BR9912239A - Catalisador de bis-fosfinoimina - Google Patents
Catalisador de bis-fosfinoiminaInfo
- Publication number
- BR9912239A BR9912239A BR9912239-1A BR9912239A BR9912239A BR 9912239 A BR9912239 A BR 9912239A BR 9912239 A BR9912239 A BR 9912239A BR 9912239 A BR9912239 A BR 9912239A
- Authority
- BR
- Brazil
- Prior art keywords
- phosphinoimine
- bis
- catalyst
- catalyst components
- polymerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- 239000012190 activator Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 125000002524 organometallic group Chemical group 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/535—Organo-phosphoranes
- C07F9/5355—Phosphoranes containing the structure P=N-
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"CATALISADOR DE BIS-FOSFINOIMINA" Complexos organometálicos possuindo dois ligantes fosfinoimina e pelo menos um ligante ativável são componentes catalisadores para a polimerização de olefinas. Os sistemas de polimerização preferidos são preparados pela combinação dos complexos organometálicos com um ativador iónico e/ou um alumoxano. Componentes catalisadores preferidos contêm titânio, zircónio, ou háfnio e são ativados com um ativador iónico para formar catalisadores para a polimerização de etileno.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2.243.783 | 1998-07-21 | ||
CA002243783A CA2243783C (en) | 1998-07-21 | 1998-07-21 | Bis-phosphinimine catalyst |
PCT/CA1999/000558 WO2000005238A1 (en) | 1998-07-21 | 1999-06-15 | Bis-phosphinimine catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
BR9912239A true BR9912239A (pt) | 2001-04-10 |
BR9912239B1 BR9912239B1 (pt) | 2011-01-11 |
Family
ID=4162684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI9912239-1A BR9912239B1 (pt) | 1998-07-21 | 1999-06-15 | sistema de catalisador de polimerização de olefina e processo para a polimerização de etileno. |
Country Status (12)
Country | Link |
---|---|
US (2) | US6239238B1 (pt) |
EP (1) | EP1098899B1 (pt) |
JP (1) | JP4443047B2 (pt) |
KR (1) | KR100545639B1 (pt) |
CN (1) | CN1190442C (pt) |
AT (1) | ATE227730T1 (pt) |
AU (1) | AU4595199A (pt) |
BR (1) | BR9912239B1 (pt) |
CA (1) | CA2243783C (pt) |
DE (1) | DE69903950T2 (pt) |
ES (1) | ES2187167T3 (pt) |
WO (1) | WO2000005238A1 (pt) |
Families Citing this family (52)
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US20060293470A1 (en) * | 2005-06-28 | 2006-12-28 | Cao Phuong A | Polymerization process using spray-dried catalyst |
US6242545B1 (en) | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
US8497330B2 (en) * | 1997-12-08 | 2013-07-30 | Univation Technologies, Llc | Methods for polymerization using spray dried and slurried catalyst |
US6664358B2 (en) * | 2001-06-28 | 2003-12-16 | Nova Chemicals (International) S.A. | Highly alternating ethylene styrene interpolymers |
JP2003207672A (ja) * | 2002-01-17 | 2003-07-25 | Sony Corp | 光ファイバー、光ファイバーモジュール及び光学ピックアップ |
EP1506974A1 (en) * | 2003-08-04 | 2005-02-16 | DSM IP Assets B.V. | Process for the preparation of a metalloorganic compound comprising at least one imine ligand |
US7683140B2 (en) * | 2004-05-20 | 2010-03-23 | Univation Technologies, Llc | Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring |
US7754830B2 (en) | 2004-05-20 | 2010-07-13 | Univation Technologies, Llc | Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events |
GB0425443D0 (en) | 2004-11-18 | 2004-12-22 | Bp Chem Int Ltd | Supported polymerisation catalysts |
EP1731536A1 (en) | 2005-06-09 | 2006-12-13 | Innovene Manufacturing France SAS | Supported polymerisation catalysts |
KR100639696B1 (ko) | 2005-07-01 | 2006-10-30 | 에스케이 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용아릴페녹시 촉매계 |
US7534842B2 (en) | 2005-11-16 | 2009-05-19 | Chevron Phillips Chemical Company, Lp | Catalysts for olefin polymerization |
KR101060838B1 (ko) | 2006-04-24 | 2011-08-30 | 에스케이이노베이션 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용비스-아릴아릴옥시 촉매계 |
JP2010502812A (ja) * | 2006-09-07 | 2010-01-28 | ユニベーション・テクノロジーズ・エルエルシー | 溶融開始温度の降下に対するモデルを用いた樹脂粘着性の程度のオンライン決定のための方法 |
CA2662796A1 (en) * | 2006-09-07 | 2008-03-13 | Univation Technologies, Llc | Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring |
KR101146875B1 (ko) | 2006-11-01 | 2012-05-16 | 에스케이이노베이션 주식회사 | 전이금속 촉매계 및 이를 이용한 에틸렌 단독중합체 또는에틸렌과 올레핀의 공중합체 제조방법 |
KR101151606B1 (ko) | 2007-12-31 | 2012-06-08 | 에스케이이노베이션 주식회사 | 전이금속 화합물, 이를 포함하는 촉매조성물 및 이를이용한 올레핀 단독중합 또는 공중합체의 제조방법 |
KR101186489B1 (ko) | 2008-01-07 | 2012-09-27 | 에스케이이노베이션 주식회사 | 전이금속 화합물 및 이를 포함하는 에틸렌 단독중합체 또는공중합체 제조용 전이금속 촉매 조성물 |
KR101142115B1 (ko) | 2008-01-07 | 2012-07-06 | 에스케이이노베이션 주식회사 | 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및이를 이용한 에틸렌 단독중합체 또는 에틸렌과α-올레핀의 공중합체의 제조방법 |
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KR101142122B1 (ko) | 2008-09-30 | 2012-05-09 | 에스케이이노베이션 주식회사 | 새로운 전이금속 촉매계 및 이를 이용한 에틸렌 단독중합체또는 에틸렌과 α-올레핀의 공중합체 제조방법 |
KR101167082B1 (ko) | 2008-11-05 | 2012-07-20 | 에스케이이노베이션 주식회사 | 에틸렌과 α-올레핀의 탄성 공중합체 제조방법 |
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US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5674795A (en) | 1993-12-23 | 1997-10-07 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
CA2206944C (en) * | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
US6013745A (en) * | 1997-08-04 | 2000-01-11 | The Governors Of The University Of Alberta | Phosphorus based catalysts for the polymerization of olefins |
-
1998
- 1998-07-21 CA CA002243783A patent/CA2243783C/en not_active Expired - Lifetime
-
1999
- 1999-06-15 US US09/333,750 patent/US6239238B1/en not_active Expired - Lifetime
- 1999-06-15 CN CNB998111392A patent/CN1190442C/zh not_active Expired - Fee Related
- 1999-06-15 AU AU45951/99A patent/AU4595199A/en not_active Abandoned
- 1999-06-15 BR BRPI9912239-1A patent/BR9912239B1/pt not_active IP Right Cessation
- 1999-06-15 WO PCT/CA1999/000558 patent/WO2000005238A1/en active IP Right Grant
- 1999-06-15 DE DE69903950T patent/DE69903950T2/de not_active Expired - Lifetime
- 1999-06-15 AT AT99928943T patent/ATE227730T1/de not_active IP Right Cessation
- 1999-06-15 KR KR1020017000733A patent/KR100545639B1/ko not_active IP Right Cessation
- 1999-06-15 ES ES99928943T patent/ES2187167T3/es not_active Expired - Lifetime
- 1999-06-15 JP JP2000561194A patent/JP4443047B2/ja not_active Expired - Fee Related
- 1999-06-15 EP EP99928943A patent/EP1098899B1/en not_active Expired - Lifetime
-
2001
- 2001-01-03 US US09/753,387 patent/US6649558B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1098899A1 (en) | 2001-05-16 |
JP4443047B2 (ja) | 2010-03-31 |
US6649558B2 (en) | 2003-11-18 |
KR20010074722A (ko) | 2001-08-09 |
DE69903950T2 (de) | 2003-07-17 |
JP2002521502A (ja) | 2002-07-16 |
DE69903950D1 (de) | 2002-12-19 |
EP1098899B1 (en) | 2002-11-13 |
KR100545639B1 (ko) | 2006-01-24 |
CN1321161A (zh) | 2001-11-07 |
US6239238B1 (en) | 2001-05-29 |
CA2243783C (en) | 2007-06-05 |
CN1190442C (zh) | 2005-02-23 |
ES2187167T3 (es) | 2003-05-16 |
CA2243783A1 (en) | 2000-01-21 |
WO2000005238A1 (en) | 2000-02-03 |
BR9912239B1 (pt) | 2011-01-11 |
AU4595199A (en) | 2000-02-14 |
US20010007895A1 (en) | 2001-07-12 |
ATE227730T1 (de) | 2002-11-15 |
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