CA2012344A1 - Process for the elimination of mercury and, eventually, of arsenic from hydrocarbons - Google Patents

Process for the elimination of mercury and, eventually, of arsenic from hydrocarbons

Info

Publication number
CA2012344A1
CA2012344A1 CA002012344A CA2012344A CA2012344A1 CA 2012344 A1 CA2012344 A1 CA 2012344A1 CA 002012344 A CA002012344 A CA 002012344A CA 2012344 A CA2012344 A CA 2012344A CA 2012344 A1 CA2012344 A1 CA 2012344A1
Authority
CA
Canada
Prior art keywords
mercury
arsenic
metal
elimination
sulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002012344A
Other languages
French (fr)
Other versions
CA2012344C (en
Inventor
Pierre Dufresne
Philippe Courty
Germain Martino
Jean-Paul Boitiaux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2012344A1 publication Critical patent/CA2012344A1/en
Application granted granted Critical
Publication of CA2012344C publication Critical patent/CA2012344C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)

Abstract

Procédé d'élimination du mercure et éventuellement d'arsenic dans les charges d'hydrocarbures contenant mercure et soufre, caractérisé en ce que l'on fait passer, sous hydrogène, ladite charge au contact d'une masse de captation d'arsenic à propriétés catalytiques renfermant au moins un métal du groupe formé par nickel cobalt fer palladium platine, au moins un métal du groupe formé par chrome molybdène tungstène uranium et un support de phase active, ladite masse étant suivie sur le trajet de la charge de, ou mélangée à, une masse de captation du mercure renfermant un sulfure d'au moins un métal du groupe cuivre fer argent ou du soufre et un support de phase active.Process for the elimination of mercury and possibly arsenic in hydrocarbon charges containing mercury and sulfur, characterized in that said charge is passed under hydrogen into contact with an arsenic capture mass with properties catalysts containing at least one metal from the group formed by nickel cobalt iron palladium platinum, at least one metal from the group formed by chromium molybdenum tungsten uranium and an active phase support, said mass being followed on the path of the charge of, or mixed with , a mercury capture mass containing a sulphide of at least one metal from the copper iron silver group or sulfur and an active phase support.

CA002012344A 1989-03-16 1990-03-16 Process for the elimination of mercury and, eventually, of arsenic from hydrocarbons Expired - Fee Related CA2012344C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8903581A FR2644472B1 (en) 1989-03-16 1989-03-16 PROCESS FOR THE REMOVAL OF MERCURY AND POSSIBLY ARSENIC IN HYDROCARBONS
FR89/03.581 1989-03-16

Publications (2)

Publication Number Publication Date
CA2012344A1 true CA2012344A1 (en) 1990-09-16
CA2012344C CA2012344C (en) 2001-05-08

Family

ID=9379843

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002012344A Expired - Fee Related CA2012344C (en) 1989-03-16 1990-03-16 Process for the elimination of mercury and, eventually, of arsenic from hydrocarbons

Country Status (12)

Country Link
EP (1) EP0463044B1 (en)
JP (1) JP2620811B2 (en)
CN (1) CN1024675C (en)
AU (1) AU634763B2 (en)
CA (1) CA2012344C (en)
DE (1) DE69002941T2 (en)
DZ (1) DZ1402A1 (en)
FR (1) FR2644472B1 (en)
MY (1) MY106411A (en)
NO (1) NO180121C (en)
WO (1) WO1990010684A1 (en)
ZA (1) ZA893265B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304693A (en) * 1990-08-29 1994-04-19 Institut Francais Du Petrole Process for eliminating mercury from steam cracking installations

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2668385B1 (en) * 1990-10-30 1993-10-15 Institut Francais Petrole PROCESS FOR THE ELIMINATION OF ARSENIC IN A GAS BY PASSING ON A MASS BASED ON A SUPPORT OF COPPER SULFIDE.
FR2668465B1 (en) * 1990-10-30 1993-04-16 Inst Francais Du Petrole PROCESS FOR REMOVAL OF MERCURY OR ARSENIC IN A FLUID IN THE PRESENCE OF A MASS OF MERCURY AND / OR ARSENIC CAPTATION.
US5064626A (en) * 1990-11-28 1991-11-12 Phillips Petroleum Company Trialkyl arsine sorbents
US5085844A (en) * 1990-11-28 1992-02-04 Phillips Petroleum Company Sorption of trialkyl arsines
FR2673192B1 (en) * 1991-02-27 1994-07-22 Inst Francais Du Petrole PROCESS FOR THE ELIMINATION OF MERCURY AND POSSIBLY ARSENIC IN THE LOADS OF CATALYTIC PROCESSES PRODUCING AROMATICS. .
FR2673191B1 (en) * 1991-02-27 1994-02-04 Institut Francais Petrole PROCESS FOR REMOVING MERCURY AND / OR ARSENIC FROM THE LOADS OF SOLVENT DEAROMATIZATION UNITS. .
FR2690923B1 (en) * 1992-05-11 1994-07-22 Inst Francais Du Petrole PROCESS FOR CAPTURING MERCURY AND ARSENIC IN A CUP OF HYDROCARBON.
FR2698372B1 (en) * 1992-11-24 1995-03-10 Inst Francais Du Petrole Process for the removal of mercury and possibly arsenic from hydrocarbons.
FR2701269B1 (en) * 1993-02-08 1995-04-14 Inst Francais Du Petrole Process for the elimination of arsenic in hydrocarbons by passage over a presulfurized capture mass.
FR2701270B1 (en) * 1993-02-08 1995-04-14 Inst Francais Du Petrole Process for removing mercury from hydrocarbons by passing over a presulfurized catalyst.
US6350372B1 (en) * 1999-05-17 2002-02-26 Mobil Oil Corporation Mercury removal in petroleum crude using H2S/C
FR2803597B1 (en) 2000-01-07 2003-09-05 Inst Francais Du Petrole PROCESS FOR CAPTURING MERCURY AND ARSENIC FROM A DISTILLED HYDROCARBON CUT
JP2002241767A (en) * 2001-02-15 2002-08-28 Idemitsu Petrochem Co Ltd Method for removing mercury from liquid hydrocarbon
CN100392046C (en) * 2003-08-07 2008-06-04 上海化工研究院 Dearsenicating agent for removing high boiling point arsonium compound in liquid-state petroleum hydrocarbon at low temperature and normal temperature
GB0611316D0 (en) * 2006-06-09 2006-07-19 Johnson Matthey Plc Improvements in the removal of metals from fluid streams
US20110005975A1 (en) * 2008-03-10 2011-01-13 Basf Se Method for removing mercury from hydrocarbon streams
KR101796792B1 (en) * 2011-02-09 2017-11-13 에스케이이노베이션 주식회사 A method for simultaneous removing of sulfur and mercury in hydrocarbon source comprising them using catalyst through hydrotreating reaction
FR2987368B1 (en) * 2012-02-27 2015-01-16 Axens PROCESS FOR REMOVING MERCURY FROM HYDROCARBON LOAD WITH HYDROGEN RECYCLE
CN104507551B (en) * 2012-08-20 2018-08-07 艺康美国股份有限公司 Mercury absorbent
FR3007415B1 (en) * 2013-06-21 2016-05-27 Ifp Energies Now PROCESS FOR REMOVING THE ARSENIC FROM A HYDROCARBON LOAD
CN104645927B (en) * 2013-11-25 2018-01-16 北京三聚环保新材料股份有限公司 A kind of preparation method of silver system mercury removal agent
CN108456574A (en) * 2018-04-12 2018-08-28 西南石油大学 A kind of mercury removal agent and preparation method thereof for moisture demercuration
CN114073961A (en) * 2021-12-08 2022-02-22 辽宁石油化工大学 Cr-Cu/SiO with dearsenization performance2Process for preparing catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3110569A (en) * 1958-02-05 1963-11-12 Socony Mobil Oil Co Inc Removal of arsenic from reformer feed
US4069140A (en) * 1975-02-10 1978-01-17 Atlantic Richfield Company Removing contaminant from hydrocarbonaceous fluid
US4474896A (en) * 1983-03-31 1984-10-02 Union Carbide Corporation Adsorbent compositions
US4709118A (en) * 1986-09-24 1987-11-24 Mobil Oil Corporation Removal of mercury from natural gas and liquid hydrocarbons utilizing downstream guard chabmer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304693A (en) * 1990-08-29 1994-04-19 Institut Francais Du Petrole Process for eliminating mercury from steam cracking installations

Also Published As

Publication number Publication date
NO913622L (en) 1991-09-13
DE69002941D1 (en) 1993-09-30
NO913622D0 (en) 1991-09-13
CN1045596A (en) 1990-09-26
CA2012344C (en) 2001-05-08
MY106411A (en) 1995-05-30
JPH02248493A (en) 1990-10-04
DE69002941T2 (en) 1993-12-23
EP0463044B1 (en) 1993-08-25
FR2644472B1 (en) 1991-06-21
CN1024675C (en) 1994-05-25
AU5331990A (en) 1990-10-09
EP0463044A1 (en) 1992-01-02
NO180121C (en) 1997-02-19
JP2620811B2 (en) 1997-06-18
WO1990010684A1 (en) 1990-09-20
ZA893265B (en) 1990-04-25
FR2644472A1 (en) 1990-09-21
NO180121B (en) 1996-11-11
DZ1402A1 (en) 2004-09-13
AU634763B2 (en) 1993-03-04

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