BR0205814A - Processo para a oxidação catalìtica de compostos sulfurados, nitrogenados e insaturados de correntes de hidrocarbonetos fósseis, processo para a remoção de ditos compostos, processo para obter uma corrente de hidrocarboneto adequada para processos de refino através de oxidação catalìtica e processo para obter um produto profundamente dessulfurizado e profundamente desnitrificado - Google Patents
Processo para a oxidação catalìtica de compostos sulfurados, nitrogenados e insaturados de correntes de hidrocarbonetos fósseis, processo para a remoção de ditos compostos, processo para obter uma corrente de hidrocarboneto adequada para processos de refino através de oxidação catalìtica e processo para obter um produto profundamente dessulfurizado e profundamente desnitrificadoInfo
- Publication number
- BR0205814A BR0205814A BR0205814-6A BR0205814A BR0205814A BR 0205814 A BR0205814 A BR 0205814A BR 0205814 A BR0205814 A BR 0205814A BR 0205814 A BR0205814 A BR 0205814A
- Authority
- BR
- Brazil
- Prior art keywords
- catalytic oxidation
- deeply
- obtaining
- compounds
- fossil
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 12
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 5
- 238000007254 oxidation reaction Methods 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 238000007670 refining Methods 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title abstract 2
- 239000011593 sulfur Substances 0.000 title abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000356 contaminant Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- CUPCBVUMRUSXIU-UHFFFAOYSA-N [Fe].OOO Chemical compound [Fe].OOO CUPCBVUMRUSXIU-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910021519 iron(III) oxide-hydroxide Inorganic materials 0.000 abstract 1
- -1 limonite clay Chemical compound 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 150000004965 peroxy acids Chemical class 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
Abstract
"PROCESSO PARA A OXIDAçãO CATALìTICA DE COMPOSTOS SULFURADOS, NITROGENADOS E INSATURADOS DE CORRENTES DE HIDROCARBONETOS FóSSEIS, PROCESSO PARA A REMOçãO DE DITOS COMPOSTOS, PROCESSO PARA OBTER UMA CORRENTE DE HIDROCARBONETO ADEQUADA PARA PROCESSOS DE REFINO ATRAVéS DE OXIDAçãO CATALìTICA E PROCESSO PARA OBTER UM PRODUTO PROFUNDAMENTE DESSULFURIZADO E PROFUNDAMENTE DESNITRIFICADO". é descrito um processo para a oxidação catalítica de contaminantes sulfurados e nitrogenados bem como de compostos insaturados presentes em um meio hidrocarboneto fóssil, o processo compreendendo efetuar a oxidação em presença de pelo menos um peróxido, pelo menos um ácido e um óxido de ferro bruto pulverizado. O processo apresenta um poder de oxidação aperfeiçoado em relação aos contaminantes tipicamente presentes em meio óleo fóssil, isto derivando da combinação do peroxiácido e do radical hidroxila gerados no meio reacional devido à presença de um oxihidróxido de ferro como a argila limonita, que apresenta uma afinidade particular pelo meio oleoso. O processo encontra uso em várias aplicações, desde uma carga para refino até a preparação de produtos profundamente dessulfurizados e desnitrificados.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/855,947 US6544409B2 (en) | 2001-05-16 | 2001-05-16 | Process for the catalytic oxidation of sulfur, nitrogen and unsaturated compounds from hydrocarbon streams |
| PCT/BR2002/000063 WO2002092726A2 (en) | 2001-05-16 | 2002-05-03 | Process for the catalytic oxidation of sulfur, nitrogen and unsaturated compounds from hydrocarbon streams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0205814A true BR0205814A (pt) | 2003-07-15 |
| BR0205814B1 BR0205814B1 (pt) | 2013-03-05 |
Family
ID=25322499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0205814-6A BR0205814B1 (pt) | 2001-05-16 | 2002-05-03 | processo para a oxidaÇço catalÍtica de compostos sulfurados, nitrogenados e insaturados de correntes de hidrocarbonetos fàsseis, processo para a remoÇço de ditos compostos, processo para obter uma corrente de hidrocarboneto adequada para processos de refino atravÉs de oxidaÇço catalÍtica e processo para obter um produto profundamente dessulfurizado e profundamente desnitrificado. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6544409B2 (pt) |
| EP (1) | EP1390441B1 (pt) |
| JP (1) | JP4159368B2 (pt) |
| AR (1) | AR033741A1 (pt) |
| AU (1) | AU2002252859A1 (pt) |
| BR (1) | BR0205814B1 (pt) |
| ES (1) | ES2274970T3 (pt) |
| WO (1) | WO2002092726A2 (pt) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7153414B2 (en) * | 2002-12-10 | 2006-12-26 | Petroleo Brasileiro S.A.-Petrobras | Process for the upgrading of raw hydrocarbon streams |
| US7252756B2 (en) | 2002-12-18 | 2007-08-07 | Bp Corporation North America Inc. | Preparation of components for refinery blending of transportation fuels |
| US7175755B2 (en) * | 2003-05-06 | 2007-02-13 | Petroleo Brasileiro S.A.-Petrobras | Process for the extractive oxidation of contaminants from raw hydrocarbon streams |
| US7666297B2 (en) * | 2004-11-23 | 2010-02-23 | Cpc Corporation, Taiwan | Oxidative desulfurization and denitrogenation of petroleum oils |
| BRPI0405847B1 (pt) * | 2004-12-21 | 2015-04-22 | Petroleo Brasileiro Sa | Processo para a oxidação extrativa de contaminantes presentes em correntes brutas de combustíveis catalisada por óxidos de ferro |
| CN100556992C (zh) * | 2005-03-18 | 2009-11-04 | 中国科学院化学研究所 | 石油产品的一种催化氧化脱硫方法 |
| US7744749B2 (en) | 2005-09-08 | 2010-06-29 | Saudi Arabian Oil Company | Diesel oil desulfurization by oxidation and extraction |
| US8715489B2 (en) | 2005-09-08 | 2014-05-06 | Saudi Arabian Oil Company | Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures |
| US20070140949A1 (en) * | 2005-12-16 | 2007-06-21 | Palmer Thomas R | Extraction of peroxide treated petroleum streams |
| CA2549358C (en) * | 2006-05-17 | 2010-02-02 | Nor Technologies Inc. | Heavy oil upgrading process |
| KR101642695B1 (ko) | 2007-05-03 | 2016-07-27 | 오테라, 인코포레이티드 | 티타닐의 단량체와 중합체를 함유하는 생성물과 이를 제조하는 방법 |
| JP2009051816A (ja) * | 2007-08-23 | 2009-03-12 | Rohm & Haas Co | 不飽和カルボン酸およびニトリルの製造方法 |
| US8241490B2 (en) * | 2008-03-26 | 2012-08-14 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| EP2265694B1 (en) * | 2008-03-26 | 2017-05-17 | Auterra, Inc. | Sulfoxidation method |
| US8298404B2 (en) * | 2010-09-22 | 2012-10-30 | Auterra, Inc. | Reaction system and products therefrom |
| US20090242459A1 (en) * | 2008-03-26 | 2009-10-01 | General Electric Company | Oxidative desulfurization of fuel oil |
| US8894843B2 (en) | 2008-03-26 | 2014-11-25 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8764973B2 (en) | 2008-03-26 | 2014-07-01 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US9206359B2 (en) | 2008-03-26 | 2015-12-08 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US9061273B2 (en) | 2008-03-26 | 2015-06-23 | Auterra, Inc. | Sulfoxidation catalysts and methods and systems of using same |
| US8197671B2 (en) * | 2008-03-26 | 2012-06-12 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8727000B2 (en) * | 2008-07-28 | 2014-05-20 | Forbes Oil And Gas Pty. Ltd. | Method of liquefaction of carbonaceous material to liquid hydrocarbon |
| US20100122937A1 (en) * | 2008-11-20 | 2010-05-20 | John Aibangbee Osaheni | Method and system for removing impurities from hydrocarbon oils via lewis acid complexation |
| BRPI0805341B1 (pt) * | 2008-12-05 | 2017-02-07 | Petroleo Brasileiro S A - Petrobras | reator multifásico multifuncional |
| US20100264067A1 (en) * | 2009-04-16 | 2010-10-21 | General Electric Company | Method for removing impurities from hydrocarbon oils |
| TWI422382B (zh) | 2010-02-24 | 2014-01-11 | Colgate Palmolive Co | 加強木蘭活性物之溶解度及傳送的組成物 |
| TWI459957B (zh) | 2010-02-24 | 2014-11-11 | Colgate Palmolive Co | 口腔保健組成物 |
| MX2012009817A (es) | 2010-02-25 | 2012-09-12 | Indian Inst Of Chemical Technology | Sintesis de magnolol y sus compuestos analogos. |
| US9296960B2 (en) | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US20110220550A1 (en) * | 2010-03-15 | 2011-09-15 | Abdennour Bourane | Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| CN101798519B (zh) * | 2010-03-25 | 2011-09-07 | 广西大学 | 一种降低柴油馏分中硫含量的方法 |
| CN101829604B (zh) * | 2010-03-25 | 2011-09-07 | 广西大学 | 降低柴油馏分硫含量的氧化脱硫催化剂及其制备方法 |
| US9039890B2 (en) | 2010-06-30 | 2015-05-26 | Chevron U.S.A. Inc. | Two-stage, close-coupled, dual-catalytic heavy oil hydroconversion process |
| US9334452B2 (en) * | 2010-06-30 | 2016-05-10 | Chevron U.S.A. Inc. | Two-stage, close-coupled, dual-catalytic heavy oil hydroconversion process |
| US20120018350A1 (en) * | 2010-07-20 | 2012-01-26 | Hsin Tung Lin | Mixing-assisted oxidative desulfurization of diesel fuel using quaternary ammonium salt and portable unit thereof |
| US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
| US9005433B2 (en) | 2011-07-27 | 2015-04-14 | Saudi Arabian Oil Company | Integrated process for in-situ organic peroxide production and oxidative heteroatom conversion |
| US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US9222034B2 (en) | 2013-11-19 | 2015-12-29 | Uop Llc | Process for removing a product from coal tar |
| WO2016106048A1 (en) * | 2014-12-24 | 2016-06-30 | Hach Company | Method for determining the chemical oxygen demand of a liquid sample |
| WO2016154529A1 (en) | 2015-03-26 | 2016-09-29 | Auterra, Inc. | Adsorbents and methods of use |
| US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
| BR102016022626B1 (pt) * | 2016-09-29 | 2021-06-01 | Petróleo Brasileiro S.A. - Petrobras | Processo de remoção simultânea de arsênio e enxofre de correntes de hidrocarbonetos |
| BR102017012313B1 (pt) | 2017-06-09 | 2022-06-28 | Petróleo Brasileiro S.A. - Petrobrás | Sistema catalítico para remoção de compostos heteroatômicos de enxofre e/ou nitrogênio dissolvidos em hidrocarbonetos |
| CN108640329B (zh) * | 2018-04-13 | 2020-09-22 | 深圳市深投环保科技有限公司 | 废水协同耦合处理方法 |
| CN109647535A (zh) * | 2018-12-28 | 2019-04-19 | 中国船舶重工集团公司第七八研究所 | 一种煤担载型铁基催化剂 |
| WO2024095167A1 (en) * | 2022-11-03 | 2024-05-10 | Bakhshi Zadeh Shahryar | Ultrasound-assisted oxidative desulfurization of fuel oil using metal oxide catalysts |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE533513A (pt) | 1953-11-25 | |||
| US4476010A (en) * | 1971-11-08 | 1984-10-09 | Biolex Corporation | Catalytic water wash |
| US3847800A (en) | 1973-08-06 | 1974-11-12 | Kvb Eng Inc | Method for removing sulfur and nitrogen in petroleum oils |
| US4311680A (en) | 1980-11-20 | 1982-01-19 | The Goodyear Tire & Rubber Company | Method for removal of sulfur compounds from a gas stream |
| WO1984002716A1 (en) * | 1983-01-07 | 1984-07-19 | British Petroleum Co Plc | Process for upgrading hydrocarbon fuels |
| JP3227521B2 (ja) | 1992-04-06 | 2001-11-12 | 舟越 泉 | 液状油中から有機硫黄化合物を回収する方法 |
| US5755977A (en) | 1996-07-03 | 1998-05-26 | Drexel University | Continuous catalytic oxidation process |
| BE1010804A3 (nl) | 1996-12-16 | 1999-02-02 | Dsm Nv | Werkwijze voor de bereiding van dicarbonzuren. |
| TW449574B (en) | 1998-05-01 | 2001-08-11 | Ind Tech Res Inst | Method of wastewater treatment by electrolysis and oxidization |
| ES2206853T3 (es) | 1998-11-10 | 2004-05-16 | Unilever N.V. | Catalizadores de blanqueo y oxidacion. |
-
2001
- 2001-05-16 US US09/855,947 patent/US6544409B2/en not_active Expired - Lifetime
-
2002
- 2002-05-03 BR BRPI0205814-6A patent/BR0205814B1/pt not_active IP Right Cessation
- 2002-05-03 EP EP02721879A patent/EP1390441B1/en not_active Expired - Lifetime
- 2002-05-03 WO PCT/BR2002/000063 patent/WO2002092726A2/en active IP Right Grant
- 2002-05-03 ES ES02721879T patent/ES2274970T3/es not_active Expired - Lifetime
- 2002-05-03 AU AU2002252859A patent/AU2002252859A1/en not_active Abandoned
- 2002-05-03 JP JP2002589595A patent/JP4159368B2/ja not_active Expired - Fee Related
- 2002-05-14 AR ARP020101766A patent/AR033741A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| ES2274970T3 (es) | 2007-06-01 |
| EP1390441B1 (en) | 2006-11-15 |
| AR033741A1 (es) | 2004-01-07 |
| JP4159368B2 (ja) | 2008-10-01 |
| BR0205814B1 (pt) | 2013-03-05 |
| WO2002092726A2 (en) | 2002-11-21 |
| AU2002252859A1 (en) | 2002-11-25 |
| US6544409B2 (en) | 2003-04-08 |
| US20020189975A1 (en) | 2002-12-19 |
| JP2004532326A (ja) | 2004-10-21 |
| WO2002092726A3 (en) | 2003-02-20 |
| EP1390441A2 (en) | 2004-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
| B04C | Request for examination: application reinstated [chapter 4.3 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 05/03/2013, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 19A ANUIDADE. |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2622 DE 06-04-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |