0.000 description 1
210000005036 nerve Anatomy 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
125000002560 nitrile group Chemical group 0.000 description 1
230000000269 nucleophilic effect Effects 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
239000006174 pH buffer Substances 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000003973 paint Substances 0.000 description 1
FHHJDRFHHWUPDG-UHFFFAOYSA-L peroxysulfate(2-) Chemical compound [O-]OS([O-])(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-L 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
239000002453 shampoo Substances 0.000 description 1
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
229910000342 sodium bisulfate Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
230000009295 sperm incapacitation Effects 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
SPALIFXDWQTXKS-UHFFFAOYSA-M tetrapentylazanium;bromide Chemical compound [Br-].CCCCC[N+](CCCCC)(CCCCC)CCCCC SPALIFXDWQTXKS-UHFFFAOYSA-M 0.000 description 1
239000003440 toxic substance Substances 0.000 description 1
HXJAYEBLPWXZLI-UHFFFAOYSA-M triacetyl(methyl)azanium;bromide Chemical compound [Br-].CC(=O)[N+](C)(C(C)=O)C(C)=O HXJAYEBLPWXZLI-UHFFFAOYSA-M 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/36—Detoxification by using acid or alkaline reagents
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/02—Chemical warfare substances, e.g. cholinesterase inhibitors

Landscapes

Business, Economics & Management (AREA)
General Health & Medical Sciences (AREA)
Toxicology (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Emergency Management (AREA)
Detergent Compositions (AREA)
Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Fire-Extinguishing Compositions (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CA2461872A 2001-10-01 2002-09-20 Enhanced formulations for neutralization of chemical, biological and industrial toxants Expired - Lifetime CA2461872C (en)

Applications Claiming Priority (7)

Application Number	Priority Date	Filing Date	Title
US32650801P	2001-10-01	2001-10-01
US60/326,508		2001-10-01
US33427101P	2001-11-30	2001-11-30
US60/334,271		2001-11-30
US38710402P	2002-06-07	2002-06-07
US60/387,104		2002-06-07
PCT/US2002/029886 WO2003028429A2 (en)	2001-10-01	2002-09-20	Enhanced formulations for neutralization of chemical, biological and industrial toxants

Publications (2)

Publication Number	Publication Date
CA2461872A1 CA2461872A1 (en)	2003-04-10
CA2461872C true CA2461872C (en)	2013-11-26

Family

ID=27406465

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA2461872A Expired - Lifetime CA2461872C (en)	2001-10-01	2002-09-20	Enhanced formulations for neutralization of chemical, biological and industrial toxants

Country Status (12)

Country	Link
EP (1)	EP1434625B1 (ja)
JP (1)	JP4582514B2 (ja)
KR (1)	KR100916328B1 (ja)
CN (1)	CN1612766B (ja)
AU (1)	AU2002341750B2 (ja)
BR (1)	BR0213019B1 (ja)
CA (1)	CA2461872C (ja)
EA (1)	EA009242B1 (ja)
HK (1)	HK1073618A1 (ja)
IL (2)	IL161200A0 (ja)
MX (1)	MXPA04003037A (ja)
WO (1)	WO2003028429A2 (ja)

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EP1928946A2 (en) *	2005-01-11	2008-06-11	Clean Earth Technologies, LLC	Formulations for the decontamination of toxic chemicals
WO2006076334A1 (en) *	2005-01-11	2006-07-20	Clean Earth Technologies, Llc	Peracid/ peroxide composition and use thereof as an anti-microbial and a photosensitizer
US9700644B2 (en)	2006-08-15	2017-07-11	American Sterilizer Company	One part, solids containing decontamination blend composition
US9724550B2 (en)	2006-08-15	2017-08-08	American Sterilizer Company	One part, solids containing decontamination blend composition
US20120141598A1 (en) *	2008-10-08	2012-06-07	Jessie Kater	Broad spectrum decontaminate and dispersement system
US8969283B2 (en) *	2009-02-05	2015-03-03	American Sterilizer Company	Low odor, hard surface sporicides and chemical decontaminants
RU2484868C2 (ru) *	2009-04-24	2013-06-20	Ольга Анатольевна Афанасьевская	Комплексная, безотходная переработка токсичных отходов
US20110177145A1 (en) *	2009-07-27	2011-07-21	E.I. Du Pont De Nemours And Company	In situ preparation of peracid-based removable antimicrobial coating compositions and methods of use
GB201010374D0 (en) *	2010-06-21	2010-08-04	Mtp Innovations Ltd	Disinfectant composition
CA2959052C (en) *	2014-09-09	2023-10-03	Lonza, Inc.	Disinfectant composition containing quaternary ammonium compounds
EA026955B1 (ru) *	2015-03-16	2017-06-30	Общество с ограниченной ответственностью "ФАРМА-ПОКРОВ"	Дезинфицирующая композиция
JP6639099B2 (ja) *	2015-03-24	2020-02-05	花王株式会社	酸化性組成物
EP4011210A1 (en) *	2015-07-17	2022-06-15	Next Science IP Holdings Pty Ltd	Use of an antimicrobial composition having efficacy against endospores
TWI774541B (zh) *	2017-06-15	2022-08-11	美商滌康７號系統股份有限公司	除污配方
US20190077970A1 (en) *	2017-07-17	2019-03-14	Tiax Llc	Neutralization compositions and methods for their use
CN111770981A (zh) *	2018-01-17	2020-10-13	涤康7号***股份公司	表面净化配制物
CN110150279B (zh) *	2019-06-03	2023-08-25	南通思锐生物科技有限公司	一种即时快速生成过氧乙酸消毒剂的配制方法
CN111388935B (zh) *	2020-04-29	2021-10-01	中国人民解放军陆军防化学院	一种耐低温泡沫洗消剂及其制备方法
KR102685656B1 (ko) *	2022-02-14	2024-07-15	국방과학연구소	그람 양성 포자의 제독 방법

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JPS526867B2 (ja) *	1972-09-14	1977-02-25
GB8304990D0 (en) *	1983-02-23	1983-03-30	Procter & Gamble	Detergent ingredients
JPH0617289B2 (ja) *	1985-12-27	1994-03-09	エーザイ株式会社	蓄舎用殺菌剤組成物
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USH366H (en) *	1987-03-18	1987-11-03	The United States Of America As Represented By The Secretary Of The Army	Microemulsions containing sulfolanes
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2002
- 2002-09-20 EA EA200400500A patent/EA009242B1/ru not_active IP Right Cessation
- 2002-09-20 JP JP2003531785A patent/JP4582514B2/ja not_active Expired - Lifetime
- 2002-09-20 AU AU2002341750A patent/AU2002341750B2/en not_active Expired
- 2002-09-20 IL IL16120002A patent/IL161200A0/xx active IP Right Grant
- 2002-09-20 MX MXPA04003037A patent/MXPA04003037A/es active IP Right Grant
- 2002-09-20 WO PCT/US2002/029886 patent/WO2003028429A2/en active Application Filing
- 2002-09-20 CN CN028241258A patent/CN1612766B/zh not_active Expired - Lifetime
- 2002-09-20 EP EP02775899.4A patent/EP1434625B1/en not_active Expired - Lifetime
- 2002-09-20 KR KR1020047004858A patent/KR100916328B1/ko active IP Right Grant
- 2002-09-20 CA CA2461872A patent/CA2461872C/en not_active Expired - Lifetime
- 2002-09-20 BR BRPI0213019-0A patent/BR0213019B1/pt not_active IP Right Cessation
2004
- 2004-03-31 IL IL161200A patent/IL161200A/en unknown
2005
- 2005-08-31 HK HK05107631.5A patent/HK1073618A1/xx not_active IP Right Cessation

Also Published As

Publication number	Publication date
IL161200A (en)	2007-09-20
EP1434625A2 (en)	2004-07-07
AU2002341750B2 (en)	2007-10-11
EA009242B1 (ru)	2007-12-28
KR100916328B1 (ko)	2009-09-11
EA200400500A1 (ru)	2004-10-28
JP4582514B2 (ja)	2010-11-17
CN1612766A (zh)	2005-05-04
JP2005504856A (ja)	2005-02-17
BR0213019B1 (pt)	2011-12-27
KR20040048923A (ko)	2004-06-10
CN1612766B (zh)	2010-10-13
WO2003028429A2 (en)	2003-04-10
EP1434625B1 (en)	2018-07-18
MXPA04003037A (es)	2005-07-01
BR0213019A (pt)	2004-10-05
IL161200A0 (en)	2004-08-31
CA2461872A1 (en)	2003-04-10
HK1073618A1 (en)	2005-10-14
WO2003028429A3 (en)	2003-12-18
EP1434625A4 (en)	2010-07-21

Legal Events

Date	Code	Title	Description
2007-09-12	EEER	Examination request
2022-11-22	MKEX	Expiry	Effective date: 20220920
2024-04-03	MKEX	Expiry	Effective date: 20220920

Publication	Publication Date	Title
US7282470B2 (en)	2007-10-16	Decontamination formulation with sorbent additive
US7390432B2 (en)	2008-06-24	Enhanced formulations for neutralization of chemical, biological and industrial toxants
CA2461872C (en)	2013-11-26	Enhanced formulations for neutralization of chemical, biological and industrial toxants
WO2005055963A2 (en)	2005-06-23	Decontamination formulation with sorbent additive
US7064241B2 (en)	2006-06-20	Chemical and biological warfare decontaminating solution using peracids and germinants in microemulsions, process and product thereof
US7271137B2 (en)	2007-09-18	Decontamination formulations for disinfection and sterilization
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Tucker et al.	2007	Decontamination formulation with sorbent additive
TW589179B (en)	2004-06-01	Enhanced formulations for neutralization of chemical, biological and industrial toxants
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