AU2009309421A1 - Cobalt catalyst precursor - Google Patents

Cobalt catalyst precursor Download PDF

Info

Publication number: AU2009309421A1
Authority: AU; Australia
Prior art keywords: catalyst precursor; cobalt; catalyst; range; hydrogen
Prior art date: 2008-10-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

AU2009309421A

Other languages

English (en)

Inventor

Peter Richard Ellis

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Johnson Matthey PLC

Original Assignee

Johnson Matthey PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2008-10-30

Filing date

2009-10-01

Publication date

2010-05-06

2009-10-01 Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC

2010-05-06 Publication of AU2009309421A1 publication Critical patent/AU2009309421A1/en

Status Abandoned legal-status Critical Current

Links

239000012018 catalyst precursor Substances 0.000 title claims description 70
229910017052 cobalt Inorganic materials 0.000 title claims description 51
239000010941 cobalt Substances 0.000 title claims description 51
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 51
238000000034 method Methods 0.000 claims description 52
239000003054 catalyst Substances 0.000 claims description 51
230000009467 reduction Effects 0.000 claims description 47
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 44
239000007789 gas Substances 0.000 claims description 38
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 35
239000000203 mixture Substances 0.000 claims description 27
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 24
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
229910052739 hydrogen Inorganic materials 0.000 claims description 24
239000001257 hydrogen Substances 0.000 claims description 24
229910052751 metal Inorganic materials 0.000 claims description 23
239000002184 metal Substances 0.000 claims description 23
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 22
229910052707 ruthenium Inorganic materials 0.000 claims description 21
239000000377 silicon dioxide Substances 0.000 claims description 20
230000008569 process Effects 0.000 claims description 19
239000000654 additive Substances 0.000 claims description 16
230000015572 biosynthetic process Effects 0.000 claims description 16
238000003786 synthesis reaction Methods 0.000 claims description 16
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 15
229910002091 carbon monoxide Inorganic materials 0.000 claims description 15
150000001875 compounds Chemical class 0.000 claims description 14
229910052697 platinum Inorganic materials 0.000 claims description 13
229910052799 carbon Inorganic materials 0.000 claims description 12
229930195733 hydrocarbon Natural products 0.000 claims description 11
150000002430 hydrocarbons Chemical class 0.000 claims description 11
239000002002 slurry Substances 0.000 claims description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
239000002245 particle Substances 0.000 claims description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
239000000843 powder Substances 0.000 claims description 9
238000006243 chemical reaction Methods 0.000 claims description 8
239000010949 copper Substances 0.000 claims description 8
229910052802 copper Inorganic materials 0.000 claims description 7
229910052746 lanthanum Inorganic materials 0.000 claims description 7
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
150000001869 cobalt compounds Chemical class 0.000 claims description 6
239000011261 inert gas Substances 0.000 claims description 5
229910052741 iridium Inorganic materials 0.000 claims description 5
150000002739 metals Chemical class 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 5
150000004645 aluminates Chemical class 0.000 claims description 4
229910052797 bismuth Inorganic materials 0.000 claims description 4
239000011651 chromium Substances 0.000 claims description 4
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
239000011777 magnesium Substances 0.000 claims description 4
239000011572 manganese Substances 0.000 claims description 4
229910052763 palladium Inorganic materials 0.000 claims description 4
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
229910010271 silicon carbide Inorganic materials 0.000 claims description 4
229910052709 silver Inorganic materials 0.000 claims description 4
239000010936 titanium Substances 0.000 claims description 4
229910018920 CoO(OH) Inorganic materials 0.000 claims description 3
230000004913 activation Effects 0.000 claims description 3
239000000919 ceramic Substances 0.000 claims description 3
150000002431 hydrogen Chemical group 0.000 claims description 3
239000011787 zinc oxide Substances 0.000 claims description 3
229910052684 Cerium Inorganic materials 0.000 claims description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
230000003213 activating effect Effects 0.000 claims description 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
229910052748 manganese Inorganic materials 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229920000307 polymer substrate Polymers 0.000 claims description 2
VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims description 2
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
238000005470 impregnation Methods 0.000 description 22
239000000243 solution Substances 0.000 description 18
230000000052 comparative effect Effects 0.000 description 17
238000001354 calcination Methods 0.000 description 15
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
239000000463 material Substances 0.000 description 14
235000010215 titanium dioxide Nutrition 0.000 description 12
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
230000000996 additive effect Effects 0.000 description 9
230000000694 effects Effects 0.000 description 9
238000011065 in-situ storage Methods 0.000 description 9
238000001035 drying Methods 0.000 description 8
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 6
239000011248 coating agent Substances 0.000 description 6
238000000576 coating method Methods 0.000 description 6
238000002474 experimental method Methods 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
239000011148 porous material Substances 0.000 description 6
229910052702 rhenium Inorganic materials 0.000 description 6
239000002904 solvent Substances 0.000 description 6
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 5
239000008188 pellet Substances 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
229910002092 carbon dioxide Inorganic materials 0.000 description 4
QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
OJLCQGGSMYKWEK-UHFFFAOYSA-K ruthenium(3+);triacetate Chemical compound [Ru+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OJLCQGGSMYKWEK-UHFFFAOYSA-K 0.000 description 4
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 3
229910001981 cobalt nitrate Inorganic materials 0.000 description 3
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 3
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
230000008021 deposition Effects 0.000 description 3
239000010931 gold Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
150000002736 metal compounds Chemical class 0.000 description 3
239000001272 nitrous oxide Substances 0.000 description 3
KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
239000002243 precursor Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
102100022840 DnaJ homolog subfamily C member 7 Human genes 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
101000903053 Homo sapiens DnaJ homolog subfamily C member 7 Proteins 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
238000003556 assay Methods 0.000 description 2
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
229910000428 cobalt oxide Inorganic materials 0.000 description 2
CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 description 2
229910021485 fumed silica Inorganic materials 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
229910001960 metal nitrate Inorganic materials 0.000 description 2
-1 nickel aluminate Chemical class 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
230000007704 transition Effects 0.000 description 2
XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
241000640882 Condea Species 0.000 description 1
102000002322 Egg Proteins Human genes 0.000 description 1
108010000912 Egg Proteins Proteins 0.000 description 1
101000801664 Homo sapiens Nucleoprotein TPR Proteins 0.000 description 1
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
102100033615 Nucleoprotein TPR Human genes 0.000 description 1
239000012494 Quartz wool Substances 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
125000005595 acetylacetonate group Chemical group 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000010923 batch production Methods 0.000 description 1
230000008901 benefit Effects 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
210000003278 egg shell Anatomy 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
229910003472 fullerene Inorganic materials 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000008187 granular material Substances 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
238000009434 installation Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
AZEGRRQOQSUJJK-UHFFFAOYSA-N nitrate;hydrochloride Chemical compound Cl.[O-][N+]([O-])=O AZEGRRQOQSUJJK-UHFFFAOYSA-N 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000003921 particle size analysis Methods 0.000 description 1
230000036581 peripheral resistance Effects 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000001698 pyrogenic effect Effects 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000011946 reduction process Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment

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Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

AU2009309421A 2008-10-30 2009-10-01 Cobalt catalyst precursor Abandoned AU2009309421A1 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GBGB0819849.1A GB0819849D0 (en)	2008-10-30	2008-10-30	Cobalt catalyst precursor
GB0819849.1		2008-10-30
PCT/GB2009/051290 WO2010049715A1 (en)	2008-10-30	2009-10-01	Cobalt catalyst precursor

Publications (1)

Publication Number	Publication Date
AU2009309421A1 true AU2009309421A1 (en)	2010-05-06

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Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU2009309421A Abandoned AU2009309421A1 (en)	2008-10-30	2009-10-01	Cobalt catalyst precursor

Country Status (5)

Country	Link
CN (1)	CN102202787A (pt)
AU (1)	AU2009309421A1 (pt)
BR (1)	BRPI0919649A2 (pt)
GB (1)	GB0819849D0 (pt)
WO (1)	WO2010049715A1 (pt)

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RU2603136C2 (ru)	2011-02-07	2016-11-20	Вилосис Текнолоджиз Лимитед	Катализаторы
JP5795483B2 (ja)	2011-03-31	2015-10-14	独立行政法人石油天然ガス・金属鉱物資源機構	活性化されたフィッシャー・トロプシュ合成反応用触媒および炭化水素の製造方法
FR2978682B1 (fr) *	2011-06-01	2016-01-01	Sicat Llc	Procede catalytique pour la conversion d'un gaz de synthese en hydrocarbures
CN102861583B (zh) *	2011-07-04	2014-10-15	中国石油化工股份有限公司	一种钴基费托合成催化剂及其制备方法
JP6004528B2 (ja)	2011-08-29	2016-10-12	地方独立行政法人東京都立産業技術研究センター	多孔質シリカ内包粒子の製造方法および多孔質シリカ
FR2984346B1 (fr)	2011-12-14	2013-12-27	IFP Energies Nouvelles	Procede de fabrication d'hydrocarbures avec chargement en continu du catalyseur
CN104661748B (zh) *	2012-06-26	2019-04-12	西卡特催化剂公司	用于费托合成的覆盖有TiO2的基于碳化硅的催化剂载体
GB201214122D0 (en)	2012-08-07	2012-09-19	Oxford Catalysts Ltd	Treating of catalyst support
CN103736493B (zh) *	2012-10-17	2015-10-21	中国石油化工股份有限公司	合成气制备重质液态烃的铁基催化剂及其生产方法
CN103785415B (zh) *	2012-10-31	2016-03-30	中国石油化工股份有限公司	羧酸加氢制备醇的钴铋催化剂
WO2015015316A2 (en)	2013-07-31	2015-02-05	Saudi Basic Industies Corporation	Catalyst for conversion of synthesis gas
CN103638943B (zh) *	2013-10-15	2016-04-13	河南省科学院能源研究所有限公司	一种用于生物质合成气的钴基费托固定床催化剂及其制备方法
EP3197598A1 (en) *	2014-09-23	2017-08-02	SABIC Global Technologies B.V.	Cobalt-based catalyst and methods related thereto
CN109072458A (zh) *	2016-04-18	2018-12-21	沙特基础工业全球技术公司	含有碳涂敷的钴(ii、iii)氧化物层的析氧电催化剂
GB201702251D0 (en) *	2017-02-10	2017-03-29	Bp Plc	Process for producting a fischer-tropsch synthesis catalyst
CN108187708B (zh) *	2018-02-01	2021-05-04	中科合成油内蒙古有限公司	一种含磷高稳定性重质烃费托合成催化剂及其制备方法和应用
WO2021139898A1 (en) *	2020-01-10	2021-07-15	Bp P.L.C.	Process for producing a fischer-tropsch synthesis catalyst and fischer-tropsch start-up process
GB202117591D0 (en)	2021-12-06	2022-01-19	Johnson Matthey Plc	Method for retrofitting a hydrogen production unit
WO2023089293A1 (en)	2021-11-17	2023-05-25	Johnson Matthey Public Limited Company	Method for retrofitting a hydrogen production unit
CN114561664B (zh) *	2022-02-17	2023-09-26	广东省科学院资源利用与稀土开发研究所	一种碱性电催化水析氧材料及其制备方法和应用

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GB0030170D0 (en) *	2000-12-11	2001-01-24	Norske Stats Oljeselskap	Fischer-tropsch catalyst
GB0410408D0 (en) *	2004-05-11	2004-06-16	Johnson Matthey Plc	Catalysts
GB0510316D0 (en) *	2005-05-20	2005-06-29	Johnson Matthey Plc	Catalyst manufacture

2008
- 2008-10-30 GB GBGB0819849.1A patent/GB0819849D0/en not_active Ceased
2009
- 2009-10-01 AU AU2009309421A patent/AU2009309421A1/en not_active Abandoned
- 2009-10-01 BR BRPI0919649A patent/BRPI0919649A2/pt not_active Application Discontinuation
- 2009-10-01 CN CN2009801436049A patent/CN102202787A/zh active Pending
- 2009-10-01 WO PCT/GB2009/051290 patent/WO2010049715A1/en active Application Filing

Also Published As

Publication number	Publication date
GB0819849D0 (en)	2008-12-03
CN102202787A (zh)	2011-09-28
BRPI0919649A2 (pt)	2015-12-08
WO2010049715A1 (en)	2010-05-06

Legal Events

Date	Code	Title	Description
2014-04-24	MK4	Application lapsed section 142(2)(d) - no continuation fee paid for the application

Publication	Publication Date	Title
AU2009309421A1 (en)	2010-05-06	Cobalt catalyst precursor
JP5090367B2 (ja)	2012-12-05	金属硝酸塩転化法
Van de Loosdrecht et al.	2003	Calcination of Co-based Fischer–Tropsch synthesis catalysts
AU2006248749B2 (en)	2010-12-02	Catalyst manufacture
RU2516467C2 (ru)	2014-05-20	Способ получения нитрата металла на подложке
AU2006260683B2 (en)	2011-05-12	Supported cobalt catalysts for the fischer tropsch synthesis
US9346038B2 (en)	2016-05-24	Fischer-tropsch catalyst comprising cobalt, magnesium and precious metal
CA2500546A1 (en)	2004-04-29	Fischer-tropsch processes and catalysts made from a material comprising boehmite
JP5284963B2 (ja)	2013-09-11	金属硝酸塩の転化方法
JP2014519976A (ja)	2014-08-21	水性ガスシフト触媒
WO2011089411A1 (en)	2011-07-28	Catalysts supports
WO2010049714A1 (en)	2010-05-06	Cobalt catalysts
WO2006090190A1 (en)	2006-08-31	Catalysts
EA025257B1 (ru)	2016-12-30	Способ каталитической конверсии синтез-газа в углеводороды