BR112017012698A2 - catalisador ziegler-natta e preparação do mesmo - Google Patents

catalisador ziegler-natta e preparação do mesmo

Info

Publication number
BR112017012698A2
BR112017012698A2 BR112017012698A BR112017012698A BR112017012698A2 BR 112017012698 A2 BR112017012698 A2 BR 112017012698A2 BR 112017012698 A BR112017012698 A BR 112017012698A BR 112017012698 A BR112017012698 A BR 112017012698A BR 112017012698 A2 BR112017012698 A2 BR 112017012698A2
Authority
BR
Brazil
Prior art keywords
catalyst component
natta catalyst
group
preparation
relates
Prior art date
Application number
BR112017012698A
Other languages
English (en)
Other versions
BR112017012698B1 (pt
Inventor
Thorman Joseph
Sumerin Victor
Original Assignee
Borealis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Ag filed Critical Borealis Ag
Publication of BR112017012698A2 publication Critical patent/BR112017012698A2/pt
Publication of BR112017012698B1 publication Critical patent/BR112017012698B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

a invenção refere-se a um componente de catalisador natta baseado em mgcl2 sólido (que foi preparado ao pré-tratar aduto de mgcl2*mroh com o composto do grupo de metal 13 e composto orgânico interno sendo éter bicíclico, e ainda tratado com composto de metal de transição de grupo 4 ou 6) para a produção de polímeros de olefina e preparação do referido componente de catalisador. além disso, a invenção refere-se a um catalisador ziegler natta que compreende o referido componente de catalisador sólido, composto de metal do grupo 13 como cocatalisador e, opcionalmente, aditivos externos. a invenção refere-se ainda à utilização do referido componente de catalisador na produção de polímeros de olefina, especialmente polímeros de etileno com as propriedades desejadas.
BR112017012698-2A 2014-12-18 2015-12-17 Catalisador ziegler-natta, componente de catalisador suportado em cloreto de magnésio sólido, seu uso, seu método de produção e processo para a produção de polímero de etileno BR112017012698B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14198874 2014-12-18
EP14198874.1 2014-12-18
PCT/EP2015/080316 WO2016097193A1 (en) 2014-12-18 2015-12-17 Ziegler-natta catalyst and preparation thereof

Publications (2)

Publication Number Publication Date
BR112017012698A2 true BR112017012698A2 (pt) 2018-01-02
BR112017012698B1 BR112017012698B1 (pt) 2021-10-26

Family

ID=52130078

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017012698-2A BR112017012698B1 (pt) 2014-12-18 2015-12-17 Catalisador ziegler-natta, componente de catalisador suportado em cloreto de magnésio sólido, seu uso, seu método de produção e processo para a produção de polímero de etileno

Country Status (11)

Country Link
US (1) US10118977B2 (pt)
EP (1) EP3233935B1 (pt)
JP (2) JP6822959B2 (pt)
KR (1) KR102542653B1 (pt)
CN (1) CN107108803B (pt)
BR (1) BR112017012698B1 (pt)
CA (1) CA2970848C (pt)
EA (1) EA033278B1 (pt)
ES (1) ES2759324T3 (pt)
TW (1) TWI693240B (pt)
WO (1) WO2016097193A1 (pt)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3385958B1 (en) 2017-04-06 2023-05-31 Borealis AG Cable jacket composition
EP3385959A1 (en) * 2017-04-06 2018-10-10 Borealis AG Cable jacket composition
CN106928380B (zh) * 2017-04-19 2019-10-11 大连理工大学 一种含呋喃类组分的齐格勒-纳塔催化剂及其制备方法
EP3418330B2 (en) 2017-06-21 2023-07-19 Borealis AG Polymer composition and a process for production of the polymer composition
EP3466708A1 (en) 2017-10-04 2019-04-10 Borealis AG Polyolefin composition for enhanced laser printing
EP3732208A1 (en) * 2017-12-27 2020-11-04 Borealis AG Ziegler-natta catalyst and preparation thereof
CN111566131B (zh) * 2017-12-28 2024-04-26 博里利斯股份公司 催化剂及其制备方法
EP3746492B1 (en) 2018-01-30 2022-10-26 Borealis AG Coupling agent
US11680114B2 (en) 2018-07-19 2023-06-20 Borealis Ag Process for the preparation of an UHMWPE homopolymer
US11897975B2 (en) 2018-09-28 2024-02-13 Borealis Ag Multi-stage process for producing a C2 to C8 olefin polymer composition
EP3873954A1 (en) 2018-10-31 2021-09-08 Borealis AG Polyethylene composition for high pressure resistant pipes with improved homogeneity
EP3647645A1 (en) 2018-10-31 2020-05-06 Borealis AG Polyethylene composition for high pressure resistant pipes
CN113166292A (zh) 2018-11-30 2021-07-23 博里利斯股份公司 洗涤工艺
WO2021064083A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
US20220411543A1 (en) 2019-10-04 2022-12-29 Borealis Ag Ziegler-natta catalysts for olefin polymerization
WO2021064080A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
CN114585654B (zh) * 2019-10-04 2023-11-07 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
EP3892653A1 (en) 2020-04-09 2021-10-13 Borealis AG (co)polymerization of ethylene
WO2022008608A1 (en) 2020-07-10 2022-01-13 Borealis Ag Polyolefin composition with improved resistance to high temperature
WO2022008607A1 (en) 2020-07-10 2022-01-13 Borealis Ag Polyethylene pipe resin with high resistance to slow crack growth
EP3988587A1 (en) 2020-10-26 2022-04-27 Borealis AG Polyolefin pipe resin with very good sagging and slow crack growth resistance
CN116601177A (zh) 2020-11-27 2023-08-15 博里利斯股份公司 工艺
EP4151677A1 (en) 2021-09-21 2023-03-22 Borealis AG Biaxially oriented film
EP4163323B1 (en) 2021-10-07 2024-05-29 Borealis AG Biaxially oriented film
EP4201969A1 (en) 2021-12-23 2023-06-28 Borealis AG Polyethylene composition for pipes having very good impact properties and slow crack growth resistance
KR20240107351A (ko) 2021-12-23 2024-07-09 보레알리스 아게 매우 좋은 충격 특성 및 저속 균열 성장 저항성을 가지는 파이프용 중합체 조성물
EP4209546A1 (en) 2022-01-10 2023-07-12 Abu Dhabi Polymers Co. Ltd (Borouge) LLC Polyethylene pipe resin with improved long term hydrostatic strength
EP4234627A1 (en) 2022-02-25 2023-08-30 Borealis AG A polyethylene composition with improved stiffness and toughness
EP4234614A1 (en) 2022-02-25 2023-08-30 Borealis AG A film comprising a polyethylene composition having improved gloss
EP4234626B1 (en) 2022-02-25 2024-07-03 Borealis AG A polyethylene composition with improved stiffness and toughness
EP4239014A1 (en) 2022-03-02 2023-09-06 Borealis AG Film comprising a polyethylene composition
EP4239015B1 (en) 2022-03-02 2024-05-22 Borealis AG Monoaxially oriented film comprising a polyethylene composition
EP4245805A1 (en) 2022-03-18 2023-09-20 Borealis AG Polyethylene blend for a film layer
EP4306444A1 (en) 2022-07-14 2024-01-17 Borealis AG Composition
EP4306442A1 (en) 2022-07-14 2024-01-17 Borealis AG Composition
EP4386046A1 (en) 2022-12-16 2024-06-19 Borealis AG Composition

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FI83331C (fi) * 1988-12-30 1991-06-25 Neste Oy Framstaellning och anvaendning av en ny ziegler-natta-katalysatorkomponent.
FI84357C (fi) 1989-10-20 1991-11-25 Neste Oy Foerfarande och apparatur foer framstaellning av baerare foer polymerisationskatalysatorer.
FI84319C (fi) 1989-11-14 1991-11-25 Neste Oy Anordning foer matning av en slammig katalytblandning till en polymerisationsreaktor.
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
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FI90248C (fi) 1991-11-29 1994-01-10 Borealis As Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
FI942949A0 (fi) 1994-06-20 1994-06-20 Borealis Polymers Oy Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
US5767034A (en) 1996-05-31 1998-06-16 Intevep, S.A. Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives
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GB0001914D0 (en) 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
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MXPA05006584A (es) 2002-12-18 2005-08-16 Basell Poliolefine Spa Componentes de catalizador para la polimerizacion de olefinas.
FI20040755A0 (fi) 2004-06-02 2004-06-02 Borealis Tech Oy Menetelmä olefiinipolymerointikatalyytin valmistamiseksi ja tällä menetelmällä valmistettu katalyytti
ES2309445T3 (es) 2004-12-17 2008-12-16 Borealis Technology Oy Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas.
EP1780225A1 (en) 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
US8575283B1 (en) 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
EP2746306B1 (en) 2012-12-21 2017-10-04 Borealis AG Supported Ziegler Natta procatalyst for ethylene polymerisation
EP2799456B1 (en) 2013-04-30 2018-11-21 Borealis AG Supported donor modified Ziegler-Natta catalysts

Also Published As

Publication number Publication date
CA2970848A1 (en) 2016-06-23
ES2759324T3 (es) 2020-05-08
KR102542653B1 (ko) 2023-06-09
JP6822959B2 (ja) 2021-01-27
CN107108803A (zh) 2017-08-29
CN107108803B (zh) 2021-03-16
EP3233935B1 (en) 2019-11-20
WO2016097193A1 (en) 2016-06-23
EP3233935A1 (en) 2017-10-25
CA2970848C (en) 2023-04-11
EA201791136A1 (ru) 2017-12-29
US20170349683A1 (en) 2017-12-07
JP2020186408A (ja) 2020-11-19
US10118977B2 (en) 2018-11-06
BR112017012698B1 (pt) 2021-10-26
TWI693240B (zh) 2020-05-11
TW201638117A (zh) 2016-11-01
JP2017538026A (ja) 2017-12-21
KR20170095277A (ko) 2017-08-22
EA033278B1 (ru) 2019-09-30

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/12/2015, OBSERVADAS AS CONDICOES LEGAIS.