BR112018077299A2 - composição de polímero de buteno-1 que tem um alto índice de fluidez - Google Patents

composição de polímero de buteno-1 que tem um alto índice de fluidez

Info

Publication number
BR112018077299A2
BR112018077299A2 BR112018077299A BR112018077299A BR112018077299A2 BR 112018077299 A2 BR112018077299 A2 BR 112018077299A2 BR 112018077299 A BR112018077299 A BR 112018077299A BR 112018077299 A BR112018077299 A BR 112018077299A BR 112018077299 A2 BR112018077299 A2 BR 112018077299A2
Authority
BR
Brazil
Prior art keywords
butene
polymer composition
mol
melt index
high melt
Prior art date
Application number
BR112018077299A
Other languages
English (en)
Other versions
BR112018077299B1 (pt
Inventor
Burgin Emanuele
Marchini Roberta
Pica Roberta
Spataro Stefano
Original Assignee
Basell Poliolefine Italia Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia Srl filed Critical Basell Poliolefine Italia Srl
Publication of BR112018077299A2 publication Critical patent/BR112018077299A2/pt
Publication of BR112018077299B1 publication Critical patent/BR112018077299B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15Isotactic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

trata-se de uma composição de polímero de buteno-1 que tem valores de mfr de 400 a 2.000 g/10 min, medidos em conformidade com a norma iso 1133 a 190 °c com uma carga de 2,16 kg que compreende: a) um homopolímero de buteno-1 ou um copolímero de buteno-1 com um ou mais comonômeros selecionados dentre etileno e alfa-olefinas superiores, que tem um teor de comonômero copolimerizado de até 5% em mol; b) um copolímero de buteno-1 com um ou mais comonômeros selecionados dentre etileno e alfa-olefinas superiores, que tem um teor de comonômero copolimerizado de 6% a 25% em mol; em que a dita composição tem um teor de comonômero copolimerizado total de 5% a 18% em mol, em relação à soma de a) e b), e um teor de fração solúvel em xileno a 0 °c de 65% em peso ou mais, determinado no peso total de a) e b).
BR112018077299-2A 2016-07-07 2017-07-03 Composição de polímero de buteno-1, processo para sua preparação e composição adesiva termofundida BR112018077299B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16178433.5A EP3266825B1 (en) 2016-07-07 2016-07-07 Butene-1 polymer composition having a high melt flow rate
EP16178433.5 2016-07-07
PCT/EP2017/066423 WO2018007279A1 (en) 2016-07-07 2017-07-03 Butene-1 polymer composition having a high melt flow rate

Publications (2)

Publication Number Publication Date
BR112018077299A2 true BR112018077299A2 (pt) 2019-04-02
BR112018077299B1 BR112018077299B1 (pt) 2022-09-27

Family

ID=56372804

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018077299-2A BR112018077299B1 (pt) 2016-07-07 2017-07-03 Composição de polímero de buteno-1, processo para sua preparação e composição adesiva termofundida

Country Status (11)

Country Link
US (1) US11015090B2 (pt)
EP (2) EP3266825B1 (pt)
JP (1) JP6896000B2 (pt)
KR (1) KR102140901B1 (pt)
CN (1) CN109312130B (pt)
BR (1) BR112018077299B1 (pt)
ES (1) ES2909805T3 (pt)
PL (1) PL3266825T3 (pt)
PT (1) PT3266825T (pt)
WO (1) WO2018007279A1 (pt)
ZA (1) ZA201807545B (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105722934B (zh) * 2013-11-25 2018-01-02 巴塞尔聚烯烃意大利有限公司 聚烯烃基热熔粘合剂组合物
PL3481896T3 (pl) * 2016-07-07 2020-12-28 Savare' I.C. S.R.L. Kleje termotopliwe nadające się do przetwarzania w procesach o dużej prędkości
ES2909824T3 (es) * 2016-07-07 2022-05-10 Basell Poliolefine Italia Srl Composición de polímero de 1-buteno que tiene un alto índice de fluidez en estado fundido
WO2019025583A1 (en) * 2017-08-04 2019-02-07 Basell Poliolefine Italia S.R.L. BUTENE-1 POLYMER COMPOSITION WITH HIGH FLUIDITY INDEX
KR102380041B1 (ko) * 2017-08-04 2022-03-29 바셀 폴리올레핀 이탈리아 에스.알.엘 높은 용융 유량을 갖는 부텐-1 중합체 조성물
US12012527B2 (en) 2018-07-18 2024-06-18 Basell Poliolefine Italia S.R.L. Polyolefin-based hot melt adhesive composition
PL3880260T3 (pl) 2018-11-15 2023-09-18 H.B. Fuller Company Kompozycje klejów termotopliwych zawierające wielocentrowo katalizowany, amorficzny polimer polialfaolefinowy i wyroby zawierające ten polimer
EP3835363A1 (en) 2019-12-12 2021-06-16 Basell Poliolefine Italia S.r.l. Mixtures of bitumen and 1-butene polymers
IT202000001660A1 (it) 2020-01-29 2021-07-29 Savare I C S R L Adesivi termofusibili con migliorata adesione e coesione
CN116348546A (zh) 2020-10-22 2023-06-27 巴塞尔聚烯烃意大利有限公司 用于注塑的聚合物组合物
CN115991804A (zh) * 2021-10-20 2023-04-21 中国石油化工股份有限公司 聚1-丁烯及其制备方法
WO2023187700A1 (en) 2022-04-01 2023-10-05 Savare' I.C. S.R.L. Hot-melt adhesives comprising butene-1 polymers and showing peculiar thermal characteristics

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677025A (en) * 1985-08-30 1987-06-30 Shell Oil Company Unique molecular weight distribution polybutylene blend and film
AU614784B2 (en) 1987-10-30 1991-09-12 Mitsui Petrochemical Industries, Ltd. Hot melt adhesive containing butene-1 polymers
US4824889A (en) 1987-10-30 1989-04-25 Shell Oil Company Poly-1-butene blend adhesives
US4937138A (en) 1988-02-29 1990-06-26 Shell Oil Company Hot melt polybutylene and poly(butylene/ethylene) adhesives and laminar structures
US4833192A (en) 1988-05-12 1989-05-23 Baychem International, Inc. Compatible polymer blends useful as melt adhesives (II)
JPH09302038A (ja) * 1996-03-14 1997-11-25 Mitsui Petrochem Ind Ltd ブテン−プロピレン系共重合体およびポリブテン−1樹脂組成物
EP1854804B1 (en) 1999-12-28 2011-05-04 Basell Polyolefine GmbH Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
DE60126952T2 (de) * 2000-07-03 2007-10-31 Mitsui Chemicals, Inc. Butencopolymer, harzzusammensetzung die dieses enthält sowie formmassen aus der zusammensetzung
JP2002241553A (ja) * 2000-11-30 2002-08-28 Mitsui Chemicals Inc ポリ1−ブテン樹脂組成物およびその用途
WO2003070788A1 (en) 2002-02-21 2003-08-28 Idemitsu Petrochemical Co., Ltd. Highly flowable 1-butene polymer and process for producing the same
JP4771938B2 (ja) 2003-05-12 2011-09-14 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
JP5006783B2 (ja) 2004-07-13 2012-08-22 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物、それらの調製で使用される配位子、1−ブテンポリマーの調製法、およびその方法から得られる1−ブテンポリマー
ATE388994T1 (de) 2004-07-22 2008-03-15 Basell Polyolefine Gmbh 1-butenpolymerzusammensetzung
PL1805231T3 (pl) 2004-10-18 2010-08-31 Basell Poliolefine Italia Srl (Ko)polimery butenu-1 o niskiej izotaktyczności
ATE501183T1 (de) 2004-10-21 2011-03-15 Basell Polyolefine Gmbh 1-buten-polymer und herstellungsverfahren dafür
JP5027665B2 (ja) 2004-10-21 2012-09-19 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンポリマー及びこの調製方法
US7981993B2 (en) 2007-06-25 2011-07-19 Basell Polyolefine Gmbh 1-butene ethylene copolymers
DE102008005949A1 (de) 2008-01-24 2009-07-30 Evonik Degussa Gmbh Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung
ATE543870T1 (de) 2008-03-20 2012-02-15 Basell Poliolefine Srl Zusammensetzungen aus polymeren auf 1-buten-basis
JP6005649B2 (ja) 2010-10-21 2016-10-12 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ブテン−1コポリマーを用いる感圧接着剤
US9505958B2 (en) 2012-09-14 2016-11-29 Mitsui Chemicals, Inc. 1-butene α-olefin copolymer composition
US8865824B2 (en) 2012-09-19 2014-10-21 IFS Industries Inc. Hot melt adhesive
WO2014069604A1 (ja) * 2012-11-02 2014-05-08 出光興産株式会社 粘接着剤組成物及びこれを用いた粘着テープ
CN105722934B (zh) 2013-11-25 2018-01-02 巴塞尔聚烯烃意大利有限公司 聚烯烃基热熔粘合剂组合物
ES2909824T3 (es) * 2016-07-07 2022-05-10 Basell Poliolefine Italia Srl Composición de polímero de 1-buteno que tiene un alto índice de fluidez en estado fundido

Also Published As

Publication number Publication date
CN109312130B (zh) 2022-01-18
US11015090B2 (en) 2021-05-25
BR112018077299B1 (pt) 2022-09-27
PL3266825T3 (pl) 2022-05-09
ZA201807545B (en) 2019-08-28
EP3266825B1 (en) 2022-03-09
WO2018007279A1 (en) 2018-01-11
JP2019525969A (ja) 2019-09-12
KR20190021383A (ko) 2019-03-05
EP3481895A1 (en) 2019-05-15
KR102140901B1 (ko) 2020-08-05
JP6896000B2 (ja) 2021-06-30
CN109312130A (zh) 2019-02-05
US20190256747A1 (en) 2019-08-22
ES2909805T3 (es) 2022-05-10
EP3266825A1 (en) 2018-01-10
PT3266825T (pt) 2022-04-11

Similar Documents

Publication Publication Date Title
BR112018077293A2 (pt) composição de polímero de buteno-1 que tem um alto índice de fluidez
BR112018077299A2 (pt) composição de polímero de buteno-1 que tem um alto índice de fluidez
BR112018010717A2 (pt) composição de polímero à base de propileno
ES2571587T3 (es) Composición de poliolefina de alta fluidez con rigidez y resistencia a la perforación elevadas
BR112017010838A2 (pt) polietileno de alta densidade (hdpe)
BR112017003388A2 (pt) composição adesiva de fusão a quente incluindo um composto em bloco cristalino
BR112016016262A8 (pt) copolímeros de impacto baseados em propileno, composição de poliolefina termoplástica e componentes automativos interior e exterior
BR112017003374A2 (pt) nucleação com nucleador de compósito em bloco
BR112019004611A2 (pt) composição à base de propileno para tubos
BR112014003238A2 (pt) sistema heterofásico com propriedades de superfície melhoradas
BR112015022786A2 (pt) filmes de polímero tendo propriedades de selagem térmica melhoradas
BR112015028319A2 (pt) copolímero de propileno para embalagem com pequena espessura
BR112014014803A2 (pt) copolímero de propileno para películas ou artigos moldados por injeção
ES2542435T3 (es) Modificador del defecto de rayas de tigre
BR112017003445A2 (pt) composição adesiva de fusão a quente incluindo um compatibilizante de compósito de bloco
BR112015026919A2 (pt) composição de polipropileno multimodal, composição de copolímero de propileno multimodal, processo para produzir composição, processo com múltiplos estágios, artigo
BR112018074650A2 (pt) mesclas de poliolefina termoplástica que têm desempenho de choque de baixa temperatura melhorado
BR112015005700A2 (pt) polímeros à base de etileno e artigos produzidos a partir deles
BR112015032443A2 (pt) composição de polietileno e seu uso, artigo
BR112018001587A2 (pt) composições elásticas à base de poliolefina, métodos de fabricação das mesmas e artigos compreendendo as mesmas
BR112012018283A2 (pt) fibra moldada por sopro em fusão
BR112014013540A2 (pt) terpolímeros para tubos à base de propileno
BR112016024101A2 (pt) copolímeros aleatórios de propileno e etileno com múltiplas camadas
BR112016024693A2 (pt) tubo compreendendo uma resina de polietileno catalisada com metaloceno
BR112019009248A2 (pt) copolímeros de propileno heterofásicos

Legal Events

Date Code Title Description
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/07/2017, OBSERVADAS AS CONDICOES LEGAIS