BRPI0408971A - composição de catalisador de cobre opticamente ativo - Google Patents

composição de catalisador de cobre opticamente ativo

Info

Publication number
BRPI0408971A
BRPI0408971A BRPI0408971-5A BRPI0408971A BRPI0408971A BR PI0408971 A BRPI0408971 A BR PI0408971A BR PI0408971 A BRPI0408971 A BR PI0408971A BR PI0408971 A BRPI0408971 A BR PI0408971A
Authority
BR
Brazil
Prior art keywords
optically active
group
lewis acidity
compounds
catalyst composition
Prior art date
Application number
BRPI0408971-5A
Other languages
English (en)
Inventor
Makoto Itagaki
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of BRPI0408971A publication Critical patent/BRPI0408971A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/325—Cyclopropanations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"COMPOSIçãO DE CATALISADOR DE COBRE OPTICAMENTE ATIVO". A presente invenção refere-se a uma composição de catalisador de cobre opticamente ativo que compreende: (a) um salicilidenoaminoálcool opticamente ativo representado pela fórmula (1): onde R¬ 1¬ e R¬ 2¬ são os mesmos ou diferentes, e independentemente representam um grupo alquila inferior substituído ou não-substituído, um grupo aralquila substituído ou não-substituído, ou um grupo arila substituído ou não-substituído; X¬ 1¬ e X¬ 2¬ são os mesmos ou diferentes, e independentemente representam um átomo de hidrogênio, um grupo alcóxi inferior, um grupo nitro, um grupo alcoxicarbonila inferior, um grupo ciano ou um átomo de halogênio; e * representa um centro assimétrico, contanto que tanto X¬ 1¬ quanto X¬ 2¬ não representem átomos de hidrogênio, (b) um composto de cobre monovalente ou divalente, e (c-1) um composto de lítio ou (c-2) um composto selecionado de compostos de alumínio que apresentam acididade de Lewis, compostos de titânio que apresentam acididade de Lewis, compostos de boro que apresentam acididade de Lewis, compostos de zircónio que apresentam acididade de Lewis e compostos de háfnio que apresentam acididade de Lewis; e um processo para produção de um composto de ciclopropano opticamente ativo utilizando a mesma.
BRPI0408971-5A 2003-03-31 2004-03-25 composição de catalisador de cobre opticamente ativo BRPI0408971A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003093750 2003-03-31
PCT/JP2004/004185 WO2004087317A1 (ja) 2003-03-31 2004-03-25 光学活性な銅触媒組成物

Publications (1)

Publication Number Publication Date
BRPI0408971A true BRPI0408971A (pt) 2006-04-04

Family

ID=33127368

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0408971-5A BRPI0408971A (pt) 2003-03-31 2004-03-25 composição de catalisador de cobre opticamente ativo

Country Status (10)

Country Link
US (1) US7253301B2 (pt)
EP (1) EP1607136B1 (pt)
KR (1) KR101113627B1 (pt)
CN (1) CN100398210C (pt)
BR (1) BRPI0408971A (pt)
IL (1) IL170728A (pt)
PL (1) PL1607136T3 (pt)
RU (1) RU2005133430A (pt)
WO (1) WO2004087317A1 (pt)
ZA (1) ZA200507564B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008050661A1 (fr) * 2006-10-26 2008-05-02 Sumitomo Chemical Company, Limited Procédé servant à produire un cristal de complexe asymétrique du cuivre
JP2008133261A (ja) * 2006-10-26 2008-06-12 Sumitomo Chemical Co Ltd 不斉銅錯体結晶の製造方法
AU2009292470B2 (en) * 2008-09-10 2014-01-16 Sumitomo Chemical Company, Limited Method for producing optically active cyclopropane carboxylic acid ester compound, asymmetric copper complex, and optically active salicylideneaminoalcohol compound
CN102533923A (zh) * 2011-12-19 2012-07-04 浙江工业大学 有机溶剂共溶剂生物拆分制备(s)-(+)-2,2-二甲基环丙烷甲酸的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59225194A (ja) * 1983-06-03 1984-12-18 Sumitomo Chem Co Ltd 新規不斉銅錯体ならびに同錯体を触媒とするシクロプロパンカルボン酸エステルの不斉合成法
DE69906607T2 (de) * 1998-01-29 2003-12-18 Sumitomo Chemical Co., Ltd. Verfahren zur Herstellung von optisch aktiven Chrysanthemumsäure
KR20010074548A (ko) 2000-01-25 2001-08-04 고사이 아끼오 키랄 구리 착물 촉매 조성물 및 그를 이용한 비대칭 제조방법
JP4742423B2 (ja) 2000-01-25 2011-08-10 住友化学株式会社 不斉銅錯体の製造法およびそれを用いる光学活性シクロプロパン化合物の製造法
JP2003012675A (ja) 2001-04-27 2003-01-15 Sumitomo Chem Co Ltd 不斉銅錯体、その製造方法および不斉銅錯体を用いる光学活性シクロプロパン化合物の製造方法
ES2354685T3 (es) 2001-04-27 2011-03-17 Sumitomo Chemical Company, Limited Complejo de cobre asimétrico y reacción de ciclopropano que utiliza el mismo.

Also Published As

Publication number Publication date
KR101113627B1 (ko) 2012-02-13
CN1798609A (zh) 2006-07-05
ZA200507564B (en) 2006-12-27
PL1607136T3 (pl) 2012-09-28
US7253301B2 (en) 2007-08-07
IL170728A (en) 2009-12-24
CN100398210C (zh) 2008-07-02
EP1607136A4 (en) 2007-07-04
EP1607136A1 (en) 2005-12-21
KR20050121707A (ko) 2005-12-27
RU2005133430A (ru) 2006-04-20
EP1607136B1 (en) 2012-05-23
WO2004087317A1 (ja) 2004-10-14
US20060211879A1 (en) 2006-09-21

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Legal Events

Date Code Title Description
B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]