BR9713041A - Composto, composição inseticida acaricida ou nematicida e processos para combater e controlar pragas tipo inseto, ácaro ou nematódeo em um local e para preparar um composto. - Google Patents
Composto, composição inseticida acaricida ou nematicida e processos para combater e controlar pragas tipo inseto, ácaro ou nematódeo em um local e para preparar um composto.Info
- Publication number
- BR9713041A BR9713041A BR9713041-9A BR9713041A BR9713041A BR 9713041 A BR9713041 A BR 9713041A BR 9713041 A BR9713041 A BR 9713041A BR 9713041 A BR9713041 A BR 9713041A
- Authority
- BR
- Brazil
- Prior art keywords
- compound
- formula
- optionally substituted
- group
- alkoxyalkyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 7
- 241000607479 Yersinia pestis Species 0.000 title abstract 4
- 241000238631 Hexapoda Species 0.000 title abstract 3
- 230000000895 acaricidal effect Effects 0.000 title abstract 3
- 241000244206 Nematoda Species 0.000 title abstract 2
- 230000000749 insecticidal effect Effects 0.000 title abstract 2
- 239000005645 nematicide Substances 0.000 title abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 4
- -1 alkenylarylalkylenyl Chemical group 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000004450 alkenylene group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229910052760 oxygen Chemical group 0.000 abstract 2
- 239000001301 oxygen Chemical group 0.000 abstract 2
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 abstract 1
- DBTDEFJAFBUGPP-UHFFFAOYSA-N Methanethial Chemical group S=C DBTDEFJAFBUGPP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical class [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000004442 acylamino group Chemical group 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000005041 acyloxyalkyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000005275 alkylenearyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001721 carbon Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 125000001841 imino group Chemical group [H]N=* 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
- MTCBLMPRPUTXHZ-UHFFFAOYSA-N n-(oxomethylidene)nitramide Chemical compound [O-][N+](=O)N=C=O MTCBLMPRPUTXHZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D451/00—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
- C07D451/02—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D519/00—Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
"COMPOSTO, COMPOSIçãO INSETICIDA, ACARICIDA OU NEMATICIDA E PROCESSOS PARA COMBATER E CONTROLAR PRAGAS TIPO INSETO, áCARO OU NEMATóDEO EM UM LOCAL E PARA PREPARAR UM COMPOSTO". Um composto de fórmula (I): P-R^ 2^-Q, em que cada um de P e Q é, independentemente, um grupo de fórmula (B), em que J é um grupo bidentado de fórmula -CH2-X-CH2- (em que X é metileno, enxofre ou oxigênio), X'C=CY OU X'WC-CYZ ( em que X', W, Y e Z são, independentemente, hidrogênio, hidróxi, acilóxi, alcóxi, alquilsililóxi ou halogênio); R^ 1^é um radical fenila opcionalmente substituído ou sistema de anel heterocíclico de 5 ou 6 membros opcionalmente substituído, contendo de 1 a 3 heteroátomos individualmente selecionados de átomos de nitrogênio, oxigênio e enxofre, e pelo menos uma insaturação (dupla ligação) entre átomos adjacentes no anel, o referido anel heterocíclico sendo opcionalmente fundido a um anel benzênico, em que os substituintes, se presentes, são selecionados de átomos de halogênio, grupos ciano, alquila, alquenila, alquinila, alcóxi, haloalquila, haloalquenila, alquiltio e alquil amino, qualquer um dos referidos grupos contendo até 6 átomos de carbono; R^ 2^é um grupo ligante bidentado e é um grupo alquileno, alquilenoarila, alquilenoeteroarila, alquenileno, alquilenilarilalquilenila, carbonila ou diacila substituído ou não substituído, desde que quando R^ 2^é alquenileno ou alquilenilarilalquilenila, o referido grupo não tenha um átomo de carbono insaturado ligado diretamente ao nitrogênio do anel de fórmula (B). R^ 3^é hidrogênio, ciano, hidróxi, alquila, alcóxi, amino, nitro, isocianato, acilamino, hidroxialquila, heteroarila opcionalmente substituído, alcoxialquila, haloalquila, halohidroxialquila, aralquiloxialquila, aciloxialquila, amidoximido, sulfoniloxialquila, aminoalquila, alcoxicarbonilamino, acilaminoalquila, cianoalquila, imino, formila, acila ou ácido carboxílico ou um éster ou amida do mesmo, ou alquenila ou alquinila qualquer um dos quais é opcionalmente substituído por halogênio, alcóxi, cicloalquila, arila opcionalmente substituído heteroarila opcionalmente substituído ou ciano, ou um sal de adição de ácido, sal quaternário de amónio, ou N-óxido derivado do mesmo; uma composição inseticida, acaricida ou nematicida, compreendendo um composto de fórmula (i) e um portador ou diluente adequado para a mesma; um processo de combater e controlar pragas tipo inseto, ácaro, nematódeo em um local, que compreende tratar as pragas ou o local das pragas com uma quantidade eficaz de um composto de fórmula (I) ou com uma composição como descrita acima.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9623944.7A GB9623944D0 (en) | 1996-11-15 | 1996-11-15 | Bicyclic amine derivatives |
PCT/GB1997/002987 WO1998022462A1 (en) | 1996-11-15 | 1997-10-30 | 8-azabicyclo[3.2.1]octane-, 8-azabicyclo[3.2.1]oct-6-ene-, 9-azabicyclo[3.3.1]nonane-, 9-aza-3-oxabicyclo[3.3.1]nonane-, 9-aza-3-thiabicyclo[3.3.1]nonane derivatives, their preparation and their use as insecticides |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9713041A true BR9713041A (pt) | 2000-04-11 |
Family
ID=10803098
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9713041-9A BR9713041A (pt) | 1996-11-15 | 1997-10-30 | Composto, composição inseticida acaricida ou nematicida e processos para combater e controlar pragas tipo inseto, ácaro ou nematódeo em um local e para preparar um composto. |
Country Status (13)
Country | Link |
---|---|
US (2) | US5912254A (pt) |
EP (1) | EP0944625A1 (pt) |
JP (1) | JP2001504476A (pt) |
KR (1) | KR20000053293A (pt) |
CN (1) | CN1237972A (pt) |
AU (1) | AU4789197A (pt) |
BR (1) | BR9713041A (pt) |
CA (1) | CA2271726A1 (pt) |
GB (1) | GB9623944D0 (pt) |
ID (1) | ID22415A (pt) |
IL (1) | IL129850A0 (pt) |
TR (1) | TR199901057T2 (pt) |
WO (1) | WO1998022462A1 (pt) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6605599B1 (en) | 1997-07-08 | 2003-08-12 | Bristol-Myers Squibb Company | Epothilone derivatives |
WO2002057263A1 (en) * | 2001-01-17 | 2002-07-25 | Syngenta Limited | 8-azabicyclo "3.2.1.! octanes as insecticides |
AU2002953128A0 (en) * | 2002-12-05 | 2002-12-19 | Osmose (Australia) Pty Ltd | Surface treatment for wood and wood products |
PL1731518T3 (pl) | 2004-03-31 | 2014-11-28 | Nippon Soda Co | Cykliczny związek aminowy oraz środek zwalczający szkodniki |
UA86328C2 (uk) * | 2005-10-06 | 2009-04-10 | Ниппон Сода Ко., Лтд. | Циклічні амінові сполуки, засіб для боротьби зі шкідниками |
JP4871289B2 (ja) * | 2005-10-06 | 2012-02-08 | 日本曹達株式会社 | 環状アミン化合物および有害生物防除剤 |
AR067673A1 (es) | 2007-07-26 | 2009-10-21 | Vitae Pharmaceuticals Inc | Derivados de 1,3 oxazinan - 2 - ona como inhibidores ciclicos de la 11 beta -hidroxiesteroide deshidrogenasa 1. composiciones farmaceuticas. |
AR069207A1 (es) | 2007-11-07 | 2010-01-06 | Vitae Pharmaceuticals Inc | Ureas ciclicas como inhibidores de la 11 beta - hidroxi-esteroide deshidrogenasa 1 |
AR069545A1 (es) | 2007-11-16 | 2010-02-03 | Boehringer Ingelheim Pharma | Derivados de aril y heteroarilcarbonilo de benzomorfanos y estructuras relacionadas, composiciones farmaceuticas que contienen dichos compuestos, obtencion de las mismas, su uso en el tratamiento de enfermedades mediadas por la inhibicion de la enzima 11beta-hidroxiesteroide deshidrogenasa (hsd) 1 y |
US8440658B2 (en) | 2007-12-11 | 2013-05-14 | Vitae Pharmaceuticals, Inc. | Cyclic urea inhibitors of 11β-hydroxysteroid dehydrogenase 1 |
TW200934490A (en) | 2008-01-07 | 2009-08-16 | Vitae Pharmaceuticals Inc | Lactam inhibitors of 11 &abgr;-hydroxysteroid dehydrogenase 1 |
WO2009094169A1 (en) | 2008-01-24 | 2009-07-30 | Vitae Pharmaceuticals, Inc. | Cyclic carbazate and semicarbazide inhibitors of 11beta-hydroxysteroid dehydrogenase 1 |
JP5730021B2 (ja) | 2008-02-15 | 2015-06-03 | ヴァイティー ファーマシューティカルズ,インコーポレイテッド | 11β−ヒドロキシステロイドデヒドロゲナーゼ1の阻害剤としてのシクロアルキルラクタム誘導体 |
CA2723034A1 (en) | 2008-05-01 | 2009-11-05 | Vitae Pharmaceuticals, Inc. | Cyclic inhibitors of 11beta-hydroxysteroid dehydrogenase 1 |
US8569292B2 (en) | 2008-05-01 | 2013-10-29 | Vitae Pharmaceuticals, Inc. | Cyclic inhibitors of 11β-hydroxysteroid dehydrogenase 1 |
ES2421537T3 (es) | 2008-05-01 | 2013-09-03 | Vitae Pharmaceuticals Inc | Inhibidores cíclicos de la 11beta-hidroxiesteroide deshidrogenasa 1 |
AR071719A1 (es) | 2008-05-13 | 2010-07-07 | Boehringer Ingelheim Int | Derivados aliciclicos de acido carboxilico de benzomorfanos y estructuras relacionadas, medicamentos que contienen dichos compuestos y su uso.procesos de obtencion |
US8846668B2 (en) | 2008-07-25 | 2014-09-30 | Vitae Pharmaceuticals, Inc. | Inhibitors of 11beta-hydroxysteroid dehydrogenase 1 |
PL2324018T3 (pl) | 2008-07-25 | 2014-02-28 | Boehringer Ingelheim Int | Cykliczne inhibitory dehydrogenazy 11 beta-hydroksysteroidowej typu 1 |
CA2744946A1 (en) | 2009-02-04 | 2010-08-12 | Boehringer Ingelheim International Gmbh | Cyclic inhibitors of 11.beta.-hydroxysteroid dehydrogenase 1 |
US8680093B2 (en) | 2009-04-30 | 2014-03-25 | Vitae Pharmaceuticals, Inc. | Cyclic inhibitors of 11beta-hydroxysteroid dehydrogenase 1 |
US8927539B2 (en) | 2009-06-11 | 2015-01-06 | Vitae Pharmaceuticals, Inc. | Cyclic inhibitors of 11β-hydroxysteroid dehydrogenase 1 based on the 1,3-oxazinan-2-one structure |
UY33001A (es) | 2009-11-06 | 2011-05-31 | Boehringer Ingelheim Int | Derivados arilo y heteroarilcarbonilo de hexahidroindenopiridina y octahidrobenzoquinolina |
EP2500345B1 (en) | 2009-11-11 | 2015-01-28 | Sumitomo Dainippon Pharma Co., Ltd. | 8-azabicyclo[3.2.1]octane-8-carboxamide derivative |
US8933072B2 (en) | 2010-06-16 | 2015-01-13 | Vitae Pharmaceuticals, Inc. | Substituted 5-,6- and 7-membered heterocycles, medicaments containing such compounds, and their use |
JP5813106B2 (ja) | 2010-06-25 | 2015-11-17 | ベーリンガー インゲルハイム インターナショナル ゲゼルシャフト ミット ベシュレンクテル ハフツング | 代謝障害の処置のための11−β−HSD1のインヒビターとしてのアザスピロヘキサノン |
AU2011325286B2 (en) | 2010-11-02 | 2015-04-16 | Boehringer Ingelheim International Gmbh | Pharmaceutical combinations for the treatment of metabolic disorders |
TWI537258B (zh) | 2010-11-05 | 2016-06-11 | 百靈佳殷格翰國際股份有限公司 | 六氫茚并吡啶及八氫苯并喹啉之芳基-及雜環芳基羰基衍生物 |
EP2744783A1 (en) | 2011-08-17 | 2014-06-25 | Boehringer Ingelheim International GmbH | Indenopyridine derivatives |
EA201500984A1 (ru) * | 2013-03-28 | 2016-04-29 | Зингента Партисипейшнс Аг | Способы контроля устойчивых к неоникотиноидам вредителей |
EA201500982A1 (ru) * | 2013-03-28 | 2016-03-31 | Зингента Партисипейшнс Аг | Способы контроля устойчивых к неоникотиноидам вредителей |
MX2015013628A (es) * | 2013-03-28 | 2016-02-18 | Syngenta Ltd | Metodos para controlar las plagas resistentes a neonicotinoides. |
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US5244906A (en) * | 1992-01-23 | 1993-09-14 | Dowelanco | Insect control with substituted oxadiazole and thiadiazole compounds |
DK78692D0 (da) * | 1992-06-12 | 1992-06-12 | Lundbeck & Co As H | Dimere piperidin- og piperazinderivater |
AU7474794A (en) * | 1993-07-22 | 1995-02-20 | E.I. Du Pont De Nemours And Company | Arthropodicidal azacyclic heterocycles |
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GB9510459D0 (en) * | 1995-05-24 | 1995-07-19 | Zeneca Ltd | Bicyclic amines |
ATE362931T1 (de) * | 1995-10-13 | 2007-06-15 | Neurosearch As | 8-azabicyclo(3.2.1)oct-2en-derivate, deren herstellung und anwendung |
IL126882A0 (en) * | 1996-05-13 | 1999-09-22 | Zeneca Ltd | Bicyclic amines as insecticides |
-
1996
- 1996-11-15 GB GBGB9623944.7A patent/GB9623944D0/en active Pending
-
1997
- 1997-10-30 BR BR9713041-9A patent/BR9713041A/pt not_active Application Discontinuation
- 1997-10-30 ID IDW990366A patent/ID22415A/id unknown
- 1997-10-30 KR KR1019990704276A patent/KR20000053293A/ko not_active Application Discontinuation
- 1997-10-30 CA CA002271726A patent/CA2271726A1/en not_active Abandoned
- 1997-10-30 IL IL12985097A patent/IL129850A0/xx unknown
- 1997-10-30 TR TR1999/01057T patent/TR199901057T2/xx unknown
- 1997-10-30 CN CN97199712A patent/CN1237972A/zh active Pending
- 1997-10-30 WO PCT/GB1997/002987 patent/WO1998022462A1/en not_active Application Discontinuation
- 1997-10-30 AU AU47891/97A patent/AU4789197A/en not_active Abandoned
- 1997-10-30 JP JP52330498A patent/JP2001504476A/ja active Pending
- 1997-10-30 EP EP97910544A patent/EP0944625A1/en not_active Withdrawn
- 1997-11-13 US US08/969,635 patent/US5912254A/en not_active Expired - Fee Related
-
1999
- 1999-02-12 US US09/248,930 patent/US6066646A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO1998022462A1 (en) | 1998-05-28 |
KR20000053293A (ko) | 2000-08-25 |
CN1237972A (zh) | 1999-12-08 |
CA2271726A1 (en) | 1998-05-28 |
JP2001504476A (ja) | 2001-04-03 |
ID22415A (id) | 1999-10-14 |
EP0944625A1 (en) | 1999-09-29 |
GB9623944D0 (en) | 1997-01-08 |
US6066646A (en) | 2000-05-23 |
IL129850A0 (en) | 2000-02-29 |
TR199901057T2 (pt) | 1999-07-21 |
AU4789197A (en) | 1998-06-10 |
US5912254A (en) | 1999-06-15 |
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