CA2087229A1 - Reduction de la teneur en benzene dans les essences - Google Patents

Reduction de la teneur en benzene dans les essences

Info

Publication number: CA2087229A1
Authority: CA; Canada
Prior art keywords: catalyst; isomerization; hydrogenation; per; platinum
Prior art date: 1992-01-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002087229A

Other languages

English (en)

French (fr)

Inventor

Christine Travers

Patrick Sarrazin

Jean-Marie Deves

Jean Cosyns

Philippe Travers

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IFP Energies Nouvelles IFPEN

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-01-13

Filing date

1993-01-13

Publication date

1993-07-14

1993-01-13 Application filed by Individual filed Critical Individual

1993-07-14 Publication of CA2087229A1 publication Critical patent/CA2087229A1/fr

Status Abandoned legal-status Critical Current

Links

UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 63
238000000034 method Methods 0.000 claims abstract description 21
238000005984 hydrogenation reaction Methods 0.000 claims abstract description 20
239000000203 mixture Substances 0.000 claims abstract description 7
238000004821 distillation Methods 0.000 claims abstract description 6
238000006317 isomerization reaction Methods 0.000 claims description 29
239000003054 catalyst Substances 0.000 claims description 28
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 24
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 14
229910052697 platinum Inorganic materials 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 9
239000002184 metal Substances 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
229910052759 nickel Inorganic materials 0.000 claims description 7
229910052763 palladium Inorganic materials 0.000 claims description 7
229910052680 mordenite Inorganic materials 0.000 claims description 6
239000000686 essence Substances 0.000 claims 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 16
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
239000010457 zeolite Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000001833 catalytic reforming Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
VBEKGXAPCZTFJW-UHFFFAOYSA-N benzene;octane Chemical compound C1=CC=CC=C1.CCCCCCCC VBEKGXAPCZTFJW-UHFFFAOYSA-N 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
239000004568 cement Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical class C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/08—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of reforming naphtha
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA002087229A 1992-01-13 1993-01-13 Reduction de la teneur en benzene dans les essences Abandoned CA2087229A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR92/00.433		1992-01-13
FR9200433A FR2686096B1 (fr)	1992-01-15	1992-01-15	Reduction de la teneur en benzene dans les essences.

Publications (1)

Publication Number	Publication Date
CA2087229A1 true CA2087229A1 (fr)	1993-07-14

Family

ID=9425702

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002087229A Abandoned CA2087229A1 (fr)	1992-01-13	1993-01-13	Reduction de la teneur en benzene dans les essences

Country Status (9)

Country	Link
EP (1)	EP0552072B1 (ko)
KR (1)	KR100242918B1 (ko)
CA (1)	CA2087229A1 (ko)
DE (1)	DE69321741T2 (ko)
ES (1)	ES2125959T3 (ko)
FR (1)	FR2686096B1 (ko)
ID (1)	ID852B (ko)
MY (1)	MY106926A (ko)
TW (1)	TW237474B (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0953626A1 (de) *	1998-04-27	1999-11-03	FE Forschungs & Entwicklung GmbH	Verfahren zur Herstellung eines benzolarmen, hochoktanigen Kohlenwasserstoffgemischs
WO2000069993A1 (en) *	1999-05-13	2000-11-23	Mobil Oil Corporation	Dual catalyst system
EP2277980B1 (fr)	2009-07-21	2018-08-08	IFP Energies nouvelles	Procédé de réduction sélective de la teneur en benzène et en composés insatures legers de differentes coupes hydrocarbures

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA975384A (en) *	1971-04-19	1975-09-30	Graham K. Hilder	Isomerisation of paraffin hydrocarbons
US5003118A (en) *	1989-12-29	1991-03-26	Uop	Isomerization of benzene-containing feedstocks

1992
- 1992-01-15 FR FR9200433A patent/FR2686096B1/fr not_active Expired - Lifetime
- 1992-12-31 TW TW081110537A patent/TW237474B/zh active
1993
- 1993-01-07 EP EP93400023A patent/EP0552072B1/fr not_active Expired - Lifetime
- 1993-01-07 DE DE69321741T patent/DE69321741T2/de not_active Expired - Lifetime
- 1993-01-07 ES ES93400023T patent/ES2125959T3/es not_active Expired - Lifetime
- 1993-01-12 KR KR1019930000301A patent/KR100242918B1/ko not_active IP Right Cessation
- 1993-01-12 ID IDP532493A patent/ID852B/id unknown
- 1993-01-12 MY MYPI93000045A patent/MY106926A/en unknown
- 1993-01-13 CA CA002087229A patent/CA2087229A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
DE69321741T2 (de)	1999-03-18
EP0552072A1 (fr)	1993-07-21
TW237474B (ko)	1995-01-01
FR2686096A1 (fr)	1993-07-16
KR930016527A (ko)	1993-08-26
DE69321741D1 (de)	1998-12-03
ID852B (id)	1996-08-02
FR2686096B1 (fr)	1994-04-29
KR100242918B1 (ko)	2000-02-01
ES2125959T3 (es)	1999-03-16
MY106926A (en)	1995-08-30
EP0552072B1 (fr)	1998-10-28

Legal Events

Date	Code	Title	Description
1999-12-01	EEER	Examination request
2005-01-13	FZDE	Discontinued

Publication	Publication Date	Title
EP0515256B1 (fr)	1997-03-05	Procédé d'hydromérisation de paraffines issues du procédé Fischer-Tropsch à l'aide de catalyseurs à base de zéolithe H.Y
EP0242260B1 (fr)	1989-03-29	Procédé de réformage catalytique
FR2720073A1 (fr)	1995-11-24	Procédé d'hydrotraitement pour la production de supercarburant léger isomérisé et système de catalyseur d'hydroconversion.
FR2611739A1 (fr)	1988-09-09	Procede d'activation d'un catalyseur d'isomerisation de paraffines normales
EP0789739A1 (fr)	1997-08-20	Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire
CA2194085C (fr)	2007-03-06	Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures
EP0661095B1 (fr)	1999-06-23	Catalyseur pour la réduction de la teneur en benzène dans les essences
EP0552070B1 (fr)	1999-08-18	Réduction de la teneur en benzène dans les essences
EP0661370B1 (fr)	2000-04-19	Catalyseur pour la réduction de la teneur en benzène dans les essences
FR2548204A1 (fr)	1985-01-04	Procede de transformation d'hydrocarbures
EP0196965B1 (fr)	1988-10-12	Nouveau catalyseur d'isomérisation de coupes riches en paraffines normales
FR2676750A1 (fr)	1992-11-27	Procede d'hydrocraquage de paraffines issue du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
EP0552069B1 (fr)	1996-04-24	Réduction de la teneur en benzène dans les essences par un procédé d'isomérisation
CA1334980C (fr)	1995-03-28	Procede d'isomerisation du butene-1 en butenes-2 dans une coupe d'hydrocarbures en c _ contenant du butadiene et des composes sulfures
EP1417283B1 (fr)	2011-04-20	Procede d'isomerisation d'une coupe c5-c8 mettant en oeuvre deux reacteurs en parallele
EP0440540B1 (fr)	1994-03-30	Procédé d'isomérisation de paraffines normales en présence d'au moins un catalyseur à base d'une zéolithe oméga particulière
EP0552072B1 (fr)	1998-10-28	Réduction de la teneur en benzène dans les essences
FR2694565A1 (fr)	1994-02-11	Réduction de la teneur en benzène dans les essences.
FR2686094A1 (fr)	1993-07-16	Production de base pour carburant exempt de benzene, presentant un indice d'octane eleve.
EP0922747B1 (fr)	2003-10-29	Procédé d'isomérisation des coupes paraffiniques C5-C8 riches en paraffines à plus de sept atomes de carbone
FR2738243A1 (fr)	1997-03-07	Procede d'hydroisomerisation de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de zeolithe nu-10
FR2738244A1 (fr)	1997-03-07	Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire