BR0313794A - Conversão de oxigenados em olefinas sobre um catalizador compreendendo uma peneira molecular ácida de átomo de carbono controlado para uma taxa de região ácida - Google Patents

Conversão de oxigenados em olefinas sobre um catalizador compreendendo uma peneira molecular ácida de átomo de carbono controlado para uma taxa de região ácida

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Publication number
BR0313794A
BR0313794A BR0313794-5A BR0313794A BR0313794A BR 0313794 A BR0313794 A BR 0313794A BR 0313794 A BR0313794 A BR 0313794A BR 0313794 A BR0313794 A BR 0313794A
Authority
BR
Brazil
Prior art keywords
molecular sieve
catalyst particles
catalyst
acid
carbon atom
Prior art date
Application number
BR0313794-5A
Other languages
English (en)
Inventor
Paul N Chisholm
Nicolas P Coute
James R Lattner
Teng Xu
Jeffrey S Smith
Keith H Kuechler
Original Assignee
Exxonmobil Chemical Patentes I
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patentes I filed Critical Exxonmobil Chemical Patentes I
Publication of BR0313794A publication Critical patent/BR0313794A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/708—Coking aspect, coke content and composition of deposits
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"CONVERSãO DE OXIGENADOS EM OLEFINAS SOBRE UM CATALISADOR COMPREENDENDO UMA PENEIRA MOLECULAR áCIDA DE áTOMO DE CARBONO CONTROLADO PARA UMA TAXA DE REGIãO áCIDA". A presente invenção fornece um processo para produção de um produto olefina a partir de uma matéria-prima contendo oxigenado compreendendo: a) contatar a matéria-prima em uma zona de reação com partículas catalisadoras compreendendo uma peneira molecular contendo regiões ácidas e tendo uma carga média de coque de 1 a 10 átomos de carbono por região ácida da mencionada peneira molecular, sob condições eficazes para converter a matéria-prima em uma corrente de produto olefina e fornecer partículas catalisadoras não regeneradas, b) remover uma porção das mencionadas partículas catalisadoras da mencionada zona de reação e contatar a mencionada porção com um meio de regeneração em uma zona de regeneração sob condições eficazes para se obter partículas catalisadoras regeneradas que têm uma carga média de coque de não mais que 10 átomos de carbono por região ácida da mencionada peneira molecular, e c) introduzir as mencionadas partículas catalisadoras regeneradas na mencionada zona de reação para fornecer uma mistura catalisadora de partículas catalisadoras não regeneradas e partículas catalisadoras regeneradas, em uma quantidade suficiente para fornecer uma carga média de coque na mencionada mistura catalisadora em uma quantidade variando de 1 a 10 átomos de carbono por região ácida da mencionada peneira molecular.
BR0313794-5A 2002-08-26 2003-06-02 Conversão de oxigenados em olefinas sobre um catalizador compreendendo uma peneira molecular ácida de átomo de carbono controlado para uma taxa de região ácida BR0313794A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/227,907 US7227048B2 (en) 2001-12-31 2002-08-26 Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio
PCT/US2003/017365 WO2004018392A1 (en) 2002-08-26 2003-06-02 Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio

Publications (1)

Publication Number Publication Date
BR0313794A true BR0313794A (pt) 2005-07-12

Family

ID=32092295

Family Applications (1)

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BR0313794-5A BR0313794A (pt) 2002-08-26 2003-06-02 Conversão de oxigenados em olefinas sobre um catalizador compreendendo uma peneira molecular ácida de átomo de carbono controlado para uma taxa de região ácida

Country Status (10)

Country Link
US (1) US7227048B2 (pt)
EP (1) EP1532088B1 (pt)
KR (1) KR20050038635A (pt)
CN (1) CN100443452C (pt)
AT (1) ATE530510T1 (pt)
AU (1) AU2003240487A1 (pt)
BR (1) BR0313794A (pt)
EA (1) EA008804B1 (pt)
TW (1) TWI224087B (pt)
WO (1) WO2004018392A1 (pt)

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CN102190537B (zh) * 2010-03-03 2013-10-16 中国石油化工股份有限公司 甲醇或二甲醚生产轻质烯烃过程中提高产品收率的方法
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CN102344366A (zh) * 2011-08-08 2012-02-08 江苏沿江化工资源开发研究院有限公司 两股溶剂侧线进料液液萃取提取丙烯酸丁酯的方法
CN103772092B (zh) * 2012-10-25 2016-04-13 中国石油化工股份有限公司 甲醇转化为低碳烯烃的反应装置
CN103772091B (zh) * 2012-10-25 2016-04-13 中国石油化工股份有限公司 由甲醇生产低碳烯烃的方法
CN103212347A (zh) * 2013-04-09 2013-07-24 张济宇 一种用于甲醇制低碳烯烃的高空速提升管反应器及应用
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CN104289115B (zh) * 2014-08-25 2016-06-01 南京工业大学 一种高硅cha型ssz-13分子筛膜的制备方法
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CN113751066B (zh) * 2020-06-05 2023-08-29 中国石油化工股份有限公司 合成气直接制备乙烯和丙烯的催化剂组合物及其用途
CN114620743A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种大晶粒rho-sapo分子筛、其制备方法及其应用
CN115845933A (zh) * 2022-11-15 2023-03-28 国家能源集团宁夏煤业有限责任公司 一种分子筛催化剂的再生方法

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CN1681752A (zh) 2005-10-12
ATE530510T1 (de) 2011-11-15
US20030125598A1 (en) 2003-07-03
US7227048B2 (en) 2007-06-05
TWI224087B (en) 2004-11-21
EA008804B1 (ru) 2007-08-31
KR20050038635A (ko) 2005-04-27
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EP1532088B1 (en) 2011-10-26
CN100443452C (zh) 2008-12-17

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