CA2086502A1 - Process for the preparation of a composite make from a vulcanized elastomer associated with a thermoplastic elastomer containing polyamide sequences, composite thus made and sportarticle made from such materials - Google Patents

Process for the preparation of a composite make from a vulcanized elastomer associated with a thermoplastic elastomer containing polyamide sequences, composite thus made and sportarticle made from such materials

Info

Publication number
CA2086502A1
CA2086502A1 CA2086502A CA2086502A CA2086502A1 CA 2086502 A1 CA2086502 A1 CA 2086502A1 CA 2086502 A CA2086502 A CA 2086502A CA 2086502 A CA2086502 A CA 2086502A CA 2086502 A1 CA2086502 A1 CA 2086502A1
Authority
CA
Canada
Prior art keywords
composite
thermoplastic elastomer
containing polyamide
elastomer containing
materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2086502A
Other languages
French (fr)
Other versions
CA2086502C (en
Inventor
Marius Hert
Patrick Alex
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Marius Hert
Patrick Alex
Elf Atochem S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Marius Hert, Patrick Alex, Elf Atochem S.A. filed Critical Marius Hert
Publication of CA2086502A1 publication Critical patent/CA2086502A1/en
Application granted granted Critical
Publication of CA2086502C publication Critical patent/CA2086502C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L13/00—Compositions of rubbers containing carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0076—Curing, vulcanising, cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/72—Cured, e.g. vulcanised, cross-linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Process for the preparation of a composite material made up of a vulcanised elastomer containing carboxylic acid or dicarboxylic acid anhydride functional groups, in combination with a thermoplastic elastomer containing polyamide blocks, characterised in that an elastomeric composition comprising the vulcanisable elastomer, a crosslinking system and optionally various adjuvants is vulcanised in a mould, part of which is occupied by the said thermoplastic elastomer containing polyamide blocks, the vulcanisation temperature being between -15 DEG C and +5 DEG C in relation to the Vicat point of the said thermoplastic elastomer containing polyamide blocks, the elastomeric composition and the vulcanisation kinetics being such that the material exhibits a cohesive rupture when stressed with the separation of the two elastomers. This process produces composite materials exhibiting excellent properties, especially tensile strength (cohesive rupture). The invention also relates to the composite material thus formed and its application to sports articles produced with the aid of these materials.
CA002086502A 1991-12-31 1992-12-30 Process for the preparation of a composite make from a vulcanized elastomer associated with a thermoplastic elastomer containing polyamide sequences, composite thus made and sportarticle made from such materials Expired - Fee Related CA2086502C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9116400A FR2685660A1 (en) 1991-12-31 1991-12-31 PROCESS FOR PREPARING COMPOSITE MATERIAL FORMED OF A VULCANIZED ELASTOMER ASSOCIATED WITH A THERMOPLASTIC ELASTOMER HAVING A POLYAMIDE SEQUENCE AND COMPOSITE MATERIAL.
FR9116400 1991-12-31

Publications (2)

Publication Number Publication Date
CA2086502A1 true CA2086502A1 (en) 1993-07-01
CA2086502C CA2086502C (en) 2000-06-27

Family

ID=9420720

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002086502A Expired - Fee Related CA2086502C (en) 1991-12-31 1992-12-30 Process for the preparation of a composite make from a vulcanized elastomer associated with a thermoplastic elastomer containing polyamide sequences, composite thus made and sportarticle made from such materials

Country Status (9)

Country Link
US (1) US5624994A (en)
EP (1) EP0550346B1 (en)
JP (1) JP2957829B2 (en)
KR (1) KR0165130B1 (en)
AT (1) ATE203198T1 (en)
CA (1) CA2086502C (en)
DE (1) DE69231944T2 (en)
ES (1) ES2158845T3 (en)
FR (1) FR2685660A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2700292B1 (en) * 1993-01-13 1995-02-24 Atochem Elf Sa Composite tubular article formed from a vulcanized elastomer associated with a thermoplastic elastomer having polyamide sequences, in particular gasoline pipe and process for preparing such an article.
DE69427069T2 (en) 1993-11-26 2001-09-13 Atofina Thermoplastic rubber polymer alloys adhering to thermoplastics
FR2719520A1 (en) 1994-05-06 1995-11-10 Atochem Elf Sa Material comprising a vulcanized elastomer associated with a thermoplastic elastomer.
EP0739931A1 (en) * 1995-04-25 1996-10-30 Elf Atochem S.A. Process for overmoulding of a thermoplastic on rubber
WO1998001500A1 (en) * 1996-07-05 1998-01-15 Dsm N.V. Vulcanized rubber product
NL1004246C2 (en) * 1996-10-10 1998-04-14 Dsm Nv Vulcanised rubber product
BR9902743C1 (en) * 1999-07-13 2001-05-22 Nitriflex S A Ind E Com Composition of carboxylated nbr copolymers or not and ethylene vinyl acetate (eva) copolymer and vulcanizable composition of carboxylated nbr copolymers or not and eva
CA2308876A1 (en) * 2000-05-12 2001-11-12 Bayer Inc. Improved rubber composition
US6726985B2 (en) 2000-11-03 2004-04-27 Nathan Amitai Shoe sole
DE10227733A1 (en) * 2002-06-21 2004-01-08 Bayer Ag Rubber mixtures containing copolymers for the manufacture of tires
FR2890969A1 (en) * 2005-09-16 2007-03-23 Arkema Sa POLYAMIDE BLOCK COPOLYMERS AND AGING RESISTANT POLYETHER BLOCKS
DE102015111716B4 (en) * 2015-07-20 2021-09-02 Hochschule Kaiserslautern Shoe and process for its manufacture

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1387583A (en) * 1971-05-21 1975-03-19 Dunlop Ltd Composite structures
GB1434719A (en) * 1972-09-01 1976-05-05 Raychem Ltd Heat recoverable products
US3972973A (en) * 1973-08-29 1976-08-03 Dunlop Limited Method of making rubber and polyester structures
MY102989A (en) * 1986-10-30 1993-03-31 Mitsui Chemicals Inc Laminate and molded article prepared therefrom
DE3818151A1 (en) * 1988-05-28 1989-12-07 Huels Chemische Werke Ag METHOD FOR PRODUCING A CHEMICAL COMPOSITE BETWEEN MOLDING MATERIALS BASED ON ALIPHATIC POLYAMIDES ON THE ONE SIDE AND CARBOXYL GROUPS CONTAINING RUBBERS ON THE OTHER, AND THE MATERIALS PRODUCED BY THIS METHOD
US4996263A (en) * 1988-10-06 1991-02-26 The Goodyear Tire & Rubber Company High modulus rubber composition

Also Published As

Publication number Publication date
FR2685660A1 (en) 1993-07-02
ATE203198T1 (en) 2001-08-15
CA2086502C (en) 2000-06-27
EP0550346B1 (en) 2001-07-18
KR930013002A (en) 1993-07-21
DE69231944T2 (en) 2002-04-04
JP2957829B2 (en) 1999-10-06
KR0165130B1 (en) 1999-03-20
EP0550346A1 (en) 1993-07-07
JPH06212022A (en) 1994-08-02
DE69231944D1 (en) 2001-08-23
ES2158845T3 (en) 2001-09-16
FR2685660B1 (en) 1995-04-14
US5624994A (en) 1997-04-29

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