CA2310899A1 - Production of a combination of active substances active as bleach catalysts - Google Patents

Production of a combination of active substances active as bleach catalysts Download PDF

Info

Publication number: CA2310899A1
Authority: CA; Canada
Prior art keywords: weight; active; anyone; transition metal; parts
Prior art date: 1999-06-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2310899

Other languages

English (en)

French (fr)

Inventor

Helmut Blum

Horst-Dieter Speckmann

Christian Nitsch

Andreas Lietzmann

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-06-04

Filing date

2000-06-05

Publication date

2000-12-04

2000-06-05 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2000-12-04 Publication of CA2310899A1 publication Critical patent/CA2310899A1/en

Status Abandoned legal-status Critical Current

Links

239000013543 active substance Substances 0.000 title claims abstract description 52
238000004519 manufacturing process Methods 0.000 title claims abstract description 7
239000007844 bleaching agent Substances 0.000 title description 19
239000003054 catalyst Substances 0.000 title description 5
239000000203 mixture Substances 0.000 claims abstract description 55
229910052723 transition metal Inorganic materials 0.000 claims abstract description 40
-1 transition metal salt Chemical class 0.000 claims abstract description 36
239000007864 aqueous solution Substances 0.000 claims abstract description 18
150000003624 transition metals Chemical class 0.000 claims abstract description 18
239000007800 oxidant agent Substances 0.000 claims abstract description 17
150000003863 ammonium salts Chemical class 0.000 claims abstract description 14
150000003839 salts Chemical class 0.000 claims abstract description 13
238000002156 mixing Methods 0.000 claims abstract description 12
239000012876 carrier material Substances 0.000 claims abstract description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
229910017052 cobalt Inorganic materials 0.000 claims abstract description 4
239000010941 cobalt Substances 0.000 claims abstract description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 4
229910052802 copper Inorganic materials 0.000 claims abstract description 4
239000010949 copper Substances 0.000 claims abstract description 4
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 3
229910052742 iron Inorganic materials 0.000 claims abstract description 3
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 3
238000000034 method Methods 0.000 claims description 31
230000008569 process Effects 0.000 claims description 31
239000000243 solution Substances 0.000 claims description 29
150000001875 compounds Chemical class 0.000 claims description 27
239000003599 detergent Substances 0.000 claims description 25
239000012190 activator Substances 0.000 claims description 16
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 14
238000004140 cleaning Methods 0.000 claims description 14
238000005469 granulation Methods 0.000 claims description 12
230000003179 granulation Effects 0.000 claims description 12
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 8
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
239000000470 constituent Substances 0.000 claims description 6
239000004615 ingredient Substances 0.000 claims description 6
239000000843 powder Substances 0.000 claims description 5
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 4
150000008041 alkali metal carbonates Chemical class 0.000 claims description 4
229920005646 polycarboxylate Polymers 0.000 claims description 4
229910019142 PO4 Inorganic materials 0.000 claims description 3
239000012266 salt solution Substances 0.000 claims description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims description 2
229910002651 NO3 Inorganic materials 0.000 claims description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
229910001514 alkali metal chloride Inorganic materials 0.000 claims description 2
229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 2
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims description 2
ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 2
229910000001 cobalt(II) carbonate Inorganic materials 0.000 claims description 2
229910000335 cobalt(II) sulfate Inorganic materials 0.000 claims description 2
239000002245 particle Substances 0.000 claims description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 2
150000004967 organic peroxy acids Chemical class 0.000 claims 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
238000004061 bleaching Methods 0.000 description 17
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 14
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
230000000694 effects Effects 0.000 description 12
239000002253 acid Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
229910052783 alkali metal Inorganic materials 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 8
239000002689 soil Substances 0.000 description 8
150000007513 acids Chemical class 0.000 description 7
230000007797 corrosion Effects 0.000 description 7
238000005260 corrosion Methods 0.000 description 7
238000004851 dishwashing Methods 0.000 description 7
229910000029 sodium carbonate Inorganic materials 0.000 description 7
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
102000004190 Enzymes Human genes 0.000 description 6
108090000790 Enzymes Proteins 0.000 description 6
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
229940088598 enzyme Drugs 0.000 description 6
230000001590 oxidative effect Effects 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
229940045872 sodium percarbonate Drugs 0.000 description 6
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
241001122767 Theaceae Species 0.000 description 5
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 5
229910052709 silver Inorganic materials 0.000 description 5
239000004332 silver Substances 0.000 description 5
UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 5
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000005187 foaming Methods 0.000 description 4
239000008187 granular material Substances 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
239000003446 ligand Substances 0.000 description 4
229910000069 nitrogen hydride Inorganic materials 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000004753 textile Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
108010065511 Amylases Proteins 0.000 description 3
102000013142 Amylases Human genes 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
108091005804 Peptidases Proteins 0.000 description 3
239000004365 Protease Substances 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 3
235000019270 ammonium chloride Nutrition 0.000 description 3
235000019418 amylase Nutrition 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
150000001868 cobalt Chemical class 0.000 description 3
GFHNAMRJFCEERV-UHFFFAOYSA-L cobalt chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Co+2] GFHNAMRJFCEERV-UHFFFAOYSA-L 0.000 description 3
230000009969 flowable effect Effects 0.000 description 3
239000002736 nonionic surfactant Substances 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
159000000001 potassium salts Chemical class 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
239000011833 salt mixture Substances 0.000 description 3
229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
235000017557 sodium bicarbonate Nutrition 0.000 description 3
239000001509 sodium citrate Substances 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
108090001060 Lipase Proteins 0.000 description 2
239000004367 Lipase Substances 0.000 description 2
102000004882 Lipase Human genes 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
102000035195 Peptidases Human genes 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
229910000318 alkali metal phosphate Inorganic materials 0.000 description 2
125000005263 alkylenediamine group Polymers 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
229940025131 amylases Drugs 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
230000008901 benefit Effects 0.000 description 2
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
239000012964 benzotriazole Substances 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
235000015165 citric acid Nutrition 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
239000000835 fiber Substances 0.000 description 2
235000013312 flour Nutrition 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 2
125000001046 glycoluril group Chemical group [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000001965 increasing effect Effects 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
235000019421 lipase Nutrition 0.000 description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
239000000463 material Substances 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000002304 perfume Substances 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
229960001922 sodium perborate Drugs 0.000 description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
239000000126 substance Substances 0.000 description 2
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
150000003852 triazoles Chemical class 0.000 description 2
238000005406 washing Methods 0.000 description 2
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229930195725 Mannitol Natural products 0.000 description 1
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102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
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KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000003082 abrasive agent Substances 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
108090000637 alpha-Amylases Proteins 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical class [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
108010005400 cutinase Proteins 0.000 description 1
150000007973 cyanuric acids Chemical class 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000000249 desinfective effect Effects 0.000 description 1
239000001177 diphosphate Substances 0.000 description 1
GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
235000012209 glucono delta-lactone Nutrition 0.000 description 1
229960003681 gluconolactone Drugs 0.000 description 1
239000001087 glyceryl triacetate Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
239000008233 hard water Substances 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
150000001469 hydantoins Chemical class 0.000 description 1
229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
239000008101 lactose Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
150000002696 manganese Chemical class 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
239000012528 membrane Substances 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011325 microbead Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000001402 nonanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000008427 organic disulfides Chemical class 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
230000004792 oxidative damage Effects 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
235000013808 oxidized starch Nutrition 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920001308 poly(aminoacid) Polymers 0.000 description 1
229920001515 polyalkylene glycol Polymers 0.000 description 1
108010064470 polyaspartate Proteins 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920002643 polyglutamic acid Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
239000001226 triphosphate Substances 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA 2310899 1999-06-04 2000-06-05 Production of a combination of active substances active as bleach catalysts Abandoned CA2310899A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19925511.3		1999-06-04
DE1999125511 DE19925511A1 (de)	1999-06-04	1999-06-04	Herstellung einer bleichkatalytisch aktiven Wirkstoffkombination

Publications (1)

Publication Number	Publication Date
CA2310899A1 true CA2310899A1 (en)	2000-12-04

Family

ID=7910168

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2310899 Abandoned CA2310899A1 (en)	1999-06-04	2000-06-05	Production of a combination of active substances active as bleach catalysts

Country Status (4)

Country	Link
AU (1)	AU5216000A (de)
CA (1)	CA2310899A1 (de)
DE (1)	DE19925511A1 (de)
WO (1)	WO2000075270A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19961687A1 (de) *	1999-12-21	2001-07-05	Henkel Kgaa	Wirkstoffkombination zur Einarbeitung in Wasch- und Reinigungsmittel

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1120944A (en) *	1964-07-24	1968-07-24	Unilever Ltd	Catalysts
US5597936A (en) *	1995-06-16	1997-01-28	The Procter & Gamble Company	Method for manufacturing cobalt catalysts
DE19620411A1 (de) *	1996-04-01	1997-10-02	Henkel Kgaa	Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen
EP0832969B1 (de) *	1996-09-26	2004-11-17	Henkel Kommanditgesellschaft auf Aktien	Katalytisch aktive Wirkstoffkombination zur Verstärkung der Bleichwirkung

1999
- 1999-06-04 DE DE1999125511 patent/DE19925511A1/de not_active Withdrawn
2000
- 2000-05-24 AU AU52160/00A patent/AU5216000A/en not_active Abandoned
- 2000-05-24 WO PCT/EP2000/004722 patent/WO2000075270A1/de active Application Filing
- 2000-06-05 CA CA 2310899 patent/CA2310899A1/en not_active Abandoned

Also Published As

Publication number	Publication date
WO2000075270A1 (de)	2000-12-14
AU5216000A (en)	2000-12-28
DE19925511A1 (de)	2000-12-07

Legal Events

Date	Code	Title	Description
2002-09-06	FZDE	Dead

Publication	Publication Date	Title
US8927478B2 (en)	2015-01-06	Use of manganese oxalates as bleach catalysts
US7205267B2 (en)	2007-04-17	Use of transition metal complexes as bleach catalysts in laundry detergents and cleaning compositions
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US6875734B2 (en)	2005-04-05	Use of transition metal complexes as bleach catalysts
US8883704B2 (en)	2014-11-11	Bleach granules
US5888954A (en)	1999-03-30	Corrosion inhibitors for silver
CA2162459A1 (en)	1994-11-24	Corrosion inhibitors for silver (ii)
JPH08509777A (ja)	1996-10-15	銀腐食保護剤（▲ｉ▼）
US6221824B1 (en)	2001-04-24	Process for the production of compounded acetonitrile derivatives
US7094745B2 (en)	2006-08-22	Use of transition metal complexes having lactam ligands as bleaching catalysts
JP5469667B2 (ja)	2014-04-16	マンガン塩及びシュウ酸もしくはそれの塩からなる漂白触媒混合物
JP2002302698A (ja)	2002-10-18	オキシム配位子を有する遷移金属錯体を漂白触媒として使用する方法
JP2002541303A (ja)	2002-12-03	漂白剤含有洗剤
EP0832969B1 (de)	2004-11-17	Katalytisch aktive Wirkstoffkombination zur Verstärkung der Bleichwirkung
US6306808B1 (en)	2001-10-23	Manganese complexes as catalysts for peroxygenated compounds to clean hard surfaces, especially dishes
CA2299437A1 (en)	2000-08-25	Compounded acetonitrile derivatives as bleach activators in detergents
US6235695B1 (en)	2001-05-22	Cleaning agent with oligoammine activator complexes for peroxide compounds
JP2002500242A (ja)	2002-01-08	過酸素化合物の漂白効果を強化するためのデンドリマー配位子を有する遷移金属錯体の使用
CA2310899A1 (en)	2000-12-04	Production of a combination of active substances active as bleach catalysts
US20090042764A1 (en)	2009-02-12	Cleaning Agent Comprising Complexes with Bleach Catalytic Activity