BG101836A - 4-ациламинопиперидин-n-оксили - Google Patents
4-ациламинопиперидин-n-оксилиInfo
- Publication number
- BG101836A BG101836A BG101836A BG10183697A BG101836A BG 101836 A BG101836 A BG 101836A BG 101836 A BG101836 A BG 101836A BG 10183697 A BG10183697 A BG 10183697A BG 101836 A BG101836 A BG 101836A
- Authority
- BG
- Bulgaria
- Prior art keywords
- alkyl
- acylaminopiperidine
- oxyls
- hydrogen
- stabilizationof
- Prior art date
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 abstract 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Hydrogenated Pyridines (AREA)
- Plural Heterocyclic Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
4-ациламинопиперидин-N-оксилите подпомагат стабилизирането на органични вещества срещу вредните ефекти на свободни радикали, по-специално при дестилация на радикаловополимеризиращи се мономери като стирен. Те имат формула А1В1, в която А1 означава водород или органичен радикал и В1 - радикал с формула, в която R1, R2, R3 и R4 означават С1-С4 алкил, като R1 и R2, както и R3 и R4, могат да бъдат свързани в 5 или 6-атомен пръстен, R5 означава Н илиС1-С4 алкил и R6 - водород или С1-С18 алкил.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19510184A DE19510184A1 (de) | 1995-03-21 | 1995-03-21 | 4-Acylaminopiperidin-N-oxyle |
PCT/EP1996/001122 WO1996029311A1 (de) | 1995-03-21 | 1996-03-15 | 4-acylaminopiperidin-n-oxyle |
Publications (1)
Publication Number | Publication Date |
---|---|
BG101836A true BG101836A (bg) | 1998-09-30 |
Family
ID=7757248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BG101836A BG101836A (bg) | 1995-03-21 | 1997-08-15 | 4-ациламинопиперидин-n-оксили |
Country Status (19)
Country | Link |
---|---|
US (1) | US5922244A (bg) |
EP (1) | EP0815082B1 (bg) |
JP (1) | JP4152435B2 (bg) |
KR (1) | KR100413167B1 (bg) |
CN (1) | CN1181056C (bg) |
AT (1) | ATE212014T1 (bg) |
AU (1) | AU5144496A (bg) |
BG (1) | BG101836A (bg) |
BR (1) | BR9607652A (bg) |
CA (1) | CA2211902A1 (bg) |
CZ (1) | CZ274397A3 (bg) |
DE (2) | DE19510184A1 (bg) |
EA (1) | EA199700246A1 (bg) |
ES (1) | ES2171659T3 (bg) |
NO (1) | NO974336D0 (bg) |
PL (1) | PL322309A1 (bg) |
SK (1) | SK108497A3 (bg) |
TW (1) | TW326446B (bg) |
WO (1) | WO1996029311A1 (bg) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19609312A1 (de) * | 1996-03-09 | 1997-09-11 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
DE19622441A1 (de) * | 1996-06-05 | 1997-12-11 | Basf Ag | Verfahren zum Verdichten ethylenisch ungesättigter Monomerer |
ES2162299T5 (es) † | 1996-06-05 | 2010-09-13 | Basf Se | Mezclas que contienen monomeros y estabilizantes. |
EP0845448B1 (en) * | 1996-12-02 | 2002-01-30 | Ondeo Nalco Energy Services, L.P. | Inhibiting polymerization of vinyl aromatic monomers |
DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US5932735A (en) * | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
US5928558A (en) * | 1997-06-13 | 1999-07-27 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
DE19725519A1 (de) | 1997-06-17 | 1998-12-24 | Basf Ag | Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US6447644B1 (en) | 1997-07-23 | 2002-09-10 | Ciba Specialty Chemicals Corporation | Inhibition of pulp and paper yellowing using nitroxides, hydroxylamines and other coadditives |
JP2001510881A (ja) | 1997-07-23 | 2001-08-07 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | ニトロキシドおよび他の補助添加剤を使用するパルプおよび紙の黄色化の抑制 |
DE59812096D1 (de) | 1997-08-07 | 2004-11-11 | Basf Ag | Verfahren zur stabilisierung von (meth)acrylsäureestern gegen unerwünschte radikalische polymerisation |
US6864313B2 (en) * | 1998-06-25 | 2005-03-08 | Ciba Specialty Chemicals Corp. | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
TWI246519B (en) | 1998-06-25 | 2006-01-01 | Ciba Sc Holding Ag | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
EP1095006B1 (en) | 1998-07-14 | 2008-12-24 | Ciba Holding Inc. | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth) acrylate monomers |
US6008359A (en) * | 1998-09-03 | 1999-12-28 | Isp Investments Inc. | Piperidine antioxidants and compositions therewith for preventing the fading of artificial hair dye |
DE19850625A1 (de) * | 1998-11-03 | 2000-05-04 | Basf Ag | Verfahren zur Herstellung von Nitroxylverbindugen sekundärer Amine |
DE19922103A1 (de) * | 1999-05-17 | 2000-11-23 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US6300533B1 (en) * | 1999-08-16 | 2001-10-09 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of ethylenically unsaturated monomers |
ES2292487T3 (es) * | 1999-12-03 | 2008-03-16 | Chemtura Corporation | Composicion y metodo para inhibir la polimerizacion y el crecimiento polimerico. |
CN100441551C (zh) * | 2000-10-16 | 2008-12-10 | 尤尼罗亚尔化学公司 | 作为聚合抑制剂的c-亚硝基苯胺化合物及其共混物 |
US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
DE10223613B4 (de) * | 2002-05-27 | 2006-01-05 | Basf Ag | Verfahren zur anionischen Polymerisation von Styrolmonomeren und deren Verwendung |
US7696290B2 (en) * | 2004-12-03 | 2010-04-13 | Crompton Corporation | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
US8013083B2 (en) * | 2005-02-04 | 2011-09-06 | Chemtura Corporation | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
DE102008040401A1 (de) | 2007-07-20 | 2009-01-22 | Basf Se | Stabilisierte Monomerzusammensetzung |
DE102008042101A1 (de) | 2007-09-24 | 2009-04-02 | Basf Se | Stabilisierte Vinylether |
MX300951B (es) * | 2008-08-28 | 2012-07-05 | Basf Se | Estabilizadores para materiales organicos inanimados. |
JP6398480B2 (ja) * | 2014-07-15 | 2018-10-03 | Jnc株式会社 | ジアミン、ポリアミック酸またはその誘導体、液晶配向剤、液晶配向膜および液晶表示素子 |
KR102568040B1 (ko) | 2015-06-17 | 2023-08-22 | 바스프 에스이 | 라디칼 중합의 즉시 중단을 위한 조성물 |
CN108586320B (zh) * | 2018-04-24 | 2020-05-19 | 宿迁联盛科技股份有限公司 | 一种聚合型橡胶稳定剂及其制备方法 |
JP7399468B2 (ja) * | 2020-01-24 | 2023-12-18 | 国立大学法人東海国立大学機構 | 有機摩擦調整剤 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU1027150A1 (ru) * | 1981-10-21 | 1983-07-07 | Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского | Способ стабилизации стирола или метилметакрилата |
JPS58194931A (ja) * | 1982-05-07 | 1983-11-14 | Adeka Argus Chem Co Ltd | 合成樹脂組成物 |
SU1139722A1 (ru) * | 1983-04-12 | 1985-02-15 | Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" | Способ ингибировани полимеризации стирола |
DE3738736A1 (de) * | 1987-11-14 | 1989-05-24 | Basf Ag | 4-formylaminopiperidinderivate und deren verwendung als stabilisatoren |
US5254760A (en) * | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
ES2126185T3 (es) * | 1994-08-19 | 1999-03-16 | Huels Chemische Werke Ag | Inhibicion de la polimerizacion del estireno. |
-
1995
- 1995-03-21 DE DE19510184A patent/DE19510184A1/de not_active Withdrawn
-
1996
- 1996-03-15 US US08/913,613 patent/US5922244A/en not_active Expired - Lifetime
- 1996-03-15 CA CA002211902A patent/CA2211902A1/en not_active Abandoned
- 1996-03-15 AT AT96908047T patent/ATE212014T1/de not_active IP Right Cessation
- 1996-03-15 BR BR9607652A patent/BR9607652A/pt not_active IP Right Cessation
- 1996-03-15 WO PCT/EP1996/001122 patent/WO1996029311A1/de active IP Right Grant
- 1996-03-15 CN CNB96192697XA patent/CN1181056C/zh not_active Expired - Fee Related
- 1996-03-15 PL PL96322309A patent/PL322309A1/xx unknown
- 1996-03-15 DE DE59608597T patent/DE59608597D1/de not_active Expired - Lifetime
- 1996-03-15 EA EA199700246A patent/EA199700246A1/ru unknown
- 1996-03-15 JP JP52805996A patent/JP4152435B2/ja not_active Expired - Fee Related
- 1996-03-15 SK SK1084-97A patent/SK108497A3/sk unknown
- 1996-03-15 ES ES96908047T patent/ES2171659T3/es not_active Expired - Lifetime
- 1996-03-15 KR KR1019970706529A patent/KR100413167B1/ko not_active IP Right Cessation
- 1996-03-15 EP EP96908047A patent/EP0815082B1/de not_active Expired - Lifetime
- 1996-03-15 AU AU51444/96A patent/AU5144496A/en not_active Abandoned
- 1996-03-15 CZ CZ972743A patent/CZ274397A3/cs unknown
- 1996-03-19 TW TW085103279A patent/TW326446B/zh not_active IP Right Cessation
-
1997
- 1997-08-15 BG BG101836A patent/BG101836A/bg unknown
- 1997-09-19 NO NO974336A patent/NO974336D0/no unknown
Also Published As
Publication number | Publication date |
---|---|
DE59608597D1 (de) | 2002-02-21 |
CA2211902A1 (en) | 1996-09-26 |
TW326446B (en) | 1998-02-11 |
KR100413167B1 (ko) | 2004-04-28 |
JPH11502212A (ja) | 1999-02-23 |
ATE212014T1 (de) | 2002-02-15 |
US5922244A (en) | 1999-07-13 |
CN1181056C (zh) | 2004-12-22 |
JP4152435B2 (ja) | 2008-09-17 |
ES2171659T3 (es) | 2002-09-16 |
WO1996029311A1 (de) | 1996-09-26 |
NO974336L (no) | 1997-09-19 |
EP0815082B1 (de) | 2002-01-16 |
SK108497A3 (en) | 1998-03-04 |
CN1179150A (zh) | 1998-04-15 |
MX9706337A (es) | 1998-07-31 |
EP0815082A1 (de) | 1998-01-07 |
AU5144496A (en) | 1996-10-08 |
CZ274397A3 (cs) | 1998-01-14 |
NO974336D0 (no) | 1997-09-19 |
BR9607652A (pt) | 1998-06-16 |
PL322309A1 (en) | 1998-01-19 |
KR19980703127A (ko) | 1998-10-15 |
DE19510184A1 (de) | 1996-09-26 |
EA199700246A1 (ru) | 1998-02-26 |
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