AU620963B2 - A process for the preparation of hydrogen peroxide (i) - Google Patents

A process for the preparation of hydrogen peroxide (i) Download PDF

Info

Publication number: AU620963B2
Authority: AU; Australia
Prior art keywords: hydrogen; catalyst; hydrogenation; static mixer; working solution
Prior art date: 1989-01-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU48660/90A

Other languages

English (en)

Other versions

AU4866090A (en

Inventor

Teuvo Manula

Eva-Liisa Mustonen

Ilkka Turunen

Pirkko Virta

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Kemira Oyj

Original Assignee

Kemira Oyj

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-01-27

Filing date

1990-01-23

Publication date

1992-02-27

1990-01-23 Application filed by Kemira Oyj filed Critical Kemira Oyj

1990-08-02 Publication of AU4866090A publication Critical patent/AU4866090A/en

1992-02-27 Application granted granted Critical

1992-02-27 Publication of AU620963B2 publication Critical patent/AU620963B2/en

2010-01-23 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 32
238000000034 method Methods 0.000 title claims description 29
238000002360 preparation method Methods 0.000 title description 5
239000012224 working solution Substances 0.000 claims description 38
239000003054 catalyst Substances 0.000 claims description 37
229910052739 hydrogen Inorganic materials 0.000 claims description 31
239000001257 hydrogen Substances 0.000 claims description 31
230000003068 static effect Effects 0.000 claims description 31
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 29
239000007789 gas Substances 0.000 claims description 20
238000002156 mixing Methods 0.000 claims description 17
239000011541 reaction mixture Substances 0.000 claims description 15
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 13
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 12
150000004056 anthraquinones Chemical class 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 claims description 7
238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 7
239000003960 organic solvent Substances 0.000 claims description 7
239000000243 solution Substances 0.000 claims description 7
229910052763 palladium Inorganic materials 0.000 claims description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
239000011949 solid catalyst Substances 0.000 claims description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
239000011248 coating agent Substances 0.000 claims description 2
238000000576 coating method Methods 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052697 platinum Inorganic materials 0.000 claims description 2
229910052703 rhodium Inorganic materials 0.000 claims description 2
239000010948 rhodium Substances 0.000 claims description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
150000002978 peroxides Chemical class 0.000 claims 1
239000000377 silicon dioxide Substances 0.000 claims 1
238000005984 hydrogenation reaction Methods 0.000 description 25
239000000463 material Substances 0.000 description 6
230000000694 effects Effects 0.000 description 5
239000008188 pellet Substances 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 4
239000012071 phase Substances 0.000 description 4
238000001816 cooling Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
238000000605 extraction Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000010517 secondary reaction Methods 0.000 description 3
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
244000144985 peep Species 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
PCFMUWBCZZUMRX-UHFFFAOYSA-N 9,10-Dihydroxyanthracene Chemical class C1=CC=C2C(O)=C(C=CC=C3)C3=C(O)C2=C1 PCFMUWBCZZUMRX-UHFFFAOYSA-N 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
238000006213 oxygenation reaction Methods 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/324—Composition or microstructure of the elements
- B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

AU48660/90A 1989-01-27 1990-01-23 A process for the preparation of hydrogen peroxide (i) Ceased AU620963B2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FI890428A FI82669C (fi)	1989-01-27	1989-01-27	Foerfarande foer framstaellning av vaeteperoxid.
FI890428		1989-01-27

Publications (2)

Publication Number	Publication Date
AU4866090A AU4866090A (en)	1990-08-02
AU620963B2 true AU620963B2 (en)	1992-02-27

Family

ID=8527797

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU48660/90A Ceased AU620963B2 (en)	1989-01-27	1990-01-23	A process for the preparation of hydrogen peroxide (i)

Country Status (12)

Country	Link
JP (1)	JPH02275703A (it)
AU (1)	AU620963B2 (it)
BR (1)	BR9000347A (it)
CA (1)	CA2008651A1 (it)
DE (1)	DE4002335A1 (it)
ES (1)	ES2019046A6 (it)
FI (1)	FI82669C (it)
FR (1)	FR2642412B1 (it)
GB (1)	GB2229173B (it)
IT (1)	IT1240869B (it)
NZ (1)	NZ232216A (it)
SE (1)	SE504578C2 (it)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4313393C2 (de) *	1993-04-07	2003-06-26	Siemens Ag	Statischer Mischer
FI95457C (fi) *	1994-03-15	1996-02-12	Kemira Chemicals Oy	Menetelmä vetyperoksidin valmistamiseksi ja siinä käytettävä reaktori
AU2001265326A1 (en) *	2000-06-07	2001-12-17	Abb Lummus Global Inc.	Heat exchanger/reactor apparatus
US20220362752A1 (en) *	2019-06-21	2022-11-17	Commonwealth Scientific And Industrial Research Organisation	Processes for catalytically coating scaffolds
CN111410176A (zh) *	2020-05-14	2020-07-14	福建永荣科技有限公司	一种生产过氧化氢的氢化塔管式反应器

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL139013B (nl) *	1965-12-04	1973-06-15	Degussa	Werkwijze voor het bereiden van waterstofperoxyde volgens het antrachinonkringloopprocede.
US3565581A (en) *	1968-05-16	1971-02-23	Fmc Corp	Production of hydrogen peroxide in the anthraquinone process using a novel catalytic fixed bed
US3615207A (en) *	1969-06-16	1971-10-26	Fmc Corp	Production of hydrogen peroxide by anthraquinone process
YU33554B (en) *	1969-07-12	1977-08-31	Degussa	Process for reactivating noble metal catalysts on a carrier for the synthesis of h2o2 by anthraquinone process
JPS4941040B1 (it) *	1970-08-18	1974-11-06
DE2042523C3 (de) *	1970-08-27	1979-09-13	Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt	Verfahren zum Regenerieren von Edelmetall-Katalysatoren für die Wasserstoffperoxidsynthese nach dem Anthrachinonverfahren
US3755552A (en) *	1970-10-21	1973-08-28	Fmc Corp	Process for producing hydrogen peroxide
US4428922A (en) *	1982-05-14	1984-01-31	Fmc Corporation	Process for manufacturing hydrogen peroxide
SE431532B (sv) *	1982-09-08	1984-02-13	Eka Ab	Forfarande vid framstellning av veteperoxid
FI77633B (fi) *	1986-12-05	1988-12-30	Kemira Oy	Foerfarande foer framstaellning av vaeteperoxid.

1989
- 1989-01-27 FI FI890428A patent/FI82669C/fi not_active IP Right Cessation
1990
- 1990-01-23 AU AU48660/90A patent/AU620963B2/en not_active Ceased
- 1990-01-23 SE SE9000227A patent/SE504578C2/sv unknown
- 1990-01-24 NZ NZ232216A patent/NZ232216A/xx unknown
- 1990-01-26 ES ES909000488A patent/ES2019046A6/es not_active Expired - Fee Related
- 1990-01-26 BR BR909000347A patent/BR9000347A/pt not_active Application Discontinuation
- 1990-01-26 JP JP2015146A patent/JPH02275703A/ja active Pending
- 1990-01-26 DE DE4002335A patent/DE4002335A1/de not_active Withdrawn
- 1990-01-26 CA CA002008651A patent/CA2008651A1/en not_active Abandoned
- 1990-01-26 GB GB9001802A patent/GB2229173B/en not_active Expired - Fee Related
- 1990-01-26 IT IT83314A patent/IT1240869B/it active IP Right Grant
- 1990-01-29 FR FR909000986A patent/FR2642412B1/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
JPH02275703A (ja)	1990-11-09
FI82669B (fi)	1990-12-31
IT9083314A1 (it)	1990-07-28
FI890428A0 (fi)	1989-01-27
BR9000347A (pt)	1990-12-04
IT1240869B (it)	1993-12-17
FI890428A (fi)	1990-07-28
NZ232216A (en)	1991-10-25
SE9000227L (sv)	1990-07-28
SE9000227D0 (sv)	1990-01-23
IT9083314A0 (it)	1990-01-26
SE504578C2 (sv)	1997-03-10
DE4002335A1 (de)	1990-09-06
ES2019046A6 (es)	1991-05-16
FR2642412B1 (fr)	1992-11-13
CA2008651A1 (en)	1990-07-27
GB9001802D0 (en)	1990-03-28
FI82669C (fi)	1991-04-10
FR2642412A1 (fr)	1990-08-03
GB2229173A (en)	1990-09-19
GB2229173B (en)	1993-03-03
AU4866090A (en)	1990-08-02

Publication	Publication Date	Title
US5071634A (en)	1991-12-10	Process for the preparation of hydrogen peroxide (i)
FI70398B (fi)	1986-03-27	Foerfarande vid framstaellning av vaeteperoxid
EP0672617B1 (en)	2000-06-21	Process for producing hydrogen peroxide and a reactor to be used in the said process
JPH105575A (ja)	1998-01-13	触媒反応の実施のための方法及び反応器
US6150564A (en)	2000-11-21	Selective liquid-phase hydrogenation of α,β-unsaturated carbonyl compounds
AU620963B2 (en)	1992-02-27	A process for the preparation of hydrogen peroxide (i)
US6521767B1 (en)	2003-02-18	Method for suspension hydrogenation of an anthraquinone compound in a special reactor in order to produce hydrogen peroxide
CA2389428C (en)	2009-02-10	Method for producing hydrogen peroxide
CA2340232C (en)	2009-08-18	Process for carrying out gas-liquid reactions and continuous flow reactor for this purpose
EP0596938B1 (en)	1998-10-07	Process for the preparation of hydrogen peroxide
JP2005538078A (ja)	2005-12-15	シトロネラールからシトロネロールを生成させるための連続的水素化方法
JPH05309258A (ja)	1993-11-22	多管式反応装置およびそれを用いた気液接触反応方法
US6369277B1 (en)	2002-04-09	Selective liquid-phase hydrogenation of α,β-unsaturated carbonyl compounds
ZA200100949B (en)	2002-06-03	Method for carrying out gas-liquid reactions and corresponding flow reactor.